CN106423093A - Adsorption plate with function of adsorbing spilled oil and preparing method thereof - Google Patents
Adsorption plate with function of adsorbing spilled oil and preparing method thereof Download PDFInfo
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- CN106423093A CN106423093A CN201610849715.3A CN201610849715A CN106423093A CN 106423093 A CN106423093 A CN 106423093A CN 201610849715 A CN201610849715 A CN 201610849715A CN 106423093 A CN106423093 A CN 106423093A
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- mixed liquor
- mixed liquid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses an adsorption plate with the function of adsorbing spilled oil and a preparing method thereof. The preparing method includes the steps that polystyrene, tetrahydrofuran and N,N-dimethylformamide are prepared into mixed liquid B; polypropylene and N,N-dimethylformamide are prepared into mixed liquid C; dicumyl peroxide and chloroform are prepared into mixed liquid D; methyl isobutyrate and a polyethylene glycol chloroform solution are prepared into mixed liquid E; the mixed liquid B is added dropwise into the mixed liquid E to obtain mixed liquid F; the mixed liquid C is added dropwise into the mixed liquid F to obtain mixed liquid G; the mixed liquid D is added drowise into the mixed liquid G to obtain mixed liquid H; distilled water is jetted into a container containing liquid nitrogen to be fast frozen to prepare ice ball granules, and the ice ball granules are screened and placed into a mold cavity to be compressed; the mixed liquid H is poured into the mold to be frozen and shaped, and the adsorption plate with the function of adsorbing spilled oil can be obtained through vacuum freeze drying.
Description
Technical field
The invention belongs to by the processing technology field of petroleum hydrocarbon contaminated water body, more particularly to a kind of have absorption oil spilling function
Adsorption plate and preparation method thereof.
Background technology
In recent years, with the demand that countries in the world day by day increase to oil and its product, exploitation at sea, handling, transport
And happened occasionally using oil spill accident during oil, not only cause substantial amounts of crude oil to be lost in, serious dirt is also caused to environment
Dye, threatens the ecological environment of water body and land-based area with being on the rise, and has length to water body environment, natural resourcess and culture resources etc.
The harm of phase, therefore, water body oil spill has become as the great environmental problem that people must face.
The method for disposing water body oil spill at present both at home and abroad mainly has Physical, chemical method and bioanalysises.Chemical method exists
It is the technology path of comparative maturity in point-source pollution improvement, has obtained extensive popularization and application.But in the dirt of water body oil spilling
Dye adopts chemical method in administering, and needs to add chemical agent in water body, and on the one hand the chemical agent for wherein adding may produce
Secondary pollution, on the other hand can produce short-term or long-term impact to water ecological setting.Bioremediation technology has efficient, warp
The features such as Ji, safety, non-secondary pollution, it has also become scene removes the important selection approach of water body oil spill, but processes week
Phase is long.Physisorphtion is a kind for the treatment of effeciency height, no low cost, sediment pollution, simple to operate and water body will not be given birth to
State environment causes method of the secondary pollution with destroying, and can preferably solve the problems of chemical method.In order to by physical absorption
Method obtain in the process of water body oil spill further promote and application, need to develop efficient adsorbing material, this for
Improve water body oil spill treatment effeciency, reduction environmental pollution to have great importance, but also lack the technology of this aspect at present
With research report.
