CN106393921A - Making method of decoration plate - Google Patents

Making method of decoration plate Download PDF

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Publication number
CN106393921A
CN106393921A CN201610765616.7A CN201610765616A CN106393921A CN 106393921 A CN106393921 A CN 106393921A CN 201610765616 A CN201610765616 A CN 201610765616A CN 106393921 A CN106393921 A CN 106393921A
Authority
CN
China
Prior art keywords
mass
modified
formaldehyde resin
biotic material
decorative plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610765616.7A
Other languages
Chinese (zh)
Inventor
曹春清
张和安
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG RUIXIN DECORATION MATERIALS Co Ltd
Original Assignee
ZHEJIANG RUIXIN DECORATION MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG RUIXIN DECORATION MATERIALS Co Ltd filed Critical ZHEJIANG RUIXIN DECORATION MATERIALS Co Ltd
Priority to CN201610765616.7A priority Critical patent/CN106393921A/en
Publication of CN106393921A publication Critical patent/CN106393921A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B29/005Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi

Abstract

The invention discloses a making method of a decoration plate, and belongs to the technical field of making methods of decoration plates. The problem of no antibacterial performance of original decoration plates is solved in the invention. The method comprises the following steps: 1, gluing modified terpolycyantoamino-formaldehyde resin to decoration paper; 2, gluing modified phenolic resin to brown paper; 3, sequentially laminating the glued decoration paper and a plurality of pieces of the modified brown paper, and carrying out heating and pressurizing formation, wherein the modified terpolycyantoamino-formaldehyde resin comprises, by mass, 87-93% of terpolycyantoamino-formaldehyde resin and 7-13% of an antibacterial nano-material, and the modified phenolic resin comprises, by mass, 87-93 % of phenolic resin and 7-13% of the antibacterial nano-material. A proper amount of the antibacterial nano-material is added to glued materials, so the decoration plate made in the invention has a good antibacterial performance.

