CN106390946A - Heavy metal adsorbing material with peanut shells and preparing method thereof - Google Patents

Heavy metal adsorbing material with peanut shells and preparing method thereof Download PDF

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CN106390946A
CN106390946A CN201611116380.0A CN201611116380A CN106390946A CN 106390946 A CN106390946 A CN 106390946A CN 201611116380 A CN201611116380 A CN 201611116380A CN 106390946 A CN106390946 A CN 106390946A
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peanut shell
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powder
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不公告发明人
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Zhengzhou Yuanran Biology Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0248Compounds of B, Al, Ga, In, Tl
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/14Diatomaceous earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/288Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/46Materials comprising a mixture of inorganic and organic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48Sorbents characterised by the starting material used for their preparation
    • B01J2220/4875Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
    • B01J2220/4881Residues from shells, e.g. eggshells, mollusk shells
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Water Treatment By Sorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a heavy metal adsorbing material with peanut shells and a preparing method thereof. The heavy metal adsorbing material is prepared from, 21-25 parts of peanut shells, 12-16 parts of diatomite, 4-7 parts of sodium lignosulfonate, 2-5 parts of aluminum chlorohydrate, 3-6 parts of cysteine and 2-5 parts of guggulsterone. The invention further discloses a preparing method of the heavy metal adsorbing material with the peanut shells. The prepared heavy metal adsorbing material has a good adsorbing effect on heavy metal lead ions and heavy metal cadmium ions, adsorbing performance is excellent and the heavy metal adsorbing material can be applied to the field of heavy metal treatment.

Description

A kind of heavy-metal adsorption material of utilization peanut shell preparation and preparation method thereof
Technical field
The present invention relates to heavy-metal adsorption material technical field, specifically a kind of heavy metal adsorption of utilization peanut shell preparation Material and preparation method thereof.
Background technology
Heavy metal is a kind of toxic element that can accumulate in vivo, and with industrial expansion, heavy metal pollution is subject to Extensively pay attention to, heavy metal can be accumulated in biological chain after entering environment and be enriched with, and can not be biodegradable, and can hide for a long time In environment, and enter human body serious harm life and health with food chain.The method going heavy metal ion in eliminating water at present is general Have:Coagulation Method, chemical precipitation method, membrane separation process, ion-exchange-resin process, bioanalysis, absorption method etc..Coagulation Method is using adding The flco Adsorption heavy metal ion that coagulant is formed, this method need to consume larger amount of coagulant, relatively costly, conventional water Under the conditions of matter, the removal effect of heavy metal ion is undesirable;Chemical precipitation method is heavy metal ion to be changed into the sulphur being insoluble in water Carry out precipitation after the salt such as compound or hydroxide to remove, have that flow process is simple, the low advantage of processing cost, but the quantity of slag is big, contain Water rate is high, dehydration is difficult, and has the risk of secondary pollution, and because this method is based on the principle of solubility product, it cannot be processed The relatively low waste water of concentration of heavy metal ion;Membrane separation process is the selectivity using film, and the energy difference being existed using film both sides is as pushing away , it is allowed to some components pass through and retain other components in mixture, thus reaching the technology separating purpose, it can be effective for power Go the heavy metal ion in eliminating water, but processing cost is very high;Ion-exchange-resin process is will to be dissolved in water by ion exchange resin In heavy metal ion exchange in resin, removed with this or reclaim heavy metal ion, but ion exchange resin is expensive, and Regeneration need to consume a large amount of medicaments;Bioanalysis be organism by physics, chemical action Adsorption of Heavy Metal Ions, there is energy-conservation, place The advantages of manage efficiency high, be easily isolated recovery heavy metal, but bioanalysis needs to carry out introducing a fine variety, cultivating and nutriment of biology Supply, runs operation inconvenience;And when concentration of heavy metal ion is higher, toxic and side effect can be given birth to bio, cause biological anti- Answer efficiency to reduce even to lose efficacy;Absorption method is a kind of tradition side using porous solid material Adsorption water pollutant Method, it is various to have raw material sources, using easy and simple to handle, renewable the advantages of, application is relatively wide at present, but is applied to heavy metals removal Efficient, economic heavy metal ion adsorbing material still rare.
It is always the study hotspot of this area using agricultural byproducts as heavy-metal adsorption material, due to agricultural byproducts source Extensively, cheap, and be not in secondary pollution during use, therefore suffer from extensive concern.Disclose in prior art In the application in heavy metal adsorption field, peanut shell is exactly one kind therein to multiple agricultural byproducts.But existing based on peanut shell system The adsorption effect of standby sorbing material heavy metal is performed poor, and practicality is not strong.
