CN106430999A - Mass-colored emerald green glass and coating manufacturing method thereof - Google Patents
Mass-colored emerald green glass and coating manufacturing method thereof Download PDFInfo
- Publication number
- CN106430999A CN106430999A CN201610536778.3A CN201610536778A CN106430999A CN 106430999 A CN106430999 A CN 106430999A CN 201610536778 A CN201610536778 A CN 201610536778A CN 106430999 A CN106430999 A CN 106430999A
- Authority
- CN
- China
- Prior art keywords
- tio
- glass substrate
- glass
- coating
- emerald green
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 208
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 title claims abstract description 80
- 238000000576 coating method Methods 0.000 title claims abstract description 74
- 239000011248 coating agent Substances 0.000 title claims abstract description 71
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 239000000758 substrate Substances 0.000 claims abstract description 97
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 78
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 7
- 239000002699 waste material Substances 0.000 claims description 86
- 238000004040 coloring Methods 0.000 claims description 62
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 32
- 239000003795 chemical substances by application Substances 0.000 claims description 27
- 238000007747 plating Methods 0.000 claims description 24
- 238000005507 spraying Methods 0.000 claims description 8
- 230000005540 biological transmission Effects 0.000 claims description 6
- 230000008021 deposition Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 7
- 239000003086 colorant Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 description 37
- 239000010410 layer Substances 0.000 description 32
- QPLDLSVMHZLSFG-UHFFFAOYSA-N CuO Inorganic materials [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 12
- 238000002834 transmittance Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000000151 deposition Methods 0.000 description 6
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229940069428 antacid Drugs 0.000 description 3
- 239000003159 antacid agent Substances 0.000 description 3
- 230000001458 anti-acid effect Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 so Afterwards Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000013475 authorization Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000007888 film coating Substances 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 210000001951 dura mater Anatomy 0.000 description 1
- 238000013003 hot bending Methods 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2456—Coating containing TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
Abstract
The invention discloses a mass-colored emerald green glass. The mass-colored emerald green glass comprises a glass substrate, the glass substrate includes a coloring agent, and the coloring agent comprises, by mass, 0.08-0.1% of Fe2O3, 0.1-0.28% of CuO and 0.3-0.5% of TiO2; and the surface of one side of the glass substrate is coated with a TiO2 coating, and the TiO2 coating is a three-layer TiO2 coating deposited on the glass substrate in a laminar flow manner. The glass is bright and clear, the coating is uniform and firm, and the glass has good wear resistance and high chemical stability, and has better alkali and acid resistance than other pieces of coated glass. The invention also discloses a coating manufacturing for producing the mass-colored emerald green glass. The emerald green glass produced through using the coating manufacturing method keeps the original color of glass, and has high output and high qualified product rate.
Description
Technical field
The invention belongs to coating film on glass technical field, more particularly, to a kind of mass colouring emerald green glass and its plated film manufacture
Method.
Background technology
With people, the requirement of construction material performance, color and purposes is increasingly improved, shades of colour glass or
Functional glass constantly occurs in face of people, and wherein emerald green glass is relatively common glass in people's daily life
One of product.So that emerald green glass has more sophisticated specific function, generally in emerald green glass in prior art
On carry out plated film.Good color and luster and shaded effects are had by the emerald green glass of plated film, is deeply liked by people.
In prior art, Authorization Notice No. is that the patent of CN20194908Y discloses a kind of single-layer silicon nitride titanium film of being coated with
Sunlight controlling coated glass, its film plating process mainly adopts offline process；Authorization Notice No. is that CN101654334A patent is public
Open a kind of off-line pale green low radiation coated glass and preparation method thereof, be also that film layer is coated with white glass using offline mode
It is made to have emerald green color and identical or better performance effect after plated film；Application publication number is CN103144381A
Patent application disclose a kind of green low radiation energy-saving glass be also with white glass for film plating substrate adopt offline mode plated film after
Obtain having and green glass identical glass colour and effect.It can be seen that, in prior art many using being coated with emerald green glass offline
Film layer.
On-line film coating method refers to molten tin bath on floatation glass production line, transition roller table or annealing kiln front end, using life
In producing line, the compound spraying on glass surface is carried out decomposing, spreads by the heat of glass itself, forms oxygen in glass surface
Compound low-radiation film.This oxide membranous layer has become as a part for glass surface composition, is referred to as " dura mater " or online film.
