CN106400539B - A kind of bronze printing adhesive and preparation method thereof based on animals and plants mucus - Google Patents
A kind of bronze printing adhesive and preparation method thereof based on animals and plants mucus Download PDFInfo
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- CN106400539B CN106400539B CN201610838989.2A CN201610838989A CN106400539B CN 106400539 B CN106400539 B CN 106400539B CN 201610838989 A CN201610838989 A CN 201610838989A CN 106400539 B CN106400539 B CN 106400539B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
- D06P1/50—Derivatives of cellulose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/628—Compounds containing nitrogen
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
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Abstract
The present invention provides a kind of bronze printing adhesive and preparation method thereof based on animals and plants mucus, and specific method includes the following steps：Fresh sassafrases seed is ground, extraction ultrasound, grinding filtering obtains sassafrases extract, and the fresh broken scraping of paper mulberry hedge clipper is obtained Chu Shu slurries, the two is added in ethanol water, stirring, gelatine mixing is then added, forms animals and plants mucus；Chitosan oligosaccharide, nano titanic oxide sol and graphene are uniformly mixed and form nano material, nano material is added in polyacrylic acid, heating stirring forms the high molecular polymer of nano modification；Animals and plants mucus is added in the high molecular polymer of nano modification, sulfobetaines and cellulose thickener is added, and adjust pH value, stirs evenly, forms the bronze printing adhesive based on animals and plants mucus.
Description
Technical field
The invention belongs to textile material technical fields, and in particular to a kind of bronze printing adhesive based on animals and plants mucus and
Preparation method.
Background technology
The textile bronze printing technology of Ancient Times in China rises and Chinese Shanxi, continues up by now, and major processes are to gild
And golden paint.Gold is the most valuable in hardware, is divided into golden block, thick gold, middle golden, thin gold and bronze etc. according to grade, and in bronze printing
Goldleaf or bronze are used in fabric.Goldleaf is that it is smoked to be clipped in kerosene using the gold bar that gold content is 99.99% as primary raw material
In the coal paper practiced, through beating, goldleaf golden yellow color, bright soft is as light as a feather, as thin as cicada's wings.In bronze printing technique
The middle more preparation for gold material of research, but it is really few for the adhesive of bronze printing.
It is found according to literature research, the adhesive used in the bronze printing in ancient times has lacquer, tung oil, papermulberry extract, peach juice, bone
Glue, fish glue, glutinous paste, garlic leaf, beans extract mucus and rock sugar water etc., these types of material all have certain tackness, but simultaneously
It is not to be suitable for textile, the adhesive for textile needs viscous Lao Duhao, and soft, appearance is thin best.China
A kind of gold stamping stamp extract adhesive agent emulsion of environment-friendlytextile textile disclosed in patent CN 102718921A and its preparation side
Method contains hard monomers, the metering systems such as soft monomers, the styrene such as lauryl sodium sulfate, butyl acrylate in adhesive agent emulsion
The initiators such as the functional monomers such as acid, ammonium persulfate, deionized water and triethanolamine neutralizer, are dissolved in deionized water by emulsifier
In, soft monomer is added, hard monomer and functional monomer form pre-emulsion, then initiator solution is added, it is heating stirring, cold
Solidifying reflux, filtering etc. obtain product.Gold and silver part adhesive and preparation method thereof and wall disclosed in Chinese patent CN 103756601B
Paper, textile, the gold and silver powder adhesive include hard monomer, soft monomer, hydroxyl ester monomer, methacrylic acid, multifunctional function
Monomer, functional performance polymerisable monomer, emulsifier, initiator and deionized water are primary raw material, and hard monomer is methacrylic acid
Methyl esters, epoxymethacrylate etc., soft monomer are methyl acrylate, ethyl acrylate etc., and hydroxyl ester monomer is acrylic acid-
2- hydroxy methacrylates, methacrylic acid -2- hydroxy methacrylates etc., multifunctional function monomer are 1,6- hexanediyl esters, two contractings
Tripropylene glycol diacrylate etc., functional polymerized monomer are acrylamide, N hydroxymethyl acrylamide etc., emulsifier oil silver from
One or more compositions in sub- emulsifier, nonionic emulsifier and reactive emulsifier, initiator are sodium peroxydisulfate, persulfuric acid
Ammonium etc. forms pre-emulsion after emulsifying mix monomer, buffer, emulsifier and deionized water is then added and reacts to form seed breast
Liquid is polymerized to form water-and acrylate lotion, then is mixed with auxiliary agents such as ammonium hydroxide, acetylphenylhydrazine, thickener and pH adjusting agents, mistake
It filters out material and forms gold and silver powder adhesive.By the above-mentioned prior art it is found that being mostly at present to be directed to adhesive for the adhesive of bronze printing
Water-fast and high temperature resistance, and the raw material used is mostly chemical synthesising technology, is had to environmental and human health impacts certain latent
It is threatening.