Content of the invention
It is an object of the invention to provide a kind of heavy-metal adsorption material of utilization peanut shell preparation and preparation method thereof, with Solve the problems, such as to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of heavy-metal adsorption material of utilization peanut shell preparation, is made up of the following raw material according to weight portion:Peanut shell 21-25 part, diatomite 12-16 part, sodium lignin sulfonate 4-7 part, chlorination hydroxyl aluminium 2-5 part, cysteine 3-6 part, myrrh sterone 2-5 part.
As the further scheme of the present invention:It is made up of the following raw material according to weight portion:Peanut shell 22-24 part, diatom Native 13-15 part, sodium lignin sulfonate 5-6 part, chlorination hydroxyl aluminium 3-4 part, cysteine 4-5 part, myrrh sterone 3-4 part.
As the present invention further scheme:It is made up of the following raw material according to weight portion:23 parts of peanut shell, diatomite 14 parts, 5.7 parts of sodium lignin sulfonate, 3.5 parts of chlorination hydroxyl aluminium, 4.4 parts of cysteine, 3.8 parts of myrrh sterone.
The preparation method of the heavy-metal adsorption material of described utilization peanut shell preparation, step is as follows:
1) weigh peanut shell, being crushed to particle diameter is 1-2mm, puts in baking oven, dried process 1-2h at 140-150 DEG C, Obtain peanut shell powder;
2) peanut shell powder is put into micronizer, carries out ultramicro grinding, after ultramicro grinding, cross 400-500 mesh sieve, Obtain peanut shell Ultramicro-powder;
3) weigh diatomite, isothermal holding 40-50min at 620-650 DEG C, after pulverizing, crosses 200-300 mesh sieve, obtains Diatomite powder, standby;
4) weigh sodium lignin sulfonate and myrrh sterone, after merging, add the deionized water of total amount 10-13 times weight, At 85-90 DEG C, stirring mixing 1-2h, obtains mixed liquor A;
5) weigh chlorination hydroxyl aluminium and cysteine, add to mixed liquor A, stirring mixing 40-50min at 60-65 DEG C, Then ultrasonication 50-60min again, obtains mixed liquid B;
6) peanut shell Ultramicro-powder and diatomite powder are added and carry out wet ball grinding to ball mill, using mixed liquid B as Lapping liquid, ball-milling treatment 3-4h, obtain slurries;
7) after slurries being vacuum dried, obtain desciccate, by desciccate at 480-490 DEG C isothermal holding 1-2h, Then naturally cool to room temperature, then grind, cross 100-200 mesh sieve, you can.
Above-mentioned sorbing material can be applied to process heavy metal wastewater thereby.
Compared with prior art, the invention has the beneficial effects as follows:
1st, the present invention preparation heavy-metal adsorption material heavy metal lead ion and heavy metal cadmium ion be respectively provided with good Adsorption effect, absorption property is excellent, can be applied to heavy metal process field.2nd, the sorbing material of present invention preparation, its utilization Peanut shell, as raw material, carries out twice laid to this agricultural byproducts of peanut shell, turns waste into wealth, reduce production cost, favorably In the heavy-metal adsorption material producing low cost, be conducive to the development of heavy metal treatment industry.
Specific embodiment
With reference to specific embodiment, technical scheme is described in more detail.
Embodiment 1
A kind of heavy-metal adsorption material of utilization peanut shell preparation, is made up of the following raw material according to weight portion:Peanut shell 21 parts, 12 parts of diatomite, 4 parts of sodium lignin sulfonate, 2 parts of chlorination hydroxyl aluminium, 3 parts of cysteine, 2 parts of myrrh sterone.
In the present embodiment, the preparation method of the heavy-metal adsorption material of described utilization peanut shell preparation, step is as follows:
1) weigh peanut shell, being crushed to particle diameter is 1mm, puts in baking oven, dried process 1h at 140 DEG C, obtains peanut Shell powder;
2) peanut shell powder is put into micronizer, carry out ultramicro grinding, after ultramicro grinding, cross 400 mesh sieves, obtain Peanut shell Ultramicro-powder;
3) weigh diatomite, isothermal holding 40min at 620 DEG C, after pulverizing, cross 200 mesh sieves, obtain diatomite powder, Standby;
4) weigh sodium lignin sulfonate and myrrh sterone, after merging, add the deionized water of 10 times of weight of total amount, at 85 DEG C Lower stirring mixing 1h, obtains mixed liquor A;
5) weigh chlorination hydroxyl aluminium and cysteine, add to mixed liquor A, stirring mixing 40min, Ran Houzai at 60 DEG C Ultrasonication 50min, obtains mixed liquid B;
6) peanut shell Ultramicro-powder and diatomite powder are added and carry out wet ball grinding to ball mill, using mixed liquid B as Lapping liquid, ball-milling treatment 3h, obtain slurries;
7) after slurries being vacuum dried, obtain desciccate, by desciccate at 480 DEG C isothermal holding 1h, then from So it is cooled to room temperature, then grinds, cross 100 mesh sieves, you can.
