CN106380878A - Wear-resistant wood-plastic profile and preparation method thereof - Google Patents
Wear-resistant wood-plastic profile and preparation method thereof Download PDFInfo
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- CN106380878A CN106380878A CN201610754187.3A CN201610754187A CN106380878A CN 106380878 A CN106380878 A CN 106380878A CN 201610754187 A CN201610754187 A CN 201610754187A CN 106380878 A CN106380878 A CN 106380878A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention belongs to the technical field of building materials and especially relates to a wear-resistant wood-plastic profile and a preparation method thereof. The wear-resistant wood-plastic profile is prepared from the following raw materials (by weight): 20-60 parts of walnut shell flour, 10-26 parts of peanut shell powder, 20-40 parts of polyethylene, 5-12 parts of glyceryl triacetate, 5-10 parts of silicone powder, 3-8 parts of polytetrafluoroethylene powder, 4-9 parts of di-n-butyl phosphate, 3-7 parts of cyclohexane dicarboxylate, 3-8 parts of diethylene glycol dibenzoate, 2-7 parts of tetramethyl divinyl disiloxane, 1-5 parts of vinyl trichlorosilane, 2-8 parts of 1,3-dimethyl-6-semicarbazide pyrimidine, 3-8 parts of alkyl glycoside, 1-5 parts of 1-vinyl imidazole and 1-6 parts of dialkyl diphenylamine. The invention also provides a preparation method of the wear-resistant wood-plastic profile. The wear-resistant wood-plastic profile has characteristics of aesthetic property, high wear resistance, waterproofness and skid resistance, durability and corrosion resistance, no release of formaldehyde and the like. In addition, the preparation technology is simple.
Description
Technical field
The invention belongs to building materials technology field, particularly to a kind of wear-resisting Wood-plastic profiles and preparation method thereof.
Background technology
Wood-plastic material, typically with raw materials such as timber rim charge, straws, then by adding the plastics such as PVC, PP, PE, squeezes
Go out, shape obtained by ornament materials.The timber processing modes such as it is suitable for boring, plane, nail, saw, laminating are it is achieved that " wood moulding generation
Wood ", protects the limited forest reserves, decreases " white pollution ", be state key promotion project.
Wood-plastic material can apply to the fields such as packaging, gardens, transport, building, car and boat interior trim.Contain due in Wood-plastic material
There are a certain amount of plastic raw materials, this just determines Wood-plastic material and has certain elasticity in itself, and due to wood-fibred and plastics
Fully integrate, therefore it has the resistance to compression suitable with hardwood, the mechanical performance such as counter-bending, its anti-strong basicity, water-fast, corrosion resistance
Can be also that general timber is incomparable, and be not in bacterial reproduction phenomenon, be difficult to be damaged by worms.
But, due to employing macromolecule polymer material in Wood-plastic material as raw material, therefore its abrasion resistance properties meeting
It is inferior to common timber, particularly cannot be compared with hard wood.Additionally, in order that Wood-plastic material is more both artistic and practical, generally
Polished in its surface and to be embossed, polishing is made Wood-plastic material form rough style, and embossing then increases its non-skid property, but
It is because the anti-wear performance of Wood-plastic material is not good, so the decorative pattern of embossing can be worn away through the long-time stream of people, therefore most of wood
Mould and be only used for the place not to skid resistance and cosmetic requirements.For the process typically to be painted of indoor Wood-plastic floor, only
The relatively low family place of flow of the people can be used for, and paint the wood moulding base plate after process and there is formaldehyde, and then direct shadow
Ring the use to consumer.Therefore studying a kind of preferable Wood-plastic profiles of wearability becomes extremely important.
Content of the invention
The technical problem to be solved is to provide wear-resisting Wood-plastic profiles, and it has aesthetic property, high-wearing feature, waterproof
The features such as skid resistance, durable rotproofness, formaldehydeless release, and preparation process is simple.
For achieving the above object, the present invention adopts the following technical scheme that：
The present invention provides wear-resisting Wood-plastic profiles, is made up of the raw material of following weight portion:20～60 parts of walnut shell powder, peanut shell
10～26 parts of powder, 20～40 parts of polyethylene, 5～12 parts of triacetyl glycerine, 5～10 parts of silicone powder, polytetrafluoroethylene powder 3～8
Part, 4～9 parts of di-n-butyl phosphite, 3～7 parts of cyclohexanedicarboxyester ester, 3～8 parts of diethylene glycol dibenzoate, tetramethyl two
2～7 parts of vinyl disiloxane, 1～5 part of vinyl trichlorosilane, 1,3- 2～8 parts of dimethyl -6- semicarbazides pyrimidine, alkyl
3～8 parts of glucosides, 1～5 part of 1- vinyl imidazole, 1～6 part of dialkyl diphenylamine.
Preferably, wear-resisting Wood-plastic profiles of the present invention, are made up of the raw material of following weight portion:40 parts of walnut shell powder,
18 parts of peanut shell powder, 30 parts of polyethylene, 8 parts of triacetyl glycerine, 8 parts of silicone powder, 5 parts of polytetrafluoroethylene powder, phosphorous acid two is just
6 parts of butyl ester, 5 parts of cyclohexanedicarboxyester ester, 5 parts of diethylene glycol dibenzoate, 5 parts of tetramethyl divinyl disiloxane, ethene
3 parts of base trichlorosilane, 1,3- 5 parts of dimethyl -6- semicarbazides pyrimidine, 5 parts of APG, 3 parts of 1- vinyl imidazole, dialkyl group two
3 parts of aniline.
