CN106477915A - Radiation coated glass capable of being toughened and its manufacture method - Google Patents
Radiation coated glass capable of being toughened and its manufacture method Download PDFInfo
- Publication number
- CN106477915A CN106477915A CN201611054071.5A CN201611054071A CN106477915A CN 106477915 A CN106477915 A CN 106477915A CN 201611054071 A CN201611054071 A CN 201611054071A CN 106477915 A CN106477915 A CN 106477915A
- Authority
- CN
- China
- Prior art keywords
- layer
- grown
- coated glass
- toughened
- graphene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 59
- 230000005855 radiation Effects 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 239000010410 layer Substances 0.000 claims abstract description 163
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000011241 protective layer Substances 0.000 claims abstract description 37
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 34
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052709 silver Inorganic materials 0.000 claims abstract description 20
- 239000004332 silver Substances 0.000 claims abstract description 20
- 238000005507 spraying Methods 0.000 claims abstract description 14
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 238000007747 plating Methods 0.000 claims abstract description 7
- 150000001336 alkenes Chemical class 0.000 claims description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 11
- 239000010439 graphite Substances 0.000 claims description 11
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical group [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims description 8
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 7
- 229910001120 nichrome Inorganic materials 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 238000002955 isolation Methods 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000004544 sputter deposition Methods 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
- C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to coated glass technical field; specifically related to a kind of radiation coated glass capable of being toughened and its manufacture method; this glass includes substrate of glass and is deposited on the film plating layer of described glass basic surface, and described film plating layer includes first medium layer, the first grown layer, the first protective layer, silver layer, the second protective layer, the second grown layer, second dielectric layer and the graphene layer from inside to outside stacking gradually.The coated glass of the present invention includes silver layer, grown layer and graphene layer, has made graphene layer using spraying method in its glass surface, strengthens the water oxygen isolation performance of this coated glass while improving infrared external reflection, improves oxidation resistance.
Description
Technical field
The present invention relates to coated glass technical field is and in particular to a kind of radiation coated glass capable of being toughened and its manufacturer
Method.
Background technology
LOW-E coated glass, also known as low radiation coated glass, is to be coated with one or more layers tool in common Float Glass Surface
The energy saving building product having the nanometer functional films of infrared external reflection characteristic and constituting.This coated glass product visible light transmissivity
Height, possesses the ultrared feature that by force intercepts very much, can play the double effects of natural lighting and heat-insulating and energy-saving.Can effectively subtract
The outer diffusing of interior heat of few winter is lost, and can intercept the secondary radiation after outdoor objects are subject to sunlight heating in summer, from
And play energy-saving effect.
Because argent is easier to aoxidize in LOW-E film layer, and in high-transparency LOW-E film layer, contain the easy moisture absorption
AZO layer, needs to synthesize hollow at short notice after therefore having plated film, leads to processing inconvenience.
In consideration of it, overcoming above defect of the prior art, provide a kind of new radiation coated glass capable of being toughened and its
Manufacture method becomes this area technical problem urgently to be resolved hurrily.
Content of the invention
Present invention aims to the drawbacks described above of prior art, provide a kind of radiation coated glass capable of being toughened and
Its manufacture method.
The purpose of the present invention can be realized by following technical measures：
A kind of radiation coated glass capable of being toughened, compared with prior art, its difference is, this glass includes substrate of glass
With the film plating layer being deposited on described glass basic surface, first medium layer that described film plating layer includes from inside to outside stacking gradually,
First grown layer, the first protective layer, silver layer, the second protective layer, the second grown layer, second dielectric layer and graphene layer.
Preferably, described graphene layer is formed by graphite spraying alkene solution post-drying.
Preferably, described Graphene is graphene oxide.
Preferably, the thickness of described graphene layer is 2～5nm.
Preferably, described first medium layer and second dielectric layer are Si3N4Layer, described first medium layer and second medium
The thickness of layer is 25～60nm.
