CN106419450A - Artificial Buddhist relics product and preparation method thereof - Google Patents
Artificial Buddhist relics product and preparation method thereof Download PDFInfo
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- CN106419450A CN106419450A CN201610902967.8A CN201610902967A CN106419450A CN 106419450 A CN106419450 A CN 106419450A CN 201610902967 A CN201610902967 A CN 201610902967A CN 106419450 A CN106419450 A CN 106419450A
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G33/00—Religious or ritual equipment in dwelling or for general use
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- C04B33/132—Waste materials; Refuse; Residues
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- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
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Abstract
The invention provides an artificial Buddhist relics product and a preparation method thereof. The artificial Buddhist relics product comprises a hard core and a bone ash outer layer. The bone ash outer layer is formed by sintering and bonding bone ash slurry to the surface of a hard core. The hard core is a metal core with the surface subjected to micro-arc oxidation to obtain a ceramic membrane layer containing hydroxyapatite; the bone ash slurry comprises bone ash crystal powder, auxiliary materials and an inorganic binder; and the bone ash crystal powder is obtained by high-temperature roasting and smashing of bone ash. In the artificial Buddhist relics product, the metal core is embedded, so that the strength of the Buddhist relics product is improved. On the surface of the metal core, the TiO2 porous ceramic membrane layer obtained by micro-arc oxidation and containing hydroxyapatite has the same ingredients as the bone ash; in the sintering and bonding process of the bone ash slurry and the metal core, the bone ash slurry can permeate into the porous ceramic membrane layer and is firmly combined with the membrane layer, and the bonding strength of the hard core and the bone ash outer layer is improved.
Description
Technical field
The present invention relates to bone ash disposal technical field, more particularly, to a kind of artificial Buddhist relics product and preparation method thereof.
Background technology
In short supply with land resource, advocate bone ash according to country and deposit, do not account for or account for less soil mode and process bone ash
Spirit, traditional burial in the ground gradually replaced by cremating although being embedded in underground or be placed on the cinerary casket after cremating
In ancestral hall, solve the problems, such as that tradition burial in the ground land used is many, but the thing followed is the storage problem of substantial amounts of cinerary casket.
For this problem, currently reported bone ash is made as Buddhist relics product etc., household is collected, or is placed on
In the ancestral hall of family, for offering a sacrifice to gods or ancestors, and cherish the memory of for descendant, give expression to one's grief over sb.'s death, that is, respected tradition, but can save a large amount of soils and its
Its burial in the ground resource.But existing artificial Buddhist relics obtains after mostly simply simply melting roasting, light weight, and easy to crack, and
Due to contain in bone ash abundant calcium, the material such as phosphorus, easy breed bacteria, be difficult long term storage.
Content of the invention
Drawbacks described above for prior art and problem, it is an object of the invention to provide a kind of artificial Buddhist relics product and its system
Preparation Method.
In order to achieve the above object, the present invention provides following technical scheme：
A kind of artificial Buddhist relics product, including hard core and bone ash matter outer layer, described bone ash matter outer layer is by starching bone ash
Material sintered bond is on the surface of described hard cores；Described hard core obtains containing hydroxyapatite through differential arc oxidation for surface
Ceramic film metallic core；Described bone ash slurry, according to mass fraction, including 70 parts -80 parts of bone ash crystalline powder, adjuvant
20 parts -30 parts and 20 parts -30 parts of inorganic binder；Described bone ash crystalline powder obtains pulverizing after bone ash high-temperature roasting.
Further, described hard core adopts titanium core, using differential arc oxidation method, in titanium whose surfaces
Obtain the TiO containing hydroxyapatite2Porous ceramicss film layer.
Further, the following process of artificial Buddhist relics product for convenience, is conveniently equipped with multiple type accessories, reaches attractive in appearance
With the purpose held a memorial ceremony for.Described metallic core includes body shape portion and extends external connection portion, one end of described extension external connection portion and institute
State body shape portion to connect, the other end is external connection end, and extends to the outside of described bone ash matter outer layer.
