CN106450498A - Encapsulation type rechargeable lithium ion button battery - Google Patents

Encapsulation type rechargeable lithium ion button battery Download PDF

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Publication number
CN106450498A
CN106450498A CN201611229769.6A CN201611229769A CN106450498A CN 106450498 A CN106450498 A CN 106450498A CN 201611229769 A CN201611229769 A CN 201611229769A CN 106450498 A CN106450498 A CN 106450498A
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CN
China
Prior art keywords
electrode
lithium ion
rubber
wrapped
button cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611229769.6A
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Chinese (zh)
Inventor
杨友清
王昉
孙法炯
黄欣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuhai Power Battery Co Ltd
Original Assignee
Zhuhai Power Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhuhai Power Battery Co Ltd filed Critical Zhuhai Power Battery Co Ltd
Priority to CN201611229769.6A priority Critical patent/CN106450498A/en
Publication of CN106450498A publication Critical patent/CN106450498A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0587Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0422Cells or battery with cylindrical casing
    • H01M10/0427Button cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/204Racks, modules or packs for multiple batteries or multiple cells
    • H01M50/207Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
    • H01M50/216Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for button or coin cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses an encapsulation type rechargeable lithium ion button battery, and is applied to the technical field of lithium ion batteries. The encapsulation type rechargeable lithium ion button battery comprises a sealing shell, electrolyte and an electrode. The electrolyte is arranged in the sealing shell, the electrode is arranged in the electrolyte and is a spirally wound electrode, and an insulating and ion-impermeable film (12) is arranged on the outermost ring of the spirally wound electrode. The encapsulation type rechargeable lithium ion button battery has the advantages of compact structure, stability in use and long service life.

