CN1063814C - 一种施胶增效剂的制造方法 - Google Patents
一种施胶增效剂的制造方法 Download PDFInfo
- Publication number
- CN1063814C CN1063814C CN97114314A CN97114314A CN1063814C CN 1063814 C CN1063814 C CN 1063814C CN 97114314 A CN97114314 A CN 97114314A CN 97114314 A CN97114314 A CN 97114314A CN 1063814 C CN1063814 C CN 1063814C
- Authority
- CN
- China
- Prior art keywords
- sizing
- synergist
- preparation
- acrylic
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000178 monomer Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 6
- DQYBDCGIPTYXML-UHFFFAOYSA-N ethoxyethane;hydrate Chemical compound O.CCOCC DQYBDCGIPTYXML-UHFFFAOYSA-N 0.000 claims abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- -1 acrylic ester Chemical class 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 229940043237 diethanolamine Drugs 0.000 claims description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract description 10
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract description 10
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract description 10
- 150000001768 cations Chemical class 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 150000002978 peroxides Chemical class 0.000 abstract description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003292 glue Substances 0.000 description 9
- 239000000123 paper Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Abstract
本发明是造纸施胶增效剂的制造方法。
近年以来，造纸施胶剂向阳离子分散松香施胶发展，即分散松香以一定的比例与阳离子分散剂混合施胶，本发明提供一种合成水溶性高分子施胶增效剂的制造方法，该方法是用烯类单体与丙烯酸共聚合，过氧化物为引发剂，在水或乙二醇乙醚，介质中聚合而成。该方法制备的施胶增效剂经使用效果良好，可使施胶效果提高2～3倍，产品成本有所降低。
Description
本发明是一种造纸施胶剂的制造方法。
施胶是使纸板获得抗水性能施胶剂的加工工序，施胶剂，通常有皂化松香胶，硬脂酸胶，石蜡胶，石腊松香胶，沥青胶，石油树脂胶等，还有合成胶料如烷基烯酮二聚体等，在上述胶料中以松香胶料用量最大，施胶效果以分散松香胶为最好。由于纸张用量大，对施胶剂的需求也大，由于松香资源有限，使得近年来松香价格不断上涨，近一段时期，国外已合成出一些新型施胶剂，合成施胶剂的共同特点是施胶效果好，但价格较高，只适合于特种纸施胶。近年来施胶剂有向阳离子型分散松香施胶发展的趋势，即将分散松香以一定的比例与阳离子分散剂混合进或将松香阳离子化进行施胶取得了良好的效果。
本发明的目的是提供一种由丙烯酸与烯类单体共聚合成一种水溶性高分子聚合物的制造方法。
本发明是通过如下的步骤实现的：丙烯酸类0.2～0.5mol，丙烯酸酯类0.1～0.4mol，苯乙烯0.2～0.6mol，采用过氧化物为引发剂，其用量为总量的1％～5％，在水，乙二醇甲醚或乙醚介质中于60-90℃温度下反应2-6小时，然后加入胺类中和至pH=8-10，最后加水调至固含量为20％，所得产物具有如下的物理指标：
外观 透明
颜色 淡黄
相对密度 1.12
粘度 100-200mPa.s
固含量 20％
pH值 8-10上述的丙烯酸类可以是甲基丙烯酸，丙烯酸酯类可以是丙烯酸甲酯、乙酯、丁酯等，加入的胺类可以是二乙醇胺、三乙醇胺，以及三甲胺等。
本发明所提供的施胶增效剂与松香施胶剂配合使用在同样条件和同样用量的情况下，其施胶效果可以提高2-3倍，加入增效剂的施胶剂比普通施胶剂的成本增加不多，因为浓度为20％的增效剂的成本比含量为50％的分散松香只稍微高一些，但是由于增效剂的协同作用使施胶剂减少了用量，所以总的来说降低了施胶成本，本发明所提供的增效剂能实现中性抄纸。
实施例一
丙烯酸0.3mol，丙烯酸甲酯0.4mol，苯乙烯0.4mol，过氧化苯甲酰3％(对单体总量)，介质：乙二醇乙醚，上述单体混合在带有搅拌的三颈瓶中在温度80℃下反应3小时，加入三乙醇胺至pH=9，充分搅拌，最后加入适量的水使产物的固含量为20％左右。
实施例二
甲基丙烯酸0.2mol，甲基丙烯酸丁酯0.25mol，苯乙烯0.5mol，过氧化苯甲酰4％(对单体总量)，介质乙二醇乙醚，上述单体混合物在有搅拌器的三颈瓶中在温度70℃下回流反应5小时，加入三乙醇胺至pH=9.5，充分搅拌，最后加入适量的水至产物固含量为20％左右。
Claims (1)
1．一种施胶增效剂的制造方法，其特征在于苯乙烯单体与丙烯酸类，丙烯酸酯类共聚，以过氧化苯甲酰为引发剂，在水或乙二醇乙醚(甲醚)介质中聚合而成，引发剂用量为单体总量的1～5％，温度60～90℃，时间2～6小时，加入胺类中和至pH=8～10，得到含固量为20％的产品，其中，丙烯酸类为丙烯酸或甲基丙烯酸，丙烯酸酯类为丙烯酸甲酯，丙烯酸乙酯，或丙烯酸丁酯，胺类为二乙醇胺，三乙醇胺或三甲胺。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97114314A CN1063814C (zh) | 1997-12-03 | 1997-12-03 | 一种施胶增效剂的制造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97114314A CN1063814C (zh) | 1997-12-03 | 1997-12-03 | 一种施胶增效剂的制造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1184185A CN1184185A (zh) | 1998-06-10 |