Further, due on bone ash sometimes also can other materials remaining so that the color of bone ash is partially yellow, or even with when
Between passage blackening, therefore, the present invention is before by bone ash high-temperature roasting, to bone ash disinfection, specific as follows：By bone ash
Pulverize as bone ash grain, then bone ash grain is immersed in hydrogen peroxide solution, soak time is 1～3 hour, obtains sterilization and brightens bone ash
Grain；Then by sterilization brighten bone ash grain output be 1000～1200W microwave under process 20～40 minutes, then stand
Naturally cool to room temperature, complete disinfecting of bone ash.
Preferably, bone ash is pulverized as bone ash grain, then bone ash grain is immersed in hydrogen peroxide solution, soak time is 2
Hour, obtain sterilization and brighten bone ash grain；Then bone ash grain is brightened in sterilization and process 30 points under the microwave for 1150W for the output
Clock, then stands and naturally cools to room temperature, complete disinfecting of bone ash.
Further, described adjuvant includes silicon dioxide, zirconium oxide, Calcium Carbonate and inorganic pigment.Specifically, described dioxy
The mass ratio of SiClx, zirconium oxide, Calcium Carbonate and inorganic pigment is 112 0.2-1.Described inorganic pigment is according to artificial Buddhist relics system
Color selecting respective color needed for product carries out selecting.As, blue series, inorganic pigment adopts copper sulfate；Red series,
Inorganic pigment adopts iron chloride.The consumption that the depth of color passes through to adjust inorganic pigment can achieve.
Further, described bone ash crystalline powder is to pulverize after bone ash is placed in roasting at a temperature of 1000-1300 DEG C
Obtain.Preferably, described bone ash crystalline powder is pulverized after bone ash is placed in roasting at a temperature of 1200 DEG C and is obtained.
Further, because the composition in bone ash contains the compositions such as substantial amounts of phosphorus, calcium, therefore, easy breed bacteria, in order to
Solve this problem, in the present invention, described bone ash crystalline powder adopts bone ash crystalline powder and the bone of silver load bone ash crystalline powder
Grey mixed-powder replaces；Wherein, the weight of silver load bone ash crystalline powder accounts for the 10%-60% of bone ash mixed-powder gross weight；
Described bone ash crystalline powder is pulverized after bone ash is placed in roasting at a temperature of 1000-1300 DEG C and is obtained.
Specifically, the preparation method of described silver load bone ash crystalline powder is as follows：A, add in bone ash crystalline powder dilute
Nitric acid, after soaking 6-10s, filters, obtains the bone ash crystalline powder of surface active；B, again to the bone ash crystalline powder of surface active
Middle addition sodium nitrate solution, soaks 12-15s, and sodium ion is exchanged with the hydrion of the surface active of bone ash crystalline powder, filters,
Surface must be arrived there is Na3PO4Bone ash crystalline powder；C, to surface, there is Na again3PO4Bone ash crystalline powder in add nitric acid
Silver-colored solution, soaks 10-15min, filters, and is dried, and obtains silver load bone ash crystalline powder.
The preparation method of a kind of artificial Buddhist relics product of the present invention, comprises the following steps：
Step one, prepare each raw material by any one of the claims 1 to 8；
Step 2, by bone ash crystalline powder (or bone ash mixed-powder), adjuvant and inorganic binder mix, be subsequently adding
Suitable quantity of water, stirring and evenly mixing, obtain bone ash slurry；Bone ash slurry is added in mould, and hard core is filled in described bone
Inside mortar, obtain artificial Buddhist relics base；
Step 3, by fill artificial Buddhist relics base mould put in sintering furnace, be warming up to 120-150 DEG C first, protect
Warm 8-10min；Then it is further continued for being warming up to 200-250 DEG C, be incubated 20-30min；Finally it is warming up to 1200-1300 DEG C again, insulation
After 3-5min；Mould is put in oil phase, carries out quenching；After cooling, mould from, obtain final product artificial Buddhist relics product.
