CN1064465A - The compound method of glaze of glazed coloured wall or floor tiles - Google Patents
The compound method of glaze of glazed coloured wall or floor tiles Download PDFInfo
- Publication number
- CN1064465A CN1064465A CN 91101273 CN91101273A CN1064465A CN 1064465 A CN1064465 A CN 1064465A CN 91101273 CN91101273 CN 91101273 CN 91101273 A CN91101273 A CN 91101273A CN 1064465 A CN1064465 A CN 1064465A
- Authority
- CN
- China
- Prior art keywords
- glaze
- zircon
- glass fibre
- raw silk
- compound method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
Abstract
A kind of glaze of glazed coloured wall or floor tiles compound method belongs to the compound method of architectural pottery glaze.It is characterized in that the glass fibre raw silk of introducing 10-60% in the glaze process for preparation substitutes frit, preparation glaze of glazed coloured wall or floor tiles, several in the selection following raw materials according, its proportioning is: glass fibre raw silk 10-60%, zircon 0-15%, illite clay 0-40%, wollastonite and/or diopside 0-50%, feldspar 0-20%, aluminium sesquioxide 0-10%, zinc oxide 0-10%, quartzy 0-15%, kaolin 0-15%, pigment (adding) 0-15%.The present invention has that power consumption is low, and cost is low, avoids suffering the infringement of the toxic compounds that brings because of preparation clinker glaze process, also can avoid high temperature, noise, pollutions such as dust.
Description
A kind of compound method of color glazed tile glaze belongs to the compound method of architectural pottery glaze.
Advanced in the world country's production is adopted glaze wall floor tile and is all adopted cryogenic quick burning technology, for realizing cryogenic quick burning, all adopt the glaze system of clinker glaze, earlier with borax, boric acid, saltpetre, water-soluble or toxic chemical raw and quartz such as red lead, feldspar, zinc oxide, lime carbonate, raw materials such as wollastonite mix according to a certain ratio, at high temperature found solution based on glassy phase, obtain frit through water liquid again, then with frit again with quartz, feldspar, zinc oxide, wollastonite, lime carbonate, aluminum oxide, illite clay, a kind of or several raw materials mixing in the kaolin are milled down to certain fineness, promptly obtain glaze of glazed coloured wall or floor tiles, advantage is that glaze easily mates with various base substrates, reduces the stripping quantity of the toxic substance of glaze, its weak point is the cost height, power consumption is high, is subject to the murder by poisoning of toxic compounds in the process for preparation, in the production with high temperature, noise, infringements such as dust.
The compound method of a kind of glaze of glazed coloured wall or floor tiles that needn't frit that the objective of the invention is to avoid above-mentioned weak point of the prior art and provide, this method cost is low, it is low to consume energy, and can avoid suffering the infringement of the toxic compounds that brings because of preparation fritted glaze process, also can avoid pollutions such as high temperature, noise, dust.
Purpose of the present invention can realize by following measure: the compound method of glaze of glazed coloured wall or floor tiles, the compound method that belongs to the architectural pottery glaze, generally be with frit and other raw material based on glassy phase, generally with zircon, feldspar, quartz, zinc oxide, lime carbonate, wollastonite, red lead, aluminium sesquioxide, in illite clay, the kaolin several mix fine grinding according to a certain ratio, make glaze, its glaze can be divided into ground-coat enamel and cover-coat enamel.Prior art generally is the glaze system of fritted glaze, is the series of malpractice of avoiding bringing because of founding of clinker, and the proximate raw material of Chemical Composition of seeking a kind of and former frit is incorporated in the glaze process for preparation.The invention is characterized in that the glass fibre raw silk of introducing 10-60% in the supporting system process of glaze substitutes frit preparation glaze of glazed coloured wall or floor tiles.Glass fibre is to be smoked to dial by the vitreum of 1100 ℃ of fusings to form, and be under 1300 ℃ high temperature, to found based on the frit of glassy phase, and make through shrend, can substitute frit with glass fibre fully, and required other raw material reasonably allocated the preparation glaze.The glass fibre raw silk is fracture of wire, the waste silk that produces in the glass fibre production process, and a large amount of glass fibre raw silks brings harm for glass fibre factory, simultaneously again for the invention provides a large amount of raw materials, turns waste into wealth, and benefits the nation and the people.The preparation glaze of glazed coloured wall or floor tiles is selected several in the following raw materials according, its proportioning is: glass fibre raw silk 10-60%, zircon 0-15%, illite clay 0-40%, wollastonite or diopside 0-50%, feldspar 0-20%, aluminium sesquioxide 0-10%, zinc oxide 0-10%, quartzy 0-15%, kaolin 0-15%, pigment (adding) 0-15%.
