CN106432936A - Coating coil for decorating interior wall - Google Patents

Coating coil for decorating interior wall Download PDF

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Publication number
CN106432936A
CN106432936A CN201610774855.9A CN201610774855A CN106432936A CN 106432936 A CN106432936 A CN 106432936A CN 201610774855 A CN201610774855 A CN 201610774855A CN 106432936 A CN106432936 A CN 106432936A
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Prior art keywords
fiber
coiled material
interior wall
decorative coating
polylactic
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CN201610774855.9A
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Chinese (zh)
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李冠辉
严晗
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Individual
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Priority to CN201610774855.9A priority Critical patent/CN106432936A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/10Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to inorganic materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a coating coil for decorating an interior wall. The coating coil comprises an interior wall coating layer, wherein the interior wall coating layer comprises polylactic acid fiber and poplar bark fiber; the length of the polylactic acid fiber is 0.5-1mm and the diameter of the polylactic acid fiber is 0.5mm or lower; the length of the poplar bark fiber is 2-5mm and the diameter of the poplar bark fiber is 0.5mm or lower; the polylactic acid fiber and the poplar bark fiber are added into a coating for the interior wall as an antibacterial agent; the interior wall coating layer comprises the following components in parts by weight: 20-25 parts of calcite powder, 5-15 parts of zinc white powder, 15-25 parts of light calcium carbonate, 20-35 parts of heavy calcium carbonate powder, 15-25 parts of ash calcium powder, 1-5 parts of the polylactic acid fiber and 1-2 parts of the poplar bark fiber.

