CN106422729A - System for treating waste gas in viscose fiber production - Google Patents
System for treating waste gas in viscose fiber production Download PDFInfo
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- CN106422729A CN106422729A CN201611081137.XA CN201611081137A CN106422729A CN 106422729 A CN106422729 A CN 106422729A CN 201611081137 A CN201611081137 A CN 201611081137A CN 106422729 A CN106422729 A CN 106422729A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/167—Separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
Abstract
The invention discloses a system for treating waste gas in the viscose fiber production. The system is characterized by comprising an alkaline liquor spraying tower, a reaction tank and a degassing tower which are sequentially connected with a waste gas header pipe; an inlet of the reaction tank is connected with a storage tank of the alkaline liquor spraying tower and an acid waste water storage tank, an outlet of the reaction tank is connected with the degassing tower, an outlet of the degassing tower is connected with a cooling dewaterer, the cooling dewaterer comprises a liquid distributor and a filler cooling tower which are sequentially connected with the outlet of the degassing tower, a wire mesh demister is arranged at each of the top parts of the liquid distributor and the filler cooling tower, and the filler cooling tower is further connected with a compressor, a condenser, a Klaus acid gas buffer tank and a high pressure carbon disulfide collection tank sequentially.
Description
Technical field
The present invention is a kind of governing system of waste gas during viscose rayon produces and in particular to right in production process of viscose fiber
The enriching apparatus of Carbon bisulfide and hydrogen sulfide in waste gas, belong to viscose fiber production technical field.
Background technology
In production process of viscose fiber, because production process is many, long the production cycle and from yellow operation to spinning work
Sequence substantial amounts of use industrial chemicals, therefore, inevitably produce some poisonous and hazardous industrial waste gases, its main component is
CS from yellow, spinning and acid station2And H2S gas.
At present, the method processing viscose rayon production waste gas mainly has following three kinds:
One, alkali cleaning sprays:Use alkali liquor(NaOH)Waste gas is carried out with spray-absorption, generates Na2S, then film-making export trade, the method pair
H2S treatment effect is obvious, but to wherein CS2Treatment effect poor;
Two, activated carbon adsorption:With carbon adsorption technique, a large amount of tail gas are processed, CS is reclaimed in desorbing2, such as patent documentation
CN103721524A(A kind of viscose rayon produces the recovery and treatment method in waste gas, 2014.04.16)Record, by enrichment
Enrichment process carries out to two kinds of gases absorbing trapping in the concentration-retort be filled with adsorbent, and desorption and regeneration process is selected again
With noble gases to CS2And H2S carry out substep be desorbed, deposit the operation that is in operation, adjustment more numerous and diverse, the degree that recycles is little, transport
The defects such as row expense height;
Three, condensation:Containing CS2The higher waste gas of concentration is through over-heat-exchanger(Condenser), with water at low temperature directly or indirectly by waste gas
Temperature is down to CS2Below boiling point, with recovering liquid CS2, such as patent documentation CN1016599B(Anti- during carbon disulphide production
Answer the method for separating and processing of product, 1990.06.13)Record, in pressure for 1.5-10 kg/cm and temperature be-
Under the conditions of 10-+20 DEG C, Carbon bisulfide is once made all to liquefy and complete the separation process with hydrogen sulfide.But it is proven, should
Method for viscose staple fibre spinning process tow solidification, decompose when discharge little tolerance, high-temperature, high concentration CS2Return
Time receiving, CS2Efficiency the most obvious.
Understood based on above-mentioned situation, existing viscose rayon produce waste gas processing method also exist treatment effect undesirable,
The problems such as production cost is high, particularly condensation reclaim CS2Method in it is desirable to high concentration CS2Recovery when its efficiency the brightest
Aobvious, based on this, for improving the treatment effeciency of viscose glue industry waste gas, the present invention proposes a kind of controlling of waste gas during viscose rayon produces
Reason system.
Content of the invention
It is an object of the invention to provide a kind of viscose rayon produce in waste gas governing system, using in alkali liquor spray column
The using cooperatively of acid waste water in alkali liquor and retort, makes that self-adhesive produces the Carbon bisulfide in waste gas and hydrogen sulfide is able to richness
Collection, then obtains high concentration Carbon bisulfide and hydrogen sulfide waste gas by degassing tower, for, in later separation method, improving two sulfur
Change the response rate of carbon, be conducive to the process of viscose rayon waste gas, reduce environmental protection pressure.
