CN106427360A - Iron picture surface treatment method and iron picture - Google Patents
Iron picture surface treatment method and iron picture Download PDFInfo
- Publication number
- CN106427360A CN106427360A CN201610834975.3A CN201610834975A CN106427360A CN 106427360 A CN106427360 A CN 106427360A CN 201610834975 A CN201610834975 A CN 201610834975A CN 106427360 A CN106427360 A CN 106427360A
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- China
- Prior art keywords
- iron picture
- surface treatment
- treatment method
- iron
- rinsing
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
- B44C5/0415—Ornamental plaques, e.g. decorative panels, decorative veneers containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
- C23C22/62—Treatment of iron or alloys based thereon
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses an iron picture surface treatment method and an iron picture. The method comprises the following technological steps of cleaning, specifically, the manufactured iron picture is cleaned; blueing, specifically, the cleaned iron picture is soaked in blueing liquid; rinsing, specifically, the blued iron picture is rinsed with rinsing liquid, washed with water and dried; and coating, specifically, the rinsed iron picture is coated with coating. Since a compact oxidation layer structure can be formed on the surface of the iron picture after blueing, and can isolate contact between water vapor as well as oxygen and the metal surface of the iron picture, an electrochemical corrosion reaction on the metal surface is prevented, and the anti-rust ability of the iron picture can be obviously improved accordingly. The iron picture is treated through the method provided by the invention so that the integrity of the surface paint layer of the iron picture can sustain 10 years or over.
Description
Technical field
The present invention relates to handicraft surface process field, more particularly, to a kind of iron picture surface treatment method and iron picture.
Background technology
Iron picture, original name " ornamental work of iron ", for one of the handicraft of Chinese unique style, is the distinctive workmanship in Wuhu City.
Composition method and the craft and techniques such as jewel, paper-cut, sculpture of China's traditional Chinese painting drawn by iron picture, make raw material with mild steel,
With iron generation ink, write on one's behalf with hammering into shape, through going out original text, cut, pound, burn beat, the operation such as upper lacquer tree fat, upper ledge and " playing works ", the technique such as " brill work ",
The various arts work such as exquisite one-tenth scenery with hills and waters, personage, flowers, worm fish, birds, beast.It by Paper-cut, carve, inlay etc. multiple
Means of artistic expression combines together, and using the Chinese painting art of composition, black and white contrast, actual situation combines, and separately has some temperament and interest.But, due to
What this products material was selected is the ferrous metal such as mild steel, leads to iron picture works to all suffer from the difficulty of antirust treatment all the time
Topic, the surface skin of paint integrity of general iron picture works can only ensure the 5-10 year.It is therefore desirable to providing one kind anti-for a long time
The only method of iron picture surface corrosion.
The information being disclosed in background of invention part is merely intended to deepen the reason of the general background technology to the present invention
Solution, and it is not construed as recognizing or imply in any form known to those skilled in the art existing of this information structure
Technology.
Content of the invention
Present invention aim to address iron picture works are difficult to preserve for a long time, easily produce the problem of corrosion.
To achieve these goals, the present invention provides a kind of iron picture surface treatment method, and the method includes following technique step
Suddenly：
Cleaning：It is carried out processing to manufacturing the iron picture completing；
Turn blue process：To be placed in bluing liquid through cleaned described iron picture and soak；
Rinsing：By the described iron picture rinsing liquid rinsing through process of turning blue, then rinsed with water and be dried；
Application：Described iron picture through rinsing is carried out application process with coating.
According to a further aspect in the invention, there is provided the iron picture that method process as above obtains.
Process step of turning blue is introduced before iron picture works carry out application using the method for the present invention, process of turning blue can make iron
Draw work surface and form one layer of fine and close oxidation Rotating fields, this oxidation Rotating fields can completely cut off steam and oxygen and iron picture metal watch
The contact in face, prevents the reaction of the electrochemical corrosion of metal surface, and then the rustless property of iron picture works is obtained substantially
Improve, carry out application again through the iron picture works of process of turning blue, the surface skin of paint integrity of iron picture works can be made to reach 10 years
More than.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific embodiment
The preferred embodiment of the present invention is described in more detail below.Although describing the side of being preferable to carry out of the present invention
Formula, however, it is to be appreciated that may be realized in various forms the present invention and should not being limited by embodiments set forth herein.Phase
Instead, these embodiments are provided so that the present invention is more thorough and complete, and can by the scope of the present invention intactly
Convey to those skilled in the art.
The present invention provides a kind of iron picture surface treatment method, and the method comprises the technical steps that：Cleaning, completes to manufacture
Iron picture be carried out process；Turn blue process, will be placed in bluing liquid through cleaned iron picture and soak；Rinsing, will be through
The iron picture crossing process of turning blue is rinsed with rinsing liquid, then is rinsed with water and be dried；Application, the iron picture through rinsing is carried out with coating
Application is processed.
Preferably, described cleaning comprises the steps：
(1) scrubbed manufacturing the iron picture completing with washing agent；
(2) the described iron picture after step (1) is processed is immersed in acid solution；
(3) wash and be dried.