Compare off-line coated, on-line film coating method has following outstanding feature：(1) one line dual-purpose, regulation produce spirit
Live, float glass line is produced using chemical vapour deposition technique (CVD), can be according to its product of market demand flexible modulation
Kind, both can produce float glass, also can produce coated glass；(2) product can carry out deep processing, uses chemical vapour deposition technique
After the coated glass producing is processed through rigidifying, hot bending, film layer and its color all do not change；(3) product good physical and chemical properties, use
Its film layer of coated glass that chemical vapour deposition technique produces firmly, wearability, resistance to acids and bases and good salt tolerance.
At present, because the plated film area of on-line coating glass is big, the limitation of plated film equipment manufacturing technology and film plating process
Etc. reason, the yield of online production coated glass and yield rate all have much room for improvement.
Content of the invention
The technical problem to be solved is to overcome the shortcomings of to mention and defect in background above technology, provide one
Kind of mass colouring emerald green glass (coated glass), this glass becomes clear exquisitely carved, and coating is uniformly firmly, wearability is good, chemically stable
Property high, alkaline-resisting Antacid effectiveness be better than other coated glasses.Present invention also offers a kind of produce the emerald green glass of above-mentioned mass colouring
The film-plating method of glass, can keep the original color of glass using the mass colouring emerald green glass that this film plating process produces,
And its yield and product percent of pass are all higher.
For solving above-mentioned technical problem, technical scheme proposed by the present invention is：
A kind of mass colouring emerald green glass, including glass substrate, includes colouring agent in described glass substrate, described
Toner includes accounting for each component of the following percentage by weight of glass substrate：0.08-0.1%Fe2O3, 0.1-0.28%CuO, 0.3-
0.5%TiO2；It is coated with TiO on one side surface of glass substrate2Coating, described TiO2Coating is in glass substrate with layer flow mode
Three layers of TiO of upper deposition2Coating, is added with TiO in colouring agent2, improve the Ti content of glass surface, and then improve glass
Surface is to plated film gas (TiO2) suction-operated, this glass plates TiO2After coating, firmly, wearability is good for even film layer, chemistry
Stability is high, and alkaline-resisting Antacid effectiveness is better than other coated glasses；In addition, adding this colouring agent to make glass more in glass substrate
Bright exquisitely carved, and Fe2O3Addition with CuO solves TiO2The glass excessively introducing and leading to produces the problem of yellow；Using layer
The mode of stream carries out plated film, three deposition film forming of a plated film, while improve film quality, improves to plated film gas
(TiO2) utilization rate, decrease waste gas discharge.
Above-mentioned mass colouring emerald green glass is it is preferred that described TiO2The gross thickness of coating is 700-800nm；Glass
The thickness of substrate is 3.6-6mm.
Above-mentioned mass colouring emerald green glass is it is preferred that the visible transmission ratio of described mass colouring emerald green glass
Less than 26%, color homogeneity is less than or equal to 2.0, and ultraviolet ray transmissivity is less than or equal to 12%, and wearability is more than or equal to
1.1, acid resistance is more than 0.20%, and alkali resistance is more than 0.60%, and shading coefficient is less than 0.25, compared to existing emerald green plated film
Glass, the properties of the emerald green coated glass (mass colouring emerald green glass) of the present invention all increase.
As a total inventive concept, another aspect of the present invention provides a kind of above-mentioned mass colouring emerald green glass
Film-plating method, comprises the following steps：
S1, emerald green glass substrate is placed in the bottom of coating apparatus, makes this glass substrate from the lower section in the first waste discharge chamber
The lower section conveying in the useless chamber of the lower direction second row through inlet chamber, includes colouring agent in described emerald green glass substrate, described
Toner includes accounting for each component of the following percentage by weight of emerald green glass substrate：0.08-0.1%Fe2O3；0.1-0.28%CuO；
0.3-0.5%TiO2；
S2, TiO is passed through into inlet chamber by air inlet pipe2Gas, deposits three layers in the way of laminar flow on a glass substrate
TiO2Coating, that is, complete the coating operation of emerald green glass substrate.