The present invention is achieved through the following technical solutions:
A kind of viscose rayon produce in waste gas governing system it is characterised in that:Spray including the alkali liquor being sequentially connected waste gas header
Drench tower, retort and degassing tower, retort entrance connects alkali liquor spray column storage tank and acid waste water storage tank, retort outlet connects
Degassing tower, described degassing tower outlet is connected with cooling de-watering device, and cooling de-watering device includes being connected with degassing tower outlet successively
Liquor separator and filling cooling tower, liquor separator and filling cooling tower top be equipped with wire mesh demister, and described filler cooling tower is also
It is connected with compressor, condenser, Crouse's acid gas surge tank and high pressure Carbon bisulfide collecting tank successively.
Described filler cooling tower is provided with the Carbon bisulfide collecting tank collecting condensed fluid.
A kind of described viscose rayon produce in waste gas governing system it is characterised in that:Also include connecting acid solution storage tank
Acid solution degassing tower, acid bath degassing tower outlet connect liquor separator.
Described alkali liquor spray column is two-stage all using the spray equipment of same absorbent liquid.
Described retort meets the vacuum response device of -50kpa~-90kpa for pressure.
One end of described condenser is provided with water inlet, and the other end is provided with outlet, for cooling chilled brine from
Water inlet flows into condenser, flows out condenser from outlet.
Described high pressure Carbon bisulfide collecting tank is the collecting tank of high-voltage-resistant anti-corrosion.
In the present invention, the viscose rayon waste gas collecting sends into alkali liquor spray column by waste gas header, and spray column is fine using half
The alkali liquor of content 3 ~ 20% sprays in alkali liquor spray column, obtains molten containing NaHS, sodium sulfide and hemicellulose sodium sulfonate
Liquid, sends into alkali liquor spray column storage tank, and this solution is delivered to retort by pump from alkali liquor spray column storage tank, stored up with from acid waste water
The acid waste water reaction of tank, reacted mixed solution enters in degassing tower and deaerates, and obtains Carbon bisulfide and the sulfuration of high concentration
Hydrogen waste gas, wherein, Carbon Disulfide content >=25%, concentration of hydrogen sulfide content >=23%.
Further, the present invention degassing tower outlet be connected with cooling de-watering device, cooling de-watering device include successively with
Liquor separator and filling cooling tower that degassing tower outlet is connected, liquor separator and filling cooling tower top are equipped with wire mesh demister.
In the present invention, filling cooling tower uses 0~5 DEG C of cleaning mixture to circulate wash cooling, waste gas can be cooled to 0~10
After DEG C, then the wire mesh demister through tower top is sent, and in waste gas, part Carbon bisulfide is condensed, therefore, cold in described filler
But tower is provided with the Carbon bisulfide collecting tank collecting condensed fluid.
For improving the response rate to Carbon bisulfide and hydrogen sulfide for this process system further, present invention additionally comprises connecting acid solution
The acid solution degassing tower of storage tank, the outlet of acid solution degassing tower connects liquor separator, is stored with the acid solution from acid bath, by this in acid solution storage tank
Part acid solution is collected to acid solution storage tank, isolates containing Carbon bisulfide through acid solution degassing tower under the kPa pressure of -20kPa~-90
With the waste gas of hydrogen sulfide, deliver to liquor separator, carry out cooling de-watering process in the lump with the viscose rayon waste gas after enrichment.
For two-stage all using the spray equipment of same absorbent liquid, absorbing liquid can concentration be 70- to described alkali liquor spray column
The absorbing liquid of the sodium hydroxide of the 150g/l and concentration alkali cellulose composition for 30-110g/l.
Described retort meets the vacuum response device of -50kpa~-90kpa for pressure.
The present invention compared with prior art, has advantages below and beneficial effect:
(1)The present invention can be used for the enrichment of Carbon bisulfide and hydrogen sulfide in viscose glue industry multi-site waste gas and acid solution, by follow-up
Separating step, improves the response rate of Carbon bisulfide and hydrogen sulfide, and the Carbon bisulfide of recovery can return to viscose glue commercial production, hydrogen sulfide
Sulphuric acid or sulfur product can be prepared, be conducive to the control of production cost.
(2)The present invention, by the way of absorbing liquid spray, acid water process combine, dissipates row etc. to from spinning, acid bath
Waste gas is processed, and can produce the enrichment waste gas containing Carbon bisulfide and hydrogen sulfide of high concentration, be next step recycle and reuse
Basis determined by pad.