Description

Rubber-wrapped chargeable lithium ion button cell
Technical field
The present invention relates to a kind of lithium ion battery, particularly to a kind of rubber-wrapped chargeable lithium ion button cell.
Background technology
Rechargeable lithium ion batteries and lithium soft-package battery are widely used in hold electronic equipment, such as mobile phone and earphone In.In especially little equipment such as sonifer, volume energy density is a critical consideration.Due to chargeable lithium ion The requirement of battery volume, can guarantee that battery applications effect to reduce again while battery volume, now many electric using screw winding Pole, but during increasing battery volume energy density, have and bring new technical problem, such as in Chinese patent application. With. and United States Patent (USP) (US, B) in, directly using the electrode after winding, its outmost turns is after the coiling by pole piece or barrier film bag Wrap up in and part is sticked adhesive tape and fixed.Because button cell need to make full use of internal limited space, the distance of box hat and electrode roll Can be arranged close, its side wall can directly contact pole piece or barrier film.In charging process, the housing electricity of contact this part of electrode roll Gesture is generally minimum, makes the deposition that the lithium ion in this region can make a mistake on box hat under the driving of electric potential difference.Stop After charging, reduced and destroyed by the oxide layer that the electrons that the lithium depositing is provided lead to box hat surface.Especially in lug With the welding position of box hat although non-directly contact electrode roll, but there is bimetallic due to welding, wherein the potential of lug is more Height is it is easier to attracting the electronics being provided by lithium and leading to original oxide layer to be reduced.Lose the metal after oxide layer protection, cruelly Dew can be corroded in the electrolytic solution, and generates new oxide-film, and so repeated multiple times, the oxide layer at lug position can be increasingly Thickness, metal level more and more thinner, finally result in open circuit, battery cycle life is short;Furthermore just it is to ensure that the sealing of battery, knot Structure is made too complicated, thus improve the production cost of battery and the complexity of technique.
Content of the invention
The technical problem to be solved is to overcome the deficiencies in the prior art, there is provided a kind of compact conformation, use The rubber-wrapped chargeable lithium ion button cell of stable and long service life.
The technical solution adopted in the present invention is:The present invention includes capsul, the electrolyte being arranged in described capsul And it is arranged at electrode in described electrolyte, described electrode is that the outmost turns of screw winding electrode and described screw winding electrode set It is equipped with the thin film that insulation and ion can not turn on.
Further, the material of described thin film is polyethylene, or is polypropylene, or is polyester, or is polyimides.
Further, the thickness of described thin film is between 0.005-0.2 millimeter.
Further, described capsul includes cooperate inner cap and shell, and described inner cap includes top cover, perpendicular to described top Lid interior stile, be located at the shoulder between described top cover and interior stile and the inner opening located at interior stile lower end, described shell bag Include drain pan, the outer stile perpendicular to described drain pan and the outward opening, described inner cap and the described shell that are located at described outer stile upper end Between be additionally provided with insulation cushion rubber, described insulation cushion rubber includes a stile and the foot side located at described stile lower end, described foot While covering described inner opening, described outward opening and described shoulder position are mutually corresponding.
Further, described screw winding electrode includes first electrode, second electrode and barrier film, described first electrode and described Second electrode is spaced to be arranged in described electrolyte with spiral-shaped, and described barrier film is arranged at described first electrode and described In the interval of second electrode;First conductive lug is provided with described first electrode, described second electrode is provided with second and leads Electrode ear, the described first conductive lug is welded with the inner surface of described top cover;The outmost turns of described screw winding electrode with described It is provided with thin film between the inner surface of interior stile;Described drain pan inner surface setting has sheet metal, described second conductive lug and institute State sheet metal welding.
Further, the one side of described sheet metal is fitted with described drain pan inner surface, and the another side of described sheet metal is provided with Felt pad one with centre bore, described second conductive lug and described sheet metal welding portion be provided with felt pad two and described absolutely Edge pad two is fitted with described felt pad one.
Further, described top cover inner surface is provided with the felt pad three with centre bore.
Further, the non-solder part of the affiliated first conductive lug is provided with insulating tape one;Described second conductive lug Non-solder part and the part not covered by described felt pad two be provided with insulating tape two.
Further, described first electrode is anode, and described second electrode is negative electrode;Or described first electrode is negative electrode, Described second electrode is anode.
The manufacture method of the present invention:It is circular or oval that described first electrode, barrier film and second electrode pass through winding formation Described screw winding electrode, described barrier film is placed between described first electrode and second electrode, described first electrode and institute The width mutually correspondence stating second electrode gradually decreases to adapt to the height change from described inner cap center to described shoulder flanges Change;Described thin film covers the outermost layer in described screw winding electrode;Described first conductive lug and the inner surface of described top cover Welding;Described insulation cushion rubber and described inner cap cooperation, described foot side covers described inner opening, pumps into electrolysis to described inner cap Matter;Described second conductive lug and described sheet metal welding;Described shell and described inner cap cooperation, using described insulation cushion rubber Plasticity is passed through described outward opening again and is fastened realization to a kind of described rubber-wrapped chargeable lithium ion button with the machinery of described shoulder The sealing of battery.
The invention has the beneficial effects as follows:Due to the present invention include capsul, the electrolyte being arranged in described capsul and It is arranged at the electrode in described electrolyte, described electrode is the outmost turns setting of screw winding electrode and described screw winding electrode Have thin film it is seen then that between this thin film is in inside helical coil outmost turns and metal sidewall, prevent helical coil outmost turns barrier film or Pole piece and side-wall metallic directly contact.We have found that outside is coated with the helical coil battery of thin film, lug in charge and discharge process It is less likely to occur to rupture, thus ensureing that battery has higher reliability and longer cycle life, so, present configuration is tight Gather, good seal performance and long service life.
Brief description
Fig. 1 is the structure cross-sectional schematic of the present invention;
Fig. 2 is the structural representation that described screw winding electrode is cooperated with described thin film.
Specific embodiment
As depicted in figs. 1 and 2, the present invention includes capsul, the electrolyte being arranged in described capsul and is arranged at institute State the electrode in electrolyte, described electrode is provided with insulation simultaneously for the outmost turns of screw winding electrode and described screw winding electrode And the thin film 12 that ion can not turn on;Described thin film 12 adopts mylar and described film thickness is 0.03 millimeter;Described spiral shell The thin film 12 that one layer of the outer presence insulation of rotation rolled electrode and ion can not turn on, thus ensure battery have higher can By property and longer cycle life.
In the present embodiment, described capsul includes cooperate inner cap and shell, and described inner cap includes top cover 1, vertical In described top cover 1 interior stile 2, be located at shoulder 3 between described top cover 1 and interior stile 2 and open in interior stile 2 lower end Mouthful, described shell includes drain pan 5, the outer stile 6 perpendicular to described drain pan 5 and the outward opening 7 being located at described outer stile 6 upper end, It is additionally provided with insulation cushion rubber 8, described insulation cushion rubber 8 includes a stile and located at described vertical between described inner cap and described shell In the foot of lower end, described foot side covers described inner opening, and described outward opening 7 and described shoulder 3 position are mutually corresponding.
In the present embodiment, described screw winding electrode includes first electrode 9, second electrode 10 and barrier film 11, and described One electrode 9 and described second electrode 10 is spaced is arranged in described electrolyte with spiral-shaped, described barrier film 11 is arranged at In the interval of described first electrode 9 and described second electrode 10;First conductive lug 91, institute are provided with described first electrode 9 State and the second conductive lug 101 is provided with second electrode 10, the described first conductive lug 91 is welded with the inner surface of described top cover 1 Connect;It is provided with thin film 12 between the inner surface of the outmost turns of described screw winding electrode and described interior stile 2;In described drain pan 5 Surface is provided with sheet metal 13, and the described second conductive lug 101 is welded with described sheet metal 13.
In the present embodiment, the one side of described sheet metal 13 is fitted with described drain pan 5 inner surface, described sheet metal 13 another Simultaneously it is provided with the felt pad 1 with centre bore, the described second conductive lug 101 and described sheet metal 13 welding portion setting There is felt pad 2 15 and described felt pad 2 15 is fitted with described felt pad 1;Described top cover 1 inner surface setting You Dai center The felt pad 3 16 in hole.
In the present embodiment, the non-solder part of the affiliated first conductive lug 91 is provided with insulating tape 1;Described The non-solder part of two conductive lugs 101 and the part not covered by described felt pad 2 15 are provided with insulating tape 2 102.
In the present embodiment, or described first electrode 9 be negative electrode, described second electrode 10 be anode.
The manufacture method of described rubber-wrapped chargeable lithium ion button cell:Described first electrode 9, barrier film 11 and the second electricity Pole 10 is passed through winding and is formed circular or oval described screw winding electrode, and described barrier film 11 is placed on described first electrode 9 And second electrode 10 between, the width of described first electrode 9 and described second electrode 10 mutually correspondence gradually decrease with adapt to from Described inner cap center is to the height change at described shoulder 3 edge;Described thin film 12 covers in described screw winding electrode Outer layer;Described first conductive lug 91 is welded with the inner surface of described top cover 1;Described insulation cushion rubber 8 and described inner cap cooperation, institute State foot side and cover described inner opening, pump into electrolyte to described inner cap;Described second conductive lug 101 and described sheet metal 13 Welding;Described shell and described inner cap cooperation, the plasticity using described insulation cushion rubber 8 passes through described outward opening 7 and described shoulder again The machinery in portion 3 fastens the sealing realized to described rubber-wrapped chargeable lithium ion button cell.
The present invention is applied to the technical field of lithium ion battery.
Although embodiments of the invention to be described with practical solution, do not constitute the limit to implication of the present invention System, for those skilled in the art, according to this specification to the modification of its embodiment and with combining of other schemes be all Obviously.