Content of the invention
It is an object of the invention to provide a kind of adsorption plate with absorption oil spilling function and preparation method thereof.Its concrete steps
As follows：
(1) by 15mL tetrahydrofuran and 35mLN, dinethylformamide mix homogeneously, it is placed in the thin opening reagent of 250mL tool plug
In bottle, 5h is stirred under the conditions of 1000r/min, obtain mixed liquor A；
(2) 10.92g polystyrene being added in mixed liquor A, 5h is stirred under the conditions of 1000r/min, obtain mixed liquid B；
(3) 3.61g polyacrylonitrile is placed in 250mL tool plug narrow mouth bottle, addition 50mLN, dinethylformamide,
10h is stirred under the conditions of 1000r/min, obtain mixed liquor C；
(4) 4.32g cumyl peroxide is placed in 250mL tool plug narrow mouth bottle, 100mL chloroform is added,
10h is stirred under the conditions of 1000r/min, obtain mixed liquor D；
(5) 140mL methyl isobutyrate and Polyethylene Glycol chloroformic solution that 60mL mass fraction is 6.5% are sufficiently mixed,
Obtain mixed liquor E；
(6) 10mL mixed liquid B is added drop-wise in mixed liquor E under 1000r/min stirring condition, obtains mixed liquor F；
(7) 8mL mixed liquor C is added drop-wise in mixed liquor F under 1000r/min stirring condition, obtains mixed liquor G；
(8) 8.5mL mixed liquor D is added drop-wise in mixed liquor G under 1000r/min stirring condition, obtains mixed liquor H；
(9) in the container for spurting into equipped with liquid nitrogen by distilled water, quick freezing makes ice hockey granule, is selected with after sieved through sieve
The ice hockey granule that grain size scope is 50～100 μm is taken, the ice hockey granule that screening is obtained is placed in mould cavity and is compacted；
Then mixed liquor H being poured in mould, and be together put into freeze settled 6 hours in liquid nitrogen, solid-state is obtained after taking out the demoulding and mix
Compound；The solid mixt vacuum lyophilization is removed the absorption for obtaining after chloroform and ice hockey granule with absorption oil spilling function
Plate.
The invention has the beneficial effects as follows, processing technology is simple, and the obtained adsorption plate with absorption oil spilling function is to oil
Hydrocarbon pollutant treatment effeciency height.
Specific embodiment
The present invention provides a kind of adsorption plate with absorption oil spilling function and preparation method thereof, is come with one embodiment below
The present invention is described.
Embodiment 1.
By 15mL tetrahydrofuran and 35mLN, dinethylformamide mix homogeneously, 250mL tool plug narrow mouth bottle is placed in
In, 5h being stirred under the conditions of 1000r/min, obtains mixed liquor A；10.92g polystyrene is added in mixed liquor A, in 1000r/
5h is stirred under the conditions of min, obtain mixed liquid B；3.61g polyacrylonitrile is placed in 250mL tool plug narrow mouth bottle, 50mLN is added,
Dinethylformamide, stirs 10h under the conditions of 1000r/min, obtains mixed liquor C；4.32g cumyl peroxide is placed in
In 250mL tool plug narrow mouth bottle, 100mL chloroform is added, 10h is stirred under the conditions of 1000r/min, obtain mixed liquor D.
140mL methyl isobutyrate and Polyethylene Glycol chloroformic solution that 60mL mass fraction is 6.5% are sufficiently mixed, are obtained
Mixed liquor E；10mL mixed liquid B is added drop-wise in mixed liquor E under 1000r/min stirring condition, obtains mixed liquor F；8mL is mixed
Close liquid C to be added drop-wise in mixed liquor F under 1000r/min stirring condition, obtain mixed liquor G；By 8.5mL mixed liquor D in 1000r/
It is added drop-wise under min stirring condition in mixed liquor G, obtains mixed liquor H.
In the container that distilled water is spurted into equipped with liquid nitrogen, quick freezing makes ice hockey granule, with choosing grain after sieved through sieve
Footpath size range is 50～100 μm of ice hockey granule；Garbled ice hockey granule is placed in mould cavity and is compacted.
Mixed liquor H is poured in mould, and is together put into freeze settled 6 hours in liquid nitrogen, obtain after taking out the demoulding solid
State mixture；The solid mixt vacuum lyophilization is removed and is obtained after chloroform and ice hockey granule with absorption oil spilling function
Adsorption plate.
It is presented herein below with the adsorption plate with absorption oil spilling function obtained in the inventive method in petroleum hydrocarbon contaminated water body
Petroleum hydrocarbon carried out adsorption test, further illustrate the present invention.
With the adsorption plate with absorption oil spilling function obtained in the inventive method to the oil in petroleum hydrocarbon contaminated water body
Hydrocarbon has carried out adsorption test, as a result shows that the particulate adsorbent material can effectively be adsorbed to the petroleum hydrocarbon in water body：When
When the initial concentration of polluted-water petrochina hydrocarbon is 580mg/L, 45g adsorption plate, water after 15 minutes is added in the water body of 500mL
The concentration of body petrochina hydrocarbon is reduced to 0.05mg/L.