(3)The present invention is inhaled to the Carbon bisulfide in waste gas and hydrogen sulfide using absorbing liquid in alkali liquor spray column simultaneously
Receive, the direct discharge up to standard of the tail gas after absorption, absorption process no environmental protection pressure, beneficial to environmental conservation.
(4)The present invention relates to the absorbing liquid that alkali liquor spray column is used can adopt and include the hydrogen that concentration is 70-150g/l
Sodium oxide and concentration are the alkali cellulose of 30-110g/l, have the characteristics that to prepare simple, cheap, alkali cellulose mostlys come from
The salkali waste of dipping process during glue, is also a kind of twice laid for viscose glue produces, reduces environmental protection of enterprise pressure.
(5)Acid waste water storage tank according to the present invention is used for collecting sulfur acid waste water, during this sulfur acid waste water exactly produces
The acid-bearing wastewater producing, such as plasticizing groove and the sulfuric acid wastewater containing containing to the discharge of fine groove, belong to viscose glue and produce twice laid.
(6)In the present invention, the sulfur acid waste water in acid waste water storage tank passes through vacuum sucting reaction tank, and alkali liquor spray column stores up
Mixed solution in groove is sent by pumping to retort, and reaction is carried out in vacuum environment, prevents air and enters, on the one hand, can protect
The safety of card reaction process, on the other hand, by vacuum degree control in the range of -50kpa~-90kpa, is conducive to continuous-stable
Obtain enrichment waste gas, improve the concentration of Carbon bisulfide and hydrogen sulfide further.
Brief description
Fig. 1 is the process chart of the present invention(One);
Fig. 2 is the process chart of the present invention(Two);
Fig. 3 is the process chart of the present invention(Three).
Reference
1 waste gas header, 2 alkali liquor spray columns, 3 retort, 4 degassing towers, 5 alkali liquor spray column storage tanks, 6 acid waste water storage tanks, 7 points of liquid
Device, 8 filling cooling towers, 9 Carbon bisulfide collecting tanks, 10 acid solution storage tanks, 11 acid solution degassing towers, 12 compressors, 13 condensers, 14 grams
Louth acid gas surge tank, 15 high pressure Carbon bisulfide collecting tanks
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention not limited to this.
Embodiment 1:
The present embodiment is related to a kind of governing system of waste gas during viscose rayon produces, as shown in Fig. 1 structure, useless including being sequentially connected
The alkali liquor spray column 2 of gas house steward 1, retort 3, degassing tower 4 and cooling de-watering device, wherein, retort 3 entrance connects alkali liquor spray
Drench tower storage tank 5 and acid waste water storage tank 6, retort 3 outlet connects degassing tower 4, cooling de-watering device include successively with degassing tower 4
Liquor separator 7 and filling cooling tower 8 that outlet is connected, liquor separator 7 and filling cooling tower 8 top are equipped with wire mesh demister.
The technological process that the present embodiment is related to is as follows:
(1)Collect viscose rayon waste gas, such as spin and practice alkali spray waste gas(Waste gas containing trench), spin and practice plasticizing groove import and export, to fine groove
Deng waste gas, cellophane waste gas, acid station dissipates aerofluxuss etc., sends into alkali liquor spray column 2 by waste gas header 1, and concentration is 120g/
The absorbing liquid of the sodium hydroxide of the l and concentration alkali cellulose composition for 100g/l carries out two-stage spray to this waste gas, and alkali liquor sprays
Tower 2 adopts turbulent tower, and spray obtains the solution containing NaHS, sodium sulfide and hemicellulose sodium sulfonate, sends into alkali liquor spray column
Storage tank 5.
(2)Solution is delivered to from alkali liquor spray column storage tank 5 by retort 3 by pump, flow-control is in 8m3/ h, retort 3 is adopted
Use vacuum response device, the vacuum degree control pH value 2 of collection, sulfur-bearing of concentration 10g/l in -80kpa, acid waste water storage tank 6
Sour waste water by vacuum sucting reaction tank 3, and the solution reaction from alkali liquor spray column storage tank 5, reacted mixed solution enters
Deaerate in degassing tower 4, obtain Carbon bisulfide and the hydrogen sulfide waste gas of high concentration, wherein, Carbon Disulfide content 26%, sulfuration
Hydrogen concentration content >=24%.
