CN105170114A - Composite adsorption material for treatment of industrial waste water and preparation method thereof - Google Patents
Composite adsorption material for treatment of industrial waste water and preparation method thereof Download PDFInfo
- Publication number
- CN105170114A CN105170114A CN201510509110.5A CN201510509110A CN105170114A CN 105170114 A CN105170114 A CN 105170114A CN 201510509110 A CN201510509110 A CN 201510509110A CN 105170114 A CN105170114 A CN 105170114A
- Authority
- CN
- China
- Prior art keywords
- parts
- industrial wastewater
- adsorbing material
- wastewater treatment
- composite adsorbing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention relates to a composite adsorption material for treatment of industrial waste water and a preparation method thereof. The composite adsorption material is characterized by comprising 5 to 15 parts of polyaluminum silicate sulfate, 3 to 10 parts of polyaluminum chloride, 4 to 8 parts of macroporous adsorption resin D1300, 4 to 9 parts of macroporous adsorption resin H103, 3 to 8 parts of polyethelene alcohol fiber, 2 to 5 parts of Arabic gum, 4 to 9 parts of hydroxypropyl chitosan, 3 to 7 parts of barium sulfate and 4 to 7 parts of lithium carbonate. The preparation method comprises the following steps: step 1, crushing barium carbonate and lithium carbonate with a crusher until the particle size of both barium carbonate and lithium carbonate is 150 to 300 meshes; and step 2, respectively weighing the above-mentioned components according to weight parts and uniformly mixing the components to prepare the composite adsorption material for treatment of industrial waste water.
Description
Technical field
The invention belongs to environmental treatment field, relate to a kind of composite adsorbing material and preparation method thereof, particularly relate to a kind of Industrial Wastewater Treatment composite adsorbing material and preparation method thereof.
Background technology
Conventional waste water processing procedure, as activated sludge process and trickling filtration, can remove gas chromatography matter by biological oxidation.This processing procedure almost can remove all organic matters forming BOD, but effectively can not remove the hardly degraded organic substance forming COD, even if process good secondary effluent still contains 50-120mg/L organic matter, these materials comprise the material of lignin, humus, ethers, proteinaceous material and some other generation look and stink, and herbicide and agrochemical.
Utilize absorption method can remove the organic matter of most of difficult degradation, in addition, absorption method has higher clearance to free chlorine and some trace meters such as mercury, silver, chromium, antimony, arsenic etc.Due to the surface-active of mineral and other resin materials, Ultrafine effect, chemical composition, crystal structure and physicochemical properties, and be aided with appropriate modification technology, make mineral and other sorbing materials have good environment attribute.Novel sorbing material is widely used in the unbalance function reparation etc. of industrial production, the environment pollution control of life and environment.
Summary of the invention
The technical problem solved: industrial wastewater is larger to environmental hazard, especially the harm of heavy metal wastewater thereby to environment is larger, processing method for heavy metal wastewater thereby is more, but it is lower for its adsorption effect of sorbing material of heavy metal containing wastewater treatment, after treatment, in heavy metal wastewater thereby, content of beary metal is still higher, therefore, the present invention discloses a kind of composite adsorbing material and preparation method thereof, improves the efficiency of its absorption heavy metal in waste water.
Technical scheme: in order to solve the problem, the invention discloses a kind of Industrial Wastewater Treatment composite adsorbing material, and described composite adsorbing material comprises the composition of following weight parts:
Poly aluminium sulfate silicate 5-15 part,
Aluminium polychloride 3-10 part,
D1300 macroporous absorbent resin 4-8 part,
H103 macroporous absorbent resin 4-9 part,
Vinal 3-8 part,
Arabic gum 2-5 part,
Hydroxypropyl chitosan 4-9 part,
Barium sulfate 3-7 part,
Lithium carbonate 4-7 part.
Preferably, described a kind of Industrial Wastewater Treatment composite adsorbing material, comprises the composition of following weight parts:
Poly aluminium sulfate silicate 8-12 part,
Aluminium polychloride 4-8 part,
D1300 macroporous absorbent resin 5-7 part,
H103 macroporous absorbent resin 5-8 part,
Vinal 4-7 part,
Arabic gum 3-4 part,
Hydroxypropyl chitosan 5-8 part,
Barium sulfate 4-6 part,
Lithium carbonate 5-6 part.