Above-mentioned film-plating method is it is preferred that in described step S2, deposit three on a glass substrate in the way of laminar flow
Layer TiO2Coating specifically refers to, the TiO in inlet chamber2Gas is divided into two flow directions after spout ejection, respectively along the first reaction zone
Enter the first waste discharge chamber from the first waste discharge mouth and along second reaction zone from second waste discharge mouth entrance the second waste discharge chamber；Glass substrate
With the TiO inversely flowing through at the first reaction zone2Gas contacts and forms ground floor TiO2Coating；Glass substrate is under spout
The TiO that Fang Yucong spout sprays2Gas contact forms second layer TiO2Coating；Glass substrate is at second reaction zone and concurrent
Dynamic TiO2Gas forms third layer TiO2Coating.
It is preferred that in described step S1, glass substrate is from the lower section in the first waste discharge chamber through entering for above-mentioned film-plating method
The transporting velocity of the lower section conveying in the useless chamber of the lower direction second row of air cavity is 460-650m/h.
Above-mentioned film-plating method is it is preferred that in described step S2, be passed through TiO into inlet chamber2In gas-operated
TiO2The flow of gas is 550-650L/min.
Compared with prior art, it is an advantage of the current invention that：
(1) pass through to add the Fe including 0.08-0.1% in glass substrate2O3, the CuO of 0.1-0.28%, 0.3-
0.5% TiO2Colouring agent exquisitely carved, and Fe so that this emerald green glass becomes clear2O3Addition with CuO compensate for TiO2Excessive
The glass introducing and leading to produces the defect of yellow.
(2) using TiO in colouring agent2Improve the TiO of glass surface2Content, and then improve glass surface to plated film
Gas (TiO2) suction-operated so that glass film layers after plated film are uniformly firm, wearability is good, and chemical stability is high, resistance to
Alkali Antacid effectiveness is better than other coated glasses.
(3) plated film is carried out using layer flow mode, one time plated film deposits film forming three times, while ensureing film quality,
Improve to plated film gas (TiO2) utilization rate, decrease waste gas discharge.
Brief description
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
Have technology description in required use accompanying drawing be briefly described it should be apparent that, drawings in the following description are the present invention
Some embodiments, for those of ordinary skill in the art, on the premise of not paying creative work, can also basis
These accompanying drawings obtain other accompanying drawings.
Fig. 1 is the structural representation of the coating apparatus used by film-plating method of the present invention.
Fig. 2 is the cross section structure diagram in the B-B face along along Fig. 1.
Marginal data：
1st, the first waste discharge chamber；2nd, inlet chamber；3rd, the second waste discharge chamber；4th, the first waste discharge mouth；5th, the second waste discharge mouth；6th, spout；
7th, the first reaction zone；8th, second reaction zone；9th, waste pipe；10th, air inlet pipe.
Specific embodiment
For the ease of understanding the present invention, below in conjunction with Figure of description and preferred embodiment, the present invention is made more complete
Face, meticulously describe, but protection scope of the present invention is not limited to embodiment in detail below.
It should be strongly noted that when a certain element is described as on " being connected to " another element, it can be direct
It is connected on another element or be indirectly coupled on another element by other intermediate connectors.
Unless otherwise defined, the implication that all technical terms used hereinafter are generally understood that with those skilled in the art
Identical.Technical term used herein is intended merely to describe the purpose of specific embodiment, is not intended to limit the present invention
Protection domain.
Unless otherwise specified, the various raw material used in the present invention, reagent, instrument and equipment etc. all can pass through city
Field is commercially available or can be prepared by existing method.
Embodiment 1
A kind of mass colouring emerald green glass (coated glass) of the present embodiment, this mass colouring emerald green glass includes glass
Glass substrate, includes colouring agent in glass substrate, the primary chemical of colouring agent becomes Fe2O3, CuO and TiO2, its content is respectively
The 0.1% of glass substrate weight, 0.28% and 0.5%.It is coated with TiO on one side surface of this glass substrate2Coating, this TiO2Plating
Layer is the three layers of coating being plated successively on a glass substrate in the way of laminar flow, wherein, TiO2The gross thickness of coating is 700nm,
The thickness of glass substrate is 3.6mm.
As depicted in figs. 1 and 2, the coating apparatus used by mass colouring emerald green glass producing the present embodiment are included successively
The first waste discharge chamber 1, inlet chamber 2 and the second waste discharge chamber 3 being set up in parallel, the bottom in this first waste discharge chamber 1 and the second waste discharge chamber 3 is divided
Be not provided with the first waste discharge mouth 4 and the second waste discharge mouth 5, the bottom of inlet chamber 2 is provided with spout 6, this spout 6 and the first waste discharge mouth 4 it
Between form the first reaction zone 7, form second reaction zone 8, spout 6 and emerald green glass substrate between spout 6 and the second waste discharge mouth 5
Wide, the first waste discharge chamber 1 is all connected with a waste pipe 9 with the top in the second waste discharge chamber 3, the top of inlet chamber 2 and an air inlet pipe
10 are connected.