Invention content
The technical problem to be solved in the present invention is to provide a kind of based on the bronze printing adhesive of animals and plants mucus and its preparation
Method improves sassafrases extract, gelatine and papermulberry extract as primary raw material, aided nano material and high molecular polymer
The bronze printing adhesive of high-performance environment-friendly is prepared in the stability and mechanical strength of animals and plants mucus.
In order to solve the above technical problems, the technical scheme is that：
A kind of bronze printing adhesive based on animals and plants mucus, the bronze printing based on animals and plants mucus are wrapped in adhesive
Sassafrases extract, gelatine, Chu Shu slurries, nano material, high molecular polymer and auxiliary agent are included, the nano material is nanometer titanium dioxide
Titanium, graphene and chitosan oligosaccharide, the high molecular polymer are polyacrylic acid, and the auxiliary agent is surfactant, thickener, pH tune
Save agent and solvent.
As a preferred embodiment of the above technical solution, the surfactant is amphoteric surfactant, and the amphoteric surface lives
Property agent be sulfobetaines, the thickener be cellulose thickener, the pH adjusting agent be ammonium hydroxide or citric acid.
As a preferred embodiment of the above technical solution, the component in the bronze printing adhesive based on animals and plants mucus, by weight
Measure part meter, including 15-25 parts of 10-20 parts of sassafrases extract, 5-10 parts of gelatine, Chu Shu slurry, 2-10 parts of nano material, polyphosphazene polymer
Close 5-10 parts of 15-20 parts of object and auxiliary agent.
As a preferred embodiment of the above technical solution, the component in the bronze printing adhesive based on animals and plants mucus, by weight
Measure part meter, including 15-23 parts of 13-19 parts of sassafrases extract, 5-10 parts of gelatine, Chu Shu slurry, 3-7 parts of nano material, polyphosphazene polymer
Close 5-10 parts of 15-20 parts of object and auxiliary agent.
A kind of preparation method of the bronze printing adhesive based on animals and plants mucus, includes the following steps：
(1) fresh sassafrases seed is ground, solvent, ultrasound is added, grinding filtering obtains sassafrases extract, will be fresh
The broken scraping of paper mulberry hedge clipper obtains Chu Shu slurries, and sassafrases extract and Chu Shu slurries are added in ethanol water, then gelatine is added in stirring
Mixing forms animals and plants mucus；
(2) nano titanic oxide sol and graphene aqueous solution is added in chitosan oligosaccharide solution, is uniformly mixed and forms nanometer material
Nano material is added in polyacrylic acid high molecular polymer material, and heating stirring forms the high molecular polymer of nano modification；
(3) high molecular polymer of nano modification prepared by step (2) is added in the animals and plants mucus for preparing step (1)
In, sulfobetaines and cellulose thickener is added, ammonium hydroxide or lemon acid for adjusting pH value is used in combination, stirs evenly, forms base
In the bronze printing adhesive of animals and plants mucus.
As a preferred embodiment of the above technical solution, in the step (1), solvent is petroleum ether.
As a preferred embodiment of the above technical solution, in the step (2), the relative molecular weight of chitosan oligosaccharide is in chitosan oligosaccharide solution
5000-20000。
As a preferred embodiment of the above technical solution, in the step (2), nano-titanium dioxide in nano titanic oxide sol
Grain size is 20-50nm.