Description

A kind of inner wall decorative coating coiled material
Technical field
The present invention relates to architectural decoration coating material coiled material, more particularly to a kind of inner wall decorative coating coiled material.
Background technology
Dope for inner wall of architecture is exposed surface area the best part in building, while being also that antibacterial, funguses, mycete multiply Main positions, and antibacterial that these are multiplied, funguses, mycete are very big to the health effect of the mankind.As people are to living quality, life The raising of prescription living, people also gradually pay attention to this problem.Antibacterial employed in current dope for inner wall of architecture Agent is mainly the inorganic salts such as mercury salt class, because the toxicity of its own, has certain injury to human body;Other antimicrobial technology are mainly light Catalyst technology, there are certain requirements to environment, and relatively costly.
Chinese invention patent application 03118030.2 provides one kind《Multifunction environment-protection type nano inner wall coating and its preparation Method》, consisting of:Pure-acrylic emulsion (or styrene-acrylic emulsion), water, sodium hexameta phosphate, dispersant, thickening agent, preservative, nanometer ZnO, Nano-meter SiO_2 #- [2], nano-TiO #- [2], triple superphosphate, titanium dioxide, wollastonite in powder, Pulvis Talci, antifreezing agent, coalescents, stream Flat agent, defoamer.Its preparation method be first by nano-component pretreatment, by uniform for dispersant nano-component and six inclined phosphorus Sour sodium and dispersant are added to the water stirring, then add remaining component step by step, are uniformly dispersed, and fill gets product.
Chinese invention patent application 99117416.X is given《A kind of interior wall coating with sterilizing function》, the coating And be made up with nano zine oxide (nano-ZnO) of filler, nontoxic, tasteless, non-stimulated to skin, and pathogenic bacteria, virus can be killed As staphylococcus aureuses, escherichia coli, killing rate is all more than 90%.
Chinese invention patent application 03108996.8 is given《Jade interior wall coating and preparation method》, be by auxiliary agent, Jade powder, antibacterial and water composition, antibacterial therein is saturation silver solution, has killing function to indoor unicellular mushroom.
The antibacterial for interior wall coating for being given in technique scheme, though kill multiple mycetes, go to eliminate the unusual smell with suppression Etc. function, but the material for adding is high-tech nano material or noble metal, its complicated process of preparation, relatively costly, indirect shadow Ring the market outlet of interior wall coating.
Dope for inner wall of architecture is exposed surface area the best part in building, while being also that antibacterial, funguses, mycete multiply Main positions, and antibacterial that these are multiplied, funguses, mycete are very big to the health effect of the mankind.
With the raising that people were required to living quality, quality of life, people also gradually pay attention to this problem.
Content of the invention
The technical problem to be solved in the present invention is for above not enough, provides inner wall decorative coating coiled material, the inner wall decoration The construction of coating coiled material is rapid, with sterilizing function.
For solving above technical problem, the present invention is employed the following technical solutions:
Inner wall decorative coating coiled material, it is characterised in that:Including interior wall coating layer, the interior wall coating layer include acid fiber by polylactic and Willow hide fiber, acid fiber by polylactic 0.5-1mm length, below diameter 0.5mm, the willow hide fiber 2-5mm length, diameter 0.5mm Hereinafter, the acid fiber by polylactic and willow hide fiber are added in interior wall coating as antibacterial.
The following is the improvement further to technique scheme:
Interior wall coating layer includes calcite powder 20-25 part, zinc oxide powder 5-15 part, precipitated calcium carbonate 15-25 part, dry powder 20- 35 parts, sierozem power 15-25 part, acid fiber by polylactic 1-5 part, willow hide fiber 1-2 part.
Also include high polymer layer, described high polymer layer is polystyrene, polyethylene, the poly- second of metallocene At least one in alkene, polypropylene, metallocene polypropylene, polyethylene terephthalate, polycaprolactam.
The method of inner wall decorative coating coiled material, 1)By described calcite powder, zinc oxide powder, precipitated calcium carbonate, dry powder, Sierozem power, acid fiber by polylactic, willow hide fiber, after mix homogeneously, dispersing apparatus are added, inorganic particle is made with Chinese white interface It is fully contacted, and dispersed;
2)By step 1)The material that obtains introduces high-speed mixer, adds grafting agent, described, 80-140 DEG C of temperature conditionss, 15-30min is reacted under 900-1500r/min stirring condition;
3)Lubricating auxiliary agent, stabilizer are added in above-mentioned high-speed mixer, in 100-140 DEG C of temperature conditionss, 900-1500r/min 5-10min is reacted under stirring condition;
4)High molecular polymer is added and is uniformly mixed in above-mentioned high-speed mixing equipment;
5)The material of above-mentioned mix homogeneously is introduced extrusion calendaring stretcher, by reactive extrursion, rolled, stretch, batching To a kind of inner wall decorative coating coiled material.
Described grafting agent is methyl methacrylate, poly- butylacrylic acid, at least one in maleic anhydride.
Dispersing apparatus are three chamber continuous way eddy airstream refining machines.
Extrusion calendaring stretcher selects screw extruder.
The willow hide fiber is that manually grinding is formed in 90 DEG C of oven drying at low temperatures by natural Cortex Populi Davidianae.
During construction, the present invention can be attached directly on metope, measure after use in 1 year through test, antibiotic rate can reach 99%;Using in rear 1-3, antibiotic rate can reach more than 95%.
With reference to embodiment, the present invention is described in detail.
Specific embodiment
Embodiment, inner wall decorative coating coiled material, including interior wall coating layer, the interior wall coating layer include acid fiber by polylactic and Willow hide fiber, acid fiber by polylactic 0.5-1mm length, below diameter 0.5mm, the willow hide fiber 2-5mm length, diameter 0.5mm Hereinafter, the acid fiber by polylactic and willow hide fiber are added in interior wall coating as antibacterial.
Interior wall coating layer includes calcite powder 20-25 part, zinc oxide powder 5-15 part, precipitated calcium carbonate 15-25 part, dry powder 20-35 part, sierozem power 15-25 part, acid fiber by polylactic 1-5 part, willow hide fiber 1-2 part.
Also include high polymer layer, described high polymer layer is polystyrene, polyethylene, the poly- second of metallocene At least one in alkene, polypropylene, metallocene polypropylene, polyethylene terephthalate, polycaprolactam.
The method of inner wall decorative coating coiled material, 1)By described calcite powder, zinc oxide powder, precipitated calcium carbonate, dry powder, Sierozem power, acid fiber by polylactic, willow hide fiber, after mix homogeneously, dispersing apparatus are added, inorganic particle is made with Chinese white interface It is fully contacted, and dispersed;
2)By step 1)The material that obtains introduces high-speed mixer, adds grafting agent, described, 80-140 DEG C of temperature conditionss, 15-30min is reacted under 900-1500r/min stirring condition;
3)Lubricating auxiliary agent, stabilizer are added in above-mentioned high-speed mixer, in 100-140 DEG C of temperature conditionss, 900-1500r/min 5-10min is reacted under stirring condition;
4)High molecular polymer is added and is uniformly mixed in above-mentioned high-speed mixing equipment;
5)The material of above-mentioned mix homogeneously is introduced extrusion calendaring stretcher, by reactive extrursion, rolled, stretch, batching To a kind of inner wall decorative coating coiled material.
Described grafting agent is methyl methacrylate, poly- butylacrylic acid, at least one in maleic anhydride.
Dispersing apparatus are three chamber continuous way eddy airstream refining machines.
Extrusion calendaring stretcher selects screw extruder.
The willow hide fiber is that manually grinding is formed in 90 DEG C of oven drying at low temperatures by natural Cortex Populi Davidianae.
During construction, the present invention can be attached directly on metope, measure after use in 1 year through test, antibiotic rate can reach 99%;Using in rear 1-3, antibiotic rate can reach more than 95%.