The preparation method of described a kind of Industrial Wastewater Treatment composite adsorbing material, step is as follows:
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 150 order-300 orders;
Step 2: get poly aluminium sulfate silicate 5-15 part, aluminium polychloride 3-10 part, D1300 macroporous absorbent resin 4-8 part, H103 macroporous absorbent resin 4-9 part, vinal 3-8 part, Arabic gum 2-5 part, hydroxypropyl chitosan 4-9 part, barium sulfate 3-7 part, lithium carbonate 4-7 part by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
Preferably, described a kind of Industrial Wastewater Treatment composite adsorbing material, when described Industrial Wastewater Treatment composite adsorbing material is used for Industrial Wastewater Treatment, its input amount is the 0.1wt%-90wt% of waste water weight.
Preferred further, described a kind of Industrial Wastewater Treatment composite adsorbing material, when described Industrial Wastewater Treatment composite adsorbing material is used for Industrial Wastewater Treatment, its input amount is the 1wt%-10wt% of waste water weight.
Described a kind of Industrial Wastewater Treatment composite adsorbing material, described industrial wastewater is heavy metal wastewater thereby.
Described a kind of Industrial Wastewater Treatment composite adsorbing material, in described heavy metal wastewater thereby, heavy metal is one or more in Cr, Ni, Hg, Co, As.
Beneficial effect: of the present invention for containing dissimilar adsorbent in the sorbing material of Industrial Wastewater Treatment, by above-mentioned sorbing material is combined, effectively raise the adsorption capacity of the composite adsorbing material heavy metal of preparation, Adsorption of Heavy Metals has played synergy, sorbing material of the present invention can effectively for reducing the content of Cr, Ni, Hg, Co, the As in waste water, more can be further used for the reduction of BOD in industrial wastewater and chemical oxygen consumption (COC), also there is very good effect.
Detailed description of the invention
Embodiment 1
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 300 orders;
Step 2: get poly aluminium sulfate silicate 15 parts, aluminium polychloride 10 parts, D1300 macroporous absorbent resin 4 parts, H103 macroporous absorbent resin 4 parts, vinal 8 parts, Arabic gum 5 parts, hydroxypropyl chitosan 4 parts, 3 parts, barium sulfate, lithium carbonate 7 parts by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
Embodiment 2
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 150 orders;
Step 2: get poly aluminium sulfate silicate 5 parts, aluminium polychloride 3 parts, D1300 macroporous absorbent resin 8 parts, H103 macroporous absorbent resin 9 parts, vinal 3 parts, Arabic gum 2 parts, hydroxypropyl chitosan 9 parts, 7 parts, barium sulfate, lithium carbonate 4 parts by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
Embodiment 3
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 300 orders;
Step 2: get poly aluminium sulfate silicate 12 parts, aluminium polychloride 4 parts, D1300 macroporous absorbent resin 5 parts, H103 macroporous absorbent resin 8 parts, vinal 4 parts, Arabic gum 4 parts, hydroxypropyl chitosan 5 parts, 4 parts, barium sulfate, lithium carbonate 6 parts by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
Embodiment 4
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 150 orders;
Step 2: get poly aluminium sulfate silicate 8 parts, aluminium polychloride 8 parts, D1300 macroporous absorbent resin 7 parts, H103 macroporous absorbent resin 5 parts, vinal 7 parts, Arabic gum 3 parts, hydroxypropyl chitosan 8 parts, 6 parts, barium sulfate, lithium carbonate 5 parts by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
Comparative example 1
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 300 orders;
Step 2: get poly aluminium sulfate silicate 15 parts, aluminium polychloride 10 parts, D1300 macroporous absorbent resin 4 parts, Arabic gum 5 parts, hydroxypropyl chitosan 4 parts, 3 parts, barium sulfate, lithium carbonate 7 parts by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
