CN106479631A - A kind of high-weatherability nano modification transformer insulation oil containing guaiacol and preparation method thereof - Google Patents

A kind of high-weatherability nano modification transformer insulation oil containing guaiacol and preparation method thereof Download PDF

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Publication number
CN106479631A
CN106479631A CN201610830685.1A CN201610830685A CN106479631A CN 106479631 A CN106479631 A CN 106479631A CN 201610830685 A CN201610830685 A CN 201610830685A CN 106479631 A CN106479631 A CN 106479631A
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guaiacol
oil
nano
weatherability
transformer insulation
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崔应文
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Tongling Rike Electronics Co Ltd
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Tongling Rike Electronics Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/14—Inorganic compounds or elements as ingredients in lubricant compositions inorganic compounds surface treated with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046—Hydroxy ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/18—Containing nitrogen-to-nitrogen bonds, e.g. hydrazine
    • C10M2215/182—Azo compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/065—Organic compounds derived from inorganic acids or metal salts derived from Ti or Zr
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/72—Extended drain
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a kind of high-weatherability nano modification transformer insulation oil containing guaiacol, which is obtained by the raw material of following weight parts：Mineral base oil 1,000 1500, castor oil 5 10, guaiacol 0.5 1, silane coupler KH 570 0.15 0.25, azodiisobutyronitrile 0.01 0.015, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 0.3 0.5, methyl methacrylate 0.5 1, ATBC 12, nano aluminium oxide 0.5 1,2,6 DI-tert-butylphenol compounds 1 1.5, BTA 0.5 1.The transformer insulation oil of the present invention can be stored for a long time and keep good performance with excellent stability and insulating properties, while with high-weatherability, stable performance, long service life, be not susceptible to go bad, with higher practical value.

