CN106418466A

CN106418466A - Dispersing performance improving food

Info

Publication number: CN106418466A
Application number: CN201610889295.1A
Authority: CN
Inventors: 钟术光
Original assignee: Individual
Current assignee: Individual
Priority date: 2016-10-12
Filing date: 2016-10-12
Publication date: 2017-02-22

Abstract

The present invention discloses a food. The food comprises an edible particulate matter (or a powder) I containing one (or more) polysaccharides (particularly starch and viscous polysaccharides) or/and peptides or protein-based macromolecular polymers, and a particulate matter (or a powder) of a (or more) hydrophilic polymers II having a higher AAP value than that of the edible particulate matter (or the powder) I. The dispersing performance of the food is improved and particularly the dispersing performance in (warm) water is improved.

Description

The food that dispersive property improves

Technical field

The present invention relates to food.It particularly relates to before use or/and use when dispersion performance improvement food.

Technical background

The products such as food, feed (or its intermediate products), relate generally to powder.Powder in these products contains polysaccharide (particularly starch, viscous polysaccharide) class, peptides or the high molecular polymer with high viscosity such as protein-based and small molecule carbohydrate, The hygroscopic component such as low molecule carbohydrate, amino acid, low molecular peptide, thus, these powders have stronger hygroscopicity, water imbibition, Mobility decline, caking, stickness after powder moisture absorption, water suction, this is difficult when will make these (powder) products before use or/and use To keep preferable dispersity, thus various problems occur.On the one hand, technique require powder material will have good flowing Property, to reach the purpose it being conveyed, stored and being processed；On the other hand, the serviceability of (powder) product, often with Its degree of scatter is directly related.Such as various instant food (such as milk powder, dried fruit powder, Vegetable powder, digested tankage, bone meal, soup stock, alternative Tea etc.) before use or/and after caking when using, will result in powder and be difficult to disperse, occurring that edible difficult, mouthfeel declines etc. asks Topic, thus directly affect the performance of its function.

Polysaccharide (particularly starch, viscous polysaccharide) class in particularly above-mentioned powder, peptides or the macromolecule such as protein-based Polymeric adhesive material, after contact with water when using can water absorption and swelling, easy generation " gel blockage " effect, particularly in pressure-bearing (reaction force of other periphery powders " four walls " when expanding, can be subject to), " gel blockage " effect (lower section herein under state In implication herewith) refer to the hydrophilic polymer particles contacting swellable with water wetted and swelling it is suppressed that fluid is to grain Other regions such as interior shifting of son simultaneously inhibits particle phenomenon swelling further, just as formation so-called " not with the face opened The phenomenon of group ", particularly will be more serious under artesian condition.After the main cause of generation gel blocking phenomenon is swelling, special It is not under artesian condition, the space between particle is reduced and viscosity increases.

After there is " gel blockage " effect, above-mentioned powder is more difficult to disperse, and defines " and the dough do not opened " " periphery Wet, ripe, centre is but fecula ", make above-mentioned problem more serious, food hydraulic performance decline, under the edible difficulty of appearance, mouthfeel The problems such as fall.

Especially, upper powder granule is more thin more easily there are the problems referred to above, and particularly after ultra micro efflorescence, product function is more difficult to Play.

Therefore, also need to the food using the front or/and performance improvement such as dispersion when using or improvement in reality.

Following patent is provided as reference.

Chinese patent CN1079698C (or US5714156) discloses has different AAP values by mixing two classes The hydrogel of (Absorption Against Pressure value, sucting wet gel material absorbs the important parameter of the ability of liquid) Type particle, can obtain cooperative effect, and the wherein AAP value of mixture is predicted than the weight percent of the component based on mixture Value is high.There is the AAP value that different TCC values can make mixture with the aquogel type particle of identical AAP value by mixing two classes unexpectedly Increase.But this patent does not refer to the application in the fields such as food, feed, health treatment.

Content of the invention

The present invention relates to a kind of (using front or/and when using) performance improvement is (especially (using front or/and when using ) dispersive property improves, particularly (using front or/and when using) powder in (warm (temperature 40-100 DEG C)) water point Scattered property is improved) food, this food comprises one (or more) and contains polysaccharide (particularly starch, viscous polysaccharide) class or/and peptide The food grain thing (or powder) I of class or protein-based high molecular polymer and AAP value (i.e. Absorption Against Pressure value, or claim pressure-bearing to expand (swelling) value, this value reflects the Swelling Capacity under polymer renitency, similarly hereinafter) ratio should 1.25 times of food grain thing (or powder) I high (it is preferred that high (containing)) one (or more) (it is preferred that water-insoluble (include " slightly molten ", " slightly soluble ", " almost insoluble " or " fairly insoluble " on ordinary meaning etc. look like, below " water-insoluble " implication all with This)) hydrophilic polymer (particulate matter (or powder)) II.

The present invention relates to a kind of use of (it is preferred that non-water-soluble) hydrophilic polymer (particulate matter (or powder)) II On the way, this hydrophilic polymer (particulate matter (or powder)) II comprises one (or more) for improvement and contains polysaccharide (particularly to form sediment Powder, viscous polysaccharide) class or/and peptides or protein-based high molecular polymer food grain thing (or powder) I edible or/and Pharmaceutical (powder) food (using front or/and when using) dispersive property, especially for improving above-mentioned edible or/and cure Medicinal (powder) food (using front or/and when using) purposes of dispersiveness in (warm (temperature 40-100 DEG C)) water, The AAP value of above-mentioned hydrophilic polymer (particulate matter (or powder)) II higher than this food grain thing (or powder) I (it is preferred that high (containing) 1.25 times).

More preferably, the AAP value of above-mentioned hydrophilic polymer II particle is at least the AAP of above-mentioned food grain thing (or powder) I 1.5 (preferably 2, more preferably 3, more preferably 5, more preferably 10, most preferably 15) times of value.

It is preferred that above-mentioned food grain thing (or powder) I is AAP with respect to the absorption value under a pressure₁, above-mentioned hydrophilic poly- Compound II particle is AAP with respect to the absorption value under a pressure₂, the two mixture with respect to the absorption value under a pressure be AAP_1,2, AAP_1,2＞ (w AAP₁+p·AAP₂) (more preferably >=1.25 (w AAP₁+p·AAP₂)), wherein, w is above-mentioned edible Particulate matter (or powder) I accounts for above-mentioned food grain thing (or powder) I and the percentage of above-mentioned hydrophilic polymer II particle gross weight, P accounts for above-mentioned food grain thing (or powder) I and above-mentioned hydrophilic polymer II particle gross weight for above-mentioned hydrophilic polymer II particle Percentage, and p+w=1, above-mentioned absorption value AAP with respect to pressure is in 21.1g/cm²(0.3psi) and 70.3g/cm² (1psi) between, preferably in 35.2g/cm²(0.5psi) and 56.2g/cm²(0.8psi) measurement, (explanation under the pressure between： For comparativity, the mensure of all absorption values AAP comparing is carried out under identical conditions (pressure) herein).

It is preferred that the TCC value of above-mentioned hydrophilic polymer II particle is higher than the TCC value of above-mentioned food grain thing (or powder) I, The AAP value of the mixture of the two is higher than any one in above-mentioned food grain thing (or powder) I and above-mentioned hydrophilic polymer II particle AAP value, the wherein said absorption value with respect to pressure is in 21.1g/cm²(0.3psi) and 70.3g/cm²Between (1psi), Preferably in 35.2g/cm²(0.5psi) and 56.2g/cm²(0.8psi) measurement under the pressure between.

It is preferred that the weight of above-mentioned food grain thing (or powder) I accounts for above-mentioned food grain thing (or powder) I and above-mentioned parent At least the 10% of aqueous polymer II particle gross weight.

It is preferred that half mass particle size of above-mentioned food grain thing (or powder) I is substantially not less than above-mentioned hydrophilic poly- Half mass particle size of compound II particle.

It is preferred that the difference at least 2 of the AAP value of above-mentioned hydrophilic polymer II and above-mentioned food grain thing (or powder) I is (preferably 5, more preferably 10, more preferably 20, most preferably 40) gram gram.

It is preferred that in 49.2g/cm²(0.7psi), under pressure, the AAP value of above-mentioned hydrophilic polymer II particle is at least 8 (preferably 15, more preferably 25) gram gram.

It is preferred that the TCC value of above-mentioned hydrophilic polymer II material is at least 10 (preferably 20, more preferably 30) gram gram.

It is preferred that it is preferred that the content of above-mentioned food grain thing (or powder) I is in above-mentioned food grain thing (or powder) I With 10% and the 97% of above-mentioned hydrophilic polymer II material gross weight (preferably 20% and 90%, more preferably 20% and 85%, more excellent Select 30% and 75%, most preferably 30% and 65%) between.

It is preferred that half mass particle size (or particle diameter) of above-mentioned hydrophilic polymer II particle is less than 212 microns (70 mesh), Preferably less than 106 microns (140 mesh), more preferably less than 53 microns (270 mesh), more preferably less than 20 microns (700 mesh), most preferably Ground is less than 10 microns (1250 mesh)；Half mass particle size (or particle diameter) of above-mentioned food grain thing (or powder) I particle is less than 300 microns (50 mesh), preferably less than 150 microns (100 mesh), more preferably less than 75 microns (200 mesh), more preferably less than 32 is micro- Rice (450 mesh), most preferably less than 18 microns (800 mesh).

" TTC value " (Teabag Centrifuge Capacity) and " AAP value " definition and during assay method sees below Determination test method part.

Have been found that by adding a fraction of inhomogeneity AAP value higher (it is preferred that half mass particle size is also less) Aquogel type particle (hydrophilic polymer II), be particularly conducive to improve low AAP value aquogel type material (food grain thing (or Powder) I) AAP value.Do not wish to be bound by any theory restrictions it is believed that the particle having higher AAP value absorbs during liquid than AAP value The ability of relatively low " compared with soft " particle deformation resistant is big.In the mixture, less, " harder " particle keeps open architecture to prevent Form impermeability barrier when " softer ", larger particle expansion, prevent or stop generation " gel blockage " effect.

Based on this it has unexpectedly been found that, add higher AAP value hydrophilic polymer II can improve low AAP value containing many Sugared (particularly starch, viscous polysaccharide) class or/and the food grain thing (or powder) I of peptides or protein-based high molecular polymer Dispersive property, thus improve above-mentioned edible or/and pharmaceutical (powder) food (using front or/and when using) (warm (temperature 40-100 DEG C)) dispersive property in water.

Specific embodiment

Edible containing polysaccharide (particularly starch, viscous polysaccharide) class or/and peptides or protein-based high molecular polymer Particulate matter (or powder) I

For the present invention containing polysaccharide (particularly starch, viscous polysaccharide) class or/and peptides or protein-based macromolecule The food grain thing (or powder) I of polymer be generally selected from containing polysaccharide (particularly starch, viscous polysaccharide) class or/and peptides or The crushed material of edible plant, animal or bacterium algae or its edible position of protein-based high molecular polymer or powder, Or it contains the extract powder of polysaccharide (particularly starch, viscous polysaccharide) class or/and peptides or protein-based high molecular polymer Not.The edible position of above-mentioned plant include but do not limit seed, fruit, stem (particularly fleshy stem, " i.e. for wooden, Non-wood, non-highly Fibrotic, below all herewith ", especially underground (meat) stem:Stem tuber is (as potato, jerusalem artichoke, grass Cadbait, rhizome (as ginger, lotus rhizome), bulb (as arrowhead, taro), bulb class (as garlic, lily)), root (particularly fleshy root, Especially (meat) root tuber such as yam bean and sweet potato), leaf, flower (or pollen crushed material of (particularly its broken wall)) or (meat) plant Thing is all, and the edible position of above-mentioned bacterium algae includes but do not limit mycelium, fructification, conidia powder (particularly its broken wall Crushed material), algae thallus, algae bulbous body, algae rhizomorph or bacterium algae all, the edible position of above-mentioned animal includes but does not limit flesh Meat, internal organ, bone, skin, blood, marrow, brains, milk or breast, ovum (or egg), seminal fluid or animal are all.Above-mentioned is edible Plant, animal or bacterium algae are so long as not being on the verge of species extinction or (wildlife) that be protected by law.