The film-plating method of the mass colouring emerald green glass of the present embodiment is as follows：By air inlet pipe 11 to inlet chamber 2
Inside it is passed through TiO2Gas, emerald green glass substrate (is included colouring agent in this emerald green glass substrate, this colouring agent includes accounting for
Each component of the following percentage by weight of glass substrate：0.08-0.1%Fe2O3；0.1-0.28%CuO；0.3-0.5%TiO2) put
In the bottom of coating apparatus, make the useless chamber 3 of the lower direction second row from the lower section in the first waste discharge chamber 1 through inlet chamber 2 for the glass substrate
Lower section conveying, the TiO in inlet chamber 22The spout 6 from bottom for the gas is divided into two flow directions after spraying, and a part of gas is along first
Reaction zone 7 enters the first waste discharge chamber 1 from the first waste discharge mouth 4, and another part gas enters along second reaction zone 8 from the second waste discharge mouth 5
Enter the second waste discharge chamber 3, glass substrate is in the lower section of the first reaction zone 7 and the TiO inversely flowing through2Gas contact forms ground floor
TiO2Coating, glass substrate is in the lower section of spout 6 and the TiO spraying from spout 62Gas contact forms second layer TiO2Coating, so
Afterwards, glass substrate continues on to the lower section of second reaction zone 8 and the TiO of co-flow2Gas forms third layer TiO2Coating,
Complete plated film, in glass substrate surface three layers of TiO of coated film deposition2Coating, the mass colouring obtaining the present invention is emerald green
Glass.TiO after plated film2Gas enters the first waste discharge chamber 1 and the second waste discharge from the first waste discharge mouth 4 and the second waste discharge mouth 5 respectively
Chamber 3, then is collected discharging by the waste pipe 9 located at the first waste discharge chamber 1 and the second waste discharge chamber 3 top.In coating process,
The transporting velocity of glass substrate is 460m/h, is passed through TiO into inlet chamber 22The flow of gas is 550L/min.
The performance comparison data before and after mass colouring emerald green glass plated film in the present embodiment is as shown in table 1.Wherein, may be used
See that transmittance and ultraviolet ray transmissivity are tested using UV3600 ultraviolet specrophotometer；Color homogeneity adopts color color
Difference meter is tested；Resistance to acids and bases test is tested using 24h in the hydrochloric acid that sample steeps 1N or sodium hydroxide solution；Resistance to
The test of mill property is carried out on abrasiometer；Shading coefficient adopts standard GB/T/T2680-94 building glass visible transmission
Than, sunshine direct transmittance, total solar energy transmittance, when the assay method about glass pane parameter is carried out ultraviolet (uv) transmission
Test.
The performance comparison data before and after mass colouring emerald green glass plated film in table 1 the present embodiment
As shown in Table 1, after the mass colouring emerald green glass plated film of the present embodiment, color is uniform, and ultraviolet ray transmissivity is low,
Less than 26%, shading coefficient is less than 0.25 to visible transmission ratio；Color homogeneity (△ E*ab)≤2.0, wearability is more than or waits
In 1.1, acid resistance is more than 0.20%, and alkali resistance is more than 0.60%.
Embodiment 2
A kind of mass colouring emerald green glass of the present embodiment, this mass colouring emerald green glass includes glass substrate, glass
Colouring agent is included, the primary chemical of colouring agent becomes Fe in glass substrate2O3, CuO and TiO2, its content is respectively glass substrate
The 0.08% of weight, 0.1% and 0.3%.It is coated with TiO on one side surface of this glass substrate2Coating, this TiO2Coating is with layer
Three layers of coating that the mode of stream plates on a glass substrate successively, wherein, TiO2The gross thickness of coating is 800nm, glass substrate
Thickness be 6mm.
