CN104087383A - Engine oil composition with diisopropyl ether as fuel - Google Patents

Engine oil composition with diisopropyl ether as fuel Download PDF

Info

Publication number
CN104087383A
CN104087383A CN201410333208.5A CN201410333208A CN104087383A CN 104087383 A CN104087383 A CN 104087383A CN 201410333208 A CN201410333208 A CN 201410333208A CN 104087383 A CN104087383 A CN 104087383A
Authority
CN
China
Prior art keywords
fuel
engine oil
oil composition
compound
mass ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410333208.5A
Other languages
Chinese (zh)
Other versions
CN104087383B (en
Inventor
黄福川
覃克
刘宇恒
邓富康
李康春
黄伊琳
马骁飞
陈彪
黄旖瑶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201410333208.5A priority Critical patent/CN104087383B/en
Publication of CN104087383A publication Critical patent/CN104087383A/en
Application granted granted Critical
Publication of CN104087383B publication Critical patent/CN104087383B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Lubricants (AREA)

Abstract

The invention discloses an engine oil composition with diisopropyl ether as a fuel. The composition adopts base oil II and poly(alpha-olefin) as base oil, is matched with various composite additives and comprises an oxidation-corrosion inhibitor, an anti-foaming agent, a viscosity index improver, a metal deactivator, a friction modifier, a detergent, a dispersing agent, an antioxidant and an antirust agent. The engine oil composition has excellent detergency and dispersibility, viscosity-temperature characteristics, base number retainability and acid neutralizing capacity, can control generation of polar materials such as high temperature oil sludge and keep engines clean, has good high-temperature oxidation stability, soot solubilizing capacity, wear resistance, shear resistance and antifriction and anti-corrosion properties, has good low-temperature startability and can reduce generation of deposited carbon and paint films of engines under the condition of high temperature, prevent abnormal wear and bearing bush corrosion of engines during starting and accelerated operation and prolong the service lives and oil draining periods of engines.