The edible position seed of above-mentioned plant or fruit example include but is not limited to the seed of grass (as little Wheat, corn, rice, oat, grain, gruel, broomcorn millet, wheat, barley, Chinese sorghum, adlay etc.), fabaceous seed is (as peanut, soybean, pea Beans, Kidney bean (kidney bean), mung bean, red bean (red bean, rde bean), broad bean, cowpea, lens (Lens culinaris), black soya bean, sword bean, pigeonpea, Goa bean, chick-pea, white jade beans, kidney bean and French beans etc.), the seed (as buckwheat) of buckwheat plant, feverfew Seed (as sunflower seed), the seed (as (black) sesame) of Pedaliaceae plant, the seed (as lotus rhizome, Gorgon fruit) of nymphaeaceae plant, calabash The seed of Lu Ke plant or fruit are (as cucumber, muskmelon, pumpkin, cucurbita pepo, watermelon, wax gourd, balsam pear, chocho, sponge gourd, snake Melon), the fruit (as eggplant, tomato, capsicum, pimento, matrimony vine) of plant of Solanaceae, additionally include nut or the heavily fortified point of kernel approaches plant Kernel (as Semen Ginkgo, Chinese chestnut, walnut kernel, fibert, Mongolian oak, oriental white oak, water caltrop, pine nut, American pistachios) in fruit or drupe.

Edible position (meat) the stem example of above-mentioned plant includes but is not limited to the subterranean stem (such as hundred of liliaceous plant Conjunction, the bulb of fritillary, onion, leek, garlic, shallot, shallot), the subterranean stem (as lotus rhizome) of nymphaeaceae plant, the subterranean stem of zingiberaceous plant The subterranean stem (as potato) of (as ginger), plant of Solanaceae, the subterranean stem of feverfew or ground (meat) stem are (as jerusalem artichoke, lettuce Lettuce), the subterranean stem (as arrowhead) of Notes On Alism At Aceae, the subterranean stem (as water chestnut) of sedge, the underground of aroid Stem (as taro, konjaku), the aerial stem of plant (fleshy stem, tender stem, bulb) of crucifer are (as turnip, turnip, cabbage mustard, knot Cabbage, brussels sprout, collard, cauliflower, broccoli, kohlrabi, pakchoi, Chinese cabbage, leaf mustard, horseradish, beans Lobe dish, shepherd's purse).

Edible position (meat) the root example of above-mentioned plant include but is not limited to Cruciferae, Umbelliferae Daucus, Chenopodiaceae Lepidium, pulse family Pueraria lobota belong to the fleshy root class (as radish, turnip, carrot, root-mustard, root vegetables etc.) of (as Pueraria lobota) plant, (meat) root tuber (loose adventitious root or lateral root) (as Chinese yam, yampi, yam bean, sweet potato etc.) of Dioscoreaceae plant.

The edible position leaf example of above-mentioned plant include but is not limited to chenopod leaf (as spinach, beet), ten Zi Hua section plant leaf (as turnip, turnip, cabbage mustard, cabbage, brussels sprout, collard, cauliflower, broccoli, Kohlrabi, Chinese cabbage, pakchoi, Chinese cabbage, leaf mustard, horseradish, Nasturtium officinale, shepherd's purse), the leaf of samphire (as celery, Coriander (caraway)), Basellaceae fall certain herbaceous plants with big flowers platymiscium leaf (as safflower fall certain herbaceous plants with big flowers, spend certain herbaceous plants with big flowers in vain), the leaf (as three-coloured amaranth) of amaranthaceous plant, rotation The leaf (as water spinach) of flower section plant, the leaf (as peppermint, Chinese artichoke) of labiate, the leaf of malvaceae plant are (as okra, winter Cold dish), the leaf (as Chinese toon) of Meliaceae Chinese toon platymiscium.

Edible bacterium algae (in the fungi) example of above-mentioned plant includes but is not limited to basidiomycetes (such as Tremellales, agaric Mesh, Dacryomycetales, Aphyllophorales) and ascomycetes edible fungi (Di Gu section, Morchellaceae, saddle Cordycepps).Wherein preferred section True such as Agaricaceae, schizophyllum commune section, silk ball Cordycepps, Agaricus edibilis, Bai Mo section, Guang Bing mushroom section, Auriculariaceae, Tremellaceae, Russulaceae Deng edible fungi.

Above-mentioned edible bacterium algae (in fungi) preferred embodiment such as white ginseng bacterium, russule, Termitomyces albuminosus, Pleurotus nebrodensis, Agricus blazei, block Bacterium, matsutake, wizened bacterium, Cordyceps sinensis, hedgehog hydnum Cordycepps Hericium monkey mushroom bacterium, Pleurotus tuber-regium, Aode mushroom (water bird is indulged), Sparassis crispa, Russula vivesscens (Schaeff.) Franch, club fungi, shuttle handle nipple mushroom, macula lutea mushroom (A.Xanthoderma), mushroom (A.Campestris), wooden mushroom (A.Sylvestris), ink cap (Coprinus comatus), bluebonnet (Tricholoma Wudurr), pleura oyster mushroom, many Hole sulphur mushroom, squama porous mushroom, honey Huang ring mushroom, phoenix-tail mushroom, beefsteak fungi, grey mushroom (abalonelike), lid capsule mushroom, apricot mushroom, red mushroom, first mushroom, Huang Umbrella, Agroeybe cylindracea mycelia, long root mushroom, Stropharia rugoso-annulata, Cordyceps militaris, glossy ganoderma, Chinese glossy ganoderma, Ganoderma capuse, Ganoderma tsugae, Poria cocos, pig Siberian cocklebur, Lip river bar dried mushroom, beef-steak fungus, brown ash dried mushroom, elm Huang mushroom, plerotus nebrodensis, sliding mushroom, agrocybe, coprinus comatus, spot jade gill fungus, delicious mushroom Mushroom, Agaricus bitorqui, Brazilian mushroom, flat mushroom, oyster cap fungus, pick up the ears in Florida State, lung shape is picked up the ears, branched oyster mushroom, powder pleat are picked up the ears, goldentop side Ear, deep recessed cup umbrella, ustilago zeae, hickory chick, purple brown hickory chick, black saddle fungus, the wrinkle white saddle fungus of handle, big spoken parts in traditional operas mushroom, alveolar substance Cup fungi, Trichotoma matsutake, Tricholoma mongolicum, yellowish-white ant umbrella, halimasch (armillaria mellea accreting with Rhizoma Gastrodiae), Armillaria luteo-virens, brown residence pleat umbrella, dun residence pleat Umbrella, Calocybe gambosa, scotch bonnet, powder purple mushroom, Lepista mucla (Bull.:Fr.) Cooke, asparagus, bark leucoagaricus naucina, agaricus bisporus, mushroom, freckle Mushroom, white forest land mushroom, pock-marked face mushroom, Stropharia rugoso annulata, straw mushroom, rivet mushroom (Gomphidius rutilus), mushroom, delicious lactarius, macula lutea Russule, bright russule, green mushroom, bolete (cepe, suillusbovinus), brown Ramaria stricta, handle mushroom, grape caulody Coral bacterium, greening Ramaria stricta, Sarcodon imbricatus (L. Ex Franch.) Karst, Hericium erinaceus, orange leather, flame ear, golden ear, white fungus, agaric (black fungus), Uricularia polytricha, Dictyophora phalloidea (Cultivation of Dictyophora, short-skirted veiled lady), meadow horizontal film Lasiosphaera fenzlii, grifola frondosus, the fragrant beautiful mushroom of apricot, Russula vinosa, pixie stool (yellow handle chicken fat Bacterium).

Above-mentioned edible bacterium algae (in algae) example includes but is not limited to Cyanophyta, Chlorophyta, Rhodophyta, Phaeophyta In edible algae.Wherein preferred edible algae kind example such as Mastigocladaceae, Rivulariaceae, Ulotrichaceae, Jiao Mo section, interior branch algae Section, Phyllophoraceae, rosetangle section, Scytosiphonales, Sheng Zao section, Mo Jiao He section, hidden Ulotrichaceae, bulk kelp section, Sargassaceae, Codiaceae, red Pi Zao section, centipede algae section, fragrant plant mentioned in ancient texts section, Zosteraceae, Ulvaceae, Shui Mian section. champiaceae, Hai Touhong section, Alariaceae, quiver algae Section, solieria section, nostocaceae, Shan Zao section, Bangiales section, chlorella section, Gelidiaceae, Oscillariaceae, edible in Hai Mo section Use algae.

Above-mentioned edible bacterium algae (in algae) preferred embodiment such as chlorella (protein pellet algae), spirulina, kylin algae, Extra large film, Irish moss, Zhegucai, coralline algae, sarcodia montagneana, Ma Nizao, sea young pilose antler muscle, red hair algae, ox hair dish, sea bud dish, half plentiful sheath Silk algae, scale dish, flaccid ulothrix algae, bag reef film, oyster dish, Enteromorpha (green moss), intestines Enteromorpha, edge pipe Enteromorpha, bar Enteromorpha, solarization Enteromorpha, edge pipe Enteromorpha, Codiumfragile(sur.) Hariot., Bangiales, seaweed, deliver vegetables, nostoc, porphyra haitanensis, side seaweed, circle seaweed, long seaweed, laver, streak purple Dish, Hai Suomian, agar, fine, soft fur agar, little parmelia saxatilis are adopted, agar of crawling, Chinese little greens, gloiopeltis, centipede algae, ligule centipede Algae, Grateloupia turuturu, solieria, withe solieria, fork branch algae, line row China fir algae, Campylaephora hypnaeoides, bowden rosetangle, trident rosetangle, tawny daylily Algae, rope algae, undaria pinnitafida, pelvetia silquosa, sargassum fusifome, bulk kelp, sargassum, dulse, fragrant plant mentioned in ancient texts (asparagus), flat fragrant plant mentioned in ancient texts, great Ye Algae (sea-tangle), green laver, water silk floss, sea lettuce (sea lettuce), Kong Shichun, link algae, Hai Touhong, bristle algae, chicken feather algae, Digenea simplex, Nostoc commune, chickweed, Meristotheca papulosa (Mont) J. Ag.

Above-mentioned edible animal is so long as not being on the verge of species extinction or the wild animal being protected by law, the example Including but not limited to (wild or raising) fowl poultry kind, the aquatic product of non-livestock and poultry are (as fish, software class (shellfish), Shrimp waste, spine skin Class), amphibian animal (as batrachia), reptiles (as terrapin, class), insects animal.

Above-mentioned edible animal position example includes but is not limited to muscle, internal organ (as the heart, liver, kidney), skin, bone, blood Liquid, milk or breast, egg, marrow, brains, ovum or seminal fluid or animal are all.

Quantity is many, source is wide, the wild animal of outlawry is preferred for the present invention.