Embodiment 2
A kind of heavy-metal adsorption material of utilization peanut shell preparation, is made up of the following raw material according to weight portion:Peanut shell 22 parts, 13 parts of diatomite, 6 parts of sodium lignin sulfonate, 4 parts of chlorination hydroxyl aluminium, 4 parts of cysteine, 4 parts of myrrh sterone.
In the present embodiment, the preparation method of the heavy-metal adsorption material of described utilization peanut shell preparation, step is as follows:
1) weigh peanut shell, being crushed to particle diameter is 1mm, puts in baking oven, dried process 1h at 145 DEG C, obtains peanut Shell powder;
2) peanut shell powder is put into micronizer, carry out ultramicro grinding, after ultramicro grinding, cross 400 mesh sieves, obtain Peanut shell Ultramicro-powder;
3) weigh diatomite, isothermal holding 43min at 630 DEG C, after pulverizing, cross 200 mesh sieves, obtain diatomite powder, Standby;
4) weigh sodium lignin sulfonate and myrrh sterone, after merging, add the deionized water of 11 times of weight of total amount, at 86 DEG C Lower stirring mixing 1.5h, obtains mixed liquor A;
5) weigh chlorination hydroxyl aluminium and cysteine, add to mixed liquor A, stirring mixing 45min, Ran Houzai at 62 DEG C Ultrasonication 60min, obtains mixed liquid B;
6) peanut shell Ultramicro-powder and diatomite powder are added and carry out wet ball grinding to ball mill, using mixed liquid B as Lapping liquid, ball-milling treatment 3h, obtain slurries;
7) after slurries being vacuum dried, obtain desciccate, by desciccate at 483 DEG C isothermal holding 1.5h, then Naturally cool to room temperature, then grind, cross 100 mesh sieves, you can.
Embodiment 3
A kind of heavy-metal adsorption material of utilization peanut shell preparation, is made up of the following raw material according to weight portion:Peanut shell 23 parts, 14 parts of diatomite, 5.7 parts of sodium lignin sulfonate, 3.5 parts of chlorination hydroxyl aluminium, 4.4 parts of cysteine, 3.8 parts of myrrh sterone.
In the present embodiment, the preparation method of the heavy-metal adsorption material of described utilization peanut shell preparation, step is as follows:
1) weigh peanut shell, being crushed to particle diameter is 1.5mm, puts in baking oven, dried process 1.5h at 145 DEG C, obtains Peanut shell powder;
2) peanut shell powder is put into micronizer, carry out ultramicro grinding, after ultramicro grinding, cross 500 mesh sieves, obtain Peanut shell Ultramicro-powder;
3) weigh diatomite, isothermal holding 45min at 640 DEG C, after pulverizing, cross 200 mesh sieves, obtain diatomite powder, Standby;
4) weigh sodium lignin sulfonate and myrrh sterone, after merging, add the deionized water of 12 times of weight of total amount, at 87 DEG C Lower stirring mixing 1.5h, obtains mixed liquor A;
5) weigh chlorination hydroxyl aluminium and cysteine, add to mixed liquor A, stirring mixing 45min, Ran Houzai at 63 DEG C Ultrasonication 55min, obtains mixed liquid B;
6) peanut shell Ultramicro-powder and diatomite powder are added and carry out wet ball grinding to ball mill, using mixed liquid B as Lapping liquid, ball-milling treatment 3.5h, obtain slurries;
7) after slurries being vacuum dried, obtain desciccate, by desciccate at 485 DEG C isothermal holding 1.5h, then Naturally cool to room temperature, then grind, cross 200 mesh sieves, you can.
Embodiment 4
A kind of heavy-metal adsorption material of utilization peanut shell preparation, is made up of the following raw material according to weight portion:Peanut shell 24 parts, 15 parts of diatomite, 5 parts of sodium lignin sulfonate, 3 parts of chlorination hydroxyl aluminium, 5 parts of cysteine, 3 parts of myrrh sterone.
