CN1064648C - Sewage treatment technology and equipment using refined diatomite as treating agent - Google Patents

Sewage treatment technology and equipment using refined diatomite as treating agent Download PDF

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CN1064648C
CN1064648C CN 96122377 CN96122377A CN1064648C CN 1064648 C CN1064648 C CN 1064648C CN 96122377 CN96122377 CN 96122377 CN 96122377 A CN96122377 A CN 96122377A CN 1064648 C CN1064648 C CN 1064648C
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sewage
diatomite
agent
treating
treating agent
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CN1184082A (en
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王庆中
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Abstract

The present invention provides a technology and equipment for treating sewage by using a refined diatomite treated agent. A sewage treating agent taking refined diatomite as the main component is added in sewage in order to make the sewage adsorbed, flocculated and settled in a centrifugal separator; then the sewage is filtered and refined in a refining separator; finally, the sewage is settled step by step by a settling separation device to become clear water. The sewage treating agent provided by the present invention has strong adsorption capacity and flocculation and settling function. Treated dirt can be fully extracted. Therefore the present invention can be used for treating various kinds of industrial sewage and domestic sewage. Moreover, the treating effect is good, the investment is low, the occupation of land is small and the energy is not consumed. The sewage can be fundamentally treated to prevent the harm from being created on the human living environment.

Description

Diatomite treatment agent and the method for disposing of sewage with the diatomite treatment agent
The present invention relates to a kind of treatment agent, especially a kind of is the treatment agent of major ingredient and the method for disposing of sewage with this treatment agent with the diatomite.
Along with industrial development, the industrial sewage amount rises just rapidly, and the sewage that especially papermaking, sugaring, rubber and other chemical industry are discharged is just polluting the great river river of China, and seriously prestige is being assisted people's survival environment.And sewage disposal of the prior art mainly adopts Coagulation Method-promptly to add various flocculation agents in sewage, makes the dirt flocculating settling, thereby purifies waste water; Activated sludge process-promptly adopt all kinds of biological bacteriums to eat up pollutent, so that purify waste water.The former is because have only throwing out, and no adsorption so just can not be adsorbed pollutent, makes treatment effect not obvious.The latter invests greatly, cost is high, and handles insufficient.In addition, also adopt sudden and violent gas oxygenation method, filtration method or the like in the prior art, but all big because of investing, energy consumption height, and can not disposable whole recovery pollutents causes treatment effect not good, even the method that has also can make the water after the processing cause secondary pollution once more.A kind of " purifying method " (its publication number is WO92/04283) abroad disclosed, it is to adopt a kind of neutral meal to filter (photography) as diatomite to develop and print waste water, though diatomite possesses certain adsorption, but because the diatom amount is low, its adsorption is limited, and there is not throwing out, therefore, can only handle a small amount of sewage (as developing and printing sewage etc.), city domestic sewage or industrial sewage etc. is difficult to handle, thereby, effective new sewage water treatment method sought, be current primary anxious, otherwise will cause great harm to human survival.
The object of the present invention is to provide the absorption of a kind of energy, flocculation, sedimentation, and the sewage water treatment method of the disposable recovery pollutent of energy.
Another object of the present invention is to provide a kind of sewage water treatment method necessary sewage-treating agent.
Treatment agent of the present invention is main raw material with the diatomite, allocates flocculation agent again into, and its proportioning is:
Diatomite: flocculation agent=8-9: 2-1
The composition of diatomite of the present invention is as follows:
The diatom amount Crystal SiO2 Pb AS
90-98% 1-2% Below the 50ppm Below the 6ppm
PH The scaling loss amount Tight bulk density Outward appearance
6-8 Below 5% 0.4 below Organize complete, hole is clear, specific surface area is big.
Flocculation agent of the present invention is Tai-Ace S 150 or aluminum chloride or inorganic salts commonly used such as polyacrylamide or iron trichloride and high score subclass flocculation agent.So that select different flocculation agents to handle according to different sewage kinds.
Because above-mentioned sewage-treating agent is made of high diatomite and the flocculation agent of diatom amount, and the specific surface area of diatomite is big, and has extremely strong adsorption and the also settled characteristics of very easily flocculating, so can adsorb the dirt in the sewage earlier, effect by flocculation agent again, make the diatomite flocculation and the sedimentation rapidly of having adsorbed pollutent, thereby remove crude removal fully, thoroughly purify waste water.
The method that the present invention disposes of sewage with the diatomite treatment agent is:
1., in sewage, add the diatom amount and be the diatomite treatment agent of 90-98%, and this diatomite treatment agent is made in the ratio of diatomite: flocculation agent=8-9: 2-1, and its add-on is: sewage per ton adds the diatomite sewage-treating agent of 0.15-0.3kg;
2., will sneak into the sewage of sewage-treating agent with 3-6 rice 3/ minute flow inject in the centrifuge separator along the tangent to periphery direction;
3., adjust sewage PH value to neutral, isolated supernatant water and throw out in clarifying treatment 20-40 minute;
4., supernatant water in settlement separator, sedimentation 20-40 minute step by step, clear water entered clean water basin, the precipitation dirt with 0.5-1 rice/minute flow velocity flow into dehydration treatment equipment, obtain containing the regenerant of diatomite and pollutent.
Above-mentioned steps 1. in, the sewage-treating agent of adding is low excessively, then treatment effect is not obvious, too highly then causes unnecessary waste, is unfavorable for reducing cost.Step 2. in the flow of sewage too small, can not form eddy current, thereby not have centrifugation, influence separating of dirt and water, flow is excessive, influences absorption, the throwing out of sewage-treating agent to dirt, can't make it sedimentation, can not eliminating impurities and water.The clarifying treatment time is too short, separates insufficiently, and the long processing efficiency that influences is unfavorable for carrying out industrial treatment.
The equipment that the present invention uses is provided with the centrifuge separator of liquid influx as cone, along the tangent to periphery direction as overflow ducts, bottom by the center, and the bottom is cone, which is provided with the liquid influx and filters the classifying separator of block and precipitate and separate device that Qi Nei is provided with the control baffle plate constitutes.Described centrifuge separator and classifying separator are right cylinder, and centrifuge separator places classifying separator to become socket integral body, and perhaps centrifuge separator and classifying separator respectively are two independently splits.The precipitate and separate device is twice ditch pond at least, and is connected with the outlet of classifying separator.Wherein the cylindrical housings of centrifuge separator is provided with the thrust-augmenting nozzle that is connected with overflow ducts, so that will removing partly, the sewage of dirt leads in the classifying separator from centrifuge separator, described thrust-augmenting nozzle is located at the middle and upper part of centrifuge separator, perhaps is located at the middle and lower part.Middle part on the cylindrical housings of classifying separator is provided with the liquid influx, is provided with polylith in the housing and filters baffle plate, and this baffle plate can be located at the intravital top of shell, is used for filtering and intercepting dirt, and only allows clear water up flow out, and throw out is sedimentation down.Be provided with polylith control baffle plate in the multiple tracks ditch pond of precipitate and separate device, be used for further intercepting the dirt of clear water, so that thoroughly discharge dirt.Cone base at centrifuge separator and classifying separator is provided with dirt and throw out outlet, and this outlet is connected with the bottom in precipitate and separate ditch pond, so that concentrate the recycling throw out.
Concrete treating processes of the present invention is:
1. pre-configured sewage-treating agent;
2. sewage is introduced sewage lagoon, and make it keep certain sewage quantity, be convenient to continuous processing;
3. with water pump sewage is evacuated to centrifuge separator, throws in the sewage-treating agent of 0.15-0.3kg by the amount of sewage per ton simultaneously and with 3-6 rice 3/ minute flow from being arranged at the liquid influx of centrifuge separator tangent to periphery position, tangentially inject in the container, make sewage in container, form eddy current, absorption, flocculation through sewage-treating agent, and under centrifugal action, dirt in the sewage is got rid of behind wall of container, be settled down to the cone base of container along wall, sewage then flows out from the upflow tube of center and liquid conduit and enters classifying separator;
4. sewage flows into from the centre entrance of classifying separator, and in uphill process, the dirt in the sewage is deposited to the bottom cone pond after being filtered the block obstruct, and clear water overflows from container top;
5. the clear water that overflows flows in the precipitate and separate ditch pond, under the control baffle effect, makes after remaining dirt carries out sedimentation step by step in the clear water, flow out from bottom of trench, enter the throw out concentration basin, so that dewatering and recovery, clear water flows out from the ditch top, enters clean water basin, so that discharging or recirculation are used.
In the sewage treatment process of the present invention, except that process 3 adopts water pump as the power, all the other processes are all finished automatically by fluid mechanics principle.
The present invention compared with prior art has following advantage and positively effect:
1. sewage-treating agent provided by the invention has extremely strong adsorptive power, and very easily flocculation, and rapid subsidence is so eliminating impurities and water completely.
2. technical process provided by the invention is simple, and can dispose of sewage continuously in enormous quantities, and the dirt that contains diatomite after the processing can all reclaim once more and utilize, and therefore can not cause the secondary pollution of water, helps improving environmental protection.
3. equipment provided by the invention, it is simple in structure, wastewater treatment efficiency is good, consumes energy not, take up an area of little, less investment.
4. the present invention can handle various industrial sewages and sanitary sewages such as paper mill (comprising wood pulp, straw pulp) sewage, printing and dyeing mill's sewage, brew-house's sewage, sugar refinery's sewage, pharmaceutical factory's sewage, Electroplate Factory's sewage, make it to meet and exceed the emission standard of regulation, fundamentally administer sewage to the harm that human environment causes, safeguard environment for human survival.
Fig. 1 is the present invention's sewage disposal device structure iron;
Fig. 2 is the present invention's precipitate and separate ditch pond longitudinal diagram.
Below in conjunction with accompanying drawing the present invention's equipment is done a detailed description.
1 is centrifuge separator among the figure, constitute housing by the right cylinder on top and the cone of bottom, 2 for being located at the overflow siphunculus on the axial line, its lower end is connected with liquid conduit 6,3 is sewage inlet, tangential direction along the housing circumference is arranged at the housing middle and upper part, be convenient to make sewage in container, to form eddy current, 4 is classifying separator, be located at the outer part of centrifuge separator, its top is cylindrical housings, the bottom is the cone housing, 5 for filtering block, be annular, be located at the top of this separator, 6 is the liquid conduit, one end is connected with the lower end of overflow siphunculus 2, the housing wall that the other end passes centrifuge separator 1 places the bottom of classifying separator 4,7,8 for the throw out outlet, places respectively at the bottom of the awl of centrifuge separator and classifying separator, 9 is precipitate and separate ditch pond, the periphery of classifying separator is located in its septal fossula pond, directly makes the clear water that overflows enter the septal fossula pond, and 10 is switchboard, multistage being arranged in the ditch pond 9, carry out settlement separately step by step, 11 is the clear water ditch, makes the clear water that overflows in the sedimentation ditch pond 9 flow into clean water basin, the dirt that discharge the throw out of bottom of trench and centrifuge separator and classifying separator bottom together enters concentration basin, dewatering and recovery.
Embodiment 1
Sewage-treating agent 1 is used to handle sanitary sewage by following proportioning preparation.
Diatomite: Tai-Ace S 150=8: 2
Sewage-treating agent 2 is used to handle papermaking wastewater by following proportioning preparation.
Diatomite: aluminium chlorohydroxide=9: 1
Sewage-treating agent 3 is used to handle dyeing and printing sewage by following proportioning preparation.
Diatomite: iron trichloride=8.5: 1.5
Embodiment 2
Adopt the sewage-treating agent 2 of embodiment 1, the composition of its diatomite is: the diatom amount is 90%, crystal SiO 22%, leaded 40PPM contains arsenic 5PPM, pH value 5, and tight bulk density 0.4, flocculation agent is commercially available aluminium chlorohydroxide.
Get Pu'er tea shore, Dali, Yunnan Province papermaking sewage and handle, its sewage composition is: SS1120, CODcr1640, BOD 5285, PH7.2.
1. the amount by 0.2kg per ton adds above-mentioned sewage-treating agent 2 in sewage, and with water pump with 6 meters 3/ minute flow sewage is evacuated in the centrifuge separator 1;
2. adjust sewage PH value to neutral, sewage was handled 20 minutes at classifying separator 4 inner filtrations;
3. supernatant water flows in the precipitate and separate ditch pond 9, and sedimentation flowed into clean water basin after 20 minutes step by step;
4. the precipitation dirt flows into dewatering unit with 0.5 meter/minute flow velocity, obtains containing the dirt of diatomite.
Clear water composition after the processing is: SS22.4, clearance 98%; CODcr57.4, clearance 96.5%; BOD 528.5, clearance 90%.
Embodiment 3
Adopt the sewage-treating agent 1 of embodiment 1.Get Xi Er river, Dali, Yunnan Province sewage and handle, its composition is: SS640, CODcr 324, BOD 5121, PH 7.1.
1. the amount by 0.15kg per ton adds sewage-treating agent 1 in sewage, and with in the flow suction centrifuge separator of water pump with 3 m3/mins;
2. adjusting pH value be neutrality, classifying separator inner filtration 10 minutes;
3. clear water flows into precipitate and separate ditch pond, and sedimentation flowed into clean water basin after 10 minutes step by step.
4. the precipitation dirt flows into dehydration treatment equipment with 1 meter/minute flow velocity, and reclaim the dehydration back.
Clear water composition after the processing is: SS 9.6, clearance 98.5%; CODcr16.2, clearance 95%; BOD 512, clearance 90%; PH6.9.