As depicted in figs. 1 and 2, the coating apparatus used by mass colouring emerald green glass producing the present embodiment are included successively
The first waste discharge chamber 1, inlet chamber 2 and the second waste discharge chamber 3 being set up in parallel, the bottom in this first waste discharge chamber 1 and the second waste discharge chamber 3 is divided
Be not provided with the first waste discharge mouth 4 and the second waste discharge mouth 5, the bottom of inlet chamber 2 is provided with spout 6, this spout 6 and the first waste discharge mouth 4 it
Between form the first reaction zone 7, form second reaction zone 8, spout 6 and emerald green glass substrate between spout 6 and the second waste discharge mouth 5
Wide, the first waste discharge chamber 1 is all connected with a waste pipe 9 with the top in the second waste discharge chamber 3, the top of inlet chamber 2 and an air inlet pipe
10 are connected.
The film-plating method of the mass colouring emerald green glass of the present embodiment is as follows：By air inlet pipe 11 to inlet chamber 2
Inside it is passed through TiO2Gas, emerald green glass substrate (is included colouring agent in this emerald green glass substrate, this colouring agent includes accounting for
Each component of the following percentage by weight of glass substrate：0.08-0.1%Fe2O3；0.1-0.28%CuO；0.3-0.5%TiO2) put
In the bottom of coating apparatus, make the useless chamber 3 of the lower direction second row from the lower section in the first waste discharge chamber 1 through inlet chamber 2 for the glass substrate
Lower section conveying, the TiO in inlet chamber 22The spout 6 from bottom for the gas is divided into two flow directions after spraying, and a part of gas is along first
Reaction zone 7 enters the first waste discharge chamber 1 from the first waste discharge mouth 4, and another part gas enters along second reaction zone 8 from the second waste discharge mouth 5
Enter the second waste discharge chamber 3, glass substrate is in the lower section of the first reaction zone 7 and the TiO inversely flowing through2Gas contact forms ground floor
TiO2Coating, glass substrate is in the lower section of spout 6 and the TiO spraying from spout 62Gas contact forms second layer TiO2Coating, so
Afterwards, glass substrate continues on to the lower section of second reaction zone 8 and the TiO of co-flow2Gas forms third layer TiO2Coating,
Complete plated film, in glass substrate surface three layers of TiO of coated film deposition2Coating, the mass colouring obtaining the present invention is emerald green
Glass.TiO after plated film2Gas enters the first waste discharge chamber 1 and the second waste discharge from the first waste discharge mouth 4 and the second waste discharge mouth 5 respectively
Chamber 3, then is collected discharging by the waste pipe 9 located at the first waste discharge chamber 1 and the second waste discharge chamber 3 top.In coating process,
The transporting velocity of glass substrate is 650m/h, is passed through TiO into inlet chamber 22The flow of gas is 650L/min.This body
Transmittance after color emerald green glass plated film, ultraviolet ray transmissivity, color homogeneity, wearability, acid resistance, alkali resistance and sunshade
Coefficient is tested (method of testing is same as Example 1), and test result is shown in Table 2.
Embodiment 3
A kind of mass colouring emerald green glass of the present embodiment, this mass colouring emerald green glass includes glass substrate, glass
Colouring agent is included, the primary chemical of colouring agent becomes Fe in glass substrate2O3, CuO and TiO2, its content is respectively glass substrate
The 0.09% of weight, 0.19% and 0.4%.It is coated with TiO on one side surface of this glass substrate2Coating, this TiO2Coating is with layer
Three layers of coating that the mode of stream plates on a glass substrate successively, wherein, TiO2The gross thickness of coating is 750nm, glass substrate
Thickness be 4.8mm.
As depicted in figs. 1 and 2, the coating apparatus used by mass colouring emerald green glass producing the present embodiment are included successively
The first waste discharge chamber 1, inlet chamber 2 and the second waste discharge chamber 3 being set up in parallel, the bottom in this first waste discharge chamber 1 and the second waste discharge chamber 3 is divided
Be not provided with the first waste discharge mouth 4 and the second waste discharge mouth 5, the bottom of inlet chamber 2 is provided with spout 6, this spout 6 and the first waste discharge mouth 4 it
Between form the first reaction zone 7, form second reaction zone 8, spout 6 and emerald green glass substrate between spout 6 and the second waste discharge mouth 5
Wide, the first waste discharge chamber 1 is all connected with a waste pipe 9 with the top in the second waste discharge chamber 3, the top of inlet chamber 2 and an air inlet pipe
10 are connected.