Description

A kind of engine oil composition taking Di Iso Propyl Ether as fuel
Technical field
The invention belongs to internal combustion engine lubricant field, particularly a kind of engine oil composition taking Di Iso Propyl Ether as fuel.
Background technology
Di Iso Propyl Ether (DIPE), colourless, at normal temperatures and pressures, there is mobility and medium volatile one-level inflammable liquid, there is the special odor of ether, can with the multiple immiscible organic solvents such as alcohol, ether, benzene.Corrosion-free to metal when dry, can in the container of iron, mild steel, copper or aluminum, store, add Resorcinol, naphthols or many alkyl phenol can suppress the generation of superoxide.Its fusing point-86.4 DEG C, 68.4 DEG C of boiling points, relative density 0.7258, specific refractory power 1.3679, flash-point-22 DEG C, can form azeotrope with water, Virahol, acetone, acetonitrile, ethanol.Its octane value is high, oxygen level is high, Reid Vapour Pressure is low, has the gasoline combustion of change performance, reduces the feature of the quantity discharged of CO.Its blending performance and physicals are suitable with MTBE, and toxicity is little.In addition, there is the distillation temperature that can reduce blended gasoline; Improve cold start-up and the warming-up performance of automobile; The sealing material of fuel system is had to good intermiscibility; Do not affect the stability of gasoline; Impact on motor vehicle exhaust is suitable with other ethers, conventionally and the blend ratio 5%~40% (mass percent content) of gasoline.Therefore, be necessary to develop a kind of engine oil composition taking Di Iso Propyl Ether as fuel.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of have good detergent-dispersant performance, sticky-temperature characteristics, base number retentivity, acid neutralization capacity, can control the generation of high temperature greasy filth isopolarity material, keeps engine washing; Good high-temperature oxidation stability, solubilising soot ability, wear-resistant, anti-shearing and anti-friction and corrosion-resistant performance, the generation that cold cranking capacity is good, can reduce engine carbon deposit, paint film under hot conditions, prevent inordinate wear and the bearing insert corrosion of engine in the time of startup and Accelerating running, the engine oil composition taking Di Iso Propyl Ether as fuel of increasing service life of engine and oil draining period.
For above-mentioned technical problem, the present invention adopts following technical scheme:
An engine oil composition taking Di Iso Propyl Ether as fuel, adopts II class base oil and Poly alpha Olefins (PAO) as base oil, coordinates multiple composite additive, and the mass percent of its each component is:
Component Mass percent content
Base oil Surplus
Purification agent 7.0%~9.0%
Dispersion agent 3.0%~5.0%
Antioxidant preservative 0.5%~1.0%
Oxidation inhibitor 0.5%~1.0%
Metal passivator 0.8%~1.0%
Friction improver 1.0%~2.0%
Rust-preventive agent 0.8%~1.5%
Kilfoam 0.005%~0.008%
Viscosity index improver 3.0%~6.0%
The mass percent summation of each component is 100% above.
Base oil is that II class base oil and 50%~60% the Poly alpha Olefins (PAO) of mass ratio 50%~40% is compound.
Purification agent is that low alkali value calcium mahogany sulfonate, 25%~30% high base number calcium mahogany sulfonate and 50%~40% the Overbased magnesium sulphonates of mass ratio 25%~30% is compound, and the mass percent sum of above-mentioned three components is 100%;
Dispersion agent is that polyisobutylene-bis-succinimide and 60%~50% the diene base succimide of mass ratio 40%~50% is compound.
Antioxidant preservative is that the dithiocarbamic acid tungsten of the two octyl group basic zinc salt of the sulphur phosphorus of mass ratio 50%~60% and 50%~40% is compound;
Oxidation inhibitor is that thiadiazole and 60%~50% the p-hydroxydiphenylamine of mass ratio 40%~50% is compound.
Metal passivator is the 124 Triazole derivative of mass ratio 40%~50% and 60%~50% N, and the sub-Whitfield's ointment propylene diamine of N-bis-is compound.
Friction improver is that alkyl phosphorous acid ester and 40%~50% the ethyl palmitate of mass ratio 60%~50% is compound.
Rust-preventive agent is that petroleum sodium sulfonate and 60%~50% the benzotriazole of mass ratio 40%~50% is compound.
Kilfoam is that ethyl silicon oil and 60%~50% acrylate and the ether copolymer of mass ratio 40%~50% is compound.
Viscosity index improver is ethylene-propylene copolymer.
Remarkable advantage of the present invention has: have good detergent-dispersant performance, sticky-temperature characteristics, base number retentivity, acid neutralization capacity, can control the generation of high temperature greasy filth isopolarity material, keep engine washing; Good high-temperature oxidation stability, solubilising soot ability, wear-resistant, anti-shearing and anti-friction and corrosion-resistant performance, the generation that cold cranking capacity is good, can reduce engine carbon deposit, paint film under hot conditions, prevent inordinate wear and bearing insert corrosion, increasing service life of engine and the oil draining period of engine in the time of startup and Accelerating running.
Embodiment
Embodiment 1:
Each component of following mass percent is in harmonious proportion and is formed:
Embodiment 2:
Each component of following mass percent is in harmonious proportion and is formed:
Embodiment 3:
Each component of following mass percent is in harmonious proportion and is formed:
The main physical and chemical index of embodiment 2 products:

Claims (9)