Further, in step 3, in the sintering process in sintering furnace, sintering atmosphere adopts reducing atmosphere, and burns
Stagnation of QI pressure adopts negative pressure.
In a kind of artificial Buddhist relics product that the present invention provides, embedded in metallic core, increased the intensity of Buddhist relics product.And
And the TiO containing hydroxyapatite that metallic core surface is obtained by differential arc oxidation2Master in porous ceramicss film layer and bone ash
Want composition the same, during the sintered bonds with metallic core for the bone ash slurry, bone ash slurry can penetrate in porous ceramicss film layer,
And with film layer strong bonded, improve the adhesion strength of hard core and bone ash matter outer layer.
Adjuvant and inorganic binder is preferably given in the present invention, especially, the biphosphate sodium powder of employing in binding agent
In sintering process, the alumina composition generating after dehydration in sodium pyrophosphate, with remaining zirconium oxide and Kaolin can occur at end
Reaction, obtain phosphoric acid salt bonding agent it is ensured that between bone ash crystalline powder and adjuvant fusion bonding, and bone ash slurry with
The bonding on metallic core surface.
Brief description
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
Have technology description in required use accompanying drawing be briefly described it should be apparent that, drawings in the following description be only this
Some embodiments of invention, for those of ordinary skill in the art, without having to pay creative labor, also may be used
So that other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the cross-sectional view of the artificial Buddhist relics product of the present invention；
Fig. 2 is the cross-sectional view of the preferably artificial Buddhist relics product of the present invention.
Specific embodiment
Below in conjunction with embodiments of the invention, technical scheme is clearly and completely described it is clear that
Described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the enforcement in the present invention
Example, the every other embodiment that those of ordinary skill in the art are obtained under the premise of not making creative work, broadly fall into
The scope of protection of the invention.
Embodiment 1
In conjunction with a kind of artificial Buddhist relics product that the present embodiment 1, shown in Fig. 1, is described, including hard core 1 and bone ash matter outer layer
2, described bone ash matter outer layer 2 passes through bone ash slurry sintered bond on the surface of described hard core 1；Described hard core 1
Obtain the metallic core of the ceramic film 101 containing hydroxyapatite for surface through differential arc oxidation；Described bone ash slurry, according to matter
Amount number, including 80 parts of bone ash crystalline powder, 30 parts of adjuvant and 30 parts of inorganic binder；Described bone ash crystalline powder is by bone ash
After high-temperature roasting, pulverizing obtains.
Described bone ash crystalline powder is pulverized after bone ash is placed in roasting at a temperature of 1200 DEG C and is obtained.Wherein, will
Before bone ash high-temperature roasting, to bone ash disinfection, specific as follows：Bone ash is pulverized as bone ash grain, then bone ash grain is soaked
In hydrogen peroxide solution, soak time is 2 hours to bubble, obtains sterilization and brightens bone ash grain；Then sterilization is brightened bone ash grain in output
Power is processed under the microwave for 1150W 30 minutes, then stands and naturally cools to room temperature, completes disinfecting of bone ash.
Described adjuvant includes silicon dioxide, zirconium oxide, Calcium Carbonate and inorganic pigment；Described silicon dioxide, zirconium oxide, carbonic acid
The mass ratio of calcium and inorganic pigment is 112 0.2-1.Described inorganic pigment is according to the color selecting needed for artificial Buddhist relics product
Respective color carries out selecting.As, blue series, inorganic pigment adopts copper sulfate；Red series, inorganic pigment adopts chlorination
Ferrum.The consumption that the depth of color passes through to adjust inorganic pigment can achieve.
Described inorganic binder adopts composite inorganic cementing compositions, including zirconium oxide, sodium dihydrogen phosphate powder, calcium phosphate
And Kaolin, wherein, zirconium oxide, sodium dihydrogen phosphate powder, calcium phosphate and kaolinic mass ratio are followed successively by 1521.