As a preferred embodiment of the above technical solution, in the step (2), the mass fraction of graphene is in graphene aqueous solution
0.5-1%.
As a preferred embodiment of the above technical solution, in the step (3), pH value 6.4-8.0.
Compared with prior art, the invention has the advantages that：
(1) bronze printing based on animals and plants mucus for preparing of the present invention with the primary raw material in adhesive be sassafrases extract,
Gelatine and Chu Shu slurries, for three as main mucus, sassafrases extract is sassafrases seed oil, has high viscosity, high temperature resistant, corrosion-resistant
And the characteristics of quick-drying, the juice that Chu Shu slurries are Chu Shu, milky white, degree of adhesion is high, and source is less, and gelatine is a kind of animal protein,
Be it is a kind of in ginger-colored solid matter, texture is thick and solid, and by triplicity, functionality doubles, color is simple and elegant, quick-drying, viscosity are good,
Feel is frivolous, does not influence the feel of fabric.
(2) it is few also to contain nano-titanium dioxide, shell in the bronze printing adhesive based on animals and plants mucus prepared by the present invention
Sugar and graphene, nano-titanium dioxide have preferable uvioresistant performance, can improve the aging speed of sassafrases extract, improve
Also there is excellent anti-microbial property, good film-forming property can improve bonding for the ageing-resistant performance of adhesive, chitosan oligosaccharide good water solubility
The nanometer of the film forming of agent, graphene is had excellent performance, and can be added to film strength, improves the thermal stability of binder.
(3) also contain cellulose thickener and high score in the bronze printing adhesive based on animals and plants mucus prepared by the present invention
Sub- polymer further increases the viscosity and resistance to chemical corrosion of adhesive.
(4) primary raw material of the adhesive of the bronze printing based on animals and plants mucus prepared by the present invention is animals and plants mucus, is adopted
Other auxiliary addition agents, it is also environmentally protective, it is biodegradable, therefore the adhesive prepared is environmentally protective, quick-drying, height is viscous, at
Film is soft, and so mechanical strength is good, can firmly adhere to goldleaf, but is influenced on the feel of fabric and permeability little.
Specific implementation mode
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative examples and explanation of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment 1：
(1) the fresh sassafrases seed of 1 parts by weight is ground to 50 mesh, the petroleum ether of 3 parts by weight is added, ultrasonic 20min is ground
Honed filter obtains sassafrases extract, and the fresh broken scraping of paper mulberry hedge clipper is obtained Chu Shu slurries.By weight, by 10 parts of sassafrases
Extract and 15 parts of Chu Shu slurries are added in 50 parts of ethanol water, stirring, and 5 parts of gelatine mixing is then added, is formed dynamic
Plant mucilage.
(2) nano-silica that grain size is 20-50nm will be added in chitosan oligosaccharide solution that relative molecular weight is 5000-20000
Change the graphene aqueous solution that titanium colloidal sol and mass fraction are 0.5%, is uniformly mixed and forms nano material, wherein in nano material
The mass ratio of chitosan oligosaccharide, nano-titanium dioxide and graphene is 5:2:1.It is high that 2 parts of nano material is added to 1 part of polyacrylic acid
In Molecularly Imprinted Polymer, the heating stirring at 70 DEG C forms the high molecular polymer of nano modification.
(3) animals and plants mucus is added in the high molecular polymer of nano modification, 5 parts of sulfobetaines and fiber is added
Plain class thickener is used in combination ammonium hydroxide or lemon acid for adjusting pH value to 6.4, is stirred evenly, and the bronze printing based on animals and plants mucus is formed
Use adhesive.
Embodiment 2：
(1) the fresh sassafrases seed of 1 parts by weight is ground to 100 mesh, is added the petroleum ether of 5 parts by weight, ultrasonic 30min,
Grinding filtering, obtains sassafrases extract, and the fresh broken scraping of paper mulberry hedge clipper is obtained Chu Shu slurries.By weight, by 19 parts of sassafras
The wooden extract and 23 parts of Chu Shu slurries are added in 50 parts of ethanol water, stirring, and 10 parts of gelatine mixing is then added, is formed
Animals and plants mucus.
(2) nano-silica that grain size is 20-50nm will be added in chitosan oligosaccharide solution that relative molecular weight is 5000-20000
Change the graphene aqueous solution that titanium colloidal sol and mass fraction are 1%, is uniformly mixed and forms nano material, wherein shell in nano material
The mass ratio of oligosaccharides, nano-titanium dioxide and graphene is 10:2:1.It is high that 7 parts of nano material is added to 20 parts of polyacrylic acid
In Molecularly Imprinted Polymer, the heating stirring at 80 DEG C forms the high molecular polymer of nano modification.
(3) animals and plants mucus is added in the high molecular polymer of nano modification, 10 parts of sulfobetaines and fibre is added
The plain class thickener of dimension, is used in combination ammonium hydroxide or lemon acid for adjusting pH value to 8.0, stirs evenly, form the print based on animals and plants mucus
Gold adhesive.
Embodiment 3：
(1) the fresh sassafrases seed of 1 parts by weight is ground to 80 mesh, the petroleum ether of 4 parts by weight is added, ultrasonic 25min is ground
Honed filter obtains sassafrases extract, and the fresh broken scraping of paper mulberry hedge clipper is obtained Chu Shu slurries.By weight, by 15 parts of sassafrases
Extract and 20 parts of Chu Shu slurries are added in 50 parts of ethanol water, stirring, and 7 parts of gelatine mixing is then added, is formed dynamic
Plant mucilage.
(2) nano-silica that grain size is 20-50nm will be added in chitosan oligosaccharide solution that relative molecular weight is 5000-20000
Change the graphene aqueous solution that titanium colloidal sol and mass fraction are 0.7%, is uniformly mixed and forms nano material, wherein in nano material
The mass ratio of chitosan oligosaccharide, nano-titanium dioxide and graphene is 8:2:1.9 parts of nano material is added to 16 parts of polyacrylic acid
In high molecular polymer, the heating stirring at 75 DEG C forms the high molecular polymer of nano modification.
(3) animals and plants mucus is added in the high molecular polymer of nano modification, 6 parts of sulfobetaines and fiber is added
Plain class thickener is used in combination ammonium hydroxide or lemon acid for adjusting pH value to 7.2, is stirred evenly, and the bronze printing based on animals and plants mucus is formed
Use adhesive.
Embodiment 4：
(1) the fresh sassafrases seed of 1 parts by weight is ground to 100 mesh, is added the petroleum ether of 3 parts by weight, ultrasonic 20min,
Grinding filtering, obtains sassafrases extract, and the fresh broken scraping of paper mulberry hedge clipper is obtained Chu Shu slurries.By weight, by 13 parts of sassafras
The wooden extract and 23 parts of Chu Shu slurries are added in 50 parts of ethanol water, stirring, and 10 parts of gelatine mixing is then added, is formed
Animals and plants mucus.
(2) nano-silica that grain size is 20-50nm will be added in chitosan oligosaccharide solution that relative molecular weight is 5000-20000
Change the graphene aqueous solution that titanium colloidal sol and mass fraction are 0.8%, is uniformly mixed and forms nano material, wherein in nano material
The mass ratio of chitosan oligosaccharide, nano-titanium dioxide and graphene is 8:2:1.4 parts of nano material is added to 17 parts of polyacrylic acid
In high molecular polymer, the heating stirring at 80 DEG C forms the high molecular polymer of nano modification.
(3) animals and plants mucus is added in the high molecular polymer of nano modification, 9 parts of sulfobetaines and fiber is added
Plain class thickener is used in combination ammonium hydroxide or lemon acid for adjusting pH value to 6.8, is stirred evenly, and the bronze printing based on animals and plants mucus is formed
Use adhesive.
Embodiment 5：
(1) the fresh sassafrases seed of 1 parts by weight is ground to 60 mesh, the petroleum ether of 5 parts by weight is added, ultrasonic 30min is ground
Honed filter obtains sassafrases extract, and the fresh broken scraping of paper mulberry hedge clipper is obtained Chu Shu slurries.By weight, by 12 parts of sassafrases
Extract and 18 parts of Chu Shu slurries are added in 50 parts of ethanol water, stirring, and 8 parts of gelatine mixing is then added, is formed dynamic
Plant mucilage.
(2) nano-silica that grain size is 20-50nm will be added in chitosan oligosaccharide solution that relative molecular weight is 5000-20000
Change the graphene aqueous solution that titanium colloidal sol and mass fraction are 0.8%, is uniformly mixed and forms nano material, wherein in nano material
The mass ratio of chitosan oligosaccharide, nano-titanium dioxide and graphene is 6:2:1.7 parts of nano material is added to 17 parts of polyacrylic acid
In high molecular polymer, the heating stirring at 70 DEG C forms the high molecular polymer of nano modification.
(3) animals and plants mucus is added in the high molecular polymer of nano modification, 10 parts of sulfobetaines and fibre is added
The plain class thickener of dimension, is used in combination ammonium hydroxide or lemon acid for adjusting pH value to 7.5, stirs evenly, form the print based on animals and plants mucus
Gold adhesive.
Embodiment 6：
(1) the fresh sassafrases seed of 1 parts by weight is ground to 80 mesh, the petroleum ether of 5 parts by weight is added, ultrasonic 25min is ground
Honed filter obtains sassafrases extract, and the fresh broken scraping of paper mulberry hedge clipper is obtained Chu Shu slurries.By weight, by 15 parts of sassafrases
Extract and 15 parts of Chu Shu slurries are added in 50 parts of ethanol water, stirring, and 5 parts of gelatine mixing is then added, is formed dynamic
Plant mucilage.
(2) nano-silica that grain size is 20-50nm will be added in chitosan oligosaccharide solution that relative molecular weight is 5000-20000
Change the graphene aqueous solution that titanium colloidal sol and mass fraction are 0.5%, is uniformly mixed and forms nano material, wherein in nano material
The mass ratio of chitosan oligosaccharide, nano-titanium dioxide and graphene is 5:2:1.3-7 parts of nano material is added to 15 parts of polypropylene
In sour high molecular polymer, the heating stirring at 80 DEG C forms the high molecular polymer of nano modification.
(3) animals and plants mucus is added in the high molecular polymer of nano modification, 5 parts of sulfobetaines and fiber is added
Plain class thickener is used in combination ammonium hydroxide or lemon acid for adjusting pH value to 7.5, is stirred evenly, and the bronze printing based on animals and plants mucus is formed
Use adhesive.
After testing, the viscosity for the bronze printing adhesive based on animals and plants mucus that prepared by embodiment 1-6, mobility, drying
Speed, viscosity fastness, the result of feel and degradability are as follows：
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Viscosity | By force | By force | By force | By force | By force | By force |
| Mobility | In | It is good | It is good | In | It is good | In |
| Rate of drying | In | Soon | In | Soon | Soon | In |
| Viscous labor degree | By force | By force | By force | By force | By force | By force |
| Feel | It is soft | In | It is soft | It is soft | It is soft | In |
| Degradable rate (%) | 95 | 98 | 96 | 94 | 97 | 96 |
As seen from the above table, the physical properties for the bronze printing adhesive based on animals and plants mucus that prepared by the present invention are excellent
It is different, also have degradability good, environmentally protective, high-performance.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology can all carry out modifications and changes to above-described embodiment without violating the spirit and scope of the present invention.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should by the present invention claim be covered.
Claims (10)
1. a kind of bronze printing adhesive based on animals and plants mucus, it is characterised in that：The bronze printing based on animals and plants mucus is used
Adhesive includes that sassafrases extract, gelatine, Chu Shu slurries, nano material, high molecular polymer and auxiliary agent, the nano material are
Nano-titanium dioxide, graphene and chitosan oligosaccharide, the high molecular polymer be polyacrylic acid, the auxiliary agent be surfactant,
Thickener, pH adjusting agent and solvent.
2. a kind of bronze printing adhesive based on animals and plants mucus according to claim 1, it is characterised in that：The surface
Activating agent is amphoteric surfactant, and the amphoteric surfactant is sulfobetaines, and the thickener increases for cellulose family
Thick dose, the pH adjusting agent is ammonium hydroxide or citric acid.
3. a kind of bronze printing adhesive based on animals and plants mucus according to claim 1, it is characterised in that：It is described to be based on
Component in the bronze printing adhesive of animals and plants mucus, by weight, including 10-20 parts of sassafrases extract, 5-10 parts of gelatine,
5-10 parts of 15-25 parts of Chu Shu slurries, 2-10 parts of nano material, 15-20 parts of high molecular polymer and auxiliary agent.
4. a kind of bronze printing adhesive based on animals and plants mucus according to claim 1, it is characterised in that：It is described to be based on
Component in the bronze printing adhesive of animals and plants mucus, by weight, including 13-19 parts of sassafrases extract, 5-10 parts of gelatine,
5-10 parts of 15-23 parts of Chu Shu slurries, 3-7 parts of nano material, 15-20 parts of high molecular polymer and auxiliary agent.
5. a kind of preparation method of the bronze printing adhesive based on animals and plants mucus, it is characterised in that：Include the following steps：
(1) fresh sassafrases seed is ground, solvent, ultrasound is added, grinding filtering obtains sassafrases extract, by fresh Chu Shu
It shreds scraping and obtains Chu Shu slurries, sassafrases extract and Chu Shu slurries are added in ethanol water, stirring, it is mixed that gelatine is then added
It closes, forms animals and plants mucus；
(2) nano titanic oxide sol and graphene aqueous solution is added in chitosan oligosaccharide solution, is uniformly mixed and forms nano material, it will
Nano material is added in polyacrylic acid high molecular polymer, and heating stirring forms the high molecular polymer of nano modification；
(3) the animals and plants mucus for preparing step (1) is added in the high molecular polymer of nano modification prepared by step (2), adds
Enter sulfobetaines and cellulose thickener, ammonium hydroxide or lemon acid for adjusting pH value is used in combination, stirs evenly, is formed and planted based on dynamic
The bronze printing adhesive of object mucus.
6. a kind of preparation method of bronze printing adhesive based on animals and plants mucus according to claim 5, feature exist
In：In the step (1), solvent is petroleum ether.
7. a kind of preparation method of bronze printing adhesive based on animals and plants mucus according to claim 5, feature exist
In：In the step (2), the relative molecular weight of chitosan oligosaccharide is 5000-20000 in chitosan oligosaccharide solution.
8. a kind of preparation method of bronze printing adhesive based on animals and plants mucus according to claim 5, feature exist
In：In the step (2), the grain size of nano-titanium dioxide is 20-50nm in nano titanic oxide sol.
9. a kind of preparation method of bronze printing adhesive based on animals and plants mucus according to claim 5, feature exist
In：In the step (2), the mass fraction of graphene is 0.5-1% in graphene aqueous solution.
10. a kind of preparation method of bronze printing adhesive based on animals and plants mucus according to claim 5, feature exist
In：In the step (3), pH value 6.4-8.0.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610838989.2A CN106400539B (en) | 2016-09-21 | 2016-09-21 | A kind of bronze printing adhesive and preparation method thereof based on animals and plants mucus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610838989.2A CN106400539B (en) | 2016-09-21 | 2016-09-21 | A kind of bronze printing adhesive and preparation method thereof based on animals and plants mucus |
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| CN101440269B (en) * | 2007-11-22 | 2013-02-13 | 汉高股份两合公司 | Adhesive, preparation and use thereof |
| CN101284981B (en) * | 2008-06-01 | 2010-08-11 | 李传涛 | Biogum adhesive and preparation method thereof |
| KR101320297B1 (en) * | 2011-10-26 | 2013-10-22 | 주식회사 제닉 | Adhesive composition for transdermal absorption comprising rice powder and method for preparing the same |
| CN102850996A (en) * | 2012-09-03 | 2013-01-02 | 南通市泓雨化工有限公司 | Bone glue adhesive for wood |
| CN103526599A (en) * | 2013-10-25 | 2014-01-22 | 合肥聚合辐化技术有限公司 | High-brilliance printing adhesive and preparation method thereof |
| CN103666368A (en) * | 2013-12-21 | 2014-03-26 | 栾晓健 | Natural adhesive |
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