The film-plating method of the mass colouring emerald green glass of the present embodiment is as follows：By air inlet pipe 11 to inlet chamber 2
Inside it is passed through TiO2Gas, emerald green glass substrate (is included colouring agent in this emerald green glass substrate, this colouring agent includes accounting for
Each component of the following percentage by weight of glass substrate：0.08-0.1%Fe2O3；0.1-0.28%CuO；0.3-0.5%TiO2) put
In the bottom of coating apparatus, make the useless chamber 3 of the lower direction second row from the lower section in the first waste discharge chamber 1 through inlet chamber 2 for the glass substrate
Lower section conveying, the TiO in inlet chamber 22The spout 6 from bottom for the gas is divided into two flow directions after spraying, and a part of gas is along first
Reaction zone 7 enters the first waste discharge chamber 1 from the first waste discharge mouth 4, and another part gas enters along second reaction zone 8 from the second waste discharge mouth 5
Enter the second waste discharge chamber 3, glass substrate is in the lower section of the first reaction zone 7 and the TiO inversely flowing through2Gas contact forms ground floor
TiO2Coating, glass substrate is in the lower section of spout 6 and the TiO spraying from spout 62Gas contact forms second layer TiO2Coating, so
Afterwards, glass substrate continues on to the lower section of second reaction zone 8 and the TiO of co-flow2Gas forms third layer TiO2Coating,
Complete plated film, in glass substrate surface three layers of TiO of coated film deposition2Coating, the mass colouring obtaining the present invention is emerald green
Glass.TiO after plated film2Gas enters the first waste discharge chamber 1 and the second waste discharge from the first waste discharge mouth 4 and the second waste discharge mouth 5 respectively
Chamber 3, then is collected discharging by the waste pipe 9 located at the first waste discharge chamber 1 and the second waste discharge chamber 3 top.In coating process,
The transporting velocity of glass substrate is 550m/h, is passed through TiO into inlet chamber 22The flow of gas is 600L/min.This body
Transmittance after color emerald green glass plated film, ultraviolet ray transmissivity, color homogeneity, wearability, acid resistance, alkali resistance and sunshade
Coefficient is tested (method of testing is same as Example 1), and test result is shown in Table 2.
Comparative example 1
A kind of emerald green coated glass not adding colouring agent of the present invention in glass substrate, this emerald green coated glass bag
Include glass substrate, a side surface of this glass substrate is coated with TiO2Coating, this TiO2Coating is in glass base in the way of laminar flow
The three layers of coating plating successively on piece.The coating apparatus of this emerald green coated glass and film plating process all with embodiment 1 and implementing
Consistent in example 2.To the transmittance after this emerald green coated glass plated film, ultraviolet ray transmissivity, color homogeneity and sunshade system
Number is tested (method of testing is identical with the method in embodiment 1 and embodiment 2), and test result is shown in Table 2.
Comparative example 2
A kind of emerald green coated glass not obtained using the film plating process of the present invention, this emerald green coated glass includes glass
Glass substrate, includes colouring agent in glass substrate, the primary chemical of colouring agent becomes Fe2O3, CuO and TiO2, its content is respectively
The 0.1% of glass substrate weight, 0.28% and 0.5%.It is coated with TiO on one side surface of this glass substrate2Coating.
The coating apparatus of this emerald green coated glass and film plating process adopt existing online CVD vapor phase growing apparatus and side
Method.To the visible transmission ratio after this emerald green coated glass plated film, ultraviolet ray transmissivity, color homogeneity and shading coefficient
Tested (method of testing is identical with the method in embodiment 1 and embodiment 2), test result is shown in Table 2.
Table 2 embodiment 1, embodiment 2, the performance of embodiment 3, comparative example 1 and the emerald green coated glass of comparative example 2 gained
Correction data
As shown in Table 2, Example 1 and Example 2 of the present invention with the addition of colouring agent in emerald green glass body, and makes
With the distinctive coating apparatus of the present invention three layers of TiO of in the way of laminar flow coated film deposition2Coating, obtained emerald green plated film
The items such as the transmittance of glass (mass colouring emerald green glass), uv transmittance, color homogeneity and shading coefficient
Can be superior in comparative example 1 do not add in glass substrate in colouring agent of the present invention and comparative example 2 not using the present invention
Coated glass obtained by distinctive film-plating method, and the emerald green coated glass of Example 1 and Example 2 of the present invention is resistance to
Mill property and resistance to acids and bases are all preferable.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, made any repair
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (7)
1. a kind of mass colouring emerald green glass, including glass substrate it is characterised in that including coloring in described glass substrate
Agent, described colouring agent includes accounting for each component of the following percentage by weight of glass substrate：0.08-0.1%Fe2O3；0.1-0.28%
CuO；0.3-0.5%TiO2；It is coated with TiO on one side surface of glass substrate2Coating, described TiO2Coating is to be existed with layer flow mode
Three layers of TiO of deposition on glass substrate2Coating.