Comparative example 2
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 300 orders;
Step 2: get poly aluminium sulfate silicate 15 parts, aluminium polychloride 10 parts of H103 macroporous absorbent resins 4 parts, vinal 8 parts, Arabic gum 5 parts, 3 parts, barium sulfate, lithium carbonate 7 parts by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
Comparative example 3
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 300 orders;
Step 2: get poly aluminium sulfate silicate 15 parts, aluminium polychloride 10 parts, D1300 macroporous absorbent resin 4 parts, vinal 8 parts, Arabic gum 5 parts, hydroxypropyl chitosan 4 parts, 3 parts, barium sulfate by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
By the composite adsorbing material of embodiment and comparative example for the treatment of heavy metal wastewater thereby, before process, in heavy metal wastewater thereby, the content of Cr, Ni, Hg is respectively 185mg/Kg, 94mg/Kg, 121mg/Kg, composite adsorbing material is fed in waste water respectively, addition is 3wt%, stir 1-2h, heavy metal wastewater thereby is centrifugal, and measure the content of Cr, Ni, Hg in supernatant, result is as follows:
| Cr content (mg/Kg) | Ni content (mg/Kg) | Hg content (mg/Kg) | |
| Embodiment 1 | 82 | 44 | 58 |
| Embodiment 2 | 79 | 42 | 62 |
| Embodiment 3 | 63 | 27 | 44 |
| Embodiment 4 | 56 | 31 | 49 |
After the composite adsorbing material process of comparative example, result is as follows:
| Cr content (mg/Kg) | Ni content (mg/Kg) | Hg content (mg/Kg) | |
| Embodiment 1 | 127 | 67 | 93 |
| Embodiment 2 | 131 | 62 | 86 |
| Embodiment 3 | 107 | 66 | 97 |
Claims (7)
1. an Industrial Wastewater Treatment composite adsorbing material, is characterized in that, described composite adsorbing material comprises the composition of following weight parts:
Poly aluminium sulfate silicate 5-15 part,
Aluminium polychloride 3-10 part,
D1300 macroporous absorbent resin 4-8 part,
H103 macroporous absorbent resin 4-9 part,
Vinal 3-8 part,
Arabic gum 2-5 part,
Hydroxypropyl chitosan 4-9 part,
Barium sulfate 3-7 part,
Lithium carbonate 4-7 part.
2. a kind of Industrial Wastewater Treatment composite adsorbing material according to claim 1, is characterized in that, described composite adsorbing material comprises the composition of following weight parts:
Poly aluminium sulfate silicate 8-12 part,
Aluminium polychloride 4-8 part,
D1300 macroporous absorbent resin 5-7 part,
H103 macroporous absorbent resin 5-8 part,
Vinal 4-7 part,
Arabic gum 3-4 part,
Hydroxypropyl chitosan 5-8 part,
Barium sulfate 4-6 part,
Lithium carbonate 5-6 part.
3. the preparation method of a kind of Industrial Wastewater Treatment composite adsorbing material according to claim 1, it is characterized in that, described preparation method is as follows:
Step 1: brium carbonate and lithium carbonate pulverizer are pulverized, the order number being crushed to brium carbonate and lithium carbonate is 150 order-300 orders;
Step 2: get poly aluminium sulfate silicate 5-15 part, aluminium polychloride 3-10 part, D1300 macroporous absorbent resin 4-8 part, H103 macroporous absorbent resin 4-9 part, vinal 3-8 part, Arabic gum 2-5 part, hydroxypropyl chitosan 4-9 part, barium sulfate 3-7 part, lithium carbonate 4-7 part by weight respectively, being mixed by above-mentioned composition, is the Industrial Wastewater Treatment composite adsorbing material of preparation.
4. a kind of Industrial Wastewater Treatment composite adsorbing material according to claim 1, is characterized in that, when described Industrial Wastewater Treatment composite adsorbing material is used for Industrial Wastewater Treatment, its input amount is the 0.1wt%-90wt% of waste water weight.
5. a kind of Industrial Wastewater Treatment composite adsorbing material according to claim 4, is characterized in that, when described Industrial Wastewater Treatment composite adsorbing material is used for Industrial Wastewater Treatment, its input amount is the 1wt%-10wt% of waste water weight.