Preferably, described first grown layer and the second grown layer are AZO film layer, described first grown layer and the second growth
The thickness of layer is 5～40nm.
Preferably, the AZO film layer that described first grown layer and the second grown layer adulterate for 2wt%.
Preferably, described first protective layer and the second protective layer are NiCr layer, described first protective layer and the second protection
The thickness of layer is 0.5～3nm.
Present invention also offers a kind of method manufacturing above-mentioned radiation coated glass capable of being toughened, comprise the steps：
（1）Substrate of glass is provided；
（2）Deposit first medium layer on the glass substrate；
（3）First grown layer is deposited on first medium layer；
（4）First protective layer is deposited on the first grown layer；
（5）Depositing silver layers on the first protective layer；
（6）Second protective layer is deposited on silver layer；
（7）Second grown layer is deposited on the second protective layer；
（8）Second dielectric layer is deposited on the second grown layer；
（9）Graphite spraying alkene layer in second dielectric layer.
Preferably, described step（9）It is specially：Graphite spraying alkene solution drying to form graphite in second dielectric layer
Alkene layer.
The coated glass of the present invention includes silver layer, grown layer and graphene layer, using spraying method in its glass surface system
Make graphene layer, while improving infrared external reflection, strengthen the water oxygen isolation performance of this coated glass.
Brief description
Fig. 1 is the structural representation of the coated glass of the present invention.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with the accompanying drawings and be embodied as
Example is described in further detail to the present invention.It should be appreciated that specific embodiment described herein is only in order to explain the present invention,
It is not intended to limit the present invention.
The coated glass of the present invention includes substrate of glass and is deposited on the film plating layer of described glass basic surface, described plated film
Layer include from inside to outside stack gradually first medium layer, the first grown layer, the first protective layer, silver layer, the second protective layer, second
Grown layer, second dielectric layer and graphene layer.
In an embodiment of the invention, described substrate of glass can be any can obtain can tempering glass
Glass.
In an embodiment of the invention, first medium layer and second dielectric layer are Si3N4Layer, in addition, first Jie
The thickness of matter layer and second dielectric layer is 25～60nm.
In an embodiment of the invention, the first grown layer and the second grown layer are AZO film layer, in addition, first
The thickness of grown layer and the second grown layer is 5～40nm.In a preferred scheme, the first grown layer and second grows
Layer is the AZO film layer of 2wt% doping.AZO is to mix aluminum（Al）Zinc oxide（ZnO）；The AZO film layer of 2wt% doping represents aluminum（Al）'s
Doping is 2wt%.
In an embodiment of the invention, the first protective layer and the second protective layer are NiCr layer, in addition, the first guarantor
The thickness of sheath and the second protective layer is 0.5～3nm.
In an embodiment of the invention, the thickness of silver layer is 8～20nm.
In an embodiment of the invention, graphene layer is formed by graphite spraying alkene solution post-drying；Graphene
For graphene oxide；The thickness of graphene layer is 2～5nm.
First, Graphene is added in solvent and prepare graphene solution；Then, graphene solution is sprayed on second medium
Layer surface；Finally, the coated glass after graphite spraying alkene solution is dried.
Graphene oxide powder is put in glycol methyl ether, ratio joins 5-10 milliliter second for every 1 gram of graphene oxide powder
Glycol methyl ether, ultrasonic 0.5-3 hour, obtain graphene oxide solution.Add excessive hydrazine hydrate as reducing agent reduction-oxidation
Graphene oxide in graphene solution, often the graphene oxide solution containing 1 gram of graphene oxide need to add 2-3 milliliter
Hydrazine hydrate, obtains graphene solution.Again the graphene solution of gained is sprayed on second medium layer surface, finally, stone will be sprayed
Coated glass after black alkene solution is dried at 150 DEG C.