Claims (7)

1. inner wall decorative coating coiled material, it is characterised in that:Including interior wall coating layer, the interior wall coating layer includes acid fiber by polylactic With willow hide fiber, acid fiber by polylactic 0.5-1mm length, below diameter 0.5mm, the willow hide fiber 2-5mm length, diameter Below 0.5mm, the acid fiber by polylactic and willow hide fiber are added in interior wall coating as antibacterial.
2. inner wall decorative coating coiled material according to claim 1, it is characterised in that:Interior wall coating layer includes calcite powder 20-25 part, zinc oxide powder 5-15 part, precipitated calcium carbonate 15-25 part, dry powder 20-35 part, sierozem power 15-25 part, acid fiber by polylactic 1-5 part, willow hide fiber 1-2 part.
3. inner wall decorative coating coiled material according to claim 2, it is characterised in that:Also include high polymer layer, institute High polymer layer is stated for polystyrene, polyethylene, metallocene PE, polypropylene, metallocene polypropylene, poly- terephthaldehyde At least one in sour second diester, polycaprolactam.
4. the method for preparing the inner wall decorative coating coiled material described in claim 3, it is characterised in that:
1)By described calcite powder, zinc oxide powder, precipitated calcium carbonate, dry powder, sierozem power, acid fiber by polylactic, Cortex Populi Davidianae fibre Dimension, after mix homogeneously, is added dispersing apparatus, so that inorganic particle is fully contacted with Chinese white interface, and dispersed;
2)By step 1)The material that obtains introduces high-speed mixer, adds grafting agent, described, 80-140 DEG C of temperature conditionss, 15-30min is reacted under 900-1500r/min stirring condition;
3)Lubricating auxiliary agent, stabilizer are added in above-mentioned high-speed mixer, in 100-140 DEG C of temperature conditionss, 900-1500r/min 5-10min is reacted under stirring condition;
4)High molecular polymer is added and is uniformly mixed in above-mentioned high-speed mixing equipment;
5)The material of above-mentioned mix homogeneously is introduced extrusion calendaring stretcher, by reactive extrursion, rolled, stretch, batching To a kind of inner wall decorative coating coiled material.
5. the method for inner wall decorative coating coiled material as claimed in claim 4, it is characterised in that described grafting agent be At least one in e pioic acid methyl ester, poly- butylacrylic acid, maleic anhydride.
6. the method for preparing inner wall decorative coating coiled material as claimed in claim 5, it is characterised in that:Dispersing apparatus are that three chambeies are continuous Formula eddy airstream refining machine.
7. the method for preparing inner wall decorative coating coiled material as claimed in claim 6, it is characterised in that:Extrusion calendaring stretcher is selected Use screw extruder.
CN201610774855.9A 2016-08-31 2016-08-31 Coating coil for decorating interior wall Pending CN106432936A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107841115A (en) * 2017-11-16 2018-03-27 周昭金 Add the preparation technology of the anti-corrosion waterproof roll of nano-sized carbon

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1422913A (en) * 2002-12-25 2003-06-11 王仙桃 Water-based ceramic-imitating coating
CN1748513A (en) * 2005-10-19 2006-03-22 沈阳建筑大学 Antibacterial agent for inner wall paint and its preparing method
CN102557518A (en) * 2011-12-28 2012-07-11 成都新柯力化工科技有限公司 Interior wall coating coil and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1422913A (en) * 2002-12-25 2003-06-11 王仙桃 Water-based ceramic-imitating coating
CN1748513A (en) * 2005-10-19 2006-03-22 沈阳建筑大学 Antibacterial agent for inner wall paint and its preparing method
CN102557518A (en) * 2011-12-28 2012-07-11 成都新柯力化工科技有限公司 Interior wall coating coil and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张大省等: "《图解纤维材料》", 31 August 2015 *
贺又顺等: "《湖南药物志 第3卷》", 31 December 2004 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107841115A (en) * 2017-11-16 2018-03-27 周昭金 Add the preparation technology of the anti-corrosion waterproof roll of nano-sized carbon

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