Above-mentioned edible animal preferred edible domestic animals animal, the example includes but is not limited to (raising) Carnivora, has Bag mesh, Lagomorpha, Rodentia, Cetacea, Artiodactyla, Perissodactyla animal, preferably Artiodactyla, Perissodactyla, in Lagomorph four Hoof animal, example is as pig, ox, sheep, rabbit, horse, deer, donkey, mule, camel, dog, whale, globefish.

Above-mentioned edible animal preferred edible poultry, the example include but is not limited to (raising) Cursores, natatorial bird, Terrestrial bird, scansorial birds, song bird, wader, example such as chicken, duck, goose, turkey, galeeny, pheasant, dove, quail, ostrich, cormorant, little egret, parrot Nautilus, cuckoo, starling, sparrow.

Above-mentioned edible animal also includes the aquatic product animal of non-livestock and poultry, and the example includes but is not limited to (wild or raise Support) fish of fresh water or seawater, shellfish, Shrimp waste, Echinodermata.

Aquatic livestock example in above-mentioned edible animal is such as：

1), fish

Sturgeon (northwest Cyprinidae no squama), sturgeon (acipenser schrencki, paddlefish), paddlefish, hilsa herring, section goby (juvenile fish is commonly called as the spring Fish), loach, swamp eel, neosalanx taihuensis, public fish, Big Salangid, salmon (dog salmon), mandarin fish, catfish, Pelteobagrus fulvidraco, snakehead (black Fish, ability fish), Silurus Soldatovi Meridionalis, long kiss, eel (common eel), filefish, Colossoma brachypomum, Pangasius sutchi, clarias leather, spot pitch Tail, Micropterus salmoides, Brazilian madai, grass carp, silver carp, bighead, black carp, dace, carp, crucian, megalobrama amblycephala, dace, Met roller, Chinese Spanish mackerel, eastern slope fish, flower loach fish, the long loach of cured light, husky loach, the flat loach of homalocephalus, climb rock loach, flat fin loach, rostellum fish, long fin fin catfish, Clarias fuscus, common eel, swamp eel, bucket fish, gourami, catfish, bream (Changchun bream), black eel, common eel, shad, tapertail anchovy, Tilapia mossambica, pike, Sweetfish, White Meat, plan are red to send fish, Lamprey, trout, China bow fish, yellow pawl fish, naked carp, bar loach, river loach, palpus glance, perch,

Large yellow croaker, refined fish, smallmouth fish, how precious fish, extra large snakeheaded fish, Careproctus, little Jie Yu, moray fish, extra large catfish, Hai Lu Fish, sea hare fish, Lao Banyu, Pi Jiangyu, stone slurry fish, American Red, as pull out freshwater mussel, live awabi, live little Bao, live sea cucumber, live sea intestines, live first Fish, shark, big opium, big moray, great Lu, salmon, smallmouth fish, excellent fish, Lao Banyu, yellow croaker, anglerfish, pull out fish, plus Lucky fish, Hai Fuyu, pogge, sardine, reddish tone fish, bullhead, prosperous fish, tip fish, hairtail, Careproctus, noodles fish, snakeheaded fish, Throw away bar fish, mullet, dace crucian, red hairtail, river hairtail, mixed sweetmeats fish, mandarin fish, major part treasured, nine rabbit fishes, big head, dish fish head, gold Marlin, octopus, island fish, happy together fish, octopus, snakeheaded fish.

2), shellfish

River snail, freshwater mussel, Xiayi shellfish, red inner sieve, red fan treasured, razor clam king, big conch, little seafood, Korea S's spiral shell, black Bao spiral shell, bird Shell, navel spiral shell, sky goose egg, mango shellfish, white clouds shellfish, butterfly shellfish, all sorts of flowers shellfish, little Jie Bei, tiger fur shellfish, red shellfish, longan shellfish, glass Shellfish, Mao Xianzi, numb a species of small clam living in fresh water, extra large oyster shell, Ark Shell, Octopus, as pull out list, Hai Hong, Mao Haihong, little razor clam, penholder Gui, little seafood, Person of low position is fresh, horseshoe shellfish, black buphthalmos, clam belt, compatriot, little hypo spiral shell, Neptunea cumingi, shampoo spiral shell, peppery ripple spiral shell, sharp wave spiral shell, partially determine spiral shell, Sea hare, flower spiral shell, steel spiral shell, Jadeite Mussel, white a species of small clam living in fresh water, conch silk, snail spiral shell.

3), Shrimp waste

Chinese prawn (oriental prawn), Chinese lute shrimp, lantern shrimp, lobster, lobster son, skin shrimp, freshwater shrimp, big sea shrimp, aunt Lu shrimp Ring shrimp, peach blossom shrimp, small shrimp, little red shrimp freshwater shrimp (river prawn, Macrobrachium nipponensis), Macrobrachium rosenbergii, Penaeus Vannmei, Penaeus monodon, The new prawn of knife volume (shrimp), Eriocheir sinensis (river crab, crab, eriocheir sinensis, big crab), mud crab, brave head crab, Japan, Portunus trituberculatus Miers, U.S. jewellery crab, emperor crab, cream crab, clear crab, soft crab, king crab.

Other animal preferred embodiments

Black finless porpoise, dolphin (Pacific Ocean short kiss dolphin, tropical true dolphin, true dolphin, Indo-Pacific Humpback Dolphins), whale (finback, short fin Navigator whale, false killer whale, killer whale, knurl tooth beak whale, bayesian beak whale, sperm whale),

Expanded letter money leech, this thorn clam worm, clam worm, artemia, jellyfish, the sea of sand bite, extra large hedgehog, horsedung sea urchin, Strongylocentrotus nudus, Haiti melon, Eumetopias, North Sea dog, harbor seal, sea cucumber, plum blossom ginseng, stichopus japonicus, Wu Can, eggplant ginseng, inkfish, squid, octopus, abalone,

Shelled Turtle Trionyx Sinensis, tortoise, Trachemys scripta, crocodile tortoise,

Giant salamander (giant salamander), frog (as Rana grylia), bullfrog (as Rana castes beiana shaw, African bullfrog, South America bullfrog),

Boa, Elaphe Carinatas, zaocys dhumnade, elaphe taeniurus Cope, Serpentis, Ptyas korras, mucosal rat snake, E .radiata, walnut husk, Elaphe anomala, eurypholis major, Coluber spinalis, cobra, king cobra, long-noded pit viper, solder horn, green bamboo snake, banked krait, Bungarus multicinctus, Pallas pit viper, sea snake, adder, dinodon rufozonatum snake, powder chain snake and various water snake,

Locust (grasshopper), mole cricket, cricket, katydid, silkworm pupa, tussah chrysalis, moth class pupa (sky chrysalis, slug moth pupa, noctuid pupa, Snout moth pupa), butterfly class pupa, termite, termite egg, ant (as polyrhachis vicina Roger, red chest thorniness ant), ant pupa, ant egg, cicada, cicada Pupa, dragonfly, belostomatid, cadbait larva, roundheaded borer, mantis, mantis ovum, predacious diving beetle, honeybee class, honeybee class pupa, big cricket, fly maggot, Huang Mealworm, earthworm, scorpion are, male silk moth.

Example is such as the preferred Leaf-feeding insects of above-mentioned edible animal (meat and other)：

Bird shellfish meat, big clam meat oyster meat, scallop fourth, scallop, husky fresh meat, ricefield eel meat, extra large intestines, hair a species of small clam living in fresh water meat, outstanding barbel, fresh fish Miscellaneous, fresh fish tripe, black carp, hairtail, shark brain, head of stinging, skin of stinging, fresh jellyfish, shark tripe, Mr.'s flesh of fish, razor clam mouth, peeled shrimp, Ripple spiral shell meat, penis otariae, fish muscle, fish intestines, the fish sperm, fish maw, shark skin, icepro fish-skin, shark larynx, crab oil, red caviar, shark's fin.

Eat for the present invention or medicinal plant, animal or Homonemeae or its application site contain generally should be first during toxin Remove or reduce toxin to complete scope, or remove the position without toxin for the position reservation containing toxin and (such as remove filefish internal organ, blood Liquid etc., has removed elapid head, processes the rhizome of Chinese monkshood).

Above-mentioned different edible plant, animal, Homonemeae or its edible position can in any combination, that is, they (crushed material or powder) any mixture, also can be used for the present invention, these combination (mixture) (there is biologically active (pharmacologically active)) carrying containing polysaccharide (particularly starch, viscous polysaccharide) class or/and peptides or protein-based high molecular polymer Thing is taken also preferably to be used for the present invention.

The polysaccharide obtaining from above-mentioned edible plant, animal, Homonemeae or its edible position (particularly forms sediment Powder, viscous polysaccharide), polypeptide, protein powder, and protein powder through hydrolysis, enzymolysis, degraded etc. mode obtain polypeptide, polypeptide The polypeptide of the even lower level obtaining through modes such as hydrolysis, enzymolysis, degradeds, polysaccharide (particularly starch, viscous polysaccharide) are through hydrolysis, enzyme The polysaccharide (particularly starch, viscous polysaccharide) of the even lower level that the modes such as solution, degraded obtain is equally applicable to the present invention.Example is such as： Starch, inulin, polyfructosan, swan-mussel polysaccharide (particularly starch, viscous polysaccharide), resistant dextrin, natural plant gum；Hydrolysis yolk powder, Pearl Gly-His-Lys, dragon protein, milk basic protein, colostrum basic protein fraction powder, corn oligopeptide powder, corn protein powder, wheat oligomeric Peptide；Degreasing (ox) meat enzymolysis is obtained beef polypeptide, and fresh (pig) Liver Channel enzymolysis, decolouring, deodorization, ultrafiltration are refining to obtain liver peptide, (pig) Blood is obtained hyperglobulinemia peptide through enzymolysis；The collagen peptide that Animal Bone or skin or squama obtain through the mode such as hydrolysis or enzymolysis, such as fish, sea cucumber Deng collagen peptide；Bird's nest collagen peptide；Milk peptide；White of an egg peptide, aquatic peptide are (as its meat albumen digests the peptide being obtained, such as Sardine meat albumen peptide；Polypeptide from Chlamys farreri, silk-fibroin peptide, complex peptides (the multiple proteins mixing such as animals and plants, aquatic products, poultry or fowl product The complex peptides that thing is obtained through enzymolysis).

Hydrophilic polymer II

Above-mentioned hydrophilic polymer II used by the present invention, be a kind of " pharmaceutically acceptable water-swellable, preferably Ground, the substantially insoluble polymer of water ".They are preferably meant that a kind of such pharmaceutically acceptable material (polymerization Thing), when it is exposed in excessive water, it is expanded to its equilibrium volume, but is substantially insoluble in solution, this polymerization Thing material is also commonly referred to as " hydrocolloid " or " superabsorbent " material.For definition used herein, if a kind of material is recognized For being water miscible, it is substantially soluble in excessive water formation solution, thus loses it initial, particularly granular Shape, and be substantially scattered in the aqueous solution with molecular state.Common criterion is that water dissolvable material is that no substantial extent is handed over Connection, because crosslinking will make material have water-insoluble.

Above-mentioned hydrophilic polymer II is typically crosslinked.Crosslinked amount generally should be enough to make polymer keep water substantially On insoluble minimum, but under maximum that also should be swelling enough in making polymer holding water, so that polymer energy Absorb the desired amount of liquid and and swelling.

