CN106400596B - A kind of durability anti-counterfeit rice paper and its manufacturing process - Google Patents
A kind of durability anti-counterfeit rice paper and its manufacturing process Download PDFInfo
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- CN106400596B CN106400596B CN201610954775.1A CN201610954775A CN106400596B CN 106400596 B CN106400596 B CN 106400596B CN 201610954775 A CN201610954775 A CN 201610954775A CN 106400596 B CN106400596 B CN 106400596B
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- rice paper
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F13/00—Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production
- D21F13/02—Making hand-made paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/48—Elements suited for physical verification, e.g. by irradiation
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Abstract
The invention discloses a kind of manufacturing process of durability anti-counterfeit rice paper, including with slurry, copy paper and shine paper, a kind of durability anti-counterfeit material is added when with slurry in the slurry, by the copy paper anti-fake material and rice paper it is completely into one and be in specific security feature, it can rapidly and accurately be identified by professional detection device, for identifying the true and false of painting and calligraphy pieces.Meanwhile security pattern is designed on rice paper copying, corresponding pattern is transferred on rice paper by when copy paper;Raised security pattern is designed on shining paper wall, and corresponding pattern is transferred on rice paper when shining paper;Pass through the identification to specific pattern on rice paper, it is possible to authenticate the true and false of painting and calligraphy pieces.
Description
Technical field
The present invention relates to a kind of durability anti-counterfeit rice paper and its manufacturing process.
Background technique
Rice paper quality is flexible, exquisiteness is neat and well spaced, color is durable, is the manual painting paper of Chinese tradition, for a long time, painting and calligraphy
The true and false identification of works is a persistence, the social problem of generality, therefore the anti-fake of rice paper is that the painting and calligraphy pieces true and false identifies
One of important component.The identification of traditional painting and calligraphy pieces is mainly focused on the artistic form and physical form of painting and calligraphy pieces
Two aspects, experience and knowledge level to identification person have higher requirement.With the rapid hair of society being constantly progressive with science and technology
Exhibition, also occur at present various advanced counterfeit protection measures come to painting and calligraphy pieces carry out it is anti-fake.Such as: some is known using radio frequency
Other technology is implanted into electronic tag or chip, but this anti-fake poor in timeliness, because electronic tag or chip are easy to tear open in works
It unloads or damages, also disappear therewith if there is this situation antiforge function.For another example: some is all using being added in paper or works
Anti-fake material progress such as fluorescence etc is anti-fake, but the resistance to physical and chemical performance of fluorescent material is poor under normal circumstances, in height
Under temperature, high humidity or acid, alkali environment, security feature can weaken until disappearing.
Summary of the invention
To solve the problems, such as that above-mentioned painting and calligraphy pieces security feature durability is poor, the present invention provides a kind of durability anti-counterfeit a surnames
Paper and its manufacturing process.
The technical solution of the invention is as follows provides a kind of durability anti-counterfeit rice paper, is made of paper pulp fiber, especially it
Be in: further include be added paper pulp fiber in anti-fake material, the anti-fake material be one or more different nanometers it is infrared
Up-conversion.In order to be applied to the rice paper of different performance, above-mentioned nanometer infrared up-conversion material can be aqueous or oiliness.No
The color that same nanometer infrared up-conversion material is presented is different.(800-1100nm) can be presented red under the conditions of infrared excitation
Color, blue and green can be added a kind of water-soluble and/or oil-soluble nanometer infrared up-conversion material, can also be added two
It is infrared that a variety of water-soluble or/and oil solubility nanometers can also be added in kind water solubility or/and oil solubility nanometer infrared up-conversion material
A kind of color or two kinds of colors or two or more face is presented in up-conversion under the conditions of 800-1100nm infrared excitation
Color.
In order to further improve security feature, rice paper of the present invention further includes protrusion or/and recess patterns, above-mentioned protrusion
Or/and recess patterns are located at rice paper edge or blank space.