Described metallic core adopts titanium core, using differential arc oxidation method, is contained in titanium whose surfaces
The TiO of hydroxyapatite2Porous ceramicss film layer.Contained in titanium alloy surface preparation using existing known disclosed micro-arc oxidation process
There is the TiO of hydroxyapatite2Porous ceramicss film layer.Specifically, provide a kind of specific differential arc oxidation in the present embodiment 1
Technological parameter：1st, bath composition：Sodium hexameta phosphate 4g/L, sodium polyphosphate 0.84g/L and sodium hydroxide 7g/L；2nd, power supply ginseng
Number：Constant current mode, electric current density 0.1A/m2, response frequency 1000Hz, dutycycle 10%, response time 30min.
The shape of metallic core can be designed it is also possible to be designed as being adapted with the profile of artificial Buddhist relics product with solid shape
Shape, design according to being actually needed.It is preferably designed for the shape being adapted with the profile of artificial Buddhist relics product.
The preparation method of the artificial Buddhist relics product of the present embodiment 1, comprises the following steps：
Step one, prepare each raw material by the composition of above-mentioned artificial Buddhist relics product；
Step 2, bone ash crystalline powder, adjuvant and inorganic binder are mixed, be subsequently adding suitable quantity of water, stirring and evenly mixing, extremely
Can pinch to molding, obtain bone ash slurry；Bone ash slurry is added in mould, and hard core is filled in described bone ash slurry
Inside, obtains artificial Buddhist relics base；
Step 3, by fill artificial Buddhist relics base mould put in sintering furnace, be evacuated to 0.09MPa, rise first
Temperature, to 130 DEG C, is incubated 10min；Then it is further continued for being warming up to 250 DEG C, be incubated 30min；Finally it is warming up to 1300 DEG C again, insulation
After 5min；Mould is put in oil phase, carries out quenching；After cooling, mould from, obtain final product artificial Buddhist relics product.
In the preparation method of the present embodiment 1, described mould adopts resistant to elevated temperatures steel mould.
Embodiment 2
Because the composition in bone ash contains the compositions such as substantial amounts of phosphorus, calcium, therefore, easy breed bacteria, asks to solve this
Topic, in the present embodiment 2, described bone ash crystalline powder adopts bone ash crystalline powder and the bone ash mixing of silver load bone ash crystalline powder
Powder replaces；Wherein, the weight of silver load bone ash crystalline powder accounts for the 10%-60% of bone ash mixed-powder gross weight；Described bone
Grey crystalline powder is pulverized after bone ash is placed in roasting at a temperature of 1200 DEG C and is obtained.
The preparation method of described silver load bone ash crystalline powder is as follows：A, addition dust technology, leaching in bone ash crystalline powder
After bubble 10s, filter, obtain the bone ash crystalline powder of surface active；B, again the addition nitre in the bone ash crystalline powder of surface active
Acid sodium solution, soaks 15s, and sodium ion is exchanged with the hydrion of the surface active of bone ash crystalline powder, filters, obtain surface and have
Na3PO4Bone ash crystalline powder；C, to surface, there is Na again3PO4Bone ash crystalline powder in add silver nitrate solution, soak
15min, filters, and is dried, and obtains silver load bone ash crystalline powder.Using bone ash mixed-powder, introduce silver ion, improve anti-
Bacterium performance.
Wherein, the weight of silver load bone ash crystalline powder accounts for the 10%-60% of bone ash mixed-powder gross weight.Preferably employ
40%.
The preparation method of the artificial Buddhist relics product of the present embodiment 2 is identical with embodiment 1.