Invention accordingly provides the manufacture method method of above-mentioned radiation coated glass capable of being toughened, walk including following
Suddenly：
（1）Substrate of glass is provided；
（2）Deposit first medium layer on the glass substrate；
（3）First grown layer is deposited on first medium layer；
（4）First protective layer is deposited on the first grown layer；
（5）Depositing silver layers on the first protective layer；
（6）Second protective layer is deposited on silver layer；
（7）Second grown layer is deposited on the second protective layer；
（8）Second dielectric layer is deposited on the second grown layer；
（9）Graphite spraying alkene layer in second dielectric layer.
In a preferred version, described step（9）It is specially：Graphite spraying alkene solution drying in second dielectric layer
To form graphene layer.
In the present invention, for depositing operation and depositing operation technological parameter not specifically limit it is preferable that this
In invention, first medium layer, the first grown layer, the first protective layer, silver layer, the second protective layer, the second grown layer and second medium
Layer all can be deposited using sputtering method.For multiple deposition process of the prior art, those skilled in the art are according to target
The composition of film layer and thickness select suitable or preferred deposition process parameters, and wherein, what technological parameter included may relate to splashes
Emanate atmosphere, target material, sputtering time.
In an embodiment of the invention, first medium layer and second dielectric layer are passed through AC magnetic controlled sputtering sial and are closed
Gold target is coated with, and in target, than Si/Al=90/10, sputtering atmosphere is Ar and N to weight2Mixed gas, gas flow ratio Ar/N2=5/
6.
In an embodiment of the invention, the first grown layer and the second grown layer are sputtered by pulsed dc magnetron
AZO ceramic target is coated with, and target consistency is more than 99.5%, and sputtering atmosphere is Ar and O2Mixed gas, gas flow ratio Ar/O2=
5%.
In an embodiment of the invention, the first protective layer and the second protective layer are closed by magnetically controlled DC sputtering nickel chromium triangle
Gold target is coated with, and in target, than Ni/Cr=80/20, sputtering atmosphere is Ar to weight.
In an embodiment of the invention, metallic silver layer is coated with by magnetically controlled DC sputtering metallic silver target, and target is pure
Degree is more than 99.9%.
Embodiment 1：
Present embodiments provide a kind of single silver LOW-E coated glass, the various film layers being coated with including substrate of glass and thereon, film
Layer has 7 film layers from inside to outside, is followed successively by first medium layer Si3N4, thickness is 50nm,；First grown layer is AZO, the doping of Al
Measure as 2wt%, thickness is 35nm；First protective layer is NiCr, and thickness is 1.5nm；Silver thickness is 12nm；Second protective layer is
NiCr, thickness is 2nm；Second grown layer is AZO, and thickness is 35nm；Second dielectric layer is Si3N4, thickness is 55nm.Will be made
The LOW-E coated glass obtaining makes 2-5nm graphene layer through physical toughened process, then using spraying method, and dries in 150 DEG C
Dry.
Embodiment 2：
Present embodiments provide a kind of single silver LOW-E coated glass, including the substrate of glass of physical toughened mistake and thereon
The various film layers being coated with, film layer has 7 film layers from inside to outside, is followed successively by first medium layer Si3N4, thickness is 50nm；First growth
Layer is AZO, and the doping of Al is 2wt%, and thickness is 35nm；First protective layer is NiCr, and thickness is 1.5nm；Silver thickness is
12nm；Second protective layer is NiCr, and thickness is 2nm；Second grown layer is AZO, and thickness is 35nm；Second dielectric layer is Si3N4,
Thickness is 55nm.Adopt spraying method to make 2-5nm graphene layer on obtained LOW-E film surface, and dry in 150 DEG C.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (10)
1. a kind of radiation coated glass capable of being toughened is it is characterised in that this glass includes substrate of glass and is deposited on described glass
The film plating layer of substrate surface, first medium layer that described film plating layer includes from inside to outside stacking gradually, the first grown layer, the first guarantor
Sheath, silver layer, the second protective layer, the second grown layer, second dielectric layer and graphene layer.