The crosslinking of usual polymer is by one of two distinct types of crosslinking agent using realizing.First type Crosslinking agent is polymerisable crosslinking agent.Suitable polymerizable crosslinking agent is in reactivity generally to the monomer for preparing polymer , and therefore usually contain at least two can be with the functional group of monomer reaction.The example of suitable polymerizable crosslinking agent, for Include vinyl-based unsaturated monomer for radical polymerization, such as N, N '-methylene-bisacrylamide, include for polycondensation Polyamines or polyol.

The crosslinking agent of Second Type is rear crosslinking agents.Rear crosslinking agents are generally not involved in whole polymerization process, but after relatively Time, it can be with polymer reaction when being supplied to suitable cross linking conditions.Suitable post-treatment condition is included using heating Process, such as greater than about 60 DEG C of temperature, be exposed to ultraviolet, be exposed to microwave, steam or high humility are processed, HIGH PRESSURE TREATMENT or with having Machine solvent is processed.

The rear crosslinking agents being applied to the present invention are usually water miscible.Suitable rear crosslinking agents be at least there are two can be with A kind of organic compound of any carboxyl on polymer, the functional group of carboxylic acid, amino or hydroxyl reaction or degree of functionality.Suitable The example of rear crosslinking agents includes but is not limited to diamine, polyamines, dihydroxylic alcohols, polyol, polycarboxylic acid and polyoxide.Another kind of suitable Suitable rear crosslinking agents contain the metal ion with more than two positive charge, such as Al3+, Fe2+, Ce3+, Ce4+, Ti4+, Zr4+ and Cr3+.

When polymer is for cationic polymer, suitable crosslinking agent is the material of polymer anion, such as polyacrylic acid Sodium, carboxymethylcellulose calcium, or polyphosphate.

Above-mentioned hydrophilic polymer II preferably (in molecular structure) contains multiple anionic functional groups, such as sulfonic group, and more allusion quotation Type ground such as the polymer of carboxyl.The example being applied to this polymer is included from polymerisable, undersaturated, acidiferous monomer preparation Those polymer.Therefore, this monomer includes the ethylenic unsaturated acid containing at least one carbon-to-carbon olefinic double bond and acid anhydride.More Body ground, these monomers are selected from ethylenically unsaturated carboxylic acids and acid anhydrides, olefinic unsaturated sulfonic acid and its mixture.

In preparing above-mentioned hydrophilic polymer II, may also comprise some generally with less amount of non-acid monomers.This non- Acid monomers may include water solubility or the dispersible ester of water of such as acidiferous monomer, and does not contain carboxylic acid or sulfonic monomer.Cause This optional non-acid monomers may include the monomer containing such as lower class functional group：Carboxylic acid or sulphonic acid ester, hydroxyl, amide groups, amino, nitrile Base and quaternary ammonium salt base.These non-acid monomers are known material, are described in more detail in the U.S. for example issuing for 28th for 2 months for 1978 In the United States Patent (USP) 4,062,817 (Westerman) that patent 4,076,663 (Masuda etc.) and on December 13rd, 1977 issue, The two is all incorporated by reference.

Ethylenically unsaturated carboxylic acids and carboxylic acid anhydride monomer include acrylic compounds, typically acrylic acid itself, methacrylic acid, Ethylacrylic acid, chloroacrylic acid, alpha-cyanoacrylate, methacrylic acid (crotonic acid), phenylacrylic acid, acryloxy propionic (- acryloxypropionic acid), sorbic acid, chlorine sorbic acid, angelic acid, cinnamic acid, to chloro-cinnamic acid ,- Sterylacrylic acid, itaconic acid, citraconic acid, mesaconic acid, glutaconate, aconitic acid, maleic acid, fumaric acid, tricarboxylic second Alkene and maleic anhydride.

Olefinic unsaturated sulfonic acid monomer includes aliphatic series or aromatic vinyl sulfonic acids such as vinyl sulfonic acid, allyl sulphonic acid, second Thiazolinyl toluenesulfonic acid and styrene sulfonic acid；Acrylic acid and methacrylic sulfonic acids such as sulfoethyl acrylate, methacrylic acid sulphur second Ester, acrylic acid sulphur propyl ester, methacrylic acid sulphur propyl ester, 2- hydroxy-3-methyl acryloxypropyl sulfonic acid and 2- acrylamide -2- Methyl propane sulfonic acid.

More preferably be preferred for the above-mentioned hydrophilic polymer of the present invention II be usually in and/or part neutralization weakly acidic or Weakly alkaline water-swellable and insoluble polymer.The pKa (or pKb) of these polymer is advisable with about 2～about 12, more favorably Ground is about 2～about 10, conveniently about 3～about 6.

It has been found that using pKa (or pKb) less than about 2 or using pKa (or pKb) greater than about 12 expansiveness, water Insoluble polymer, generally will appear from the unwanted performance of the present invention, such as low absorption liquid rate, low Release Performance, and And there may also be larger excitant etc.

Above-mentioned suitable slightly acidic water swellability and insoluble polymer (in molecular structure) comprises to be used as weak acid Functional group.These functional groups include but is not limited to carboxyl, sulfate groups, inferior sulfate radical group, and phosphate groups.Suitable Functional group is carboxyl.Generally, these functional groups are connected on the base polymer of crosslinking.Suitable base polymer includes poly- third Acrylamide, polyvinyl alcohol, EMA anhydride copolymer, polyvingl ether, polyacrylic acid, poly- carbon number is C1～C4 alkyl Acrylic acid, poly- hydroxyl carbon atom number is C1～C4 alkyl acrylic, PVP, polyvinyl beautiful jade, and they Copolymer.Can also be using natural polysaccharide (particularly starch, viscous polysaccharide) polymer, including carboxymethylcellulose calcium, carboxylic Methyl starch, hydroxypropyl or ethyl cellulose, alginic acid, alginate, humic acid, carrageenan, acrylic acid-grafted starch, third The cellulose of olefin(e) acid grafting, and their copolymer., can also be gathered as poly-aspartate, polyglutamic acid using the polypeptide of synthesis Mixing acidic amino acid (such as poly- mixing aspartic acid, such as poly-aspartate-aspartic acid-lysine acid (4: 2: 1) in fact； Poly- mixing glutamic acid, such as polyglutamic acid-lysine acid (4: 1) in fact.Term " poly- mixing acidic amino acid " refers to chain herein In containing several amino acids including acidic amino acid, and the molal quantity of acidic amino acid (as aspartic acid, glutamic acid) The poly- several amino acids assuming acidity more than the molal quantity of basic amino acid (as lysine, arginine) (gather multiple amino Acid is referring to document：US5247068A).Preferably it is suitable for the above-mentioned slightly acidic water swellability of the present invention and water-insoluble polymerization The example of thing is generally greater than about 100000 acroleic acid polymerization including but not limited to (in and/or part neutralization) weight average molecular weight Thing, poly- carbon number are C1～C4 alkyl acrylic, poly- hydroxyl carbon atom number is C1～C4 alkyl acrylic, acrylic acid-acrylic Acid ester polymer, polyvinyl alcohol-acrylic block copolymers, starch graft acrylic acid polymer, cellulose graft acrylic acid gather Compound, humic acid, polycarbophil (Polycarbophil polymers), alginic acid, poly-aspartate, polyglutamic acid, poly- mixed Close aspartic acid and poly- mixing glutamic acid, and their mixture.

Above-mentioned suitable alkalescent water swellability and insoluble polymer (in molecular structure) comprises to be used as weak base Functional group.These functional groups include but is not limited to primary, secondary and tertiary amino, imino group, and acylamino-.Suitable functional group is ammonia Base.Generally, these functional groups are connected on the matrix polymer of crosslinking.Suitable matrix polymer includes polyamine or polyimides, Polyethyleneimine, polyethylenepolyamine, polyacrylamide, polypropylene amine, polypropylene carbon number is C1～C4 alkylamine, and poly- carbon is former Subnumber is C1～C4 alkyl amine, and poly- carbon number is C1～C4 alkyl carbon number is C1～C4 alkylamine, poly- hydroxyl Base carbon number is C1～C4 alkyl amine, and poly- hydroxyl carbon atom number is C1～C4 alkyl carbon number is C1～C4 alkane Base amine, and polyquaternium, and their copolymer.Can also be using natural polysaccharide (particularly starch, viscous polysaccharide) polymerization Thing, including chitin (particularly starch, viscous polysaccharide) and chitosan (particularly starch, viscous polysaccharide) and other ammonia Quito sugar (particularly starch, viscous polysaccharide).Can also be using the polypeptide of synthesis, such as poly-asparagine, polyglutamine, gathers and relies Propylhomoserin, poly arginine, poly- mixed-alkali amino acid is (as poly- mixing lysine, such as polyglutamic acid-lysine (1: 3) in fact；Poly- Mixing arginine, such as poly-aspartate-arginine (1: 4) in fact.Term " poly- mixed-alkali amino acid " refers in chain herein Containing the several amino acids including basic amino acid, and the molal quantity of basic amino acid (as lysine, arginine) is more than Acidic amino acid (as aspartic acid, glutamic acid) molal quantity and assume poly- several amino acids (the poly- several amino acids of alkalescence Referring to document：US5247068A).Preferably it is suitable for the above-mentioned alkalescent water swellability of the present invention and water-insoluble polymer Example including but not limited to (in and/or part neutralization) weight average molecular weight be generally greater than about 100000 polyamine or polyimides, Polyethyleneimine, polypropylene amine, polyethylenepolyamine, polypropylene carbon number be C1～C4 alkylamine, poly- carbon number be C1～ C4 alkyl amine, poly- carbon number are C1～C4 alkyl carbon number is C1～C4 alkylamine, poly- hydroxyl carbon atom number For C1～C4 alkyl amine, poly- hydroxyl carbon atom number be C1～C4 alkyl atomicity be C1～C4 alkylamine, chitin, Chitosan, other glycosaminoglycans, poly-asparagine, polyglutamine, polylysine, poly arginine, gathers mixing and relies ammonia Acid and poly- mixing arginine, and their mixture.

The above-mentioned hydrophilic polymer II being more preferably preferred for the present invention is water-soluble containing carboxyl selected from (in molecular structure) Swollen property and insoluble polymer.The example of these polymer includes hydrolyzed starch-acrylonitrile graft copolymer, part neutralizes Starch-Acrylontirile Graft Copolymer, starch-acrylate graft copolymer, part neutralization starch-acrylate graft copolymer, Sapond vinyl acetate-acrylate copolymer, the acrylonitrile of hydrolysis or acrylamide copolymer, any of the above described copolymer The polymer of micro- cross-linked network, part neutralization polyacrylic acid and part neutralization polyacrylic micro- cross-linked network polymerization Thing, (pregelatinated 20-80%'s) partially pregelatinized starch (explanation：After starch pregelatinated, its AAP value rises from on pregelatinated degree Now first rise to maximum and then decline, after complete pregelatinated, AAP value is very low, difficult AAP value is to survey in cold water and normal-temperature water Determine or indeterminacy), and their mixture.These polymer can be used alone or the mixing with two or more different polymer The form of thing uses.The example of these polymeric materials is disclosed in United States Patent (USP) 3,661,875, United States Patent (USP) 4,076,663, U.S. In state's patent 4,093,776, United States Patent (USP) 4,666,983 and United States Patent (USP) 4,734,478.

The most preferably being preferred for preparing above-mentioned hydrophilic polymer II is (part neutralization) polyacrylic micro- cross-linked network Polymer and its starch derivatives.

In weak acid (or weak base) property functional group in above-mentioned weak acid (or alkali) property water-swellable and insoluble polymer It is about 5～about 100 moles of % with degree, more advantageously about 30～about 95 moles of %, suitably about 50～about 90 moles of %, optimum About 70～about 80 moles of % in ground.