(3)Above-mentioned high-concentration waste gas are sent into liquor separator 7, liquor separator 7 top sets wire mesh demister;By liquor separator 7 out
Waste gas send into filling cooling tower 8, filling cooling tower 8 use 2 DEG C cleaning mixture circulate wash cooling, waste gas is cooled to 4 DEG C
Afterwards, the wire mesh demister through tower top is sent, Carbon Disulfide content 25%, concentration of hydrogen sulfide content 23%, water in gained waste gas
Divide content 0.5%, Carbon bisulfide collecting tank 9 sent into by condensed fluid.
By the waste gas of above-mentioned levels, using condensation method(It is forced into 0.25~1.6MPa, condensation temperature controls -15
~0 DEG C)Respectively to its recovering liquid sulfur dioxide, the response rate of sulfur dioxide can reach 80~95%.
Embodiment 2:
The present embodiment is related to a kind of governing system of waste gas during viscose rayon produces, as shown in Fig. 2 structure, except inclusion is sequentially connected
Outside the alkali liquor spray column 2 of waste gas header 1, retort 3, degassing tower 4 and cooling de-watering device, also include connecting acid solution storage tank 10
Acid solution degassing tower 11.Wherein, retort 3 entrance connects alkali liquor spray column storage tank 5 and acid waste water storage tank 6, and retort 3 outlet is even
Connect degassing tower 4, cooling de-watering device includes the liquor separator 7 being sequentially connected and filling cooling tower 8, liquor separator 7 and filling cooling tower 8
Top is equipped with wire mesh demister, and degassing tower 4 outlet and acid solution degassing tower 11 outlet are all connected with liquor separator 7
The technological process that the present embodiment is related to is as follows:
(1)Collect viscose rayon waste gas, such as spin and practice alkali spray waste gas(Waste gas containing trench), spin and practice plasticizing groove import and export, to fine groove
Deng waste gas, cellophane waste gas, acid station dissipates aerofluxuss etc., sends into alkali liquor spray column 2 by waste gas header 1, and concentration is 135g/
The absorbing liquid of the sodium hydroxide of the l and concentration alkali cellulose composition for 98g/l carries out two-stage spray, alkali liquor spray column to this waste gas
2 adopt turbulent tower, and spray obtains the solution containing NaHS, sodium sulfide and hemicellulose sodium sulfonate, send into the storage of alkali liquor spray column
Groove 5.
(2)Solution is delivered to from alkali liquor spray column storage tank 5 by retort 3 by pump, flow-control is in 8m3/ h, retort 3 is adopted
Use vacuum response device, vacuum degree control in -70kpa, the pH value 1.5 collected in acid waste water storage tank 6, the containing of concentration 20g/l
Sulfuric acid wastewater containing by vacuum sucting reaction tank 3, and the solution reaction from alkali liquor spray column storage tank 5, reacted mixed solution enters
Enter degassing in degassing tower 4, obtain Carbon bisulfide and the hydrogen sulfide waste gas of high concentration, wherein, Carbon Disulfide content 26.5%,
Concentration of hydrogen sulfide content >=28%.
(3)The acid solution that acid bath is produced delivers to acid solution storage tank 10, isolates through acid solution degassing tower 11 under -90 kPa pressure
Waste gas containing Carbon bisulfide and hydrogen sulfide.
(4)By step(2)With(3)The waste gas obtaining sends into liquor separator 7, and liquor separator 7 top sets wire mesh demister;By a point liquid
Device 7 waste gas out sends into filling cooling tower 8, and filling cooling tower 8 uses 2 DEG C of cleaning mixture to circulate wash cooling, and waste gas is cold
But to after 4 DEG C, the wire mesh demister through tower top is sent, Carbon Disulfide content 28%, concentration of hydrogen sulfide content in gained waste gas
32%th, moisture 0.3%, Carbon bisulfide collecting tank 9 sent into by condensed fluid.
By the waste gas of above-mentioned levels, using condensation method(It is forced into 0.25~1.6MPa, condensation temperature controls -15
~0 DEG C)Respectively to its recovering liquid Carbon bisulfide, the response rate of Carbon bisulfide can reach 93%.
Embodiment 3:
A kind of viscose rayon produce in waste gas governing system it is characterised in that:Spray including the alkali liquor being sequentially connected waste gas header 1
Drench tower 2, retort 3 and degassing tower 4, retort 3 entrance connects alkali liquor spray column storage tank 5 and acid waste water storage tank 6, retort 3
Outlet connects degassing tower 4, and the outlet of described degassing tower 4 is connected with cooling de-watering device, cooling de-watering device include successively with degassing
Liquor separator 7 and filling cooling tower 8 that tower 4 outlet is connected, liquor separator 7 and filling cooling tower 8 top are equipped with wire mesh demister, institute
State filling cooling tower 8 also successively with compressor 12, condenser 13, Crouse's acid gas surge tank 14 and high pressure Carbon bisulfide collecting tank
15 are connected.