6. a kind of Industrial Wastewater Treatment composite adsorbing material according to claim 4 or 5, is characterized in that, described industrial wastewater is heavy metal wastewater thereby.
7. a kind of Industrial Wastewater Treatment composite adsorbing material according to claim 6, is characterized in that, in described heavy metal wastewater thereby, heavy metal is one or more in Cr, Ni, Hg, Co, As.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510509110.5A CN105170114A (en) | 2015-08-19 | 2015-08-19 | Composite adsorption material for treatment of industrial waste water and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510509110.5A CN105170114A (en) | 2015-08-19 | 2015-08-19 | Composite adsorption material for treatment of industrial waste water and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105170114A true CN105170114A (en) | 2015-12-23 |
Family
ID=54892826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510509110.5A Pending CN105170114A (en) | 2015-08-19 | 2015-08-19 | Composite adsorption material for treatment of industrial waste water and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105170114A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106378107A (en) * | 2016-09-21 | 2017-02-08 | 苏州佰思科节能环保科技有限公司 | Composite material for rapidly absorbing petroleum pollutant and preparation method thereof |
| CN106390946A (en) * | 2016-12-07 | 2017-02-15 | 郑州源冉生物技术有限公司 | Heavy metal adsorbing material with peanut shells and preparing method thereof |
| CN106390945A (en) * | 2016-12-07 | 2017-02-15 | 郑州源冉生物技术有限公司 | Heavy metal adsorbing material prepared from straws and preparation method thereof |
| CN106552594A (en) * | 2016-12-07 | 2017-04-05 | 郑州源冉生物技术有限公司 | A kind of heavy metal composite adsorbing material based on volcanic ash and preparation method thereof |
| CN106732419A (en) * | 2016-12-07 | 2017-05-31 | 郑州源冉生物技术有限公司 | One kind is based on kaolinic heavy metal composite adsorbing material and preparation method thereof |
| CN115155516A (en) * | 2022-09-09 | 2022-10-11 | 淄博正河净水剂有限公司 | Heavy metal wastewater adsorbent and preparation method thereof |
| CN115155510A (en) * | 2022-08-04 | 2022-10-11 | 成都开飞高能化学工业有限公司 | Preparation method of aluminum salt lithium extraction functional material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102951715A (en) * | 2012-11-13 | 2013-03-06 | 山东泰德新能源有限公司 | Treating agent applied to papermaking sewage |
| CN103288292A (en) * | 2013-05-07 | 2013-09-11 | 江苏长华聚氨酯科技有限公司 | Processing method for polyether-containing wastewater |
| CN104276641A (en) * | 2014-10-29 | 2015-01-14 | 山东华亚环保科技有限公司 | Flocculating agent for textile printing and dyeing wastewater |
-
2015
- 2015-08-19 CN CN201510509110.5A patent/CN105170114A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102951715A (en) * | 2012-11-13 | 2013-03-06 | 山东泰德新能源有限公司 | Treating agent applied to papermaking sewage |
| CN103288292A (en) * | 2013-05-07 | 2013-09-11 | 江苏长华聚氨酯科技有限公司 | Processing method for polyether-containing wastewater |
| CN104276641A (en) * | 2014-10-29 | 2015-01-14 | 山东华亚环保科技有限公司 | Flocculating agent for textile printing and dyeing wastewater |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106378107A (en) * | 2016-09-21 | 2017-02-08 | 苏州佰思科节能环保科技有限公司 | Composite material for rapidly absorbing petroleum pollutant and preparation method thereof |
| CN106390946A (en) * | 2016-12-07 | 2017-02-15 | 郑州源冉生物技术有限公司 | Heavy metal adsorbing material with peanut shells and preparing method thereof |
| CN106390945A (en) * | 2016-12-07 | 2017-02-15 | 郑州源冉生物技术有限公司 | Heavy metal adsorbing material prepared from straws and preparation method thereof |
| CN106552594A (en) * | 2016-12-07 | 2017-04-05 | 郑州源冉生物技术有限公司 | A kind of heavy metal composite adsorbing material based on volcanic ash and preparation method thereof |
| CN106732419A (en) * | 2016-12-07 | 2017-05-31 | 郑州源冉生物技术有限公司 | One kind is based on kaolinic heavy metal composite adsorbing material and preparation method thereof |