2. mass colouring emerald green glass according to claim 1 it is characterised in that：Described TiO2The gross thickness of coating is
700-800nm；The thickness of glass substrate is 3.6-6mm.
3. mass colouring emerald green glass according to claim 1 and 2 it is characterised in that：Described mass colouring is emerald green
Less than 26%, ultraviolet ray transmissivity is less than or equal to 12% to the visible transmission ratio of glass, and color homogeneity is less than or equal to
1.95, wearability is more than or equal to 1.1, and acid resistance is more than 0.20%, and alkali resistance is more than 0.60%, and shading coefficient is less than 0.25.
4. a kind of film-plating method of the mass colouring emerald green glass as any one of claim 1-3, including with
Lower step：
S1, emerald green glass substrate is placed in the bottom of coating apparatus, makes this glass substrate from the lower section warp in the first waste discharge chamber (1)
The lower section conveying in the useless chamber (3) of the lower direction second row of inlet chamber (2), includes colouring agent in described emerald green glass substrate, institute
State colouring agent to include accounting for each component of the following percentage by weight of emerald green glass substrate：0.08-0.1%Fe2O3；0.1-0.28%
CuO；0.3-0.5%TiO2；
S2, TiO is passed through into inlet chamber (2) by air inlet pipe (11)2Gas, deposits three in the way of laminar flow on a glass substrate
Layer TiO2Coating, that is, complete the coating operation of emerald green glass substrate.
5. film-plating method according to claim 4 is it is characterised in that in described step S2, in the way of laminar flow
Three layers of TiO are deposited on glass substrate2Coating specifically refers to：TiO in inlet chamber (2)2Gas is divided into two after spout (6) ejection
Individual flow direction, enters the first waste discharge chamber (1) and along second reaction zone (8) along the first reaction zone (7) from the first waste discharge mouth (4) respectively
Enter the second waste discharge chamber (3) from the second waste discharge mouth (5)；Glass substrate is in the first reaction zone (7) place and the TiO inversely flowing through2Gas
Body contacts and forms ground floor TiO2Coating；Glass substrate is in the lower section of spout (6) and the TiO spraying from spout (6)2Gas connects
Touch and form second layer TiO2Coating；Glass substrate is in the TiO at second reaction zone (8) place and co-flow2Gas forms third layer
TiO2Coating.
6. the film-plating method according to claim 4 or 5 it is characterised in that：In described step S1, glass substrate is from
The transporting velocity of the lower section conveying in the useless chamber (3) of the lower direction second row through inlet chamber (2) for the lower section in one waste discharge chamber (1) is 460-
650m/h.
7. the film-plating method according to claim 4 or 5 it is characterised in that：In described step S2, to inlet chamber (2)
Inside it is passed through TiO2TiO in gas-operated2The flow of gas is 550-650L/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610536778.3A CN106430999A (en) | 2016-07-08 | 2016-07-08 | Mass-colored emerald green glass and coating manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610536778.3A CN106430999A (en) | 2016-07-08 | 2016-07-08 | Mass-colored emerald green glass and coating manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106430999A true CN106430999A (en) | 2017-02-22 |
Family
ID=58183897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610536778.3A Pending CN106430999A (en) | 2016-07-08 | 2016-07-08 | Mass-colored emerald green glass and coating manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106430999A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117361894A (en) * | 2023-10-23 | 2024-01-09 | 中国耀华玻璃集团有限公司 | Glass rapid coloring and color changing equipment and process method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1899998A (en) * | 2006-07-18 | 2007-01-24 | 福耀集团双辽有限公司 | Method and device for online coating flat glass |
| CN1944310A (en) * | 2006-10-19 | 2007-04-11 | 福耀集团双辽有限公司 | Sunlight controlled self cleaning glass and its producing method |