Embodiment 4:
A kind of viscose rayon produce in waste gas governing system it is characterised in that:Spray including the alkali liquor being sequentially connected waste gas header 1
Drench tower 2, retort 3 and degassing tower 4, retort 3 entrance connects alkali liquor spray column storage tank 5 and acid waste water storage tank 6, retort 3
Outlet connects degassing tower 4, and the outlet of described degassing tower 4 is connected with cooling de-watering device, cooling de-watering device include successively with degassing
Liquor separator 7 and filling cooling tower 8 that tower 4 outlet is connected, liquor separator 7 and filling cooling tower 8 top are equipped with wire mesh demister, institute
State filling cooling tower 8 also successively with compressor 12, condenser 13, Crouse's acid gas surge tank 14 and high pressure Carbon bisulfide collecting tank
15 are connected.
Described filler cooling tower 8 is provided with the Carbon bisulfide collecting tank 9 collecting condensed fluid.
A kind of described viscose rayon produce in waste gas governing system it is characterised in that:Also include connecting acid solution storage tank
10 acid solution degassing tower 11, the outlet of acid bath degassing tower connects liquor separator 7.
Embodiment 5:
A kind of viscose rayon produce in waste gas governing system it is characterised in that:Spray including the alkali liquor being sequentially connected waste gas header 1
Drench tower 2, retort 3 and degassing tower 4, retort 3 entrance connects alkali liquor spray column storage tank 5 and acid waste water storage tank 6, retort 3
Outlet connects degassing tower 4, and the outlet of described degassing tower 4 is connected with cooling de-watering device, cooling de-watering device include successively with degassing
Liquor separator 7 and filling cooling tower 8 that tower 4 outlet is connected, liquor separator 7 and filling cooling tower 8 top are equipped with wire mesh demister, institute
State filling cooling tower 8 also successively with compressor 12, condenser 13, Crouse's acid gas surge tank 14 and high pressure Carbon bisulfide collecting tank
15 are connected.
Described filler cooling tower 8 is provided with the Carbon bisulfide collecting tank 9 collecting condensed fluid.
Embodiment 6:
A kind of viscose rayon produce in waste gas governing system it is characterised in that:Spray including the alkali liquor being sequentially connected waste gas header 1
Drench tower 2, retort 3 and degassing tower 4, retort 3 entrance connects alkali liquor spray column storage tank 5 and acid waste water storage tank 6, retort 3
Outlet connects degassing tower 4, and the outlet of described degassing tower 4 is connected with cooling de-watering device, cooling de-watering device include successively with degassing
Liquor separator 7 and filling cooling tower 8 that tower 4 outlet is connected, liquor separator 7 and filling cooling tower 8 top are equipped with wire mesh demister, institute
State filling cooling tower 8 also successively with compressor 12, condenser 13, Crouse's acid gas surge tank 14 and high pressure Carbon bisulfide collecting tank
15 are connected.
Described filler cooling tower 8 is provided with the Carbon bisulfide collecting tank 9 collecting condensed fluid.
A kind of described viscose rayon produce in waste gas governing system it is characterised in that:Also include connecting acid solution storage tank
10 acid solution degassing tower 11, the outlet of acid bath degassing tower connects liquor separator 7.
Described alkali liquor spray column 2 is two-stage all using the spray equipment of same absorbent liquid.
Described retort 3 meets the vacuum response device of -50kpa~-90kpa for pressure.
Embodiment 7:
A kind of viscose rayon produce in waste gas governing system it is characterised in that:Spray including the alkali liquor being sequentially connected waste gas header 1
Drench tower 2, retort 3 and degassing tower 4, retort 3 entrance connects alkali liquor spray column storage tank 5 and acid waste water storage tank 6, retort 3
Outlet connects degassing tower 4, and the outlet of described degassing tower 4 is connected with cooling de-watering device, cooling de-watering device include successively with degassing
Liquor separator 7 and filling cooling tower 8 that tower 4 outlet is connected, liquor separator 7 and filling cooling tower 8 top are equipped with wire mesh demister, institute
State filling cooling tower 8 also successively with compressor 12, condenser 13, Crouse's acid gas surge tank 14 and high pressure Carbon bisulfide collecting tank
15 are connected.