It preferably, further include the anti-fake material on rice paper surface where being located at above-mentioned protrusion or/and recess patterns, it is above-mentioned anti-fake
Material is nanometer infrared up-conversion material.
Above-mentioned anti-fake material includes two kinds of nanometer infrared up-conversion materials being located in the protrusion and recess patterns.
The present invention also provides a kind of manufacturing process of durability anti-counterfeit rice paper, including with slurry, copy paper and solarization paper process, match
During slurry, anti-fake material is added in paper pulp fiber, which is one or more nanometers of infrared up-conversion materials;
Preferably, further include the steps that security pattern is arranged;
The step of above-mentioned setting security pattern specifically:
Pattern is set on copying by way of machining, when copy paper, is transferred the pattern on rice paper;
Alternatively, design protrusion or/and recess patterns on shining paper wall, transfer the pattern on rice paper when shining paper;
Alternatively, pattern is arranged on copying by way of machining, when copy paper, transfer the pattern on rice paper;
Meanwhile design protrusion or/and recess patterns on shining paper wall, it is transferred the pattern on rice paper when shining paper.
In order to provide a variety of different antifalse effects, nanometer infrared up conversion can be added in the fixation position of paper pulp fiber
Material.
In order to enhance nanometer infrared up-conversion material in the adhesion effect of rice paper, reinforcing agent is added in paper pulp fiber, on
Stating reinforcing agent is fumed silica and/or gum arabic and/or gelatin.
In order to further reinforce the binding strength of nanometer infrared up-conversion material and rice paper, the present invention also provides in addition
A kind of manufacturing process of durability anti-counterfeit rice paper, including with slurry, copy paper and shine paper process, process with slurry the following steps are included:
Step 1: nanometer infrared up-conversion material is added in the fibrous raw material of melting and it is red containing nanometer to be spun into silk formation
The fiber filament of outer up-conversion;
Step 2: the resulting fiber filament of step 1 is added in paper pulp fiber;
Preferably, further include the steps that security pattern is arranged;
The step of above-mentioned setting security pattern specifically:
Pattern is set on copying by way of machining, when copy paper, is transferred the pattern on rice paper;
Alternatively, design protrusion or/and recess patterns on shining paper wall, transfer the pattern on rice paper when shining paper;
Alternatively, pattern is arranged on copying by way of machining, when copy paper, transfer the pattern on rice paper;
Meanwhile design protrusion or/and recess patterns on shining paper wall, it is transferred the pattern on rice paper when shining paper.
In order to realize a variety of antifalse effects, above-mentioned steps two are that the resulting fiber of step 1 is added in the fixation position of slurry
Silk;Upper nanometer infrared up-conversion material is a variety of.
Above-mentioned fiber is polyester fiber, regenerated fiber, spandex fibre, cotton synthetic fibre fiber, vinylon, poly- third
The fine fiber of alkene, polypropylene fibre, polyvinyl chloride fibre, aramid fiber, vinylon fibre, polyester fiber, acrylic fiber, polypropylene fibre are fine
One of dimension, viscose rayon, polyvinyl chloride fibre fiber etc. are a variety of.
The beneficial effects of the present invention are:
1, the resistance to physical and chemical performance of the used nanometer infrared up-conversion material of the present invention is preferable, and having can be invisible
Infrared laser excitation is lower to absorb the security feature that energy is converted into visible light wave, is used for rice paper, can be according to different a surname
Aqueous or oiliness nanometer infrared up-conversion material is added in paper selection, does not influence paper performance, and the anti-fake spy of the rice paper not only
Property it is hidden, persistently and convenient for identification.
2, corresponding pattern is transferred on rice paper by the Machine Design security pattern on rice paper copying, when copy paper;Shining paper
Raised security pattern is designed on wall, and corresponding pattern is transferred on rice paper when shining paper;By the identification to specific pattern on rice paper,
The true and false of painting and calligraphy pieces can be identified.