| CN115155510A (en) * | 2022-08-04 | 2022-10-11 | 成都开飞高能化学工业有限公司 | Preparation method of aluminum salt lithium extraction functional material |
| CN115155510B (en) * | 2022-08-04 | 2023-11-10 | 成都开飞高能化学工业有限公司 | Preparation method of aluminum salt lithium extraction functional material |
| CN115155516A (en) * | 2022-09-09 | 2022-10-11 | 淄博正河净水剂有限公司 | Heavy metal wastewater adsorbent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105170114A (en) | Composite adsorption material for treatment of industrial waste water and preparation method thereof | |
| Younas et al. | Current and emerging adsorbent technologies for wastewater treatment: trends, limitations, and environmental implications | |
| Yang et al. | Electrocatalysis degradation of tetracycline in a three-dimensional aeration electrocatalysis reactor (3D-AER) with a flotation-tailings particle electrode (FPE): Physicochemical properties, influencing factors and the degradation mechanism | |
| Owamah | Biosorptive removal of Pb (II) and Cu (II) from wastewater using activated carbon from cassava peels | |
| Ahmadpour et al. | Rapid removal of cobalt ion from aqueous solutions by almond green hull | |
| Jayaram et al. | Biosorption of lead from aqueous solution by seed powder of Strychnos potatorum L. | |
| Zhou et al. | Pb (II), Cr (VI) and atrazine sorption behavior on sludge-derived biochar: role of humic acids | |
| Khan et al. | Isotherm and kinetics modeling of Pb (II) and Cd (II) adsorptive uptake from aqueous solution by chemically modified green algal biomass | |
| Ou et al. | Preparation of iron/calcium-modified biochar for phosphate removal from industrial wastewater | |
| Dalal et al. | A novel nano zero-valent iron biomaterial for chromium (Cr 6+ to Cr 3+) reduction | |
| Akpomie et al. | Biosorption and regeneration potentials of magnetite nanoparticle loaded Solanum tuberosum peel for celestine blue dye | |
| Mahajan et al. | Modified agricultural waste biomass with enhanced responsive properties for metal-ion remediation: a green approach | |
| Liu et al. | Adsorption characteristics and removal mechanism of malathion in water by high and low temperature calcium–modified water hyacinth–based biochar | |
| Vinodhini et al. | Biowaste materials as sorbents to remove chromium (VI) from aqueous environment-a comparative study | |
| Sousa et al. | Multivariable optimization of activated carbon production from microwave pyrolysis of brewery wastes-Application in the removal of antibiotics from water | |
| Nadeem et al. | Pb (II) sorption by acidically modified Cicer arientinum biomass | |
| Kamsonlian et al. | Biosorption of arsenic from contaminated water onto solid Psidium guajava leaf surface: equilibrium, kinetics, thermodynamics, and desorption study | |
| Lekić et al. | Arsenic Removal from Water Using Industrial By‐Products | |
| Moradi et al. | A comparative study of nitrate removal from aqueous solutions using zeolite, nZVI-zeolite, nZVI and iron powder adsorbents. | |
| Al-Badaani et al. | Low-cost biosorption of Fe (II) and Fe (III) from single and binary solutions using Ulva lactuca-derived cellulose nanocrystals-graphene oxide composite film | |
| Alali et al. | Hydroxyapatite@ Mn–Fe composite as a reusable sorbent for removal of Nile blue dye and Cr (VI) from polluted water | |
| CN106242013B (en) | Method for treating heavy metal ion-containing wastewater by mixing natural pyrrhotite and zero-valent iron | |
| Sharma et al. | Removal of divalent nickel from aqueous solutions using Carissa carandas and Syzygium aromaticum: isothermal studies and kinetic modelling | |
| Salihi et al. | Zinc removal from aqueous solution using novel adsorbent MISCBA | |
| Dong et al. | Performance of biochar derived from rice straw for removal of Ni (II) in batch experiments |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151223 |
|
| RJ01 | Rejection of invention patent application after publication |