Molecular weight ranges for the hydrophilic polymer II in the present invention are very wide.The water-swellable of relatively high molecular weight and water Insoluble polymer, typically favourable for the use in the present invention.It is applied to water-swellable and the water-insoluble of the present invention The weight average molecular weight of polymer is generally greater than about 20000, is preferred with being greater than about 100000, preferably greater than about 200000, more preferably Greater than about 500000, preferably more than 1000000, up to about 10000000.The method measuring polymer molecular weight generally exists It is known in the art.

Sometimes more easily the mode of expression polymer molecular weight is at 25 DEG C, the aqueous solutions of polymers of 1.0 weight % Viscosity.It is applied to the polymer of the present invention, the viscosity with its 1.0 weight % aqueous solution at 25 DEG C is about 200～about 80000 centipoises (mPa s) is advisable, preferably about 500～about 80000 centipoises, and optimum is about 1000～about 80000 centipoises.

Currently preferred hydrophilic polymer II is that have higher absorption ability or Teabag Centrifuge Capacity Value.Absorbability or Teabag Centrifuge Capacity mean given polymer absorbs under the conditions of non-swelling and The ability of the liquid that it contacts.TCC can with the way of contact of the property of absorbed liquid and liquid and polymeric material not Significantly change together.

Determination test method

AAP value (with respect to the absorption value of pressure) determination test

This test measurement superabsorbent is with respect to external pressure between 21.1g/cm (0.3psi) and 70.3g/cm (1psi) Absorbability, represents so that superabsorbent is swelling with respect to the single shaft of this pressure.Aquogel type to two or more types The sucting wet gel material mixture of grain, observes Absorption AgainstPressure and changes with the percentage composition of component of mixture The curve becoming, depends primarily on pressure condition.Adequately reflect use condition, the pressure of measurement AAP value is in 21.1g/cm (0.3psi) and 70.3g/cm (1psi) between.AAP value reflects the gel hardness of hygroscopic material.Grain structure is kept during wetting The moisture absorption particle of (keeping space) will show good liquid absorption and not collapse to impermeability blob of viscose.AAP value Low aquogel type material will tend to forming the Weak Gels that the permeability to liquid is relatively low and subsides under stress.

The ceramic filter plate of 120 millimeters of diameter and porosity are " Zero " (ceramic filter bought from Schott Duran) it is placed in 150 millimeters of diameter, high 30 millimeters of Petri dish (Petridsh).By 0.9% in distilled water The sodium-chloride water solution of (weight) adds Petri dish so that filter is capped.By 125 millimeters of circular filter paper of diameter (Schwarzband 589 having bought from Schleicher and Schull) is placed on filter plate, and is chlorinated sodium solution completely Wetting.

The plexiglass cylinder bottom aperture of internal diameter 60+/- 0.1 millimeter and high 50 millimeters is 36 microns (400 mesh) Sieving cloth seals.0.9000+/- 0.0005 gram superabsorbent is carefully sprinkling upon described heat-resisting organic glass clean and being dried On the screen of glass cylinder.Superabsorbent must be made to be uniformly distributed on sieve.

The external diameter of one cover plate is 59+/- 0.1 millimeter, internal diameter is 51 millimeters and a height of 25 millimeters, and has a diameter of 50 millimeters With a height of 34 millimeters of additional load, the weight of cover plate and the pre- level pressure in the scope between 21.1g/cm and 70.3g/cm Power is corresponding, and this pressure is generally default to be set to 49.2g/cm²(0.7psi).Cover plate and load are placed in cylinder, and whole cylinder device exists Weigh on balance, be accurate to 0.01 gram.Then whole cylinder device is placed on the moistening filter paper in Petri dish so as to Absorb 1 hour.Then this equipment is removed from filter plate, be re-weighed.

Thoroughly cleaning answered by cylinder device and filter plate between measurements, and measurement afterchlorinate sodium solution and filter paper should be changed every time.

AAP value (with respect to the absorption value of pressure) is calculated as below：

AAP value=[(weight of cylinder device after absorption)-(weight of cylinder device when being dried)]：(superabsorbent initial Weight).

TTC value (Teabag Cetrifuge Capacity) determination test

Teabag Centrifuge Capacity test measurement Teabag Centrifuge Capacity value, it is right The measurement of liquid is retained in gel rubber material under static pressure.

Superabsorbent is placed in " tea bag ", 20 minutes in the sodium chloride solution of immersion 0.9% (weight), is then centrifuged for 3 minutes.The ratio of the weight and the initial weight of dry superabsorbent that retain liquid is the absorbability of superabsorbent.

The sodium chloride solution of 2 liters of 0.9% (weight) in distilled water is injected 5 lis of a size of 24 cm x 30 cm x In the disk of rice.Liquid packed height should be about 3 centimetres.

The size of tea bag bag is 6.5 centimetres of 6.5 cm x, can be from Teekanne in Dusseldorf, and Germany is public Department obtains.This bag plastic bag sealing device for kitchen use (such as from Krups, the VACUPACK PLUS that Germany has bought) of standard Heat seal.

Tea bag is opened by carefully partial cut, then weighs.Superabsorbent examination by 0.200+/- 0.005 gram Sample is put in tea bag.Then sealed with heat sealer.It is referred to as sample tea bag.

Seal tea bag as blank test.

Then make each tea bag holding level, vibration sample tea bag is so that superabsorbent is evenly distributed in whole bag In.Then sample tea bag and blank tea bag are placed on the surface of salt solution, make tea bag submergence 5 seconds with a flat spoon so that its Moisten (tea bag will float over salt solution surface but completely moistening) completely.Immediately begin to timing.

Dipping, after 20 minutes, sample tea bag and blank tea bag is removed from salt solution, and puts into Bauknecht In the centrifuge (230 millimeters of diameter) of WS130, Bosch 772NZK 096 or equivalence, so that each Bao Jun sticks to centrifuge On the outer wall of cylinder.Cover the lid of centrifuge, start centrifuge, and speed is increased to rapidly 1400 revs/min.Centrifuge is 1400 After stablizing under rev/min, immediately begin to timing.After 3 minutes, close centrifuge.

Take out sample tea bag and blank tea bag, weigh respectively.

The Teabag Centrifuge Capacity (TCC value) of aquogel type superabsorbent sample is calculated as below：

TCC value=[(weight of sample tea bag after centrifugation)-(weight of blank tea bag after centrifugation)-(dry one-tenth hydrogel The weight of superabsorbent)] ÷ (weight of dry superabsorbent).

The determination of half mass particle size

By putting into the sample of known weight in Retsch mechanical sifter, and vibration one is specific under qualifications Time cycle, determine the particle size distribution of superabsorbent.Weigh the sample parts being retained on each sieve and chassis Weight, and it is recorded as the percentage of original sample weight.

Add specimen mounting after superabsorbent polymeric material dry for 100+/- 0.5 gram is weighed, then cover specimen mounting with cover.

Four sieves are stacked from bottom to up as follows：Stainless steel bottom plate, No. 325, No. 100, No. 50 and No. 20；These Screen size (ASTM-E-11-61) for the U.S..Sample is delivered to the top flat of this sieve series, powder is evenly distributed on sieve. Stainless steel cover is placed on No. 20 sieve.

Stacked sieve is placed on the Retsch testing sieve shaker Vibotronic of timer Appropriate location on TypeVE1.Guarantee that Retsch lid coordinates with the tight of vibrator as far as possible.Timer is located at 10 minutes, start to test.When vibrator stops, bushing screen is removed from vibrator.

Then, for example by different measurements, weigh the retained screening of each sieve, be accurate to 0.01 gram.

Rapid operation is important to avoid superabsorbent to absorb moisture in this test.

Half mass particle size of given aquogel type absorbent polymer particle sample is defined as being divided sample according to quality Become the particle size of half, that is, half sample will have the particle size less than half mass size by weight, and half sample will have Particle size more than half mass size.When 50% mass value does not correspond to U.S.A.Standard Testing Sieve (U.S. National standard testing sieve) size perforate when, logical working standard particle size method for drafting (wherein on graph paper draw retain Open with sieve size on given sieve size perforate or by the accumulating weight percentage of the particle sample of given sieve size perforate The relation curve in hole) determine half mass particle size.For determine aquogel type hygroscopic polymeric composition granule particle size this A little methods further describe authorizes the United States Patent (USP) 5 of Goldman etc. on October 29th, 1991, and in 061,259, the document introduces For reference.

Embodiment

Lower non-limiting examples further describe the preferred embodiment in the scope of the invention.Within the scope of the invention These embodiments also can have many changes.

Embodiment 1

Wheat seed crushed material and the mixture of partially pregelatinized starch, the part by weight of the two is 10:2.

Reference examples 1

In embodiment, partially pregelatinized starch is dried waxy corn starch (full pregelatinated) by drum-type and replaces, and other are constant.

Explanation：The APP value that above-mentioned crushed material, partially pregelatinized starch, drum-type are dried waxy corn starch three is respectively 1.8g/g, 3.4g/g, 0.3g/g, half mass particle size is 180 microns, 200 microns, 200 microns, and the TCC value of three is respectively For 2.4g/g, 4.6g/g, 0.2g, the APP value of the former two's mixture is 3.2g/g, the 1st, the APP value of 3 mixtures be 1.0g/ g.

Embodiment 2

The mixture of peanut seed crushed material (300 mesh) and sodium carboxymethylcellulose (400 mesh), the part by weight of the two is 10:1.

Reference examples 2

In embodiment, sodium carboxymethylcellulose is replaced by lactose, and other are constant.

Explanation：Above-mentioned crushed material, sodium carboxymethylcellulose, lactose three APP value be respectively 1.3g/g, 3.1g/g, 0.02g/g, the TCC value of three is respectively 2.1g/g, 4.6g/g, 0.04g/g, and the APP value of the former two's mixture is 3.4g/g, the 1st, the APP value of 3 mixtures is 1.0g/g.

Embodiment 3

Soya seeds crushed material (200 mesh) and the mixture of CMS (150 mesh), the part by weight of the two is 10: 3.

Reference examples 3

In embodiment, CMS is replaced by starch, and other are constant.

Explanation：Above-mentioned crushed material, CMS, the APP value of starch three are respectively 1.7g/g, 3.8g/g, 1.5g/g, The TCC value of three is respectively 2.8g/g, 5.6g/g, 2.5g/g, and the APP value of the former two's mixture is 4.4g/g, the 1st, 3 mixing The APP value of thing is 1.6g/g.

Embodiment 4

Buckwheat seed crushed material (100 mesh) and the mixture of polylysine (150 mesh), the part by weight of the two is 10:5.

Reference examples 4

In embodiment, polylysine is replaced by soluble soybean polysaccharide, and other are constant.

Explanation：Above-mentioned crushed material, polylysine, the APP value of soluble soybean polysaccharide three are respectively 1.8g/g, 15.2g/ G, 0.1g/g, the TCC value of three is respectively 2.7g/g, 20.4g/g, 0.07g/g, and the APP value of the former two's mixture is 16.8g/ G, the 1st, the APP value of 3 mixtures be 1.1g/g.

Embodiment 5

The mixture of sesame seed crushed material (200 mesh) and hydroxypropyl cellulose (250 mesh), the part by weight of the two is 10:1.

Reference examples 5

In embodiment, hydroxypropyl cellulose is replaced by microcrystalline cellulose, and other are constant.

Explanation：Above-mentioned crushed material, hydroxypropyl cellulose, the APP value of microcrystalline cellulose three are respectively 1.4g/g, 3.8g/ g、2.3g/g.