Glaze of glazed coloured wall or floor tiles can be divided into ground-coat enamel and cover-coat enamel, below ground-coat enamel and cover-coat enamel is narrated respectively, and the proportioning of ground-coat enamel is glass fibre raw silk 20-40%, zircon 0-15%, illite clay 0-30%, feldspar 0-20%, aluminium sesquioxide 0-5%, quartzy 5-15%, kaolin 0-15%, its preferable proportioning is: glass fibre raw silk 20-40%, quartzy 5-15%, zircon 5-15%, feldspar 0-10%, kaolin 5-15%, illite clay 10-30%, aluminium sesquioxide 0-5%.The proportioning of cover-coat enamel is: glass fibre raw silk 10-60%, wollastonite and (or) diopside 10-50%, zircon 0-15%, illite clay 0-40%, feldspar 0-10%, aluminium sesquioxide 0-5%, or glass fibre raw silk 10-60%, wollastonite and (or) diopside 0-30%, zircon 5-15%, illite clay 0-25%, feldspar 0-20%, zinc oxide 0-10%, aluminium sesquioxide 5-15%, kaolin 0-15%.。The optimal components ratio of its cover-coat enamel is: glass fibre raw silk 25-50%, wollastonite and (or) diopside 20-35%, zircon 5-10%, illite clay 15-25%, feldspar 0-10%, aluminium sesquioxide 0-5%, perhaps glass fibre raw silk 25-35%, zircon 5-10%, wollastonite 15-25%, feldspar 10-15%, illite clay 10-15%, zinc oxide 0-5%, aluminium sesquioxide 5-10%, kaolin 0-5%.
The Chemical Composition (weight %) that the present invention is raw materials used
The Chemical Composition of glass fibre raw silk following (weight %)
| Glass fibre raw silk kind | SiO 2 | Al 2O 3 | CaO | MgO | Na 2O | K 2O | B 2O 3 |
| Middle alkali fiber raw silk | 67.3±0.5 | 6.4±0.4 | 9.5±0.3 | 4.2±0.3 | 11.9±0.4 | ＜0.5 | - |
| No alkali fiber raw silk | 54.1±0.5 | 14.6±0.4 | 16.6±0.3 | 4.6±0.3 | - | ＜0.8％ | 8.8±0.3 |
The present invention has compared to existing technology that cost is low, power consumption is low, and can avoid suffering encroaching on because of the toxic compounds that preparation fritted glaze process is brought, and also can avoid pollutions such as high temperature, noise, dust.
The present invention will now be further detailed embodiment:
The ground-coat enamel proportioning:
Embodiment 1, glass fibre raw silk 30%, zircon 10%, feldspar 15%, illite clay 25%, kaolin 5%.Quartzy 15%.
Embodiment 2, glass fibre raw silk 25%, zircon 15%, feldspar 20%, illite clay 25%, kaolin 15%.
The cover-coat enamel proportioning:
Embodiment 3, glass fibre raw silk 15%, zircon 15%, illite clay 40%, wollastonite 28%, aluminium sesquioxide 2%, pigment (adding) 6%.
Embodiment 4, glass fiber 30%, zircon 5%, diopside 5%, feldspar 10%, illite clay 20%, wollastonite 30%, aluminium sesquioxide 2%.
Embodiment 5, glass fibre raw silk 40%, zircon 5%, diopside 35%, feldspar 10%, illite clay 10%.
Embodiment 6, glass fibre raw silk 50%, wollastonite 40%, zircon 8%, illite clay 10%, aluminium sesquioxide 2%.
Embodiment 7, glass fibre raw silk 60%, wollastonite 30%, zircon 5%, aluminium sesquioxide 5%.
Embodiment 8, glass fibre raw silk 20%, feldspar 10%, zircon 5%, kaolin 5%, illite clay 25%, aluminium sesquioxide 10%.Zinc oxide 10%, wollastonite 15%.
Embodiment 9, glass fibre raw silk 30%, zircon 10%, feldspar 10%, aluminium sesquioxide 10%, zinc oxide 5%, illite clay 15%, wollastonite 20%.
Embodiment 10, glass fibre raw silk 40%, feldspar 20%, illite clay 15%, zircon clay 15%, diopside 20%.
Embodiment 11, glass fibre raw silk 50%, illite clay 15%, wollastonite 25%, zircon 5%, zinc oxide 5%.
Embodiment 12, glass fibre raw silk 60%, illite clay 15%, wollastonite 20%, zircon 5%,
The present invention can produce the matt glaze glaze and light (semi-matt) glaze is arranged, as the production matte glaze product, and available medium-alkali glass fibre raw silk, producing has light (semi-matt) glaze product, available alkali free glass fibre raw silk.The glaze of the present invention preparation is adapted at burning till in 1100-1150 ℃ the scope.