2. radiation coated glass capable of being toughened according to claim 1 is it is characterised in that described graphene layer passes through spraying
Graphene solution post-drying is formed.
3. radiation coated glass capable of being toughened according to claim 1 is it is characterised in that described Graphene is graphite oxide
Alkene.
4. radiation coated glass capable of being toughened according to claim 1 is it is characterised in that the thickness of described graphene layer is
2～5nm.
5. radiation coated glass capable of being toughened according to claim 1 is it is characterised in that described first medium layer and second
Dielectric layer is Si3N4Layer, the thickness of described first medium layer and second dielectric layer is 25～60nm.
6. radiation coated glass capable of being toughened according to claim 1 is it is characterised in that described first grown layer and second
Grown layer is AZO film layer, and the thickness of described first grown layer and the second grown layer is 5～40nm.
7. radiation coated glass capable of being toughened according to claim 6 is it is characterised in that described first grown layer and second
The AZO film layer that grown layer adulterates for 2wt%.
8. radiation coated glass capable of being toughened according to claim 1 is it is characterised in that described first protective layer and second
Protective layer is NiCr layer, and the thickness of described first protective layer and the second protective layer is 0.5～3nm.
9. a kind of method manufacturing radiation coated glass capable of being toughened as claimed in claim 1 is it is characterised in that include as follows
Step：
（1）Substrate of glass is provided；
（2）Deposit first medium layer on the glass substrate；
（3）First grown layer is deposited on first medium layer；
（4）First protective layer is deposited on the first grown layer；
（5）Depositing silver layers on the first protective layer；
（6）Second protective layer is deposited on silver layer；
（7）Second grown layer is deposited on the second protective layer；
（8）Second dielectric layer is deposited on the second grown layer；
（9）Graphite spraying alkene layer in second dielectric layer.
10. the manufacture method of radiation coated glass capable of being toughened according to claim 9 is it is characterised in that described step
（9）It is specially：Graphite spraying alkene solution drying to form graphene layer in second dielectric layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611054071.5A CN106477915A (en) | 2016-11-25 | 2016-11-25 | Radiation coated glass capable of being toughened and its manufacture method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611054071.5A CN106477915A (en) | 2016-11-25 | 2016-11-25 | Radiation coated glass capable of being toughened and its manufacture method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106477915A true CN106477915A (en) | 2017-03-08 |
Family
ID=58274367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611054071.5A Pending CN106477915A (en) | 2016-11-25 | 2016-11-25 | Radiation coated glass capable of being toughened and its manufacture method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106477915A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108455876A (en) * | 2018-02-13 | 2018-08-28 | 江苏奥蓝工程玻璃有限公司 | A kind of golden low radiation film coating glass and preparation method thereof |
| CN110629178A (en) * | 2019-09-24 | 2019-12-31 | 武汉长利新材料科技有限公司 | Energy-saving cathode cooling water utilization system for coated glass production line |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173145A (en) * | 2011-01-06 | 2011-09-07 | 西安理工大学 | Method for preparing oxidized graphene coated film |
| US20140308523A1 (en) * | 2013-03-15 | 2014-10-16 | Vijayen S. Veerasamy | Methods for direct production of graphene on dielectric substrates, and associated articles/devices |
| CN104230182A (en) * | 2014-09-28 | 2014-12-24 | 中国建材国际工程集团有限公司 | Preparation method of high-transmittance tempered low-emissivity coated glass |
| CN105198230A (en) * | 2015-09-25 | 2015-12-30 | 沙嫣 | Production method of solar panel with graphene coating |