Claims (9)

1. a kind of rubber-wrapped chargeable lithium ion button cell, it includes capsul, the electrolyte being arranged in described capsul And be arranged at electrode in described electrolyte it is characterised in that:Described electrode is screw winding electrode and described screw winding electricity The outmost turns of pole are provided with the thin film that insulation and ion can not turn on(12).
2. rubber-wrapped chargeable lithium ion button cell according to claim 1 it is characterised in that:Described thin film(12)'s Material is polyethylene, or is polypropylene, or is polyester, or is polyimides.
3. rubber-wrapped chargeable lithium ion button cell according to claim 1 it is characterised in that:Described thin film(12)'s Thickness is between 0.005-0.2 millimeter.
4. rubber-wrapped chargeable lithium ion button cell according to claim 1 it is characterised in that:Described capsul includes Cooperate inner cap and shell, and described inner cap includes top cover(1), perpendicular to described top cover(1)Interior stile(2), be located at described Top cover(1)With interior stile(2)Between shoulder(3)And located at interior stile(2)The inner opening of lower end, described shell includes drain pan (5), perpendicular to described drain pan(5)Outer stile(6)And it is located at described outer stile(6)The outward opening of upper end(7), described inner cap and It is additionally provided with insulation cushion rubber between described shell(8), described insulation cushion rubber(8)Including a stile with located at described stile lower end Foot side, described foot side covers described inner opening, described outward opening(7)With described shoulder(3)Position is mutually corresponding.
5. rubber-wrapped chargeable lithium ion button cell according to claim 4 it is characterised in that:Described screw winding electricity Pole includes first electrode(9), second electrode(10)And barrier film(11), described first electrode(9)With described second electrode(10)Phase Mutually interval is arranged in described electrolyte with spiral-shaped, described barrier film(11)It is arranged at described first electrode(9)With described Two electrodes(10)Interval in;Described first electrode(9)On be provided with the first conductive lug(91), described second electrode(10)On It is provided with the second conductive lug(101), the described first conductive lug(91)With described top cover(1)Inner surface welding;Described thin Film(12)It is arranged on the outmost turns of described screw winding electrode and described interior stile(2)Inner surface between;Described drain pan(5)Interior Surface is provided with sheet metal(13), the described second conductive lug(101)With described sheet metal(13)Welding.
6. rubber-wrapped chargeable lithium ion button cell according to claim 5 it is characterised in that:Described sheet metal(13) One side and described drain pan(5)Inner surface is fitted, described sheet metal(13)Another side be provided with the felt pad one with centre bore (14), the described second conductive lug(101)With described sheet metal(13)Welding portion is provided with felt pad two(15)And it is described exhausted Edge pad two(15)With described felt pad one(14)Laminating.
7. rubber-wrapped chargeable lithium ion button cell according to claim 6 it is characterised in that:Described top cover(1)Interior Surface is provided with the felt pad three with centre bore(16).
8. rubber-wrapped chargeable lithium ion button cell according to claim 7 it is characterised in that:Affiliated first conductive electrode Ear(91)Non-solder part be provided with insulating tape one(92);Described second conductive lug(101)Non-solder part and not By described felt pad two(15)The part covering is provided with insulating tape two(102).
9. rubber-wrapped chargeable lithium ion button cell according to claim 5 it is characterised in that:Described first electrode (9)For anode, described second electrode(10)For negative electrode;Or described first electrode(9)For negative electrode, described second electrode(10)For Anode.
CN201611229769.6A 2016-12-28 2016-12-28 Encapsulation type rechargeable lithium ion button battery Pending CN106450498A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611229769.6A CN106450498A (en) 2016-12-28 2016-12-28 Encapsulation type rechargeable lithium ion button battery