Embodiment 6

Cucumber crushed material (250 mesh) and the mixture of hydroxyethyl cellulose (300 mesh), the part by weight of the two is 10:10.

Reference examples 6

In embodiment, hydroxyethyl cellulose is replaced by lactose, and other are constant.

Explanation：Above-mentioned crushed material, hydroxyethyl cellulose, lactose three APP value be respectively 1.2g/g, 2.7g/g, 0.02g/g.

Embodiment 7

Walnut kernel and the mixture of carrageenan (300 mesh), the part by weight of the two is 10:0.5.

Reference examples 7

In embodiment, carrageenan is replaced by lactose, and other are constant.

Explanation：Above-mentioned crushed material, carrageenan, the APP value of lactose three are respectively 1.8g/g, 3.9g/g, 0.1g/g.

Embodiment 8

Gumbo (Fruit pod) crushed material (100 mesh) and the mixture of ammonium alginate (200 mesh), the part by weight of the two is 10: 2.

Reference examples 8

In embodiment, ammonium alginate is dried waxy corn starch (full pregelatinated) by drum-type and replaces, and other are constant.

Explanation：Above-mentioned crushed material, ammonium alginate, drum-type be dried waxy corn starch three APP value be respectively 2.2g/g, 5.6g/g, 0.1g/g, the TCC value of three is respectively 2.8g/g, 6.8g/g, 0.2g/g, and the APP value of the former two's mixture is 6.1g/g, the 1st, the APP value of 3 mixtures be 1.3g/g.

Embodiment 9

Lotus rhizome crushed material (100 mesh) and the mixture of CMS (200 mesh), the part by weight of the two is 10:1.5.

Reference examples 9

In embodiment, CMS is replaced by calcium silicates, and other are constant.

Explanation：Above-mentioned crushed material, CMS, the APP value of calcium silicates three are respectively 2.3g/g, 4.9g/g, 2.1g/ g.

Embodiment 10

Dehydrated potato powder minces the mixture of (150 mesh) and sodium alginate (200 mesh), and the part by weight of the two is 10:0.2.

Reference examples 10

In embodiment, sodium alginate is replaced by microcrystalline cellulose, and other are constant.

Explanation：Above-mentioned crushed material, sodium alginate, microcrystalline cellulose three APP value be respectively 1.9g/g, 5.8g/g, 2.5g/g.

Embodiment 11

The mixture of the starch (250 mesh) of arrowhead crushed material (200 mesh) and sodium acrylate graft, the part by weight of the two is 10:3.

Reference examples 11

In embodiment, the starch of sodium acrylate graft is replaced by anticaking agent E551 (silica), and other are constant.

Explanation：Above-mentioned crushed material, the starch of sodium acrylate graft, the APP value point of anticaking agent E551 (silica) three Not Wei 1.8g/g, 15.6g/g, 2.3g/g, the TCC value of three is respectively 2.6g/g, 23.4g/g, 3.6g/g, the former two's mixture APP value be 13.6g/g, the 1st, the APP value of 3 mixtures be 1.9g/g.

Embodiment 12

Konjaku crushed material (300 mesh) and the mixture of polylysine hydrochloride (350 mesh), the part by weight of the two is 10: 2.5.

Reference examples 12

In embodiment, polylysine hydrochloride is replaced by Arabic gum, and other are constant.

Explanation：Above-mentioned crushed material, polylysine hydrochloride, the APP value of Arabic gum three are respectively 3.8g/g, 13.5g/ G, 2.6g/g, the TCC value of three is respectively 5.3g/g, 24.7g/g, 3.8g/g, and the APP value of the former two's mixture is 15.4g/g, 1st, the APP value of 3 mixtures is 3.2g/g.

Embodiment 13

The mixture of the cellulose (250 mesh) of kohlrabi crushed material (200 mesh) and sodium acrylate graft, the weight of the two Ratio is 10:1.

Reference examples 13

In embodiment, the cellulose of sodium acrylate graft is replaced by sodium silicoaluminate, and other are constant.

Explanation：Above-mentioned crushed material, the cellulose of sodium acrylate graft, sodium silicoaluminate three APP value be respectively 0.8g/g, 26.4g/g、2.5g/g.

Embodiment 14

Root of kudzu vine crushed material (200 mesh) and the mixture of poly-aspartate (300 mesh), the part by weight of the two is 10:2.

Reference examples 14

In embodiment, poly-aspartate is replaced by ca aluminosilicate sodium, and other are constant.

Explanation：Above-mentioned crushed material, poly-aspartate, ca aluminosilicate sodium three APP value be respectively 2.6g/g, 21.5g/g, 2.7g/g.

Embodiment 15

Chinese yam root crushed material (200 mesh) and the mixture of chitosan hydrochloride (250 mesh), the part by weight of the two For 10:2.5.

Reference examples 15

In embodiment, chitosan hydrochloride is dried waxy corn starch (full pregelatinated) by drum-type and replaces, and other are not Become.

Explanation：Above-mentioned crushed material, chitosan hydrochloride, drum-type are dried the APP value point of waxy corn starch three Wei not 2.5g/g, 7.4g/g, 0.3g/g.

Embodiment 16

Lily crushed material (200 mesh) and the mixture of polyglutamic acid sodium (200 mesh), the part by weight of the two is 10:3.

Reference examples 16

In embodiment, polyglutamic acid sodium is replaced by carboxymethylcellulose calcium, and other are constant.

Explanation：Above-mentioned crushed material, polyglutamic acid sodium, the APP value of carboxymethylcellulose calcium three are respectively 0.7g/g, 17.3g/ g、3.6g/g.

Embodiment 17

Termitomyces albuminosus crushed material (200 mesh) and the mixture of poly (sodium aspartate) (200 mesh), the part by weight of the two is 10: 2.

Reference examples 17

In embodiment, poly (sodium aspartate) is replaced by CMS, and other are constant.

Explanation：Above-mentioned crushed material, poly (sodium aspartate), the APP value of CMS three are respectively 2.4g/g, 18.3g/ g、3.7g/g.

Embodiment 18

Monkey mushroom bacterium powder minces the mixing of (100 mesh) and poly-aspartate-aspartic acid-lysine acid (4: 2: 1) (100 mesh) Thing, the part by weight of the two is 10:4.

Reference examples 18

In embodiment, poly-aspartate-aspartic acid-lysine acid (4: 2: 1) is replaced by microcrystalline cellulose, and other are constant.

Explanation：Above-mentioned crushed material, poly-aspartate-aspartic acid-lysine acid (4: 2: 1), microcrystalline cellulose three APP value is respectively 2.9g/g, 15.8g/g, 2.3g/g, and the TCC value of three is respectively 4.1g/g, 23.4g/g, 3.6g/g, the first two The APP value of person's mixture is 17.4g/g, the 1st, the APP value of 3 mixtures be 2.5g/g.

Embodiment 19

Poria cocos crushed material (250 mesh) and the mixture of polyglutamic acid-lysine acid sodium-salt (4: 1) (300 mesh), the weight of the two Amount ratio is 10:2.

Reference examples 19

In embodiment, polyglutamic acid-lysine acid sodium-salt (4: 1) is replaced by hydroxymethyl cellulose, and other are constant.

Explanation：Above-mentioned crushed material, polyglutamic acid-lysine acid sodium-salt (4: 1), the APP value point of hydroxymethyl cellulose three Wei not 1.8g/g, 23.7g/g, 3.2g/g.

Embodiment 20

Armillaria mellea accreting with Rhizoma Gastrodiae crushed material (300 mesh) and the mixture of polycarbophil (400 mesh), the part by weight of the two is 10: 5.

Reference examples 20

In embodiment, polycarbophil is replaced by starch, and other are constant.

Explanation：Above-mentioned crushed material, polycarbophil, the APP value of starch three are respectively 1.8g/g, 3.9g/g, 1.7g/g, front The APP value of the two mixture is 5.4g/g, the 1st, the APP value of 3 mixtures be 1.8g/g.

Embodiment 21

Agaric crushed material (300 mesh) and the mixture of polyvinyl alcohol-acrylic block copolymers sodium salt (200 mesh), the two Part by weight be 10:1.

Reference examples 21

In embodiment, polyvinyl alcohol-acrylic block copolymers sodium salt is replaced by carboxymethylethylcellulose, and other are constant.

Explanation：Above-mentioned crushed material, polyvinyl alcohol-acrylic block copolymers sodium salt, carboxymethylethylcellulose three APP value is respectively 3.2g/g, 16.3g/g, 3.2g/g.

Embodiment 22

Irish moss crushed material (200 mesh) and the mixture of PAA-acrylate polymer (200 mesh), the weight of the two Amount ratio is 10:0.5.

Reference examples 22

In embodiment, PAA-acrylate polymer is replaced by calcium stearate, and other are constant.

Explanation：Above-mentioned crushed material, PAA-acrylate polymer, the APP value of calcium stearate three are respectively 3.5g/g、23.2g/g、0.3g/g.

Embodiment 23

The mixture of Enteromorpha crushed material (200 mesh) and poly- hydroxy sodium (200 mesh), the part by weight of the two is 10:0.1.

Reference examples 23

In embodiment, poly- hydroxy sodium is replaced by guar gum, and other are constant.

Explanation：Above-mentioned crushed material, poly- hydroxy sodium, guar gum three APP value be respectively 3.2g/g, 22.5g/g、3.1g/g.

Embodiment 24

Pelvetia silquosa crushed material (200 mesh) and the mixture of poly-aspartate-arginine (1: 4) hydrochloride (200 mesh), the two Part by weight be 10:2.

Reference examples 24

In embodiment, poly-aspartate-arginine (1: 4) hydrochloride is replaced by pectin, and other are constant.

Explanation：Above-mentioned crushed material, poly-aspartate-arginine (1: 4) hydrochloride, the APP value of pectin three are respectively 3.8g/g、25.2g/g、3.3g/g.

Embodiment 25

(degreasing) domestic animals muscle (venison) crushed material (200 mesh) and poly-aspartate sodium salt (degree of neutralization 30%) (250 mesh) Mixture, the part by weight of the two be 10:3.

Reference examples 25

In embodiment, poly-aspartate sodium salt (degree of neutralization 30%) is denatured starch and replaces, and other are constant.

Explanation：Above-mentioned crushed material, poly-aspartate sodium salt (degree of neutralization 30%), the APP value of converted starch three are respectively 3.9g/g、17.2g/g、3.6g/g.

Embodiment 26

Poultry muscle (pheasant meat) crushed material (200 mesh) and the mixture of poly- ethylacrylic acid sodium (200 mesh), the weight of the two Amount ratio is 10:2.5.

Reference examples 26

In embodiment, poly- ethylacrylic acid sodium is replaced by carrageenan, and other are constant.

Explanation：Above-mentioned crushed material, poly- ethylacrylic acid sodium, the APP value of carrageenan three are respectively 2.8g/g, 15.5g/ G, 3.1g/g, the APP value of the former two's mixture is 7.9g/g, the 1st, the APP value of 3 mixtures be 2.9g/g.

Embodiment 27

Fish muscle (loach) crushed material (200 mesh) and the mixture of polyacrylic acid sodium salt (degree of neutralization 80%) (250 mesh), two The part by weight of person is 10:2.

Reference examples 27

In embodiment, polyacrylic acid sodium salt (degree of neutralization 80%) is replaced by calcium phosphate, and other are constant.

Explanation：Above-mentioned crushed material, polyacrylic acid sodium salt (degree of neutralization 80%), the APP value of calcium phosphate three are respectively 2.6g/ G, 15.8g/g, 0.3g/g, the APP value of the former two's mixture is 9.2g/g, the 1st, the APP value of 3 mixtures be 1.1g/g.