The glaze Chemical Composition scope following (weight %) of the present invention's preparation
| Heavy glaze kind amount (%) composition | Ground-coat enamel | Unglazed cover-coat enamel | Light (semi-matt) cover-coat enamel is arranged |
| SiO 2Al 2O 3 | 53.21-65.88 15.11-22.88 | 41.24-62.09 17.54-26.49 | 42.13-60.66 10.84-21.32 |
| Fe 2O 3 | 0.20-0.44 | 0.12-0.41 | 0.15-0.30 |
| TiO 2 | 0.18-0.48 | 0.10-0.30 | 0.07-0.38 |
| CaO | 1.62-4.08 | 8.03-17.12 | 10.78-25.03 |
| MgO | 0.94-1.65 | 0.88-5.54 | 0.72-8.87 |
| K 2O | 2.65-5.16 | 0.50-4.95 | 1.06-4.32 |
| Na 2O | 3.33-5.67 | 2.17-9.36 | 0.60-1.21 |
| B 2O 3 | -- | -- | 0.92-5.58 |
| ZnO | -- | 0.00-11.23 | -- |
| ZrO 2Pigment (adding) | 0.00-11.13 | 0.00-11.13 0-15％ | 0.00-11.13 0-15％ |
Claims (16)
1, a kind of glaze of glazed coloured wall or floor tiles compound method belongs to the compound method of architectural pottery glaze, generally with zircon, and feldspar, quartz, zinc oxide, carbide of calcium, wollastonite, red lead, aluminium sesquioxide, illite clay, several in the kaolin and frit.Mix fine grinding according to a certain ratio; Make glaze, its glaze can be divided into ground-coat enamel and cover-coat enamel, and the present invention is characterised in that glaze process for preparation introducing 10-60% glass fibre raw silk replaces frit, the preparation glaze of glazed coloured wall or floor tiles, several in the selection following raw materials according, its proportioning is: glass fibre raw silk 10-60%, zircon 0-15%, illite clay 0-40%, wollastonite or diopside 0-50%, feldspar 0-20%, aluminium sesquioxide 0-15%, zinc oxide 0-10%, quartzy 0-15%, kaolin 0-15% pigment (adding) 0-15%.
2, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 is characterized in that the proportioning of ground-coat enamel is: glass fibre raw silk 20-40%, zircon 0-15%, illite clay 0-30%, feldspar 0-20%, aluminium sesquioxide 0-5%, quartzy 5-15%, kaolin 0-15%, the proportioning of cover-coat enamel is: glass fibre raw silk 10-60%, wollastonite or diopside 10-50%, zircon 0-15%, illite clay 0-40%, feldspar 0-10%, aluminium sesquioxide 0-5%, or glass fibre raw silk 10-60%, wollastonite or diopside 0-30%, zircon 5-15%, illite clay 0-25%, feldspar 0-20%, zinc oxide 0-10%, aluminium sesquioxide 5-10%, kaolin 0-15%.
3, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the ground-coat enamel proportioning is: glass fibre raw silk 20-40%, quartzy 5-15%, zircon 5-10%, feldspar 0-10%, kaolin 5-15%, the clay 10-30% of Erie, aluminium sesquioxide 0-5%.
4, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the ground-coat enamel proportioning is: glass fibre raw silk 30%, zircon 10%, feldspar 15%, illite clay 25%, kaolin 5%.Quartzy 15%.
5, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the ground-coat enamel proportioning is: glass fibre raw silk 25%, zircon 15%, feldspar 20%, illite clay 25%, kaolin 15%.
6, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 25-50%, wollastonite and (or) diopside 20-35%, zircon 5-10%, illite clay 15-25%, feldspar 0-10%, aluminium sesquioxide 0-50%, perhaps glass fibre raw silk 25-35%, zircon 5-10%, wollastonite 15-25%, feldspar 10-15%, illite clay 10-15%, zinc oxide 0-5%, aluminium sesquioxide 5-10%, kaolin 0-5%.
7, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 15%, zircon 15%, illite clay 40%, wollastonite 28%, aluminium sesquioxide 2%, pigment (adding) 6%.
8, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fiber 30%, zircon 5%, diopside 5%, feldspar 10%, illite clay 20%, wollastonite 30%, aluminium sesquioxide 2%.
9, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 40%, zircon 5%, diopside 35%, feldspar 10%, illite clay 10%.
10, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 50%, wollastonite 40%, zircon 8%, illite clay 10%, aluminium sesquioxide 2%.
11, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 60%, wollastonite 30%, zircon 5%, aluminium sesquioxide 5%.
12, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 20%, feldspar 10%, zircon 5%, kaolin 5%, illite clay 25%, aluminium sesquioxide 10%.Zinc oxide 10%, wollastonite 15%.
13, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 30%, zircon 10%, feldspar 10%, aluminium sesquioxide 10%, zinc oxide 5%, illite clay 15%, wollastonite 20%.
14, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 40%, feldspar 20%, illite clay 15%, zircon 5%, diopside 20%.
15, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 50%, illite clay 15%, wollastonite 25%, zircon 5%, zinc oxide 5%.
16, the compound method of glaze of glazed coloured wall or floor tiles according to claim 1 and 2 is characterized in that the cover-coat enamel proportioning is: glass fibre raw silk 60%, illite clay 15%, wollastonite 20%, zircon 5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91101273 CN1026889C (en) | 1991-03-04 | 1991-03-04 | Method for compounding glaze of glazed coloured wall or floor tiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91101273 CN1026889C (en) | 1991-03-04 | 1991-03-04 | Method for compounding glaze of glazed coloured wall or floor tiles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1064465A true CN1064465A (en) | 1992-09-16 |
| CN1026889C CN1026889C (en) | 1994-12-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91101273 Expired - Fee Related CN1026889C (en) | 1991-03-04 | 1991-03-04 | Method for compounding glaze of glazed coloured wall or floor tiles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1026889C (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039489C (en) * | 1993-12-21 | 1998-08-12 | 华南理工大学 | Process for producing ceramic clinker clew with szaibelyite |
| CN101838152A (en) * | 2009-04-30 | 2010-09-22 | 山东圣川陶瓷材料有限公司 | Ceramic internal cylinder for dry method cement rotary cement kiln |
| CN101913910A (en) * | 2010-07-30 | 2010-12-15 | 湖南醴陵红官窑瓷业有限公司 | Multicolor furnace transmutation glaze ground coat and manufacturing method thereof |
| CN101306955B (en) * | 2008-07-03 | 2011-05-04 | 醴陵腾瑞工贸有限公司 | Method of making cedar glaze |
| CN102731164A (en) * | 2012-06-27 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Anti-skid glaze for floor tiles |
| CN107777884A (en) * | 2017-11-15 | 2018-03-09 | 金丽梅 | A kind of preparation method of purple glaze |
| CN107793029A (en) * | 2017-11-15 | 2018-03-13 | 金丽梅 | A kind of preparation method of milky white colour glaze |
| CN107804973A (en) * | 2017-11-21 | 2018-03-16 | 常州市奥普泰科光电有限公司 | A kind of ceramic glaze |
| CN111285608A (en) * | 2020-04-22 | 2020-06-16 | 姬存永 | Formula and preparation method of zirconium silicate-free wear-resistant glaze |
| CN113880433A (en) * | 2021-09-29 | 2022-01-04 | 福建省德化弘展艺品有限公司 | Ceramic product prepared by pressureless sintering process |
-
1991
- 1991-03-04 CN CN 91101273 patent/CN1026889C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039489C (en) * | 1993-12-21 | 1998-08-12 | 华南理工大学 | Process for producing ceramic clinker clew with szaibelyite |
| CN101306955B (en) * | 2008-07-03 | 2011-05-04 | 醴陵腾瑞工贸有限公司 | Method of making cedar glaze |
| CN101838152A (en) * | 2009-04-30 | 2010-09-22 | 山东圣川陶瓷材料有限公司 | Ceramic internal cylinder for dry method cement rotary cement kiln |
| CN101838152B (en) * | 2009-04-30 | 2013-06-26 | 山东圣川陶瓷材料有限公司 | Ceramic internal cylinder for dry method cement rotary cement kiln |
| CN101913910A (en) * | 2010-07-30 | 2010-12-15 | 湖南醴陵红官窑瓷业有限公司 | Multicolor furnace transmutation glaze ground coat and manufacturing method thereof |
| CN102731164A (en) * | 2012-06-27 | 2012-10-17 | 卡罗比亚釉料（昆山）有限公司 | Anti-skid glaze for floor tiles |
| CN102731164B (en) * | 2012-06-27 | 2013-12-25 | 卡罗比亚釉料（昆山）有限公司 | Anti-skid glaze for floor tiles |
| CN107777884A (en) * | 2017-11-15 | 2018-03-09 | 金丽梅 | A kind of preparation method of purple glaze |
| CN107793029A (en) * | 2017-11-15 | 2018-03-13 | 金丽梅 | A kind of preparation method of milky white colour glaze |
| CN107804973A (en) * | 2017-11-21 | 2018-03-16 | 常州市奥普泰科光电有限公司 | A kind of ceramic glaze |
| CN111285608A (en) * | 2020-04-22 | 2020-06-16 | 姬存永 | Formula and preparation method of zirconium silicate-free wear-resistant glaze |
| CN113880433A (en) * | 2021-09-29 | 2022-01-04 | 福建省德化弘展艺品有限公司 | Ceramic product prepared by pressureless sintering process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1026889C (en) | 1994-12-07 |
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