In the present embodiment, the preparation method of the heavy-metal adsorption material of described utilization peanut shell preparation, step is as follows:
1) weigh peanut shell, being crushed to particle diameter is 2mm, puts in baking oven, dried process 1.5h at 143 DEG C, obtains flower Raw shell powder;
2) peanut shell powder is put into micronizer, carry out ultramicro grinding, after ultramicro grinding, cross 400 mesh sieves, obtain Peanut shell Ultramicro-powder;
3) weigh diatomite, isothermal holding 47min at 630 DEG C, after pulverizing, cross 300 mesh sieves, obtain diatomite powder, Standby;
4) weigh sodium lignin sulfonate and myrrh sterone, after merging, add the deionized water of 13 times of weight of total amount, at 87 DEG C Lower stirring mixing 1h, obtains mixed liquor A;
5) weigh chlorination hydroxyl aluminium and cysteine, add to mixed liquor A, stirring mixing 47min, Ran Houzai at 62 DEG C Ultrasonication 50min, obtains mixed liquid B;
6) peanut shell Ultramicro-powder and diatomite powder are added and carry out wet ball grinding to ball mill, using mixed liquid B as Lapping liquid, ball-milling treatment 3.5h, obtain slurries;
7) after slurries being vacuum dried, obtain desciccate, by desciccate at 485 DEG C isothermal holding 1.5h, then Naturally cool to room temperature, then grind, cross 100 mesh sieves, you can.
Embodiment 5
A kind of heavy-metal adsorption material of utilization peanut shell preparation, is made up of the following raw material according to weight portion:Peanut shell 25 parts, 16 parts of diatomite, 7 parts of sodium lignin sulfonate, 5 parts of chlorination hydroxyl aluminium, 6 parts of cysteine, 5 parts of myrrh sterone.
In the present embodiment, the preparation method of the heavy-metal adsorption material of described utilization peanut shell preparation, step is as follows:
1) weigh peanut shell, being crushed to particle diameter is 2mm, puts in baking oven, dried process 2h at 150 DEG C, obtains peanut Shell powder;
2) peanut shell powder is put into micronizer, carry out ultramicro grinding, after ultramicro grinding, cross 500 mesh sieves, obtain Peanut shell Ultramicro-powder;
3) weigh diatomite, isothermal holding 50min at 650 DEG C, after pulverizing, cross 300 mesh sieves, obtain diatomite powder, Standby;
4) weigh sodium lignin sulfonate and myrrh sterone, after merging, add the deionized water of 13 times of weight of total amount, at 90 DEG C Lower stirring mixing 2h, obtains mixed liquor A;
5) weigh chlorination hydroxyl aluminium and cysteine, add to mixed liquor A, stirring mixing 50min, Ran Houzai at 65 DEG C Ultrasonication 60min, obtains mixed liquid B;
6) peanut shell Ultramicro-powder and diatomite powder are added and carry out wet ball grinding to ball mill, using mixed liquid B as Lapping liquid, ball-milling treatment 4h, obtain slurries;
7) after slurries being vacuum dried, obtain desciccate, by desciccate at 490 DEG C isothermal holding 2h, then from So it is cooled to room temperature, then grinds, cross 200 mesh sieves, you can.
Comparative example 1
Compared with Example 3, without myrrh sterone, other are same as Example 3.
Comparative example 2
Compared with Example 3, without cysteine, other are same as Example 3.
Comparative example 3
Compared with Example 3, without myrrh sterone and cysteine, other are same as Example 3.
Comparative example 4
Compared with Example 3, using conventional preparation method, other are same as Example 3.Wherein, described conventional preparation Method is to be pulverized and mixed uniformly each raw material.
Heavy metal adsorption test is carried out using the sorbing material prepared by embodiment 1-5 and comparative example 1-4, measures each absorption The absorption property of material heavy metal under conditions of 20 DEG C, pH=7, result of the test is as shown in table 1.
Table 1 absorption property table
Group Cd(mg/g) Pb(mg/g)
Embodiment 1 76.83 225.73
Embodiment 2 76.56 232.85
Embodiment 3 82.54 236.47
Embodiment 4 81.36 228.96
Embodiment 5 79.91 229.58
Comparative example 1 68.20 187.26
Comparative example 2 65.72 186.54
Comparative example 3 58.46 158.43
Comparative example 4 63.57 173.52
As can be seen from the above table, the sorbing material heavy metal lead ion of present invention preparation and heavy metal cadmium ion are respectively provided with Good adsorption effect, absorption property is excellent, can be applied to heavy metal process field.The sorbing material of present invention preparation, its By the use of peanut shell as raw material, twice laid is carried out to this agricultural byproducts of peanut shell, turns waste into wealth, reduce production cost, Be conducive to producing the heavy-metal adsorption material of low cost, be conducive to the development of heavy metal treatment industry.