Description

A kind of high-weatherability nano modification transformer insulation oil containing guaiacol and its preparation Method
Technical field
The present invention relates to transformer oil technical field, more particularly to a kind of high-weatherability nano containing guaiacol is modified to be become Depressor insulating oil and preparation method thereof.
Background technology
Paper oil insulation is a kind of typical liquid-solid composite insulation, has a wide range of applications in oil-filled transformer.With Voltage class of electric power system and the continuous lifting of transmission capacity, oil-paper combination insulation have been increasingly difficult to meet voltage levels To Large Copacity, miniaturization, the requirement of high stability insulation system.In order to lift the performance of transformer insulating system, how to improve The insulation characterisitic of dielectric has become as one of current study hotspot.Transformer oil is that important insulation in transformer is situated between Matter, seeks to improve the effective way of transformer oil insulating properties and heat dispersion, to improving efficiency and the safety of transformer station high-voltage side bus Reliability is significant.
At present, be improve insulating materials performance, insulating materials field introduce nanometer technology be an important development Direction.Wherein, the research of nano modification transformer oil brings new raising to traditional transformer oilpaper composite insulation structure Space.Document《The insulating properties and Mechanism Study of semi-conductor nano particles modification transformer oil》Using nano-particle TiO2To becoming Depressor oil is modified, it is found that the addition of nano-particle can significantly improve the insulation characterisitic of transformer oil.But in practical application, Nano particle is susceptible to reunite, and causes the reduction of reliability.Dispersion of the conventional surfactant facture to nano-particle The improvement of property and stability is limited, and the insulating properties of nano modification transformer oil can be had a negative impact.Therefore, how Dispersion of the nano-particle in transformer oil, stability and insulating properties are taken into account, becomes the major issue for needing at present to solve.
Content of the invention
The object of the invention is exactly to make up the defect of prior art, provides one kind and takes into account nano-particle dispersion, stability And the high-weatherability nano modification transformer insulation oil containing guaiacol of superior isolation performance and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of high-weatherability nano modification transformer insulation oil containing guaiacol, which is obtained by the raw material of following weight parts：
Mineral base oil 1000-1500, castor oil 5-10, guaiacol 0.5-1, Silane coupling reagent KH-570 0.15-0.25, Azodiisobutyronitrile 0.01-0.015, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 0.3-0.5, methyl methacrylate Ester 0.5-1, ATBC 1-2, nano aluminium oxide 0.5-1,2,6- DI-tert-butylphenol compounds 1-1.5, BTA 0.5- 1.
A kind of preparation method of the high-weatherability nano modification transformer insulation oil containing guaiacol, comprises the following steps：
（1）By Silane coupling reagent KH-570 by weight 1:100-1:150 are mixed with absolute ethyl alcohol, are subsequently adding nano oxygen Change aluminium ultrasonic disperse 5-10min, then in 40-50 DEG C stir 1-2h, centrifugation after cooling, by the solid particle for obtaining in 90-100 DEG C of drying and processing 10-15min；
（2）By step（1）In the material that obtains by weight 1:40-1:50 are mixed with absolute ethyl alcohol and ultrasonic disperse 10- 20min, is then slowly added to methyl methacrylate and azodiisobutyronitrile and stirs anti-in 60-70 DEG C under nitrogen protection successively 2-4h is answered, centrifugation after cooling, by the solid particle for obtaining again with absolute ethyl alcohol cyclic washing 2-4 time；
（3）First 50-60 DEG C is incorporated in by mixed to castor oil, guaiacol and isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters Add after stirring 1-2h and stir in mineral base oil, add step（2）In material and remaining raw material ultrasonic disperse Uniformly, then carry out refined filtration and impurity is removed, vacuum dehydration degassing is eventually passed, is obtained final product the high-weatherability nano containing guaiacol and changes Property transformer insulation oil.
It is an advantage of the invention that：
The present invention carries out surface silanization by Silane coupling reagent KH-570 to nano-particle, then grafted methacrylic acid first Ester, can substantially increase sterically hindered between nano-particle, effective mutual aggtegation for reducing nano-particle, improve nanoparticle Dispersiveness and stability of the son in transformer oil, while improve the insulating properties of nano-particle；By raw materials such as guaiacol Compound synergic, be effectively improved the weatherability of transformer oil, compound with remaining raw material after obtained transformer insulation oil with Excellent stability and insulating properties, can store for a long time and keep good performance, while with high-weatherability, performance is steady Fixed, long service life, it is not susceptible to go bad, with higher practical value.
Specific embodiment
A kind of high-weatherability nano modification transformer insulation oil containing guaiacol, by the component raw material of following weight (kg) It is prepared from：
Mineral base oil 1000, castor oil 5, guaiacol 0.5, Silane coupling reagent KH-570 0.15, azodiisobutyronitrile 0.01, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 0.3, methyl methacrylate 0.5, ATBC 1, receive Rice 0.5,2,6- DI-tert-butylphenol compounds 1 of aluminum oxide, BTA 0.5.
A kind of preparation method of the high-weatherability nano modification transformer insulation oil containing guaiacol, comprises the following steps：
（1）By Silane coupling reagent KH-570 by weight 1:100 are mixed with absolute ethyl alcohol, are subsequently adding nano aluminium oxide and are surpassed Sound disperses 5min, then stirs 1h in 40 DEG C, and centrifugation after cooling, by the solid particle for obtaining in 90 DEG C of drying and processings 10min；
（2）By step（1）In the material that obtains by weight 1:40 are mixed with absolute ethyl alcohol and ultrasonic disperse 10min, then nitrogen Methyl methacrylate and azodiisobutyronitrile stirring reaction 2h are slowly added to successively in 60 DEG C under gas shielded, are centrifuged after cooling Separate, by the solid particle for obtaining again with absolute ethyl alcohol cyclic washing 2 times；
（3）First it is incorporated in mixed to castor oil, guaiacol and isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 50 DEG C and stirs Add after mixing 1h and stir in mineral base oil, add step（2）In material and remaining raw material ultrasonic disperse uniform, Then carry out refined filtration and impurity is removed, vacuum dehydration degassing is eventually passed, obtain final product the high-weatherability nano modification containing guaiacol and become Depressor insulating oil.
Above-mentioned mineral base oil chooses 60 base oil of sinopec HVI Ia.
Through inspection, transformer insulation oil performance obtained above is as follows：
Average frequency breakdown voltage：84.8kV；
Dielectric dissipation factor（90℃）：0.00059；
185 DEG C, the heat ageing of 12 weeks process after dielectric dissipation factor（90℃）：0.0152；
Standing still keeps transparent clarification after 1 year, nothing is precipitated.