1. the engine oil composition taking Di Iso Propyl Ether as fuel, is characterized in that: adopt II class base oil and Poly alpha Olefins (PAO) as base oil, coordinate multiple composite additive, the mass percent of its each component is:
Component Mass percent content Base oil Surplus Purification agent 7.0%~9.0% Dispersion agent 3.0%~5.0% Antioxidant preservative 0.5%~1.0% Oxidation inhibitor 0.5%~1.0% Metal passivator 0.8%~1.0% Friction improver 1.0%~2.0% Rust-preventive agent 0.8%~1.5% Kilfoam 0.005%~0.008% Viscosity index improver 3.0%~6.0%
The mass percent summation of each component is 100% above.
2. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, is characterized in that, base oil is that II class base oil and 50%~60% the Poly alpha Olefins (PAO) of mass ratio 50%~40% is compound.
3. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, it is characterized in that, purification agent is that low alkali value calcium mahogany sulfonate, 25%~30% high base number calcium mahogany sulfonate and 50%~40% the Overbased magnesium sulphonates of mass ratio 25%~30% is compound, and the mass percent sum of above-mentioned three components is 100%; Dispersion agent is that polyisobutylene-bis-succinimide and 60%~50% the diene base succimide of mass ratio 40%~50% is compound.
4. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, is characterized in that, antioxidant preservative is that the dithiocarbamic acid tungsten of the two octyl group basic zinc salt of the sulphur phosphorus of mass ratio 50%~60% and 50%~40% is compound; Oxidation inhibitor is that thiadiazole and 60%~50% the p-hydroxydiphenylamine of mass ratio 40%~50% is compound.
5. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, is characterized in that, metal passivator is the 124 Triazole derivative of mass ratio 40%~50% and 60%~50% N, and the sub-Whitfield's ointment propylene diamine of N-bis-is compound.
6. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, is characterized in that, friction improver is that alkyl phosphorous acid ester and 40%~50% the ethyl palmitate of mass ratio 60%~50% is compound.
7. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, is characterized in that, rust-preventive agent is that petroleum sodium sulfonate and 60%~50% the benzotriazole of mass ratio 40%~50% is compound.
8. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, is characterized in that, kilfoam is that ethyl silicon oil and 60%~50% acrylate and the ether copolymer of mass ratio 40%~50% is compound.
9. a kind of engine oil composition taking Di Iso Propyl Ether as fuel as claimed in claim 1, is characterized in that, viscosity index improver is ethylene-propylene copolymer.
CN201410333208.5A 2014-07-14 2014-07-14 A kind of take Di Iso Propyl Ether as the engine oil composition of fuel Expired - Fee Related CN104087383B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410333208.5A CN104087383B (en) 2014-07-14 2014-07-14 A kind of take Di Iso Propyl Ether as the engine oil composition of fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410333208.5A CN104087383B (en) 2014-07-14 2014-07-14 A kind of take Di Iso Propyl Ether as the engine oil composition of fuel

Publications (2)

Publication Number Publication Date
CN104087383A true CN104087383A (en) 2014-10-08
CN104087383B CN104087383B (en) 2016-04-13

Family

ID=51635147

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410333208.5A Expired - Fee Related CN104087383B (en) 2014-07-14 2014-07-14 A kind of take Di Iso Propyl Ether as the engine oil composition of fuel

Country Status (1)

Country Link
CN (1) CN104087383B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017030508A1 (en) * 2015-08-19 2017-02-23 Agency For Science, Technology And Research A base oil additive
CN106479644A (en) * 2016-09-26 2017-03-08 广西谛恒生物能源投资有限公司 A kind of isobutanol petrol engine composition
CN106479641A (en) * 2016-09-26 2017-03-08 广西谛恒生物能源投资有限公司 A kind of composition of amylalcohol fuel combination compression ignition engine oil
CN106479640A (en) * 2016-09-26 2017-03-08 广西谛恒生物能源投资有限公司 A kind of normal propyl alcohol gasoline engine engine oil base oil
CN106520277A (en) * 2016-09-21 2017-03-22 广西大学 Sec-butyl alcohol gasoline engine oil composition
CN106520278A (en) * 2016-09-21 2017-03-22 广西大学 Isopropanol gasoline engine oil composition
CN106833842A (en) * 2017-01-17 2017-06-13 广西谛恒生物能源投资有限公司 A kind of gasoline engine lubricant composition for possessing dual fuel injection system
CN112442396A (en) * 2019-09-05 2021-03-05 浙江天瑞化学有限公司 Strong antiknock ether fuel oil based on diisopropyl ether as raw material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130012418A1 (en) * 2010-06-15 2013-01-10 Yukio Tatsumi Lubricating oil composition for internal combustion engine
CN103205307A (en) * 2013-04-12 2013-07-17 广西大学 Environment-friendly and energy-saving diesel engine oil
CN103525522A (en) * 2013-10-21 2014-01-22 广西大学 Stirling engine lubricant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130012418A1 (en) * 2010-06-15 2013-01-10 Yukio Tatsumi Lubricating oil composition for internal combustion engine
CN103205307A (en) * 2013-04-12 2013-07-17 广西大学 Environment-friendly and energy-saving diesel engine oil
CN103525522A (en) * 2013-10-21 2014-01-22 广西大学 Stirling engine lubricant