Claims (1)
1. a kind of with adsorption plate for adsorbing oil spilling function and preparation method thereof, it is characterised in that the concrete steps of the method are such as
Under：
(1) by 15mL tetrahydrofuran and 35mLN, dinethylformamide mix homogeneously, it is placed in 250mL tool plug narrow mouth bottle
In, 5h being stirred under the conditions of 1000r/min, obtains mixed liquor A；
(2) 10.92g polystyrene being added in mixed liquor A, 5h is stirred under the conditions of 1000r/min, obtain mixed liquid B；
(3) 3.61g polyacrylonitrile is placed in 250mL tool plug narrow mouth bottle, addition 50mLN, dinethylformamide,
10h is stirred under the conditions of 1000r/min, obtain mixed liquor C；
(4) 4.32g cumyl peroxide is placed in 250mL tool plug narrow mouth bottle, 100mL chloroform is added, in 1000r/
10h is stirred under the conditions of min, obtain mixed liquor D；
(5) 140mL methyl isobutyrate and Polyethylene Glycol chloroformic solution that 60mL mass fraction is 6.5% are sufficiently mixed, obtain
Mixed liquor E；
(6) 10mL mixed liquid B is added drop-wise in mixed liquor E under 1000r/min stirring condition, obtains mixed liquor F；
(7) 8mL mixed liquor C is added drop-wise in mixed liquor F under 1000r/min stirring condition, obtains mixed liquor G；
(8) 8.5mL mixed liquor D is added drop-wise in mixed liquor G under 1000r/min stirring condition, obtains mixed liquor H；
(9) in the container for spurting into equipped with liquid nitrogen by distilled water, quick freezing makes ice hockey granule, with choosing grain after sieved through sieve
Footpath size range is 50～100 μm of ice hockey granule, and the ice hockey granule that screening is obtained is placed in mould cavity and is compacted；Then
Mixed liquor H is poured in mould, and is together put into freeze settled 6 hours in liquid nitrogen, after taking out the demoulding, obtain solid mixt；
The solid mixt vacuum lyophilization is removed the adsorption plate for obtaining after chloroform and ice hockey granule with absorption oil spilling function.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610849715.3A CN106423093A (en) | 2016-09-24 | 2016-09-24 | Adsorption plate with function of adsorbing spilled oil and preparing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610849715.3A CN106423093A (en) | 2016-09-24 | 2016-09-24 | Adsorption plate with function of adsorbing spilled oil and preparing method thereof |
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| CN106423093A true CN106423093A (en) | 2017-02-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610849715.3A Pending CN106423093A (en) | 2016-09-24 | 2016-09-24 | Adsorption plate with function of adsorbing spilled oil and preparing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108993910A (en) * | 2018-06-04 | 2018-12-14 | 青海黄河上游水电开发有限责任公司光伏产业技术分公司 | A kind of ice hockey prepares screening system automatically |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103623793A (en) * | 2013-12-12 | 2014-03-12 | 北京师范大学 | Porous adsorption plate with multiple functions for petroleum hydrocarbon polluted water bodies and preparation method thereof |
| CN103965835A (en) * | 2014-05-13 | 2014-08-06 | 西南石油大学 | Ultra-light magnetic oil absorption material and preparation method thereof |
| CN104209014A (en) * | 2013-06-04 | 2014-12-17 | 中国石油天然气股份有限公司 | Biological pollution resistant porous membrane and preparation method thereof |
| CN105541874A (en) * | 2016-01-25 | 2016-05-04 | 辽宁大学 | Porous metal organic skeleton based on CuII and preparation method and application thereof |
-
2016
- 2016-09-24 CN CN201610849715.3A patent/CN106423093A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104209014A (en) * | 2013-06-04 | 2014-12-17 | 中国石油天然气股份有限公司 | Biological pollution resistant porous membrane and preparation method thereof |
| CN103623793A (en) * | 2013-12-12 | 2014-03-12 | 北京师范大学 | Porous adsorption plate with multiple functions for petroleum hydrocarbon polluted water bodies and preparation method thereof |
| CN103965835A (en) * | 2014-05-13 | 2014-08-06 | 西南石油大学 | Ultra-light magnetic oil absorption material and preparation method thereof |
| CN105541874A (en) * | 2016-01-25 | 2016-05-04 | 辽宁大学 | Porous metal organic skeleton based on CuII and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| N·格雷赛等: "《聚合物降解过程化学》", 30 June 1965 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108993910A (en) * | 2018-06-04 | 2018-12-14 | 青海黄河上游水电开发有限责任公司光伏产业技术分公司 | A kind of ice hockey prepares screening system automatically |
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Application publication date: 20170222 |