Embodiment 3
As artificial Buddhist relics product, generally require and be equipped with other type accessories again, therefore, artificial Buddhist relics product for convenience
Following process, be conveniently equipped with multiple type accessories, reach purpose attractive in appearance and holding a memorial ceremony for.As shown in Fig. 2 the people of the present embodiment 3
Worker's dormitory profit product is improved to the structure of metallic core.Described metallic core 1 includes body shape portion 11 and extends external
Portion 12, described one end extending external connection portion 12 is connected with described body shape portion 11, and the other end is external connection end, and extends to described
The outside of bone ash matter outer layer 2, connects for outside type accessories, facilitates following process.As outside the described extension that is given in Fig. 2
Socket part 12 is coupling type, and the extension external connection portion 12 described in certain the present embodiment 3 is not limited to the shape in Fig. 2, any other
It is conveniently used for the version being connected with outside type accessories.Body shape portion 11 becomes with extending external connection portion 12 one
Type.
The above, the only specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and any
Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, all should contain
Cover within protection scope of the present invention.Therefore, protection scope of the present invention should described be defined by scope of the claims.
Claims (10)
1. it is characterised in that including hard core and bone ash matter outer layer, described bone ash matter outer layer passes through a kind of artificial Buddhist relics product
By bone ash slurry sintered bond on the surface of described hard cores；Described hard core obtains containing hydroxyl through differential arc oxidation for surface
The metallic core of the ceramic film of base apatite；Described bone ash slurry, according to mass fraction, including 70 parts of bone ash crystalline powder-
80 parts, 20 parts -30 parts of adjuvant and 20 parts -30 parts of inorganic binder；Described bone ash crystalline powder is by powder after bone ash high-temperature roasting
Broken obtain.
2. a kind of artificial Buddhist relics product according to claim 1 is it is characterised in that described hard core adopts titanium genotype
Core, using differential arc oxidation method, obtains the TiO containing hydroxyapatite in titanium whose surfaces2Porous ceramicss film layer.
3. a kind of artificial Buddhist relics product according to claim 2 is it is characterised in that described metallic core includes body shape
Portion and extension external connection portion, one end of described extension external connection portion is connected with described body shape portion, and the other end is external connection end, and extends
Outside to described bone ash matter outer layer.
4. a kind of artificial Buddhist relics product according to claim 1 is it is characterised in that by before bone ash high-temperature roasting, to bone ash
Disinfection, specific as follows：Bone ash is pulverized as bone ash grain, then bone ash grain is immersed in hydrogen peroxide solution, soak
Time is 1～3 hour, obtains sterilization and brightens bone ash grain；Then sterilization being brightened bone ash grain in output is 1000～1200W's
Process under microwave 20～40 minutes, then stand and naturally cool to room temperature, complete disinfecting of bone ash.
5. a kind of artificial Buddhist relics product according to claim 1 is it is characterised in that described adjuvant includes silicon dioxide, oxygen
Change zirconium, Calcium Carbonate and inorganic pigment；
Described inorganic binder adopts composite inorganic cementing compositions, including zirconium oxide, sodium dihydrogen phosphate powder, calcium phosphate and height
Ridge soil, wherein, zirconium oxide, sodium dihydrogen phosphate powder, calcium phosphate and kaolinic mass ratio are followed successively by 1521.
6. a kind of artificial Buddhist relics product according to any one of claim 1 to 5 is it is characterised in that described bone ash crystallizes
Powder is pulverized after bone ash is placed in roasting at a temperature of 1000-1300 DEG C and is obtained.
7. a kind of artificial Buddhist relics product according to any one of claim 1 to 5 is it is characterised in that described bone ash crystallizes
Powder adopts bone ash crystalline powder and the bone ash mixed-powder of silver load bone ash crystalline powder to replace；Wherein, silver load bone ash knot
The weight at crystalline flour end accounts for the 10%-60% of bone ash mixed-powder gross weight；Described bone ash crystalline powder is to be placed in bone ash
After roasting at a temperature of 1000-1300 DEG C, pulverizing obtains.