Detailed description of the invention
Fig. 1 is schematic diagram of the invention.
Appended drawing reference in figure are as follows: 1- rice paper, 2- pattern.
Specific embodiment
Embodiment one
Nanometer infrared up-conversion material is added in paper pulp fiber, the parts by weight of this nanometer of infrared up-conversion material are 0.5-
30, the parts by weight of corresponding paper pulp are 99.5-70, and the two gross weight is 100.
The resistance to physical and chemical performance of this nanometer of infrared up-conversion material is preferable, is scattered in paper pulp, can also be added
Enter the fixation position of paper pulp, when copy paper nanometer infrared up-conversion material can natural fusion in the fiber of paper pulp, after shining paper molding
The anti-fake material can be coated by toughness fiber, be embedded in paper and be not easily disconnected from, and be viewed as common rice paper in appearance, but with dedicated inspection
Measurement equipment can identify its security feature, have the characteristics that security feature it is hidden, persistently and convenient for identification.
Random on rice paper or positioning distribution anti-fake material can be identified using dedicated identification instrument, i.e., in instrument transmitting
Green luminous point or red luminous point or blue spot are presented under the irradiation of infrared laser, on rice paper or red blue green combines luminous point.
Embodiment two
The present embodiment is added while nanometer infrared up-conversion material is added in the slurry unlike embodiment one to be increased
Strong agent, with improve nanometer it is infrared on turn adhesion effect of the material on rice paper, turn on infrared nanometer used in the embodiment
The parts by weight 0.5-30 of conversion materials, reinforcing agent used are fumed silica, and the parts by weight of fumed silica are 0.1-10,
The parts by weight of paper pulp are surplus, add up to 100.
Reinforcing agent can also be Arabic gum in the embodiment, and the parts by weight of Arabic gum are 0.1-10 parts, the weight of paper pulp
Amount part is surplus, adds up to 100 parts.Reinforcing agent is also possible to gelatin, and the parts by weight of gelatin are 0.1-10 parts, and the weight of paper pulp is remaining
Amount adds up to 100 parts.
When copy paper nanometer infrared up-conversion material under the action of reinforcing agent in conjunction with the fiber in paper pulp, binding strength
Height, it is not easily to fall off, it is viewed as common rice paper in appearance after shining paper molding, but can identify its anti-fake spy with special inspecting equipment
Property, have the characteristics that security feature it is hidden, persistently and convenient for identification.
Random on rice paper or positioning distribution anti-fake material can be identified using dedicated identification instrument, i.e., in instrument transmitting
Green luminous point or red luminous point or blue spot are presented under the irradiation of infrared laser, on rice paper or red blue green combines luminous point.
Embodiment three
Nanometer infrared up-conversion material is uniformly mixed by the present embodiment with the synthetic fibers of melting first, is then set dedicated
Standby to be above spun into fiber filament, filametntary diameter is 0.1-50 μm, is declared being added containing the fiber filament of nanometer infrared up-conversion material
In paper paper pulp, the rice paper with nanometer infrared up-conversion material is made.
The fiber that the present embodiment is selected is spandex fibre, and the parts by weight of spandex fibre are 1-50 parts, nanometer infrared up conversion
The parts by weight of material are 1-50 parts, and the total weight parts of spandex fibre and nanometer infrared up-conversion material are 100 parts;It is red containing nanometer
The filametntary parts by weight of outer up-conversion are 1-40 parts, the filametntary total weight of paper pulp and nanometer infrared up-conversion material
Part is 100 parts.
The present embodiment can also select polyester fiber, and the parts by weight of polyester fiber are 1-50 parts, nanometer infrared up conversion material
The parts by weight of material are 1-50 parts, and the total weight parts of polyester fiber and nanometer infrared up-conversion material are 100 parts;It is infrared containing nanometer
The filametntary parts by weight of up-conversion are 1-40 parts, the filametntary total weight parts of paper pulp and nanometer infrared up-conversion material
It is 100 parts.