Described filler cooling tower 8 is provided with the Carbon bisulfide collecting tank 9 collecting condensed fluid.
A kind of described viscose rayon produce in waste gas governing system it is characterised in that:Also include connecting acid solution storage tank
10 acid solution degassing tower 11, the outlet of acid bath degassing tower connects liquor separator 7.
Described alkali liquor spray column 2 is two-stage all using the spray equipment of same absorbent liquid.
Described retort 3 meets the vacuum response device of -50kpa~-90kpa for pressure.
Embodiment 8:
A kind of viscose rayon produce in waste gas governing system it is characterised in that:Spray including the alkali liquor being sequentially connected waste gas header 1
Drench tower 2, retort 3 and degassing tower 4, retort 3 entrance connects alkali liquor spray column storage tank 5 and acid waste water storage tank 6, retort 3
Outlet connects degassing tower 4, and the outlet of described degassing tower 4 is connected with cooling de-watering device, cooling de-watering device include successively with degassing
Liquor separator 7 and filling cooling tower 8 that tower 4 outlet is connected, liquor separator 7 and filling cooling tower 8 top are equipped with wire mesh demister, institute
State filling cooling tower 8 also successively with compressor 12, condenser 13, Crouse's acid gas surge tank 14 and high pressure Carbon bisulfide collecting tank
15 are connected.
Described filler cooling tower 8 is provided with the Carbon bisulfide collecting tank 9 collecting condensed fluid.
A kind of described viscose rayon produce in waste gas governing system it is characterised in that:Also include connecting acid solution storage tank
10 acid solution degassing tower 11, the outlet of acid bath degassing tower connects liquor separator 7.
Described alkali liquor spray column 2 is two-stage all using the spray equipment of same absorbent liquid.
Described retort 3 meets the vacuum response device of -50kpa~-90kpa for pressure.
One end of described condenser 13 is provided with water inlet, and the other end is provided with outlet, for the chilled brine of cooling
Flow into condenser 13 from water inlet, flow out condenser 13 from outlet.
The above, be only presently preferred embodiments of the present invention, and not the present invention is done with any pro forma restriction, every according to
Any simple modification above example made according to the technical spirit of the present invention, equivalent variations, each fall within the protection of the present invention
Within the scope of.
Claims (7)
1. during a kind of viscose rayon produces waste gas governing system it is characterised in that:Including being sequentially connected waste gas header(1)Alkali
Liquid spray column(2), retort(3)And degassing tower(4), retort(3)Entrance connects alkali liquor spray column storage tank(5)And acid waste water
Storage tank(6), retort(3)Outlet connects degassing tower(4), described degassing tower(4)Outlet is connected with cooling de-watering device, and cooling removes
Water installations include successively with degassing tower(4)The liquor separator that outlet is connected(7)And filling cooling tower(8), liquor separator(7)Cold with filler
But tower(8)Top is equipped with wire mesh demister, described filler cooling tower(8)Also successively with compressor(12), condenser(13), gram
Louth acid gas surge tank(14)With high pressure Carbon bisulfide collecting tank(15)It is connected.
2. during a kind of viscose rayon according to claim 2 produces waste gas governing system it is characterised in that:Described filler
Cooling tower(8)It is provided with the Carbon bisulfide collecting tank collecting condensed fluid(9).
3. during a kind of viscose rayon according to claim 2 produces waste gas governing system it is characterised in that:Also include even
Connect acid solution storage tank(10)Acid solution degassing tower(11), acid bath degassing tower outlet connection liquor separator(7).
4. during a kind of viscose rayon according to claim 1 produces waste gas governing system it is characterised in that:Described alkali liquor
Spray column(2)For two-stage all using the spray equipment of same absorbent liquid.
5. during a kind of viscose rayon according to claim 1 produces waste gas governing system it is characterised in that:Described reaction
Tank(3)Meet the vacuum response device of -50kpa~-90kpa for pressure.
6. during a kind of viscose rayon according to claim 1 produces waste gas governing system it is characterised in that:Described condensation
Device(13)One end be provided with water inlet, the other end is provided with outlet, for cooling chilled brine from water inlet flow into cold
Condenser(13), flow out condenser from outlet(13).
7. during a kind of viscose rayon according to claim 1 produces waste gas governing system it is characterised in that:Described high pressure
Carbon bisulfide collecting tank(15)Collecting tank for high-voltage-resistant anti-corrosion.
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