Iron picture can be stained with the impurity such as greasy dirt dust during manufacturing processing unavoidably, and the iron picture process-cycle is long,
In process because iron picture will be exposed in the air for a long time, thus iron picture surface easily produces slight corrosion, and these are all
Can affect iron picture surface turn blue process so that the treatment effect that turns blue undesirable it is impossible to metal surface formed densification oxidation
Film.Therefore, by washing agent matting, the impurity such as dust, the greasy dirt on iron picture surface are first removed；Soaked by acid solution and remove
The floating rust on iron picture surface, is then cleaned with clear water and processes, due to preamble, the Liquid Residue residing in iron picture surface, finally make iron picture table
Face reaches drying.
According to the present invention, described washing agent can be for the various washing agent that can go to degrease it is preferable that washing agent be to wash
Clothing liquid, liquid detergent, industrial cleaning agent or soap lye.
According to the present invention, the concentration of described acid solution and soak time can meet washes floating rust off.Preferably, described acid
Solution is the oxalic acid of 1-5% for mass percent concentration or mass percent concentration is the dilute hydrochloric acid solution of 10-20%.Soak
Time can be 2-10 minute, preferably 3-5 minute.
Preferably, described bluing liquid contains：The water of 100 weight portions, the sodium nitrate of 5-10 weight portion, 60-70 weight portion
NaOH and the natrium nitrosum of 10-20 weight portion.
Preferably, the condition of described process of turning blue includes：Temperature is 110-130 DEG C, and the time is 0.5-2 hour.
The bluing liquid configuring according to the method described above carries out turning blue and processes the oxide-film that can form densification on iron picture surface, reaches
To effect of preferably turning blue.
According to the present invention, when preparing bluing liquid, the feed postition of described sodium nitrate, NaOH and natrium nitrosum can be
Solid or liquid.Described sodium nitrate, NaOH and natrium nitrosum can be for commercially available various analyses are pure or chemical pure medicine.Example
As described sodium nitrate can be 95% sodium nitrate, and described NaOH can be 98% NaOH.
Preferably, described rinsing liquid is soap lye, more preferably liquid soap.
Preferably, the temperature of rinsing is 40-60 DEG C, and the time is 2-5min.Remove the work of turning blue on iron picture surface by rinsing
Sequence Liquid Residue, in order to avoid residual component affects the painting effect of next procedure.
Preferably, coating is nitrate paint.Nitrate paint color is preferably black.Coating process for brushing or can spray.
According to the present invention, described drying can be the various conventional mode in this area, for example, natural air drying or set with air-dried
Standby air-dried.
Another aspect provides the iron picture that method process as above obtains.
By following examples, the present invention is further described.
Embodiment 1
The collocation method of bluing liquid：150g natrium nitrosum is completely dissolved in 1000g deionized water, obtains natrium nitrosum
Solution；98% NaOH of 95% sodium nitrate of 80g and 650g is respectively added in sodium nitrite solution, makes three kinds of materials
Obtain described bluing liquid by stirring abundant blending.
It is carried out to manufacturing the iron picture completing.First, iron picture is scrubbed with industrial cleaning agent；Then, will pass through
Scrubbing the iron picture after process and being immersed in mass percent concentration is 4 minutes in 2% oxalic acid solution；Finally, washed with clear water and be used in combination
Apparatus for drying makes iron picture surface reach drying.
Carry out process of turning blue to through cleaned iron picture.Iron picture is placed in immersion 1 in 120 DEG C of bluing liquid little
When.
Iron picture through process of turning blue is rinsed.Iron picture is rinsed 3 minutes with 50 DEG C of liquid soaps, then with water by iron picture
The rinsing liquid of remained on surface is rinsed well and makes iron picture surface reach drying with apparatus for drying.
Application is carried out to the iron picture processing through rinsing.Brush black nitrate paint on iron picture surface, make black nitrate paint equal
Even be distributed on iron picture surface, formed coating layer.
Embodiment 2
The collocation method of bluing liquid：100g natrium nitrosum is completely dissolved in 1000g deionized water, obtains natrium nitrosum
Solution；98% NaOH of 95% sodium nitrate of 50g and 600g is respectively added in sodium nitrite solution, makes three kinds of materials
Obtain described bluing liquid by stirring abundant blending.
It is carried out to manufacturing the iron picture completing.First, iron picture is scrubbed with soap lye；Then, will be through scrubbing place
It is 5 minutes in 1% oxalic acid solution that iron picture after reason is immersed in mass percent concentration；Finally, washed with clear water and use air-dried setting
Standby iron picture surface is made to reach drying.
Carry out process of turning blue to through cleaned iron picture.Iron picture is placed in immersion 2 in 110 DEG C of bluing liquid little
When.
Iron picture through process of turning blue is rinsed.Iron picture is rinsed 5 minutes with 40 DEG C of liquid soaps, then with water by iron picture
The rinsing liquid of remained on surface is rinsed well and makes iron picture surface reach drying with apparatus for drying.
Application is carried out to the iron picture processing through rinsing.Brush black nitrate paint on iron picture surface, make black nitrate paint equal
Even be distributed on iron picture surface, formed coating layer.