The binding strength of the present embodiment nanometer infrared up-conversion material and rice paper is stronger, is viewed as in appearance after shining paper molding
Common rice paper, but its security feature can be identified with special inspecting equipment, it is hidden with security feature, lasting and convenient for identification
Feature.
Random on rice paper or positioning distribution anti-fake material can be identified using dedicated identification instrument, i.e., in instrument transmitting
Green luminous point or red luminous point or blue spot are presented under the irradiation of infrared laser, on rice paper or red blue green combines luminous point.
Infrared nanometer up-conversion in above three embodiments can be one kind be also possible to it is a variety of, it is a variety of to realize
Different antifalse effects.
In above three embodiments, (its material can be bamboo curtain splint, copper curtain, stainless steel curtain to copying used in paper-making process
Deng) on according to rice paper demander requirement design personalized pattern, paper curtain transfers the pattern on rice paper when copy paper, and is shining
Raised or sunken personalized pattern is designed on paper wall according to the requirement of rice paper demander, transfers the pattern onto rice paper when shining paper
On, this anti-counterfeiting characteristic coexists with rice paper, and durability is good, can be used for carrying out true and false identification to painting and calligraphy pieces.
Claims (2)
1. a kind of manufacturing process of durability anti-counterfeit rice paper, including with slurry, copy paper and solarization paper process, it is characterised in that: mistake with slurry
The anti-fake material that parts by weight are 0.5-30 is added in Cheng Zhong in paper pulp fiber;The anti-fake material is nanometer infrared up conversion material
Material;
During with slurry, the reinforcing agent that parts by weight are 0.1-10 is added in paper pulp fiber, the reinforcing agent is gas phase titanium dioxide
Silicon or gum arabic or gelatin, the parts by weight of paper pulp are surplus, add up to 100.
2. a kind of manufacturing process of durability anti-counterfeit rice paper, the process including with slurry, copy paper and solarization paper, it is characterised in that: with slurry
Process the following steps are included:
Step 1: nanometer infrared up-conversion material is added in the spandex fibre or polyester fiber raw material of melting and is spun into diameter and is
0.1-50 μm of fiber filament forms the fiber filament containing nanometer infrared up-conversion material;
The parts by weight of the fibrous raw material are 1-50 parts, and the parts by weight of nanometer infrared up-conversion material are 1-50 parts;Spandex fibre
Or the total weight parts of polyester fiber and nanometer infrared up-conversion material are 100 parts;
Step 2: the resulting fiber filament of step 1 is added in paper pulp fiber;Further include the steps that security pattern is arranged;Step 1
Resulting filametntary parts by weight are 1-40 parts, and the filametntary total weight parts of paper pulp and nanometer infrared up-conversion material are 100
Part.
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CN201610954775.1A CN106400596B (en) | 2016-10-27 | 2016-10-27 | A kind of durability anti-counterfeit rice paper and its manufacturing process |
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CN106400596B true CN106400596B (en) | 2019-05-10 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108560305B (en) * | 2017-12-19 | 2019-09-20 | 扬州古籍线装文化有限公司 | A kind of rice paper production method without holding in the palm mounting |
CN109763371A (en) * | 2019-03-22 | 2019-05-17 | 东莞市幸运天使实业有限公司 | Embossment hand made paper and preparation method thereof |
CN111576089B (en) * | 2020-05-06 | 2021-12-31 | 泾县艺宣阁宣纸工艺品有限公司 | Rice paper for ink-jet printing and preparation method thereof |
CN114875706B (en) * | 2022-04-02 | 2023-02-10 | 浙江凯恩新材料有限公司 | Raw paper of high-performance all-in-one machine thermosensitive version paper, production process and thermosensitive version paper prepared by production process |
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