Description

Method for making decorative plate
Technical field
The invention belongs to method for making decorative plate technical field.
Background technology
It is face that decorative panel typically has melamine impregnated paper, and resin impregnating paper is for sandwich layer processes through High Temperature High Pressure Become, but there is no printing opacity and anti-microbial property, easy breed bacteria.Special use occasion can not use, such as:Hospital's sterilizing room and Higher dresser of hygienic requirements etc..
Content of the invention
The purpose of the present invention is that there are the problems referred to above for existing technology it is proposed that a kind of anti-microbial property is preferably decorated Board manufacturing method.
The purpose of the present invention can be realized by following technical proposal:
Method for making decorative plate is it is characterised in that comprise the following steps:
A, by modified melamine-formaldehyde resin gluing to facing paper;
B, by phenol-formaldehyde resin modified gluing to kraft paper;
C, if the facing paper after gluing and dried layer kraft paper are arranged successively poststack heating extrusion forming;
Wherein, modified melamine-formaldehyde resin is by the melamine resin of 87%-93% mass and 7%-13% The nano anti-biotic material composition of quality;The phenolic resin by 87-93% mass for the phenol-formaldehyde resin modified and the nanometer of 7-13% mass Anti-biotic material forms.
In the method, due in the material of gluing containing nano anti-biotic material so that the decorative panel after molding has relatively Good anti-microbial property is so that decorative panel can use in the higher occasion of hygienic requirements.Further, since selecting 87%-93% The proportioning of the nano anti-biotic material of the melamine resin of quality and 7%-13% mass, and 87%-93% mass The proportioning of the nano anti-biotic material of phenolic resin and 7%-13% mass is so that decorative panel also can while having preferable intensity There is preferable anti-microbial property.
In above-mentioned method for making decorative plate, before step A and step B, by melamine resin and nanometer Anti-biotic material is put into and is mixed into modified cyanurotriamide in dispersion machine;Phenolic resin and nano anti-biotic material are put in dispersion machine It is mixed into phenol-formaldehyde resin modified.
Melamine resin and nano anti-biotic material are put in dispersion machine mixing so that melamine resin Can sufficiently mix with nano anti-biotic material so that nano anti-biotic material be more uniformly distributed be dispersed in melamine resin In, so that the anti-microbial property of decorative panel is preferable;In the same manner, phenolic resin and nano anti-biotic material are put into mixing in dispersion machine Become phenol-formaldehyde resin modified so that the anti-microbial property of decorative panel is preferable.
In above-mentioned method for making decorative plate, in step, facing paper spread is 110%-150% mass, volatilization Measure as 5%-10% mass.
Because upper glue material is above-mentioned certain material, therefore, the upper trial of strength on corresponding facing paper and volatile quantity are set, make Obtain the intensity of facing paper preferably, and be easy to molding, improve the anti-microbial property of decorative panel.And,
In above-mentioned method for making decorative plate, in stepb, the spread of kraft paper is 40-70% mass, volatile quantity For 5%-10% mass.
Because upper glue material is above-mentioned certain material, therefore, the upper trial of strength on corresponding facing paper and volatile quantity are set, make Obtain kraft paper intensity preferably, and be easy to molding, improve the anti-microbial property of decorative panel.
In above-mentioned method for making decorative plate, in step C, the pressure of pressurization is 100kg/cm2-110kg/cm2, and Temperature is made to rise to one of 115 DEG C -145 DEG C temperature values, keeping temperature 20-30 minute within 20-50 minute.
Select such heating pressurization parameter, on the one hand corresponding with upper glue material, on the other hand also contribute to surface compact Degree and the raising of smoothness, and make the surface of decorative panel be difficult dust.
In above-mentioned method for making decorative plate, described phenol-formaldehyde resin modified is by the phenolic resin of 90% mass and 10% matter The nano anti-biotic material composition of amount;Modified melamine-formaldehyde resin is by the melamine resin of 90% mass and 10% matter The nano anti-biotic material composition of amount.
Select through the mixed modified melamine-formaldehyde resin of aforementioned proportion and phenol-formaldehyde resin modified so that decorative panel exists Have while preferable intensity and also can have preferable anti-microbial property.
In above-mentioned method for making decorative plate, described nano anti-biotic material is nano silver-supported antibacterial material or nanometer two Titanium oxide anti-biotic material or the mixture of the two.Nano anti-biotic material selects nano silver-supported antibacterial material or nano titanium oxide to resist Bacterium material or the mixture of the two are so that the anti-microbial property of decorative panel is more preferable.
Setting such heating pressurization parameter is so that the decorative panel intensity after molding is preferable.
The decorative panel being made by this manufacture method, expands the purposes of decorative panel so that decorative panel can be used as medical With the materials for wall in food place and work top etc., and make the resistance to cleaning of decorative panel.
Further, since employing modified melamine-formaldehyde resin and phenol-formaldehyde resin modified so that the surface of decorative panel can With effective growth suppressing antibacterial and the effect playing very strong killing antibacterial.Detected to Staphylococcus aureus according to SGS antibacterial Bacillus activity value reaches 99% for 4.4,24 hours killing rates, to colibacillary antibacterial activity value for 5.1,24 hours killing rates is 99%, the antibacterial activity value to streptococcus faecalis is 99 for 4.8,24 hours killing rates, the antibacterial activity value to the mould Salmonella of pneumonia gram For 2.5, killing rate reaches 98% within 24 hours, has reached product requirement, meets the demand in client and market.
Compared with prior art, this method for making decorative plate has advantages below:
1st, facing paper adopts modified melamine-formaldehyde resin and phenol-formaldehyde resin modified as upper glue material so that after molding Decorative panel there is preferable anti-microbial property;
2nd, bottom paper using phenol-formaldehyde resin modified as upper glue material so that the decorative panel after molding has preferable antibacterial Performance;
3rd, select facing paper with suitable spread on kraft paper with volatile quantity so that decorative panel intensity preferably, be easy to into Type, and anti-microbial property is preferable;
4th, the certain heating pressurization parameter of setting is so that the decorative panel intensity after molding is preferable.
Specific embodiment
The following is the specific embodiment of the present invention, and technical scheme is further retouched in conjunction with the embodiments State, but the present invention is not limited to these embodiments.
Embodiment one
Method for making decorative plate is it is characterised in that comprise the following steps:
A0, the anti-microbial property in order to improve decorative panel, melamine resin and nano anti-biotic material are put into dispersion It is mixed into modified melamine-formaldehyde resin in machine;Phenolic resin and nano anti-biotic material are put in dispersion machine and is mixed into Phenol-formaldehyde resin modified.
A, by mixed modified melamine-formaldehyde resin gluing on facing paper;So that the intensity of facing paper is relatively Good, and it is easy to molding, improve the anti-microbial property of decorative panel, facing paper spread is 110% mass, volatile quantity is 5% mass.
B, by mixed phenol-formaldehyde resin modified gluing on kraft paper;So that the intensity of kraft paper is preferably, and It is easy to molding, improve the anti-microbial property of decorative panel, in above-mentioned method for making decorative plate, in stepb, the gluing of kraft paper Measure as 40% mass, volatile quantity is 5% mass.
C, if the facing paper after gluing and dried layer kraft paper are arranged successively poststack heating extrusion forming;So that after molding Decorative panel intensity preferably, the pressure of pressurization is 100kg/cm2, and made temperature rise to 115 DEG C within 20 minutes, keep temperature Degree 20 minutes.
Wherein, the nanometer of the melamine resin by 87% mass for the modified melamine-formaldehyde resin and 13% mass Anti-biotic material forms;Phenol-formaldehyde resin modified is made up of the phenolic resin of 87% mass and the nano anti-biotic material of 13% mass.? In the present embodiment, nano anti-biotic material is nanometer titanium dioxide antibiotic material.Alternatively, nano anti-biotic material is to receive Rice Ag-carried antibacterial material or the mixture of nanometer titanium dioxide antibiotic material and nano silver-supported antibacterial material.
In the method, due in the material of gluing containing nano anti-biotic material so that the decorative panel after molding has relatively Good anti-microbial property is so that decorative panel can use in the higher occasion of hygienic requirements.Further, since selecting 87% mass The proportioning of the nano anti-biotic material of melamine resin and 13% mass, and the phenolic resin of 87% mass and 13% matter The proportioning of the nano anti-biotic material of amount is so that decorative panel also can have preferable anti-microbial property while having preferable intensity.
Embodiment two
Method for making decorative plate is it is characterised in that comprise the following steps:
A0, the anti-microbial property in order to improve decorative panel, melamine resin and nano anti-biotic material are put into dispersion It is mixed into modified melamine-formaldehyde resin in machine;Phenolic resin and nano anti-biotic material are put in dispersion machine and is mixed into Phenol-formaldehyde resin modified.
A, by mixed modified melamine-formaldehyde resin gluing on facing paper;So that the intensity of facing paper is relatively Good, and it is easy to molding, improve the anti-microbial property of decorative panel, facing paper spread is 150% mass, volatile quantity is 10% matter Amount.
B, by mixed phenol-formaldehyde resin modified gluing on kraft paper;So that the intensity of kraft paper is preferably, and It is easy to molding, improve the anti-microbial property of decorative panel, in above-mentioned method for making decorative plate, in stepb, the gluing of kraft paper Measure as 70% mass, volatile quantity is 10% mass.
C, if the facing paper after gluing and dried layer kraft paper are arranged successively poststack heating extrusion forming;So that after molding Decorative panel intensity preferably, the pressure of pressurization is 110kg/cm2, and made temperature rise to 145 DEG C within 50 minutes, keep temperature Degree 30 minutes.
Wherein, modified melamine-formaldehyde resin by 93% mass melamine resin and7The nanometer of % mass Anti-biotic material forms;Phenol-formaldehyde resin modified is made up of the phenolic resin of 93% mass and the nano anti-biotic material of 7% mass.
Embodiment three
Method for making decorative plate is it is characterised in that comprise the following steps:
A0, the anti-microbial property in order to improve decorative panel, melamine resin and nano anti-biotic material are put into dispersion It is mixed into modified melamine-formaldehyde resin in machine;Phenolic resin and nano anti-biotic material are put in dispersion machine and is mixed into Phenol-formaldehyde resin modified.
A, by mixed modified melamine-formaldehyde resin gluing on facing paper;So that the intensity of facing paper is relatively Good, and it is easy to molding, improve the anti-microbial property of decorative panel, facing paper spread is 130% mass, volatile quantity is 7% mass.
B, by mixed phenol-formaldehyde resin modified gluing on kraft paper;So that the intensity of kraft paper is preferably, and It is easy to molding, improve the anti-microbial property of decorative panel, in above-mentioned method for making decorative plate, in stepb, the gluing of kraft paper Measure as 55% mass, volatile quantity is 7% mass.
C, if the facing paper after gluing and dried layer kraft paper are arranged successively poststack heating extrusion forming;So that after molding Decorative panel intensity preferably, the pressure of pressurization is 105kg/cm2, and made temperature rise to 130 DEG C within 35 minutes, keep temperature Degree 25 minutes.
Wherein, the nanometer of the melamine resin by 90% mass for the modified melamine-formaldehyde resin and 10% mass Anti-biotic material forms;Phenol-formaldehyde resin modified is made up of the phenolic resin of 90% mass and the nano anti-biotic material of 10% mass.

Claims (7)

1. method for making decorative plate is it is characterised in that comprise the following steps:
A, by modified melamine-formaldehyde resin gluing to facing paper;
B, by phenol-formaldehyde resin modified gluing to kraft paper;
C, if the facing paper after gluing and dried layer kraft paper are arranged successively poststack heating extrusion forming;
Wherein, modified melamine-formaldehyde resin is by the melamine resin of 87%-93% mass and 7%-13% mass Nano anti-biotic material composition;The phenolic resin by 87%-93% mass for the phenol-formaldehyde resin modified and the nanometer of 7%-13% mass Anti-biotic material forms.
2. method for making decorative plate according to claim 1 is it is characterised in that before step A and step B, by trimerization Cyanamide formaldehyde resin and nano anti-biotic material are put into and are mixed into modified melamine-formaldehyde resin in dispersion machine;By phenolic resin Put into nano anti-biotic material and in dispersion machine, be mixed into phenol-formaldehyde resin modified.
3. method for making decorative plate according to claim 1 and 2 it is characterised in that in step, facing paper spread For 110%-150% mass, volatile quantity is 5%-10% mass.
4. method for making decorative plate according to claim 1 and 2 it is characterised in that in stepb, the gluing of kraft paper Measure as 40-70% mass, volatile quantity is 5%-10% mass.
5. method for making decorative plate according to claim 1 and 2 is it is characterised in that in step C, the pressure of pressurization is 100kg/cm2-110kg/cm2, and making temperature rise to 115 DEG C -145 DEG C within 20-50 minute, keeping temperature 20-30 is divided Clock.
6. method for making decorative plate according to claim 1 and 2 is it is characterised in that described modified melamine-formaldehyde tree Fat is made up of the melamine resin of 90% mass and the nano anti-biotic material of 10 mass;Phenol-formaldehyde resin modified is by 90% matter The nano anti-biotic material composition of the phenolic resin of amount and 10% mass.
7. method for making decorative plate according to claim 1 and 2 is it is characterised in that described nano anti-biotic material is to receive Rice Ag-carried antibacterial material or nanometer titanium dioxide antibiotic material or the mixture of the two.
CN201610765616.7A 2016-08-29 2016-08-29 Making method of decoration plate Pending CN106393921A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610765616.7A CN106393921A (en) 2016-08-29 2016-08-29 Making method of decoration plate

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Application Number Priority Date Filing Date Title
CN201610765616.7A CN106393921A (en) 2016-08-29 2016-08-29 Making method of decoration plate

Publications (1)

Publication Number Publication Date
CN106393921A true CN106393921A (en) 2017-02-15

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107686280A (en) * 2017-08-31 2018-02-13 苏州仲勉装饰有限公司 A kind of decorative panel of loaded modified nano titanium oxide and preparation method thereof
CN112743955A (en) * 2021-01-30 2021-05-04 河南永威安防股份有限公司 High-voltage decorative board with diffuse reflection surface
CN114481686A (en) * 2020-10-27 2022-05-13 龙岩市锐美家装饰材料有限公司 Kraft paper soaking and pressing preparation process for corrosion-resistant plate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1454776A (en) * 2003-05-16 2003-11-12 马青 Antibacterial fire-proofing board and manufacturing method thereof
WO2006078358A2 (en) * 2005-01-21 2006-07-27 Microban Products Company Antimicrobial melamine resin and products
CN103711410A (en) * 2013-12-20 2014-04-09 河南永威安防股份有限公司 Integrally-formed high-pressure single-sided decorative door panel and manufacturing method thereof
CN105584162A (en) * 2012-06-19 2016-05-18 孙学民 Antibacterial and antifungal high-density decorative plate
CN105856779A (en) * 2016-03-30 2016-08-17 宜昌武星材料科技股份有限公司 Decorative laminated board with bacteriostatic function and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1454776A (en) * 2003-05-16 2003-11-12 马青 Antibacterial fire-proofing board and manufacturing method thereof
WO2006078358A2 (en) * 2005-01-21 2006-07-27 Microban Products Company Antimicrobial melamine resin and products
CN105584162A (en) * 2012-06-19 2016-05-18 孙学民 Antibacterial and antifungal high-density decorative plate
CN103711410A (en) * 2013-12-20 2014-04-09 河南永威安防股份有限公司 Integrally-formed high-pressure single-sided decorative door panel and manufacturing method thereof
CN105856779A (en) * 2016-03-30 2016-08-17 宜昌武星材料科技股份有限公司 Decorative laminated board with bacteriostatic function and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107686280A (en) * 2017-08-31 2018-02-13 苏州仲勉装饰有限公司 A kind of decorative panel of loaded modified nano titanium oxide and preparation method thereof
CN114481686A (en) * 2020-10-27 2022-05-13 龙岩市锐美家装饰材料有限公司 Kraft paper soaking and pressing preparation process for corrosion-resistant plate
CN112743955A (en) * 2021-01-30 2021-05-04 河南永威安防股份有限公司 High-voltage decorative board with diffuse reflection surface

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Application publication date: 20170215

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