Embodiment 3
The collocation method of bluing liquid：200g natrium nitrosum is completely dissolved in 1000g deionized water, obtains natrium nitrosum
Solution；98% NaOH of 95% sodium nitrate of 100g and 700g is respectively added in sodium nitrite solution, makes three kinds of things
Matter is passed through the abundant blending of stirring and is obtained described bluing liquid.
It is carried out to manufacturing the iron picture completing.First, iron picture is scrubbed with liquid detergent；Then, will be through scrubbing
It is 3 minutes in 5% oxalic acid solution that iron picture after process is immersed in mass percent concentration；Finally, washed with clear water and use air-dried
Equipment makes iron picture surface reach drying.
Carry out process of turning blue to through cleaned iron picture.Iron picture is placed in immersion 0.5 in 130 DEG C of bluing liquid little
When.
Iron picture through process of turning blue is rinsed.Iron picture is rinsed 2 minutes with 60 DEG C of liquid soaps, then with water by iron picture
The rinsing liquid of remained on surface is rinsed well and makes iron picture surface reach drying with apparatus for drying.
Application is carried out to the iron picture processing through rinsing.Brush black nitrate paint on iron picture surface, make black nitrate paint equal
Even be distributed on iron picture surface, formed coating layer.
Test case
Accelerated corrosion test, result are carried out to the iron picture obtaining in embodiment 1-3 and the iron picture processing through conventional application
Show, be about 2 times of the iron picture obtain in embodiment 1-3 through the corrosion rate of the iron picture that conventional application is processed.It can be seen that, pass through
More resistant to corrosion, its surface skin of paint integrity can reach more than 10 years to the iron picture that the method for the present invention is processed.
Claims (10)
1. a kind of iron picture surface treatment method is it is characterised in that the method comprises the technical steps that：
Cleaning：It is carried out processing to manufacturing the iron picture completing；
Turn blue process：To be placed in bluing liquid through cleaned described iron picture and soak；
Rinsing：By the described iron picture rinsing liquid rinsing through process of turning blue, then rinsed with water and be dried；
Application：Described iron picture through rinsing is carried out application process with coating.
2. iron picture surface treatment method according to claim 1, wherein, described cleaning comprises the steps：
(1) scrubbed manufacturing the described iron picture completing with washing agent；
(2) the described iron picture after step (1) is processed is immersed in acid solution；
(3) wash and be dried.
3. iron picture surface treatment method according to claim 2, wherein, described washing agent is liquid detergent, liquid detergent, industry
Cleaning agent or soap lye.
4. iron picture surface treatment method according to claim 2, wherein, described acid solution is 1- for mass percent concentration
5% oxalic acid solution or mass percent concentration are the dilute hydrochloric acid solution of 10-20%；The time of described immersion divides for 2-10
Clock.
5. iron picture surface treatment method according to claim 1, wherein, described bluing liquid contains：The water of 100 weight portions,
The sodium nitrate of 5-10 weight portion, the natrium nitrosum of the NaOH of 60-70 weight portion and 10-20 weight portion.
6. iron picture surface treatment method according to claim 1, wherein, the condition of described process of turning blue includes：Temperature is
110-130 DEG C, the time is 0.5-2 hour.
7. iron picture surface treatment method according to claim 1, wherein, described rinsing liquid is soap lye.
8. iron picture surface treatment method according to claim 1, wherein, the temperature of described rinsing is 40-60 DEG C, and the time is
2-5min.
9. iron picture surface treatment method according to claim 1, wherein, described coating is nitrate paint.
10. the iron picture that the method process described in any one in claim 1-9 obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834975.3A CN106427360A (en) | 2016-09-20 | 2016-09-20 | Iron picture surface treatment method and iron picture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834975.3A CN106427360A (en) | 2016-09-20 | 2016-09-20 | Iron picture surface treatment method and iron picture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106427360A true CN106427360A (en) | 2017-02-22 |
Family
ID=58166084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610834975.3A Pending CN106427360A (en) | 2016-09-20 | 2016-09-20 | Iron picture surface treatment method and iron picture |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106427360A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107740089A (en) * | 2017-09-06 | 2018-02-27 | 芜湖徽艺坊铁画工艺品有限公司 | A kind of iron picture surface anticorrosive treatment method |
| CN115094408A (en) * | 2022-06-27 | 2022-09-23 | 黑龙江北方工具有限公司 | Oxidation processing method for iron-based alloy parts |
-
2016
- 2016-09-20 CN CN201610834975.3A patent/CN106427360A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| 王荣才: "《芜湖铁画产业化发展研究》", 30 June 2016, 安徽师范大学出版社 * |
| 秦国治 等: "《化学清洗实用技术》", 30 November 1996, 中国石化出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107740089A (en) * | 2017-09-06 | 2018-02-27 | 芜湖徽艺坊铁画工艺品有限公司 | A kind of iron picture surface anticorrosive treatment method |
| CN115094408A (en) * | 2022-06-27 | 2022-09-23 | 黑龙江北方工具有限公司 | Oxidation processing method for iron-based alloy parts |
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Application publication date: 20170222 |
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