| CN1063814C true CN1063814C (zh) | 2001-03-28 |
Family
ID=5172874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97114314A Expired - Fee Related CN1063814C (zh) | 1997-12-03 | 1997-12-03 | 一种施胶增效剂的制造方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1063814C (zh) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116361C (zh) * | 2000-08-08 | 2003-07-30 | 杭州化工研究所职工技术协会 | 一种低泡、高效的分散松香胶 |
| CN1295014C (zh) * | 2005-05-23 | 2007-01-17 | 山东轻工业学院 | 一种阳离子分散松香胶 |
| CN101125977B (zh) * | 2006-08-15 | 2011-04-13 | 东莞市英科水墨有限公司 | 一种水性柔版印刷油墨及其制备方法 |
| CN106638140A (zh) * | 2016-12-10 | 2017-05-10 | 钦州学院 | 一种施胶剂及其制备方法 |
| JP6676222B2 (ja) * | 2017-08-18 | 2020-04-08 | 松本油脂製薬株式会社 | 強化繊維用集束剤及びその利用 |
| CN108411651B (zh) * | 2018-03-20 | 2020-09-11 | 惠州长联新材料科技有限公司 | 一种烫金用浆料及其制备方法和用途 |
| CN109594415A (zh) * | 2018-12-28 | 2019-04-09 | 营口理工学院 | 一种新型阳离子无皂淀粉基苯丙-松香乳液及制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109489A (zh) * | 1994-03-30 | 1995-10-04 | 近代化学工业株式会社 | 施胶剂用的分散剂以及水乳胶施胶剂的制备方法 |
-
1997
- 1997-12-03 CN CN97114314A patent/CN1063814C/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109489A (zh) * | 1994-03-30 | 1995-10-04 | 近代化学工业株式会社 | 施胶剂用的分散剂以及水乳胶施胶剂的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1184185A (zh) | 1998-06-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1137165C (zh) | 含咪唑基的支化聚合物及其生产方法和用途 | |
| CN102219873B (zh) | 三烯丙基异氰脲酸酯改性水性羟基丙烯酸树脂及其制备方法 | |
| EP2231580A1 (en) | Triglyceride macromonomers | |
| FI120695B (fi) | Luonnonrasvahappopohjaista akrylaattihybridihartsia sisältävät komposiitit | |
| CN102838953A (zh) | 一种纸上珠光粉用水性丙烯酸酯乳液连接料及其制备方法 | |
| CN102226051B (zh) | 一种用于水性木器涂装的格丽斯擦色剂及其制备方法 | |
| WO2007101909A1 (en) | Acrylate hybride polymer based on natural fatty acids and method for the manufacture thereof | |
| CN107313292A (zh) | 一种包装纸用表面施胶剂及其制备方法 | |
| CN1063814C (zh) | 一种施胶增效剂的制造方法 | |
| CN107513124B (zh) | 一种聚酯丙烯酸酯水分散体及其制备方法 | |
| EP2643360A1 (en) | Finely divided, cationic or amphoteric, aqueous polymer dispersions, process for their preparation, their use, cationic or amphoteric protective colloids and their preparation | |
| CN101173030B (zh) | 一种超高固含量羟基丙烯酸树脂的制备方法 | |
| CN102230301B (zh) | 阳离子苯丙类表面施胶剂的制备方法 | |
| JP3689131B2 (ja) | 不粘着性、耐引掻性で且つ耐薬品性の塗料のためのバインダーとしてのポリマー水性分散物 | |
| CN103232566A (zh) | 密封胶用高固含量低粘度丙烯酸酯乳液的制备方法 | |
| KR20040054658A (ko) | 압력 민감성 접착제의 수-백화현상 저항성 개선방법 | |
| CN111087548B (zh) | 一种高光快干高固低粘丙烯酸酯乳液及其制备方法 | |
| CN108794703B (zh) | 一种具有优良耐盐雾功能的聚丙烯酸酯防腐乳液的制备方法 | |
| US5902846A (en) | High-performance overprint varnishes comprising composite SMA latices | |
| JP4756444B2 (ja) | 粘着付与樹脂エマルジョン、接着剤組成物および床材用接着剤組成物 | |
| CN110105500A (zh) | 一种超疏水纸张表面处理剂的制备方法 | |
| EP2072544A1 (en) | Triglyceride macromonomers | |
| CN111944100B (zh) | 一种水性丙烯酸树脂制备方法 | |
| CN1458176A (zh) | 乙烯三元共聚物蜡及其制备和用途 | |
| CN1062745A (zh) | 水基磁性清漆及制法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |