CN106459628A - Plastic waterborne gravure ink and preparation method thereof - Google Patents
Plastic waterborne gravure ink and preparation method thereof Download PDFInfo
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- CN106459628A CN106459628A CN201580015527.4A CN201580015527A CN106459628A CN 106459628 A CN106459628 A CN 106459628A CN 201580015527 A CN201580015527 A CN 201580015527A CN 106459628 A CN106459628 A CN 106459628A
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- plastics
- printing ink
- intaglio printing
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
Abstract
The invention provides plastic waterborne gravure ink, and the ink comprises the following components by weight percentage: 25-35% of amino resin, 3-8% of aliphatic waterborne polyurethane resin, 30-40% of solvent, 8-12% of an addition agent, 8-12% of pigment, and 8-12% of diluent. The preparation method of the ink comprises the following steps: dissolving the amino resin under the condition of thermostatic water bath under the temperature 80-100 DEG C through the solvent, and preparing an aqueous solution; sequentially adding the aliphatic waterborne polyurethane resin, the catalyst and surfactant; carrying out the reaction for 1.5-2.5 hours under the temperature from 20 DEG C to 25 DEG C, and adding an antifoaming agents and a flatting agent, and then continuously carrying out stirring for 10-20 min; adding the pigment and continuing to carry out the stirring for 15-25 min, adding the diluent and preservative, and carrying out stirring for 5-10 min.
Description
Technical field
The invention belongs to aquosity intaglio printing ink technical field is and in particular to a kind of plastics aquosity intaglio printing ink and its preparation side
Method.
Background technology
, as a kind of environment-protecting asepsis energy-conservation, solvent-free discharge, no sharp aroma, with traditional print for plastics aquosity intaglio printing ink
Brush method is identical just to obtain clear, fresh and new picture and text effect.In plastic gravure ink traditional for a long time substantially
It is all solvent type ink, be all that the compound such as butyl acetate forms, volatile, inflammable, explosive, has with benzene, formaldehyde, dimethylbenzene
Poison, has strong impulse, even today that the feature of environmental protection improves, ink used also simply eliminates the molten of benzene, methanol etc
Agent.Still remain esters and alcohols solvent although increasing in terms of environmental protection, but still suffer from greatly at inflammable and explosive aspect
Hidden danger.
The use of existing plastics aquosity intaglio printing ink has clear and definite specificity, can only use in certain kind.Than
The ink prepared as water color ink binder as aliphatic modified polyvinyl alcohol, aromatic waterborne polyurethane modified polyvinylalcohol
As water color ink binder prepare ink, independent polyvinyl alcohol prepare as binder water color ink, independent polyurethane
Ink that the ink prepared as binder, independent acrylic acid are prepared as binder and make solvent with benzene,toluene,xylene
The ink prepared, they are very low to the cohesive of pigment and other fine particles, and volatile material residual quantity is many, printing water resistant
Property, weatherability, stability is poor, is restricted in application.
Content of the invention
Can only be imprinted on above single product and print quality difference for solve that existing plastics aquosity intaglio printing ink exists
Problem, the present invention proposes a kind of plastics aquosity intaglio printing ink, using heat cured amino resins as binder, simultaneously with modifying agent
Aliphatic aqueous polyurethane resin synergism, can be applied to above multiple products, thus change presently, there are printing image
Coarse, water wrinkle manifests, double exposure is poor and the restricted problem of range of application.
The technical scheme is that and be achieved in that:
A kind of plastics aquosity intaglio printing ink, according to percentage by weight, is made up of following component:25-35% amino resins, 3-
8% aliphatic aqueous polyurethane resin, 30-40% solvent, 8-12% auxiliary agent, 8-12% pigment, 8-12% diluent.
Further, described amino resins are selected from Lauxite, melamine resin and polyamide polyamines epoxy chloropropionate
In alkane one or more.
Further, described solvent is water, and described diluent is deionized water and ethanol is 8 by volume:2 mixture.
Further, described auxiliary agent is that dispersant, catalyst, surfactant, defoamer, preservative and levelling agent form
Mixture;The weight of described dispersant, catalyst, surfactant, defoamer, preservative and levelling agent is than for 2.5:2.5:
1.5:1.5:0.2:1.8.
Further, described dispersant is diisopropanolamine (DIPA) or monoethanolamine;Described defoamer be SPA102 or
SPA202;Described catalyst is SPAN85, single lauric acid/dodecanoic acid Isosorbide Dinitrate or Sorbitan Palmitate;Described surface
Activating agent is OP-10 or polysorbate60;Described preservative is imidazolidinyl urea or dehydroactic acid;Described levelling agent is ethylene glycol
Or propylene glycol.
Further, described pigment is selected from everbright fast yellow, permanent bordeaux, phthalocyanine blue, dark green, forever solid orange, sun-proof purple, carbon black and titanium
One of white lead.
Further, the pH value of described plastics aquosity intaglio printing ink is 8.5-9.5.
It is a further object to provide a kind of preparation method of plastics aquosity intaglio printing ink, including specifically walking as follows
Suddenly:
1) 25-35% amino resins, 3-8% aliphatic aqueous polyurethane resin, 30- are weighed respectively according to percentage by weight
40% solvent, 8-12% auxiliary agent, 8-12% pigment, 8-12% diluent, described auxiliary agent is dispersant, catalyst, surface activity
Agent, the mixture of defoamer, preservative and levelling agent composition;
2) utilize step 1) solvent that weighs, dissolves amino resin formulations under conditions of 80 DEG C -100 DEG C of water bath with thermostatic control
Become the aqueous solution of amino resins;
3) aqueous solution of the amino resins preparing is poured in reaction vessel, in turn add aliphatic aqueous polyurethane
Resin, catalyst and surfactant, under conditions of temperature 20-25 DEG C react 1.5-2.5 hour, be subsequently adding defoamer and
Levelling agent, more continuously stirred 10-20 minute;
4) in temperature 20-25 DEG C, add pigment to continue stirring 15-25 minute, add diluent and stir 5- with preservative
10 minutes, rewinding obtained final product.
Further, described amino resins are selected from Lauxite, melamine resin and polyamide polyamines epoxy chloropropionate
In alkane one or more.
Further, described solvent is water, and described diluent is deionized water and ethanol is 8 by volume:2 mixture.
Further, described dispersant is diisopropanolamine (DIPA) or monoethanolamine;Described defoamer be SPA102 or
SPA202;Described catalyst is SPAN85, single lauric acid/dodecanoic acid Isosorbide Dinitrate or Sorbitan Palmitate;Described surface
Activating agent is OP-10 or polysorbate60;Described preservative is imidazolidinyl urea or dehydroactic acid;Described levelling agent is ethylene glycol
Or propylene glycol;The weight of described dispersant, catalyst, surfactant, defoamer, preservative and levelling agent is than for 2.5:
2.5:1.5:1.5:0.2:1.8.
Further, described step 1) amino resins content be 30%, aliphatic aqueous polyurethane resin content be 6%, molten
Agent content is 34%, and auxiliary agent content is 10%, and pigment content is 10% and amount of diluent is 10%;Described step 2) reaction temperature
Spend for 95 DEG C;Described step 3) reaction temperature be 23 DEG C, 2.2 hours response time, mixing time 15 minutes;Described step 4) anti-
Answer temperature to be 23 DEG C, add the stir dye time to be 13 minutes, the time that is again stirring for is 8 minutes.
Beneficial effect of the present invention:
1st, the binder of the present invention is amino resins, and amino resins are water-soluble low-molecular resins few in number, are made with it
The solvent-free volatilization of binder;Modifying agent is modified to amino resins for water-based aliphaic polyurethane resin, using the poly- ammonia of aqueouss
The advantage of ester, improves the rate of drying of amino resins, strengthens adhesive force, and ratio reduces drying time admittedly to improve amino resins high temperature.
Aqueous polyurethane is a kind of macromolecular material in itself, and it has fire-retardant with water as medium, free from environmental pollution, easy to process etc. excellent
Point.
2nd, surfactant is OP-10 or polysorbate60, is mainly to increase the flexibility in plastics aquosity intaglio printing ink.Urge
Agent is SPAN85, single lauric acid/dodecanoic acid Isosorbide Dinitrate or Sorbitan Palmitate, is mainly to increase water-based plastic recessed
Flexibility in printing ink.Impacted during ink backflow when defoamer is used to suppress Printing ink producing and printer to run up
Foam, improve ink stability.Preservative is used to suppress the procreation with killing microorganisms, in ink printing process,
Diluent added by scene is possible to just use unboiled water, and the microorganism in unboiled water is a lot.Levelling agent is used to improve ink be printed onto and holds
Play moistening base material when on print thing, improve ink and iridescence occurs, the even phenomenon showing money or valuables one carries unintentionally of irregular colour occurs.The acting on of diluent
Improve print speed printing speed, drying property, the stability of color in printing, viscosity controls.
3rd, the resistance to water of plastics aquosity intaglio printing ink of the present invention, resistance to acids and bases, solvent resistance, rub resistance is more similar than other
Ink improves significantly, and can apply to high-quality printing.Plastics aquosity intaglio printing ink of the present invention can be applied to multiple products
Above, above the product of such as PE, PET, POPP and PVC.
4th, traditional aquosity intaglio printing ink great majority be pH value below 8.0, and think that pH value is less than 8.0 and is conducive to improving
Print speed printing speed, but the problem of blocking printed panel often occurs in actual intaglio process.Iff by water above market
Property gravure ink pH value be adjusted to more than 8.0 and occur that stability is poor, the problem of gravure effect difference.For solving this problem, I
By improving to binder, using amino resins and water-based aliphaic polyurethane resin as raw material, by dispersant
8.5-9.5 is adjusted to its pH value, it has surprisingly been found that not only the problem blocking printed panel in this aquosity intaglio printing ink,
And there is good stability, i.e. the big feature of the three of the transitivity of ink, wettability and solubility.In actual printing process
In, the features such as production efficiency is high, bright-colored and Well-recovered.
Specific embodiment
Embodiment 1
1) weigh 25kg Lauxite, 3kg aliphatic aqueous polyurethane resin, 40kg water, 8kg auxiliary agent, 12kg everbright fast yellow,
12kg diluent, auxiliary agent be 2kg diisopropanolamine (DIPA), 2kg SPAN85,1.2kg polysorbate60,1.2kgSPA102,
0.16kg imidazolidinyl urea and the mixture of 1.44kg ethylene glycol composition;Diluent is deionized water and ethanol is 8 by volume:
2 mixture;
2) utilize step 1) water that weighs, under conditions of 80 DEG C of waters bath with thermostatic control, dissolving Lauxite is configured to Lauxite
Aqueous solution;
3) aqueous solution of the Lauxite preparing is poured in reaction vessel, in turn add aliphatic aqueous polyurethane
Resin, SPAN85 and polysorbate60, react 2.5 hours under conditions of 20 DEG C of temperature, be subsequently adding SPA102 and
Ethylene glycol, more continuously stirred 10 minutes;
4) in 25 DEG C of temperature, add everbright fast yellow to continue stirring 25 minutes, add diluent and stir 5 points with imidazolidinyl urea
Clock, rewinding obtains final product plastics aquosity intaglio printing ink.
Embodiment 2
1) weigh 30kg melamine resin, 5kg aliphatic aqueous polyurethane resin, 35kg water, 12kg auxiliary agent,
8kg phthalocyanine blue, 10kg diluent, described auxiliary agent is 3kg monoethanolamine, 3kg mono- lauric acid/dodecanoic acid Isosorbide Dinitrate, 1.8kgOP-
10th, the mixture of 1.8kgSPA202,0.24kg dehydroactic acid and 2.16kg propylene glycol composition;Diluent is deionized water and second
Alcohol is 8 by volume:2 mixture;
2) utilize step 1) water that weighs, under conditions of 90 DEG C of water bath with thermostatic control, dissolving melamine resin is prepared
Become the aqueous solution of melamine resin;
3) aqueous solution of the melamine resin preparing is poured in reaction vessel, in turn add aliphatic water
Property polyurethane resin, single lauric acid/dodecanoic acid Isosorbide Dinitrate and OP-10, react 1.5 hours under conditions of 25 DEG C of temperature, Ran Houjia
Enter SPA202 and propylene glycol, more continuously stirred 20 minutes;
4) in 20 DEG C of temperature, add phthalocyanine blue to continue stirring 25 minutes, add diluent and stir 10 points with dehydroactic acid
Clock, rewinding obtains final product plastics aquosity intaglio printing ink.
Embodiment 3
1) 35kg Polyamide-Polyamsne-Epichlorohydrin, 8kg aliphatic aqueous polyurethane resin, 30kg water, 10kg auxiliary agent,
9kg carbon black, 8kg diluent, described auxiliary agent be 2.5kg monoethanolamine, 2.5kg Sorbitan Palmitate, 1.5kgOP-10,
1.5kgSPA202,0.2kg dehydroactic acid and 1.8kg ethylene glycol composition mixture;Diluent is deionized water and body pressed by ethanol
Long-pending ratio is 8:2 mixture;
2) utilize step 1) water that weighs, dissolves polyamide polyamines epoxy chloropropionate under conditions of 100 DEG C of water bath with thermostatic control
The aqueous solution of alkane;
3) aqueous solution of the Polyamide-Polyamsne-Epichlorohydrin preparing is poured in reaction vessel, in turn add fat
Race's aqueous polyurethane resin, Sorbitan Palmitate and OP-10, react 2 hours under conditions of 22 DEG C of temperature, are subsequently adding SPA202
And ethylene glycol, more continuously stirred 15 minutes;
4) in 22 DEG C of temperature, add carbon black to continue stirring 20 minutes, add diluent and stir 8 minutes with dehydroactic acid,
Rewinding obtains final product plastics aquosity intaglio printing ink.
Embodiment 4
1) 30kg Polyamide-Polyamsne-Epichlorohydrin, 6kg aliphatic aqueous polyurethane resin, 34kg water, 10kg auxiliary agent,
10kg forever solid orange, 10kg diluent, described auxiliary agent is 2.5kg diisopropanolamine (DIPA), 2.5kg SPAN85,1.5kg tell
The mixture of temperature 60,1.5kgSPA102,0.2kg imidazolidinyl urea and 1.8kg propylene glycol composition;Diluent be deionized water and
Ethanol is 8 by volume:2 mixture;
2) utilize step 1) water that weighs, dissolves Polyamide-Polyamsne-Epichlorohydrin under conditions of 95 DEG C of water bath with thermostatic control
It is configured to the aqueous solution of Polyamide-Polyamsne-Epichlorohydrin;
3) aqueous solution of the Polyamide-Polyamsne-Epichlorohydrin preparing is poured in reaction vessel, in turn add fat
Race's aqueous polyurethane resin, SPAN85 and polysorbate60, react 2.2 hours under conditions of 23 DEG C of temperature, then
Add SPA102 and propylene glycol, more continuously stirred 15 minutes;
4) in 23 DEG C of temperature, add forever solid orange to continue stirring 13 minutes, add diluent and stir 8 points with imidazolidinyl urea
Clock, rewinding obtains final product plastics aquosity intaglio printing ink.
The plastics aquosity intaglio printing ink that embodiment 1-4 is prepared is tested as follows:
1st, pH value test result:The pH value of embodiment 1 is 8.5, and the pH value of embodiment 2 is 9.0, and the pH value of embodiment 3 is
9.2, the pH value of embodiment 4 is 9.5.
2nd, viscosity experiment result:25 DEG C of embodiment 1 Cai's grace 2# cup 45 seconds, 25 DEG C of embodiment 2 Cai's grace 2# cup 50 seconds, embodiment
3 25 DEG C of Cai's grace 2# cups 50 seconds, 25 DEG C of embodiment 4 Cai's grace 2# cup 60 seconds.
3rd, resistance to water experiment:Fill 100 grams of pure water with beaker, take 10X10mm's to be printed on oil in the environment of 25 DEG C of room temperature
The normal temperature drying 24h that the PVC base printing of ink completes places 24 hours in water, and embodiment 1-4 does not all fade.
4th, alkali resistance:It is configured to 1% 100 grams of aqueous solutions of sodium hydroxide with beaker, in the environment of 25 DEG C, take 10X10mm
The normal temperature drying 24h that completes of the POPP base material printing being printed on ink place in sodium hydroxide solution and soak 2 hours, embodiment 1-
4 all do not fade.
5th, acid resistance:It is configured to 1% 100 grams of aqueous hydrochloric acid solution with beaker, take the print of 10X10mm in the environment of 25 DEG C
The normal temperature drying that the PET base material printing having ink completes is placed in aqueous hydrochloric acid solution, and embodiment 1-4 does not all fade.
6th, solvent resistance:Taken in 100 grams of normal hexane beakers with beaker and take being printed on of 10X10mm under conditions of 25 DEG C of room temperature
The normal temperature drying 24h that the PE base material printing of ink completes places in normal hexane and soaks 2 hours, and embodiment 1-4 does not all fade.
7th, stability:Aquosity intaglio printing ink is carried out with freezing and the heat run of 6h, observes whether ink has gel situation
Or anti-thick phenomenon.Result shows, embodiment 1-4 does not all have gel situation and anti-thick phenomenon.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.
Claims (10)
1. a kind of plastics aquosity intaglio printing ink is it is characterised in that according to percentage by weight, be made up of following component:25-35% ammonia
Base resin, 3-8% aliphatic aqueous polyurethane resin, 30-40% solvent, 8-12% auxiliary agent, 8-12% pigment, 8-12% dilutes
Agent.
2. plastics aquosity intaglio printing ink according to claim 1 is it is characterised in that described amino resins are selected from ureaformaldehyde tree
In fat, melamine resin and Polyamide-Polyamsne-Epichlorohydrin one or more.
3. plastics aquosity intaglio printing ink according to claim 2 it is characterised in that described solvent be water, described diluent
Be deionized water and ethanol be 8 by volume:2 mixture.
4. plastics aquosity intaglio printing ink according to claim 2 it is characterised in that described auxiliary agent be dispersant, catalyst,
Surfactant, the mixture of defoamer, preservative and levelling agent composition;Described dispersant, catalyst, surfactant, disappear
The weight of infusion, preservative and levelling agent is than for 2.5:2.5:1.5:1.5:0.2:1.8.
5. plastics aquosity intaglio printing ink according to claim 4 it is characterised in that described dispersant be diisopropanolamine (DIPA) or
Person's monoethanolamine;Described defoamer is SPA102 or SPA202;Described catalyst is SPAN85, single lauric acid/dodecanoic acid
Isosorbide Dinitrate or Sorbitan Palmitate;Described surfactant is OP-10 or polysorbate60;Described preservative is imidazolidinyl
Urea or dehydroactic acid;Described levelling agent is ethylene glycol or propylene glycol.
6. the plastics aquosity intaglio printing ink according to claim 1 to 5 any one is it is characterised in that described plastics aqueouss
The pH value of gravure ink is 8.5-9.5.
7. the preparation method of plastics aquosity intaglio printing ink according to claim 1 is it is characterised in that include specifically walking as follows
Suddenly:
1) 25-35% amino resins, 3-8% aliphatic aqueous polyurethane resin, 30-40% are weighed respectively according to percentage by weight
Solvent, 8-12% auxiliary agent, 8-12% pigment, 8-12% diluent, described auxiliary agent is dispersant, catalyst, surfactant, disappears
The mixture of infusion, preservative and levelling agent composition;
2) utilize step 1) solvent that weighs, dissolves amino resin formulations ammonification under conditions of 80 DEG C -100 DEG C of water bath with thermostatic control
The aqueous solution of base resin;
3) aqueous solution of the amino resins preparing is poured in reaction vessel, in turn add aliphatic aqueous polyurethane tree
Fat, catalyst and surfactant, react 1.5-2.5 hour under conditions of temperature 20-25 DEG C, are subsequently adding defoamer and stream
Flat agent, more continuously stirred 10-20 minute;
4) in temperature 20-25 DEG C, add pigment to continue stirring 15-25 minute, add diluent and divide with preservative stirring 5-10
Clock, rewinding obtains final product.
8. the preparation method of plastics aquosity intaglio printing ink according to claim 7 is it is characterised in that described amino resins select
From in Lauxite, melamine resin and Polyamide-Polyamsne-Epichlorohydrin one or more;Described solvent is water,
Described diluent is deionized water and ethanol is 8 by volume:2 mixture.
9. the preparation method of plastics aquosity intaglio printing ink according to claim 7 is it is characterised in that described dispersant is two
Isopropanolamine or monoethanolamine;Described defoamer is SPA102 or SPA202;Described catalyst is sorbitol anhydride three Oleic acid
Ester, single lauric acid/dodecanoic acid Isosorbide Dinitrate or Sorbitan Palmitate;Described surfactant is OP-10 or polysorbate60;Described anti-corrosion
Agent is imidazolidinyl urea or dehydroactic acid;Described levelling agent is ethylene glycol or propylene glycol;Described dispersant, catalyst, table
The weight of face activating agent, defoamer, preservative and levelling agent is than for 2.5:2.5:1.5:1.5:0.2:1.8.
10. the preparation method of plastics aquosity intaglio printing ink according to claim 7 is it is characterised in that described step 1) ammonia
Base resin content is 30%, and aliphatic aqueous polyurethane resin content is 6%, and solvent is 34%, and auxiliary agent content is 10%,
Pigment content is 10% and amount of diluent is 10%;Described step 2) reaction temperature be 95 DEG C;Described step 3) reaction temperature
For 23 DEG C, 2.2 hours response time, mixing time 15 minutes;Described step 4) reaction temperature be 23 DEG C, add stir dye when
Between be 13 minutes, be again stirring for the time be 8 minutes.
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PCT/CN2015/088369 WO2017035693A1 (en) | 2015-08-28 | 2015-08-28 | Plastic aqueous gravure ink and preparation method therefor |
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CN109337081A (en) * | 2018-09-04 | 2019-02-15 | 天津大学 | For reducing the method for water-soluble sulphur free formaldehyde in urea-formaldehyde resin |
CN110903699A (en) * | 2019-12-23 | 2020-03-24 | 江门市大度高科有限公司 | Water-based gravure plastic ink |
CN112646413A (en) * | 2020-09-25 | 2021-04-13 | 东莞市万润涂料有限公司 | Novel MY-R soft PVC gravure ink and preparation method thereof |
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