Embodiment 28

Shellfish meat (longan shellfish) crushed material (200 mesh) and the mixture of polyethyleneimine amine hydrochlorate (250 mesh), the weight of the two Amount ratio is 10:4.

Reference examples 28

In embodiment, polyethyleneimine amine hydrochlorate is replaced by magnesium silicate, and other are constant.

Explanation：Above-mentioned crushed material, polyethyleneimine amine hydrochlorate, the APP value of magnesium silicate three are respectively 2.7g/g, 17.8g/ G, 2.5g/g, the TCC value of three is respectively 4.6g/g, 28.3g/g, 4.1g/g, and the APP value of the former two's mixture is 20.3g/g, 1st, the APP value of 3 mixtures is 2.2g/g.

Embodiment 29

Shrimp waste (lobster) digested tankage minces the mixture of (200 mesh) and polyallylamine hydrochloride (250 mesh), the weight of the two Ratio is 10:3.

Reference examples 29

In embodiment, polyallylamine hydrochloride is replaced by hydroxypropyl methyl cellulose, and other are constant.

Explanation：Above-mentioned crushed material, polyallylamine hydrochloride, the APP value of hydroxypropyl methyl cellulose three are respectively 2.5g/ g、23.2g/g、3.5g/g.

Embodiment 30

Expanded letter money leech crushed material (200 mesh) and the mixture of polyethylenepolyamine hydrochloride (200 mesh), the weight ratio of the two Example is 10:1.

Reference examples 30

In embodiment, polyethylenepolyamine hydrochloride is replaced by mannitol, and other are constant.

Explanation：Above-mentioned crushed material, polyethylenepolyamine hydrochloride, the APP value of mannitol three are respectively 2.8g/g, 20.6g/ g、0.01g/g.

Embodiment 31

Horsedung sea urchin crushed material (200 mesh) and the mixture of polypropylene ethylamine hydrochloride (200 mesh), the weight ratio of the two Example is 10:2.

Reference examples 31

In embodiment, polypropylene ethylamine hydrochloride is replaced by calcium fumarate, and other are constant.

Explanation：Above-mentioned crushed material, polypropylene ethylamine hydrochloride, calcium fumarate three APP value be respectively 2.2g/g, 16.6g/g、0.2g/g.

Embodiment 32

The mixture of Carnis Zaocys crushed material (100 mesh) and poly- hydrochloride salt of arginin (150 mesh), the part by weight of the two is 10:5.

Reference examples 32

In embodiment poly- hydrochloride salt of arginin be modified starch replace, other are constant.

Explanation：Above-mentioned crushed material, poly- hydrochloride salt of arginin, the APP value of modified starch three are respectively 2.9g/g, 17.8g/ G, 3.5g/g, the TCC value of three is respectively 4.2g/g, 29.4g/g, 4.7g/g, and the APP value of the former two's mixture is 20.7g/g, 1st, the APP value of 3 mixtures is 3.2g/g.

Embodiment 33

Ant crushed material (200 mesh) and the mixture of poly- ethyl propylene methylamine hydrochloride (250 mesh), the weight ratio of the two Example is 10:2.

Reference examples 33

In embodiment, poly- ethyl propylene methylamine hydrochloride is replaced by maltodextrin, and other are constant.

Explanation：Above-mentioned crushed material, poly- ethyl propylene methylamine hydrochloride, the APP value of maltodextrin three are respectively 2.3g/g、13.8g/g、0.1g/g.

Embodiment 34

Fish-egg crushed material (200 mesh) and the mixture of poly-asparagine (250 mesh), the part by weight of the two is 10:1.

Reference examples 34

In embodiment, poly-asparagine is replaced by beta-schardinger dextrin, and other are constant.

Explanation：Above-mentioned crushed material, poly-asparagine, beta-schardinger dextrin three APP value be respectively 2.7g/g, 14.9g/g, 0.6g/g, the APP value of the former two's mixture is 6.7g/g, the 1st, the APP value of 3 mixtures be 1.3g/g.

Embodiment 35

Tripe crushed material (200 mesh) and the mixture of poly- hydroxybutyl allylamine hydrochloride (300 mesh), the weight ratio of the two Example is 10:0.5.

Reference examples 35

In embodiment, poly- hydroxybutyl allylamine hydrochloride is replaced by powdered celluloses, and other are constant.

Explanation：Above-mentioned crushed material, poly- hydroxybutyl allylamine hydrochloride, the APP value of powdered celluloses three are respectively 2.5g/g、16.8g/g、2.6g/g.

Embodiment 36

Deerskin crushed material (200 mesh) and the mixture of poly- hydroxymethyl propylene butyl amine hydrochlorate (250 mesh), the weight of the two Amount ratio is 10:2.

Reference examples 36

In embodiment, poly- hydroxymethyl propylene butyl amine hydrochlorate is replaced by magnesium phosphate, and other are constant.

Explanation：Above-mentioned crushed material, poly- hydroxymethyl propylene butyl amine hydrochlorate, the APP value of magnesium phosphate three are respectively 2.4g/g, 13.8g/g, 0.3g/g, the APP value of the former two's mixture is 7.1g/g, the 1st, the APP value of 3 mixtures be 1.2g/ g.

Embodiment 37

The mixture of crab oil crushed material (200 mesh) and chitin phosphate phosphoric acid (300 mesh), the part by weight of the two is 10:1.

Reference examples 37

In embodiment, chitin phosphate phosphoric acid is replaced by sucrose glyceryl monostearate, and other are constant.

Explanation：Above-mentioned crushed material, chitin phosphate phosphoric acid, the APP value of sucrose glyceryl monostearate three are respectively 2.2g/g、5.3g/g、0.1g/g.

Embodiment 38

The cellulose graft acroleic acid polymerization that the crushed material (200 mesh) of the concentrated dry product of aloe leaf juice neutralizes with 30% The mixture of thing (200 mesh), the part by weight of the two is 10:2.

Reference examples 38

In embodiment, the cellulose graft acrylate copolymer of 30% neutralization is replaced by methylcellulose, and other are constant.

Explanation：Above-mentioned crushed material, the cellulose graft acrylate copolymer of 30% neutralization, the APP of methylcellulose three Value is respectively 1.2g/g, 13.2g/g, 1.6g/g.

Embodiment 39

The mixture of the polyglutamic acid (200 mesh) that the water extract dry extract (200 mesh) of purple sesame neutralizes with 70%, the two Part by weight be 10:3.

Reference examples 39

In embodiment, the polyglutamic acid of 70% neutralization is dried waxy corn starch (full pregelatinated) by drum-type and replaces, and other are not Become.

Explanation：Above-mentioned powder thing, the polyglutamic acid of 70% neutralization, drum-type are dried the APP value point of waxy corn starch three Wei not 1.2g/g, 17.7g/g, 0.2g/g.

Embodiment 40

Datlily crushed material (200 mesh) and the mixture of sodium carboxymethyl starch (200 mesh), the part by weight of the two is 10: 10.

Reference examples 40

In embodiment, sodium carboxymethyl starch is dried waxy corn starch (full pregelatinated) by drum-type and replaces, and other are constant.

Explanation：The APP value that above-mentioned crushed material, sodium carboxymethyl starch, drum-type are dried waxy corn starch three is respectively 1.1g/g, 5.4g/g, 0.2g/g, the TCC value of three is respectively 2.5g/g, 8.3g/g, 0.3g/g, the APP of the former two's mixture Be worth for 7.3g/g, the 1st, the APP value of 3 mixtures be 0.6g/g

Embodiment 41

Glutinous rice crushed material (250 mesh) and polylysine-glutamic acid (1:1) mixture of (250 mesh), the part by weight of the two For 10:2.

Reference examples 41

Polylysine-glutamic acid (1 in embodiment:1) replaced by aluminium hydroxide desiccant gel, other are constant.

Explanation：Above-mentioned crushed material, polylysine-glutamic acid (1:1), the APP value difference of aluminium hydroxide desiccant gel three For 2.1g/g, 17.4g/g, 3.3g/g, the APP value of the former two's mixture is 14.4g/g, the 1st, the APP value of 3 mixtures be 2.4g/g.

Embodiment 42

Swan-mussel polysaccharide (200 mesh) and the mixture of calcium carboxymethylcellulose (200 mesh), the part by weight of the two is 10:2.

Reference examples 42

In embodiment, calcium carboxymethylcellulose is dried waxy corn starch (full pregelatinated) by drum-type and replaces, and other are constant.

Explanation：The APP value that above-mentioned powder thing, calcium carboxymethylcellulose, drum-type are dried waxy corn starch three is respectively 1.5g/g, 3.6g/g, 0.4g/g, the TCC value of three is respectively 3.1g/g, 5.2g/g, 0.3g/g, the APP of the former two's mixture Be worth for 5.1g/g, the 1st, the APP value of 3 mixtures be 1.0g/g.

Embodiment 43

Hydrolysis yolk powder (200 mesh) and the mixture of sodium starch glycollate (200 mesh), the part by weight of the two is 10: 1.

Reference examples 43

In embodiment, sodium starch glycollate is dried waxy corn starch (full pregelatinated) by drum-type and replaces, and other are constant.

Explanation：The APP value that above-mentioned powder thing, sodium starch glycollate, drum-type are dried waxy corn starch three is respectively 2.7g/g, 5.8g/g, 0.3g/g, the APP value of the former two's mixture is 5.4g/g, the 1st, the APP value of 3 mixtures be 1.1g/ g.

Embodiment 44p

Nucleoprotamine powder (200 mesh) and the mixture of aluminium alginate (200 mesh), the part by weight of the two is 10:2.

Reference examples 44p

In embodiment, aluminium alginate is replaced by guar gum, and other are constant.

Explanation：Above-mentioned powder thing, aluminium alginate, guar gum three APP value be respectively 2.4g/g, 5.4g/g, 1.25g/g, the APP value of the former two's mixture is 6.5g/g, the 1st, the APP value of 3 mixtures be 1.3g/g.

Embodiment 45

Nucleoprotamine powder (200 mesh) and the mixture of sodium alginate (200 mesh), the part by weight of the two is 10:2.

Reference examples 45

In embodiment, sodium alginate is replaced by guar gum, and other are constant.

Explanation：Above-mentioned powder thing, sodium alginate, guar gum three APP value be respectively 2.4g/g, 3.4g/g, 1.25g/g, the APP value of the former two's mixture is 4.4g/g, the 1st, the APP value of 3 mixtures be 1.3g/g.

Embodiment 46

Animal Bone or skin are through hydrolyzing or collagen Gly-His-Lys (200 mesh) that the mode such as digest obtains and poly-aspartate-arginine (3:1) mixture of (200 mesh), the part by weight of the two is 10:1.

Reference examples 46

Poly-aspartate-arginine (3 in embodiment:1) waxy corn starch (full pregelatinated) is dried by drum-type to replace, its He is constant.

Explanation：Above-mentioned powder thing, poly-aspartate-arginine (3:1), drum-type is dried the APP of waxy corn starch three Value is respectively 2.5g/g, 18.6g/g, 0.3g/g, and the APP value of the former two's mixture is 8.1g/g, and the 1st, the APP of 3 mixtures It is worth for 1.2g/g.

Embodiment 47

The mixture of the poly arginine (200 mesh) that oyster meat (doing) crushed material (200 mesh) neutralizes with 45%, the weight of the two Ratio is 10:4.