In addition, the sorbing material from the Data Comparison with comparative example 1-3 for the embodiment 3 as can be seen that prepared by embodiment 3 Performance be better than comparative example 1-3, and the performance of the sorbing material prepared by comparative example 1-2 be better than comparative example 3.Due to comparative example 1 Compared with Example 3, without myrrh sterone, other are same as Example 3;Comparative example 2 compared with Example 3, without half Guang ammonia Acid, other are same as Example 3;Comparative example 3 compared with Example 3, without myrrh sterone and cysteine, other and embodiment 3 is identical.It can therefore be seen that the present invention passes through to add myrrh sterone and cysteine, myrrh sterone, cysteine and other groups Divide synergy, be conducive to improving the adsorption effect of heavy metal.
The performance of the sorbing material from the Data Comparison with comparative example 4 for the embodiment 3 as can be seen that prepared by embodiment 3 Better than comparative example 4, due to comparative example 4 compared with Example 3, using conventional preparation method, other are same as Example 3, because Using preparation method of the present invention, to the present invention, each raw material is processed for this, is conducive to improving the adsorption effect of heavy metal.
Above the better embodiment of the present invention is explained in detail, but the present invention is not limited to above-mentioned embodiment party Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of without departing from present inventive concept Various changes can be made.

Claims (5)

1. a kind of heavy-metal adsorption material of utilization peanut shell preparation is it is characterised in that by the following raw material system according to weight portion Become:Peanut shell 21-25 part, diatomite 12-16 part, sodium lignin sulfonate 4-7 part, chlorination hydroxyl aluminium 2-5 part, cysteine 3-6 part, Myrrh sterone 2-5 part.
2. utilization peanut shell according to claim 1 preparation heavy-metal adsorption material it is characterised in that by following according to The raw material of weight portion is made:Peanut shell 22-24 part, diatomite 13-15 part, sodium lignin sulfonate 5-6 part, chlorination hydroxyl aluminium 3-4 part, Cysteine 4-5 part, myrrh sterone 3-4 part.
3. utilization peanut shell according to claim 2 preparation heavy-metal adsorption material it is characterised in that by following according to The raw material of weight portion is made:23 parts of peanut shell, 14 parts of diatomite, 5.7 parts of sodium lignin sulfonate, 3.5 parts of chlorination hydroxyl aluminium, half Guang ammonia Sour 4.4 parts, 3.8 parts of myrrh sterone.
4. a kind of preparation method of the described heavy-metal adsorption material of utilization peanut shell preparation as arbitrary in claim 1-3, its It is characterised by, step is as follows:
1) weigh peanut shell, being crushed to particle diameter is 1-2mm, puts in baking oven, dried process 1-2h at 140-150 DEG C, obtains Peanut shell powder;
2) peanut shell powder is put into micronizer, carry out ultramicro grinding, after ultramicro grinding, cross 400-500 mesh sieve, obtain Peanut shell Ultramicro-powder;
3) weigh diatomite, isothermal holding 40-50min at 620-650 DEG C, after pulverizing, crosses 200-300 mesh sieve, obtains diatom Native powder, standby;
4) weigh sodium lignin sulfonate and myrrh sterone, after merging, add the deionized water of total amount 10-13 times weight, in 85-90 At DEG C, stirring mixing 1-2h, obtains mixed liquor A;
5) weigh chlorination hydroxyl aluminium and cysteine, add to mixed liquor A, stirring mixing 40-50min at 60-65 DEG C, then Ultrasonication 50-60min again, obtains mixed liquid B;
6) peanut shell Ultramicro-powder and diatomite powder are added and carry out wet ball grinding to ball mill, using mixed liquid B as grinding Liquid, ball-milling treatment 3-4h, obtain slurries;
7) after slurries being vacuum dried, obtain desciccate, by desciccate at 480-490 DEG C isothermal holding 1-2h, then Naturally cool to room temperature, then grind, cross 100-200 mesh sieve, you can.
5. purposes in heavy metal containing wastewater treatment field for the described sorbing material as arbitrary in claim 1-3.
CN201611116380.0A 2016-12-07 2016-12-07 Heavy metal adsorbing material with peanut shells and preparing method thereof Withdrawn CN106390946A (en)

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