| CN101054268A (en) * | 2007-05-24 | 2007-10-17 | 卢秀强 | Coating glass with function of sunlight control low radiation, ultraviolet radiation stopping and photocatalysis sterilization, and preparation method thereof |
| CN101405134A (en) * | 2006-02-14 | 2009-04-08 | 皮尔金顿汽车有限公司 | Vehicle glazing |
| US20160115072A1 (en) * | 2012-12-19 | 2016-04-28 | Vidrio Plano De Mexico, S.A. De C.V. | Aqua blue glass composition |
-
2016
- 2016-07-08 CN CN201610536778.3A patent/CN106430999A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101405134A (en) * | 2006-02-14 | 2009-04-08 | 皮尔金顿汽车有限公司 | Vehicle glazing |
| CN1899998A (en) * | 2006-07-18 | 2007-01-24 | 福耀集团双辽有限公司 | Method and device for online coating flat glass |
| CN1944310A (en) * | 2006-10-19 | 2007-04-11 | 福耀集团双辽有限公司 | Sunlight controlled self cleaning glass and its producing method |
| CN101054268A (en) * | 2007-05-24 | 2007-10-17 | 卢秀强 | Coating glass with function of sunlight control low radiation, ultraviolet radiation stopping and photocatalysis sterilization, and preparation method thereof |
| US20160115072A1 (en) * | 2012-12-19 | 2016-04-28 | Vidrio Plano De Mexico, S.A. De C.V. | Aqua blue glass composition |
Non-Patent Citations (3)
| Title |
|---|
| 游二川著: "《绘画材料与技法研究》", 30 June 2011, 重庆大学出版社 * |
| 王徽枢编著: "《实用宝玉石学》", 31 August 2015, 中国地质大学出版社 * |
| 王芬等编著: "《硅酸盐制品的装饰及装饰材料》", 31 August 2004, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117361894A (en) * | 2023-10-23 | 2024-01-09 | 中国耀华玻璃集团有限公司 | Glass rapid coloring and color changing equipment and process method |
| CN117361894B (en) * | 2023-10-23 | 2024-03-26 | 中国耀华玻璃集团有限公司 | Glass rapid coloring and color changing equipment and process method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103562152B (en) | There is the clear glass substrate of the coating being made up of successive layer | |
| CN103508678B (en) | Preparation method of wear-resistant antireflective coating comprising mesopores, and wear-resistant antireflective coating comprising mesopores | |
| PL185279B1 (en) | Glazing provided with a conductive and/or low-emissivity layer | |
| CN1951985A (en) | Transparent heat-insulating film and its preparing process | |
| CN102702877A (en) | Preparation process of insulating, self-cleaning and transparent fluorocarbon coating | |
| CN101767939B (en) | High-permeability, tempered and low-radiation coated glass and manufacturing method thereof | |
| CN101434759B (en) | Preparation of high glaze glass-based pearlescent pigment | |
| CN101448754A (en) | A method for producing functional glass surfaces by changing the composition of the original surface | |
| CN102395536A (en) | Coated substrate | |
| CN102834363A (en) | Photocatalytic material and glass sheet or photovoltaic cell including said material | |
| CN108493264A (en) | A kind of colour cadmium telluride diaphragm solar battery and preparation method thereof | |
| CN108490511A (en) | A kind of anti-reflection laminated film | |
| CN102922824A (en) | Low-emissivity glass with siloxicon barrier layer films and preparation method thereof | |
| CN106186724A (en) | A kind of high light green color bendable steel Three-silver-layer low-radiation coated glass and preparation method thoroughly | |
| EP1608793A1 (en) | Titania coatings | |
| CN106430999A (en) | Mass-colored emerald green glass and coating manufacturing method thereof | |
| CN104071988A (en) | Preparation method of wear-resistant long-acting self-cleaning anti-reflecting coating, and wear-resistant long-acting self-cleaning anti-reflecting coating | |
| CN103524048A (en) | Preparation method of multi-layer SiO2 inorganic anti-reflection film | |
| CN103781738A (en) | Photocatalytic material and window glass or photovoltaic cell comprising the material | |
| CN205917177U (en) | Emerald green glass's film coating system | |
| CN104310800B (en) | Glass metal vacuum plated film modelled after an antique and technique thereof | |
| CN107352814A (en) | A kind of Ford indigo plant coated glass and preparation method thereof | |
| CN204506030U (en) | A kind of nano ceramics heat insulating membrane | |
| CN103692728A (en) | Low-emissivity coated glass and preparation process thereof | |
| CN103370441B (en) | For obtaining the method for photocatalyst material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170222 |