Reference examples 47

In embodiment, the poly arginine of 45% neutralization is replaced by hydroxyethyl cellulose, and other are constant.

Explanation：Above-mentioned crushed material, the poly arginine of 45% neutralization, the APP value of hydroxyethyl cellulose three are respectively 2.9g/ G, 13.2g/g, 2.8g/g, the TCC value of three is respectively 4.1g/g, 21.2g/g, 3.8g/g, and the APP value of the former two's mixture is 14.8g/g, the 1st, the APP value of 3 mixtures be 2.7g/g.

Powder caking performance detection under detection example 1 high humidity environment

Embodiment, reference examples sample powder are with, after the sieved sieve of same mesh number, taking the powder that sieves of identical weight respectively It is concurrently placed at 2～15 days under 90%-95% relative humidity and occurs taking out after caking after wherein sample segment simultaneously, be placed in above-mentioned Gently vibration screening on sieve, measure respectively by the caking powder of sieve account for whole powder (by sieve+unsanctioned) weight Amount ratio.The results are shown in Table 2.

Dispersiveness (or caking capacity) detection in warm water for detection example 2 powder

The embodiment of identical weight, reference examples sample powder is taken to be scattered in the warm of the same temperature of 6 times of its weight respectively In water (50～80 DEG C), gently disturb the iron wire strainer filtering using 2mm aperture after mixing 2 minutes, measure filter screen and its above respectively The gross weight of filter residue and air filter net weight (after being washed down and be dried with water or prior measure), ask for poor the filter residue of the two Weight and deduct wherein moisture (normal temperature or more low-temperature reduced-pressure drying remove water) filter residue dry weight, calculate embodiment filter residue dry weight with right The ratio (setting reference examples filter residue dry weight as 1) of filter residue dry weight as usual.The results are shown in Table 3.

Powder caking performance test results under table 2 embodiment and reference examples sample high humidity environment

Embodiment 9	36.3%	Embodiment 11	24.6%	Embodiment 13	21.8%
						Reference examples 9	60.7%	Reference examples 11	55.7%	Reference examples 13	50.4%
Embodiment 14	33.5%	Embodiment 17	18.7%	Embodiment 18	22.5%
						Reference examples 14	65.3%	Reference examples 17	38.2%	Reference examples 18	47.2%
Embodiment 22	28.5%	Embodiment 27	25.3%	Embodiment 28	27.4%
						Reference examples 22	67.4%	Reference examples 27	46.2%	Reference examples 28	53.6%
Embodiment 31	26.1%	Embodiment 36	28.3%	Embodiment 37	37.2%
						Reference examples 31	68.3%	Reference examples 36	61.7%	Reference examples 37	65.8%

Table 3-1 embodiment and reference examples sample dispersive property testing result in warm water

Embodiment 1	0.49	Embodiment 4	0.32	Embodiment 7	0.37
						Reference examples 1	1	Reference examples 4	1	Reference examples 7	1
Embodiment 10	0.23	Embodiment 12	0.35	Embodiment 15	0.41
						Reference examples 10	1	Reference examples 12	1	Reference examples 15	1
Embodiment 16	0.26	Embodiment 17	0.42	Embodiment 24	0.38
						Reference examples 16	1	Reference examples 17	1	Reference examples 24	1
Embodiment 25	0.38	Embodiment 32	0.32	Embodiment 34	0.37
						Reference examples 25	1	Reference examples 32	1	Reference examples 34	1

Table 3-2 embodiment and reference examples sample dispersive property testing result in warm water

Claims

1. a kind of (using front or/and when using) dispersive property improve (particularly (and using front or/and when using) powder exists Dispersiveness improvement in (warm) water) food, this food comprises one (or more) and contains polysaccharide (particularly starch, viscosity Polysaccharide) the food grain thing (or powder) I of class or/and peptides or protein-based high molecular polymer and AAP value are (i.e. Absorption Against Pressure value, or claim pressure-bearing to expand (swelling) value, under this value reflection polymer renitency 1.25 times of Swelling Capacity, similarly hereinafter) high than food grain thing (or powder) I (it is preferred that high (containing)) one (or more) hydrophilic Polymer (particulate matter (or powder)) II.

2. food according to claim 1, wherein said particulate matter (or powder) I is AAP with respect to the absorption value under a pressure₁, Wherein said hydrophilic polymer II particle is AAP with respect to the absorption value under a pressure₂, the two mixture with respect to a pressure Under absorption value be AAP_1,2, AAP_1,2＞ (w AAP₁+p·AAP₂) (more preferably >=1.25 (w AAP₁+p·AAP₂)), its In, w accounts for described food grain thing (or powder) I and described hydrophilic polymer II particle for described food grain thing (or powder) I The percentage of gross weight, p accounts for described food grain thing (or powder) I and described hydrophilic polymeric for described hydrophilic polymer II particle The percentage of thing II particle gross weight, and p+w=1, described absorption value AAP with respect to pressure is in 21.1g/cm2 (0.3psi) and 70.3g/cm2 (1psi) between, preferably between 35.2g/cm2 (0.5psi) and 56.2g/cm2 (0.8psi) Pressure under measurement, the mensure of described absorption value AAP comparing is carried out under identical conditions (pressure).

3. food according to claim 1 is it is characterised in that the TCC value of described hydrophilic polymer II particle is higher than described edible The TCC value of particulate matter (or powder) I, the AAP value of the mixture of the two is higher than described food grain thing (or powder) I and described parent The AAP value of any one in aqueous polymer II particle, the wherein said absorption value with respect to pressure is at 21.1g/cm2 (0.3psi) Under pressure and 70.3g/cm2 (1psi) between, preferably between 35.2g/cm2 (0.5psi) and 56.2g/cm2 (0.8psi) Measurement, the mensure of described absorption value AAP comparing is carried out under identical conditions (pressure).

4. food according to claim 1 is it is characterised in that described food grain thing (or powder) I is selected from containing polysaccharide (especially It is starch, viscous polysaccharide) edible of class or/and peptides or protein-based high molecular polymer or/and pharmaceutical plant, dynamic The crushed material at thing or bacterium algae or its edible or/and pharmaceutical position or or powder, or its contain polysaccharide (particularly starch, Viscous polysaccharide) extract of class or/and peptides or protein-based high molecular polymer or powder.

5. food according to claim 4 it is characterised in that described edible or/and pharmaceutical plant, animal or bacterium algae or Its edible or/and pharmaceutical position are selected from seed (such as the wheat, corn, rice, oat, grain, gruel, broomcorn millet, little of grass Wheat, barley, Chinese sorghum, adlay etc.), fabaceous seed (as (red in peanut, soybean, pea, Kidney bean (kidney bean), mung bean, red bean Red bean, rde bean), broad bean, cowpea, lens (Lens culinaris), black soya bean, sword bean, pigeonpea, goa bean, chick-pea, white jade beans, the four seasons Beans and French beans etc.), the seed (as buckwheat) of buckwheat plant, the seed (as sunflower seed) of feverfew, Pedaliaceae plant Seed (as (black) sesame), the seed (as lotus rhizome, Gorgon fruit) of nymphaeaceae plant, the seed of cucurbitaceous plant or fruit be (as yellow Melon, muskmelon, pumpkin, cucurbita pepo, watermelon, wax gourd, balsam pear, chocho, sponge gourd, serpent melon), the fruit of plant of Solanaceae (as eggplant, kind Eggplant, capsicum, pimento, matrimony vine), additionally include kernel in the nut of nut or kernel approaches plant or drupe (as Semen Ginkgo, plate Chestnut, walnut kernel, fibert, Mongolian oak, oriental white oak, water caltrop, pine nut, American pistachios).

6. food according to claim 4 it is characterised in that described edible or/and pharmaceutical plant, animal or bacterium algae or Its edible or/and pharmaceutical position are selected from subterranean stem (such as the lily, bulb of fritillary, onion, leek, garlic, big of liliaceous plant Green onion, shallot), the subterranean stem (as lotus rhizome) of nymphaeaceae plant, the subterranean stem (as ginger) of zingiberaceous plant, the subterranean stem of plant of Solanaceae (as potato), the subterranean stem of feverfew or on the ground (meat) stem (as jerusalem artichoke, lettuce), Notes On Alism At Aceae subterranean stem (such as Arrowhead), the subterranean stem (as water chestnut) of sedge, the subterranean stem (as taro, konjaku) of aroid, crucifer The aerial stem of plant (fleshy stem, tender stem, bulb) (as turnip, turnip, cabbage mustard, cabbage, brussels sprout, collard, flower Cabbage, broccoli, kohlrabi, pakchoi, Chinese cabbage, leaf mustard, horseradish, Nasturtium officinale, shepherd's purse), Cruciferae, Umbelliferae are recklessly Rhaphanus, Chenopodiaceae Lepidium, pulse family Pueraria lobota belong to the fleshy root class of (as Pueraria lobota) plant (as radish, turnip, carrot, root-mustard, root Dish etc.), (meat) root tuber (loose adventitious root or lateral root) (as Chinese yam, yampi, yam bean, sweet potato etc.) of Dioscoreaceae plant.

7. food according to claim 4 it is characterised in that described edible or/and pharmaceutical plant, animal or bacterium algae or Its edible or/and pharmaceutical position are selected from basidiomycetes (such as Tremellales, Agaricales, Dacryomycetales, Aphyllophorales) and ascus Mushroom edible fungi (Di Gu section, Morchellaceae, saddle Cordycepps).The wherein true such as Agaricaceae of preferred section, schizophyllum commune section, embroidery The edible fungies such as Coccaceae, Agaricus edibilis, Bai Mo section, Guang Bing mushroom section, Auriculariaceae, Tremellaceae, Russulaceae, Cyanophyta, Chlorophyta, Edible algae in Rhodophyta, Phaeophyta.Wherein preferably edible algae kind example for example Mastigocladaceae, Rivulariaceae, Ulotrichaceae, Jiao Mo section, Endocladiaceae, Phyllophoraceae, rosetangle section, Scytosiphonales, Sheng Zao section, Mo Jiao He section, hidden Ulotrichaceae, bulk kelp section, sargassum Section, Codiaceae, dulse section, centipede algae section, fragrant plant mentioned in ancient texts section, Zosteraceae, Ulvaceae, Shui Mian section, champiaceae, Hai Touhong section, Alariaceae, Oscillariaceae, solieria section, nostocaceae, Shan Zao section, Bangiales section, chlorella section, Gelidiaceae, Oscillariaceae, extra large film Edible algae in section, (wild or raise) fowl poultry kind, non-livestock and poultry aquatic product (as fish, software class (shellfish), Shrimp waste, Echinodermata), amphibian animal (as batrachia), reptiles (as terrapin, class), insects animal.

8. food according to claim 1 it is characterised in that described hydrophilic polymer II be selected from and/or part neutralization weak acid Property or weakly alkaline water-swellable and insoluble polymer or partially pregelatinized starch.

9. food according to claim 1 it is characterised in that described hydrophilic polymer II be selected from starch graft acrylic acid polymer, Cellulose graft acrylate copolymer, humic acid, polycarbophil (Polycarbophil polymers), alginic acid, chitin, Chitosan, other glycosaminoglycans, poly-aspartate, polyglutamic acid, poly- mixing aspartic acid, poly- mixing glutamic acid, poly- Asparagine, polyglutamine, polylysine, poly arginine, poly- mixing lysine, poly- mixing arginine, and their mixing Thing.

10. according to Claim 8 or 9 food is it is characterised in that the weak acid in described hydrophilic polymer II or alkalescent sense The degree of neutralization of group is 5～100 moles of %.