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017030508A1 (en) * 2015-08-19 2017-02-23 Agency For Science, Technology And Research A base oil additive
CN106520277A (en) * 2016-09-21 2017-03-22 广西大学 Sec-butyl alcohol gasoline engine oil composition
CN106520278A (en) * 2016-09-21 2017-03-22 广西大学 Isopropanol gasoline engine oil composition
CN106479644A (en) * 2016-09-26 2017-03-08 广西谛恒生物能源投资有限公司 A kind of isobutanol petrol engine composition
CN106479641A (en) * 2016-09-26 2017-03-08 广西谛恒生物能源投资有限公司 A kind of composition of amylalcohol fuel combination compression ignition engine oil
CN106479640A (en) * 2016-09-26 2017-03-08 广西谛恒生物能源投资有限公司 A kind of normal propyl alcohol gasoline engine engine oil base oil
CN106833842A (en) * 2017-01-17 2017-06-13 广西谛恒生物能源投资有限公司 A kind of gasoline engine lubricant composition for possessing dual fuel injection system
CN112442396A (en) * 2019-09-05 2021-03-05 浙江天瑞化学有限公司 Strong antiknock ether fuel oil based on diisopropyl ether as raw material

Also Published As

Publication number Publication date
CN104087383B (en) 2016-04-13

Similar Documents

Publication Publication Date Title
CN104087383B (en) A kind of take Di Iso Propyl Ether as the engine oil composition of fuel
CN104194891B (en) A kind of dibutoxy methane engine fluid composition
CN104087382B (en) A kind of formaldehyde fat diesel engine oil composition
CN103113966B (en) Lubricating oil of gas turbine of ship
CN103571565B (en) Castor-oil-based ethanol fuel engine oil composition
CN104087381B (en) A kind of two n-pentyl ether diesel engine oil compositions
CN104087384A (en) Coal slurry oil fuel engine oil composition
CN104087375B (en) A kind of coal water slurry mixed fuel engine oil compositions
CN104087373B (en) A kind of washing oil fuel delivery engine oil base oil
CN104140864A (en) F-T engine oil composition
CN104087371B (en) A kind of coal tar diesel engine oil composition
CN104087378A (en) Dimethyl ether compression ignition type engine oil composition
CN104087370B (en) A kind of damaged tire fuel delivery engine oil base oil
CN104087377A (en) Diethylene glycol dimethyl ether engine oil composition
CN104087372B (en) A kind of ethylene glycol dimethyl ether fuel delivery engine oil base oil
CN104087386A (en) Oil composition for emulsified diesel oil engines
CN104087374B (en) A kind of dimethyl carbonate diesel engine oil composition
CN104194890B (en) A kind of Ramulus Uncariae Cum Uncis base cis butadiene two acid esters engine oil composition
CN104140865A (en) Diethylene glycol diethyl ether fuel engine oil composition
CN104194894A (en) Aether fuel diesel engine oil composition
CN104140863B (en) A kind of butyl ether fuel delivery engine oil base oil
CN104087380B (en) A kind of dimethoxym ethane diesel engine oil composition
CN104119994B (en) A kind of tripropylene glycol dimethyl fuel delivery engine oil base oil
CN104087379A (en) Engine oil composition taking waste plastic oil as fuel
CN103571594B (en) Lubricant special for purified canned biogas engine

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160413

CF01 Termination of patent right due to non-payment of annual fee