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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108682755A (en) * 2018-05-09 2018-10-19 广东弘捷新能源有限公司 Button cell and its manufacturing method
CN109148932A (en) * 2018-08-23 2019-01-04 曙鹏科技(深圳)有限公司 A kind of minicell group and its manufacturing method
WO2020036440A1 (en) * 2018-08-16 2020-02-20 주식회사 엘지화학 Secondary battery
CN111463395A (en) * 2020-04-24 2020-07-28 福建南平延平区南孚新能源科技有限公司 Button cell production method capable of reducing false welding rate and button cell produced by button cell production method
CN112635878A (en) * 2021-01-19 2021-04-09 广东至力科技有限公司 Miniature lithium ion battery with welding protection washer
JP2021530843A (en) * 2018-08-16 2021-11-11 エルジー・ケム・リミテッド Rechargeable battery
US20210384482A1 (en) * 2020-06-05 2021-12-09 Chongqing Vdl Electronics Co., Ltd. Button-type lithium ion battery with metal housing

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2331602A1 (en) * 1992-11-30 1994-05-31 Canon Kabushiki Kaisha Method of manufacturing a positive electrode active material of a secondary battery
JP2001085066A (en) * 1999-07-09 2001-03-30 Matsushita Electric Ind Co Ltd Nonaqueous electrolyte battery
US6443999B1 (en) * 2000-03-16 2002-09-03 The Gillette Company Lithium cell with heat formed separator
CN104332647A (en) * 2013-04-19 2015-02-04 王昉 Rechargeable lithium ion button cell battery
CN206422171U (en) * 2016-12-28 2017-08-18 珠海市至力电池有限公司 Rubber-wrapped chargeable lithium ion button cell

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2331602A1 (en) * 1992-11-30 1994-05-31 Canon Kabushiki Kaisha Method of manufacturing a positive electrode active material of a secondary battery
JP2001085066A (en) * 1999-07-09 2001-03-30 Matsushita Electric Ind Co Ltd Nonaqueous electrolyte battery
US6443999B1 (en) * 2000-03-16 2002-09-03 The Gillette Company Lithium cell with heat formed separator
CN104332647A (en) * 2013-04-19 2015-02-04 王昉 Rechargeable lithium ion button cell battery
CN206422171U (en) * 2016-12-28 2017-08-18 珠海市至力电池有限公司 Rubber-wrapped chargeable lithium ion button cell

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108682755A (en) * 2018-05-09 2018-10-19 广东弘捷新能源有限公司 Button cell and its manufacturing method
WO2020036440A1 (en) * 2018-08-16 2020-02-20 주식회사 엘지화학 Secondary battery
JP2021530843A (en) * 2018-08-16 2021-11-11 エルジー・ケム・リミテッド Rechargeable battery
JP7102674B2 (en) 2018-08-16 2022-07-20 エルジー エナジー ソリューション リミテッド Secondary battery
CN109148932A (en) * 2018-08-23 2019-01-04 曙鹏科技(深圳)有限公司 A kind of minicell group and its manufacturing method
CN111463395A (en) * 2020-04-24 2020-07-28 福建南平延平区南孚新能源科技有限公司 Button cell production method capable of reducing false welding rate and button cell produced by button cell production method
CN111463395B (en) * 2020-04-24 2021-01-15 福建南平延平区南孚新能源科技有限公司 Button cell production method capable of reducing false welding rate and button cell produced by button cell production method
US20210384482A1 (en) * 2020-06-05 2021-12-09 Chongqing Vdl Electronics Co., Ltd. Button-type lithium ion battery with metal housing
US11901569B2 (en) * 2020-06-05 2024-02-13 Chongqing Vdl Electronics Co., Ltd. Button-type lithium ion battery with metal housing
CN112635878A (en) * 2021-01-19 2021-04-09 广东至力科技有限公司 Miniature lithium ion battery with welding protection washer

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Application publication date: 20170222