8. a kind of artificial Buddhist relics product according to claim 7 is it is characterised in that described silver loads bone ash crystalline powder
Preparation method is as follows：A, in bone ash crystalline powder add dust technology, soak 6-10s after, filter, obtain the bone ash of surface active
Crystalline powder；B, the addition sodium nitrate in the bone ash crystalline powder of surface active again, soak 12-15s, and sodium ion is crystallized with bone ash
The hydrion of the surface active of powder exchanges, and filters, obtains surface and have Na3PO4Bone ash crystalline powder；C, again to surface have
There is Na3PO4Bone ash crystalline powder in add silver nitrate solution, soak 10-15min, filter, be dried, obtain silver load bone ash knot
Crystalline flour end.
9. a kind of preparation method of artificial Buddhist relics product is it is characterised in that comprise the following steps：
Step one, prepare each raw material by any one of the claims 1 to 8；
Step 2, by bone ash crystalline powder or bone ash mixed-powder, adjuvant and inorganic binder mixing, be subsequently adding appropriate
Water, stirring and evenly mixing, to pinching to molding, obtain bone ash slurry；Bone ash slurry is added in mould, and hard core is filled
Inside described bone ash slurry, obtain artificial Buddhist relics base；
Step 3, by fill artificial Buddhist relics base mould put in sintering furnace, be warming up to 120-150 DEG C first, be incubated 8-
10min；Then it is further continued for being warming up to 200-250 DEG C, be incubated 20-30min；Finally it is warming up to 1200-1300 DEG C again, be incubated 3-
After 5min；Mould is put in oil phase, carries out quenching；After cooling, mould from, obtain final product artificial Buddhist relics product.
10. a kind of preparation method of artificial Buddhist relics product according to claim 9 is it is characterised in that in step 3, burning
In sintering process in freezing of a furnace, sintering atmosphere adopts reducing atmosphere, and sintering air pressure adopts negative pressure.
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| CN1408305A (en) * | 2001-09-27 | 2003-04-09 | 苏景颂 | Method for producing simulated buddhist relics |
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| CN1579811A (en) * | 2003-08-09 | 2005-02-16 | 王勇 | Body ash sculpture |
| CN101011211A (en) * | 2007-01-30 | 2007-08-08 | 赵东年 | Method for making sarira |
| CN201295358Y (en) * | 2008-10-31 | 2009-08-26 | 有限会社奇迹 | Sacrifice storage object |
| CN101617909A (en) * | 2009-03-20 | 2010-01-06 | 赵东年 | Preparation method of Buddhist bone relic product |
| KR20120046938A (en) * | 2010-11-03 | 2012-05-11 | 정해광 | A process for the preparation of sarira from powdered bone of human being |
| CN105060859A (en) * | 2015-07-30 | 2015-11-18 | 叶俊 | Remains bone ash treatment method and product thereof |
| CN105859253A (en) * | 2016-04-28 | 2016-08-17 | 付永烈 | Preparation method of artificial relics |
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| CN1408305A (en) * | 2001-09-27 | 2003-04-09 | 苏景颂 | Method for producing simulated buddhist relics |
| US20030080479A1 (en) * | 2001-10-26 | 2003-05-01 | Chingsung Su | Method of forming Sarira |
| CN1579811A (en) * | 2003-08-09 | 2005-02-16 | 王勇 | Body ash sculpture |
| CN101011211A (en) * | 2007-01-30 | 2007-08-08 | 赵东年 | Method for making sarira |
| CN201295358Y (en) * | 2008-10-31 | 2009-08-26 | 有限会社奇迹 | Sacrifice storage object |
| CN101617909A (en) * | 2009-03-20 | 2010-01-06 | 赵东年 | Preparation method of Buddhist bone relic product |
| KR20120046938A (en) * | 2010-11-03 | 2012-05-11 | 정해광 | A process for the preparation of sarira from powdered bone of human being |
| CN105060859A (en) * | 2015-07-30 | 2015-11-18 | 叶俊 | Remains bone ash treatment method and product thereof |
| CN105859253A (en) * | 2016-04-28 | 2016-08-17 | 付永烈 | Preparation method of artificial relics |
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