Claims (4)

1, a kind of diatomite treatment agent is characterized in that it is that the diatomite of 90-98% is a main raw material with the diatom amount, and formulated by following proportioning:
Diatomite: flocculation agent=8-9: 2-1.
2, sewage-treating agent according to claim 1 is characterized in that other composition of described diatomite is:
Crystalline silica: 1-2%; Plumbous: below the 50PPM;
Arsenic: below the 6PPM; PH value: 6-8;
Scaling loss amount: below 5%; Tight bulk density: below 0.4.
3, sewage-treating agent according to claim 1 is characterized in that described flocculation agent is Tai-Ace S 150 or aluminum chloride or polyacrylamide or iron trichloride or other inorganic salt flocculation agent commonly used or polymeric flocculant.
4, a kind of method of disposing of sewage with the described diatomite treatment agent of claim 1 is included in and adds diatomite in the sewage, it is characterized in that:
1.. add the diatom amount and be the diatomite treatment agent of 90-98% in sewage, and this diatomite treatment agent is made in the ratio of diatomite: flocculation agent=8-9: 2-1, its add-on is the diatomite treatment agent of sewage adding 0.15-0.3kg per ton;
2.. the sewage that will be mixed with the diatomite treatment agent is with 3-6 rice 3/ minute flow inject in the centrifuge separator along the tangent to periphery direction;
3.. adjust sewage PH value to neutral, in classifying separator clarifying treatment 20-40 minute, isolate supernatant water and precipitation dirt;
4.. supernatant water is in the precipitate and separate device, and settlement separate step by step 20-40 minute, clear water flowed into clean water basin, the precipitation dirt with 0.5-1 rice/minute flow velocity flow into dehydration treatment equipment.
CN 96122377 1996-12-04 1996-12-04 Sewage treatment technology and equipment using refined diatomite as treating agent Expired - Lifetime CN1064648C (en)

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Application Number Priority Date Filing Date Title
CN 96122377 CN1064648C (en) 1996-12-04 1996-12-04 Sewage treatment technology and equipment using refined diatomite as treating agent

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Application Number Priority Date Filing Date Title
CN 96122377 CN1064648C (en) 1996-12-04 1996-12-04 Sewage treatment technology and equipment using refined diatomite as treating agent

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CN1064648C true CN1064648C (en) 2001-04-18

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Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1301920C (en) * 2004-03-29 2007-02-28 福建凤竹纺织科技股份有限公司 Method for treating dyeing and finishingw aste water using diatomaceous earth and active carbon and its special equipment
CN100408161C (en) * 2005-02-28 2008-08-06 福建省瑞泉环保科技有限公司 Recipe and prepn process of modified diatomite for treating waste water
CN102600795B (en) * 2012-03-26 2014-09-03 杨俊义 Sewage treatment bentonite adsorbent and preparation process thereof
CN102863059A (en) * 2012-09-07 2013-01-09 上海同济环境工程科技有限公司 Additive for enhancing function of organism in aspect of ammonia nitrogen removal in water and use method of additive
CN103466772B (en) * 2013-10-25 2014-11-19 山西科元晟地科技有限公司 Diatomite reactor device
SG10201509295UA (en) * 2015-11-11 2017-01-27 Kytolink Tech Pte Ltd Process and System for Treating Waste Water
CN107261569B (en) * 2017-08-13 2018-05-25 贵州同成环境科技有限公司 A kind of settler for life kind sewage
CN110316912A (en) * 2019-07-26 2019-10-11 重庆市梁平区畜牧渔业发展中心 A kind of aquaculture tail water treatment system

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