| CN105985019A (en) * | 2015-02-16 | 2016-10-05 | 马锐 | Multifunctional glass and plastic product production technology |
| CN206244650U (en) * | 2016-11-25 | 2017-06-13 | 武汉长利新材料科技有限公司 | Radiation coated glass capable of being toughened |
-
2016
- 2016-11-25 CN CN201611054071.5A patent/CN106477915A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173145A (en) * | 2011-01-06 | 2011-09-07 | 西安理工大学 | Method for preparing oxidized graphene coated film |
| US20140308523A1 (en) * | 2013-03-15 | 2014-10-16 | Vijayen S. Veerasamy | Methods for direct production of graphene on dielectric substrates, and associated articles/devices |
| CN104230182A (en) * | 2014-09-28 | 2014-12-24 | 中国建材国际工程集团有限公司 | Preparation method of high-transmittance tempered low-emissivity coated glass |
| CN105985019A (en) * | 2015-02-16 | 2016-10-05 | 马锐 | Multifunctional glass and plastic product production technology |
| CN105198230A (en) * | 2015-09-25 | 2015-12-30 | 沙嫣 | Production method of solar panel with graphene coating |
| CN206244650U (en) * | 2016-11-25 | 2017-06-13 | 武汉长利新材料科技有限公司 | Radiation coated glass capable of being toughened |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108455876A (en) * | 2018-02-13 | 2018-08-28 | 江苏奥蓝工程玻璃有限公司 | A kind of golden low radiation film coating glass and preparation method thereof |
| CN110629178A (en) * | 2019-09-24 | 2019-12-31 | 武汉长利新材料科技有限公司 | Energy-saving cathode cooling water utilization system for coated glass production line |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105814150B (en) | Low emissivity coated film, its preparation method and the functional building materials of window comprising it | |
| CN105814149B (en) | Low emissivity coated film, its preparation method and the functional building materials of window comprising it | |
| DK160758B (en) | PROCEDURE FOR PREPARING A LOW EMISSION CAPACITY ON A TRANSPARENT SUBSTRATE | |
| CN110418710A (en) | Low emissivity coatings for glass baseplate | |
| CN103144381B (en) | A kind of green low radiation energy-saving glass | |
| CN106242313A (en) | A kind of film plating process of Wear-resistant, high-temperature resistant low radiation coated glass | |
| CN105269893B (en) | A kind of low reflection high temperature resistant can tempering wear-resisting coated glass and production method | |
| CN208250167U (en) | High low anti-double-silver low-emissivity coated glass thoroughly | |
| CN106477915A (en) | Radiation coated glass capable of being toughened and its manufacture method | |
| CN106116177B (en) | Green can be heat-treated double-silver low-emissivity coated glass and preparation method thereof | |
| CN102582167B (en) | Low-emission glass and manufacturing method for low-emission glass | |
| CN103896497A (en) | Single silver thermochromism glass and preparation method thereof | |
| CN205874224U (en) | Low -emissivity coated glass is passed through to superelevation | |
| CN103910495A (en) | Double-silver thermochromic glass and preparation method thereof | |
| WO2012116518A1 (en) | Low emissivity thin film, low emissivity coated glass and producing method thereof | |
| CN106966608A (en) | A kind of preparation method of high transmission rate low radiation coated glass | |
| US20190368026A1 (en) | New high temperature air stable ceramic metallic material used in solar selective surface and its production method | |
| CN201817409U (en) | Low-emitting glass capable of being tampered and processed in different places | |
| CN104310801A (en) | Tri-silver LOW-E glass with neutral color and preparation method thereof | |
| CN206244650U (en) | Radiation coated glass capable of being toughened | |
| CN107560200A (en) | A kind of stable solar selectively absorbing coating under high temperature atmospheric environment | |
| CN205838842U (en) | Off-line Europe ash low radiation coated glass | |
| CN105130208B (en) | A kind of coated glass and preparation method thereof of superelevation visible light transmittance | |
| CN204955584U (en) | Low radiation coated glass of rose pinchbeck silver | |
| CN106995282A (en) | Golden yellow pattern printing ambetti of metal-like and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170308 |