Claims (2)

1. a kind of containing guaiacol high-weatherability nano modification transformer insulation oil, it is characterised in that its be by following weight The raw material of part is obtained：
Mineral base oil 1000-1500, castor oil 5-10, guaiacol 0.5-1, Silane coupling reagent KH-570 0.15-0.25, Azodiisobutyronitrile 0.01-0.015, isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters 0.3-0.5, methyl methacrylate Ester 0.5-1, ATBC 1-2, nano aluminium oxide 0.5-1,2,6- DI-tert-butylphenol compounds 1-1.5, BTA 0.5- 1.
2. according to claim 1 a kind of containing guaiacol high-weatherability nano modification transformer insulation oil preparation side Method, it is characterised in that comprise the following steps：
（1）By Silane coupling reagent KH-570 by weight 1:100-1:150 are mixed with absolute ethyl alcohol, are subsequently adding nano oxygen Change aluminium ultrasonic disperse 5-10min, then in 40-50 DEG C stir 1-2h, centrifugation after cooling, by the solid particle for obtaining in 90-100 DEG C of drying and processing 10-15min；
（2）By step（1）In the material that obtains by weight 1:40-1:50 are mixed with absolute ethyl alcohol and ultrasonic disperse 10- 20min, is then slowly added to methyl methacrylate and azodiisobutyronitrile and stirs anti-in 60-70 DEG C under nitrogen protection successively 2-4h is answered, centrifugation after cooling, by the solid particle for obtaining again with absolute ethyl alcohol cyclic washing 2-4 time；
（3）First 50-60 DEG C is incorporated in by mixed to castor oil, guaiacol and isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters Add after stirring 1-2h and stir in mineral base oil, add step（2）In material and remaining raw material ultrasonic disperse Uniformly, then carry out refined filtration and impurity is removed, vacuum dehydration degassing is eventually passed, is obtained final product the high-weatherability nano containing guaiacol and changes Property transformer insulation oil.
CN201610830685.1A 2016-09-19 2016-09-19 A kind of high-weatherability nano modification transformer insulation oil containing guaiacol and preparation method thereof Withdrawn CN106479631A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117723A (en) * 2019-12-30 2020-05-08 国网河南省电力公司电力科学研究院 Preparation method and preparation device of natural ester insulating oil containing nano powder
CN114318942A (en) * 2021-11-25 2022-04-12 国网上海市电力公司 Preparation method of amino silane modified cellulose insulation paper of vegetable oil transformer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105779094A (en) * 2016-04-26 2016-07-20 苏州思创源博电子科技有限公司 Method for preparing transformer insulating heat conduction oil

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN105779094A (en) * 2016-04-26 2016-07-20 苏州思创源博电子科技有限公司 Method for preparing transformer insulating heat conduction oil

Non-Patent Citations (3)

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惠晓霞 等: "《国外燃料油和润滑油添加剂发展情况》", 31 October 1964, 中国工业出版社 *
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117723A (en) * 2019-12-30 2020-05-08 国网河南省电力公司电力科学研究院 Preparation method and preparation device of natural ester insulating oil containing nano powder
CN114318942A (en) * 2021-11-25 2022-04-12 国网上海市电力公司 Preparation method of amino silane modified cellulose insulation paper of vegetable oil transformer

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