Preferably, the particle diameter of walnut shell powder of the present invention is 120～160 mesh.Walnut shell powder under this particle size range,
The stretching of Wood-plastic profiles is slight and impact strength reaches maximum, and mechanical property is best.
Preferably, the particle diameter of peanut shell powder of the present invention is 100～140 mesh.Peanut shell powder under this particle size range,
The Wood-plastic profiles of Wood-plastic profiles have best wearability and bending strength, and mechanical property is best.
The present invention also provides the preparation method of wear-resisting Wood-plastic profiles, including following preparation process：By walnut shell powder and peanut
Shell powder puts into the machine that is mixed, and heats 3～8min, sequentially add APG, 1,3- dimethyl -6- semicarbazides at 80～95 DEG C
Pyrimidine, di-n-butyl phosphite, dialkyl diphenylamine and 1- vinyl imidazole, under 100～110rpm rotating speed, mixing 10～
20min, then rise high-temperature to 120～150 DEG C, continue to put into triacetyl glycerine, cyclohexanedicarboxyester ester and tetramethyl diethyl
Thiazolinyl disiloxane, under 120～140rpm rotating speed, mixes 15～25min, continues to rise high-temperature to 175～195 DEG C, finally
Add diethylene glycol dibenzoate, silicone powder, polytetrafluoroethylene powder, vinyl trichlorosilane and polyethylene, in 150～190rpm
Under rotating speed, mix 20～40min, be cooled to normal temperature, extruded by double screw extruder melt blending, shaping, obtain final product resistance to ground wood
Plastic section bar.
Preferably, in preparation method of the present invention, before being cooled to normal temperature, being dried at 70～90 DEG C to water content is 1%
～3%.
The beneficial effects of the present invention is：
1st, the Wood-plastic profiles of the present invention have higher wearability, do not reduce material itself while improving wearability
Intensity, has very excellent mechanical performance, 10～12 times of the suitable solid wood of its durable performance or composite wooden profile；Wood plastic sectional
The erosion of various corrosive deposits of damaging by worms, be not afraid of is not afraid of by material, and its weathering rotproofness is very outstanding；And Wood-plastic profiles, it is unlikely to deform,
Durable in use, there is water-proof skid-proof.
2nd, the raw material of the present invention improves string and Compatibility in Plastics, generates inierpeneirating network structure (IPN), reduces
The polarity of string, significantly reduces water absorption rate, has good resistance to water, extends service life.
3rd, the raw material of the present invention has larger elasticity and plasticity, can absorb one by viscoelastic effect in friction process
Divide frictional work, energy is discharged when deformation recovers again, thus improving the wearability of Wood-plastic profiles, Wood-plastic profiles tool simultaneously
There are higher intensity and toughness.
4th, the Wood-plastic profiles of the present invention also have preferable boat oxidation and anti-light capacity of decomposition, improve the anti-old of Wood-plastic profiles
Performance, has good heat endurance, keeps intensity and the color fastness of product, improves aesthetic property.
5th, the raw material of the present invention does not contain the features such as formaldehyde, Environmental Safety, formaldehydeless release.
6th, the preparation process is simple of the present invention, shortens manufacturing cycle, increases economic efficiency.
Specific embodiment
The invention will be further described with reference to embodiments, but the invention is not limited in these embodiments.
Embodiment 1
Wear-resisting Wood-plastic profiles, are made up of the raw material of following weight portion:60 parts of walnut shell powder (particle diameter is 120 mesh), peanut shell
26 parts of powder (particle diameter is 100 mesh), 20 parts of polyethylene, 12 parts of triacetyl glycerine, 5 parts of silicone powder, 8 parts of polytetrafluoroethylene powder, sub-
4 parts of phosphoric acid di-n-butyl, 7 parts of cyclohexanedicarboxyester ester, 3 parts of diethylene glycol dibenzoate, tetramethyl divinyl disiloxane 7
Part, 1 part of vinyl trichlorosilane, 1,3- 2 parts of dimethyl -6- semicarbazides pyrimidine, 8 parts of APG, 1 part of 1- vinyl imidazole,
1 part of dialkyl diphenylamine.
The preparation method of wear-resisting Wood-plastic profiles, including following preparation process：Walnut shell powder and peanut shell powder are put into and is mixed
Machine, heats 8min at 80 DEG C, sequentially adds APG, 1,3- dimethyl -6- semicarbazides pyrimidine, the positive fourth of phosphorous acid two
Ester, dialkyl diphenylamine and 1- vinyl imidazole, under 100rpm rotating speed, mix 20min, then rise high-temperature to 120 DEG C, continue
Put into triacetyl glycerine, cyclohexanedicarboxyester ester and tetramethyl divinyl disiloxane, under 140rpm rotating speed, mixing
15min, continues to rise high-temperature to 195 DEG C, is eventually adding diethylene glycol dibenzoate, silicone powder, polytetrafluoroethylene powder, vinyl
Trichlorosilane and polyethylene, under 150rpm rotating speed, mix 40min, and being dried at 70 DEG C to water content is 3%, is often cooled to
Temperature, is extruded by double screw extruder melt blending, shaping, obtains final product wear-resisting Wood-plastic profiles.
Embodiment 2
Wear-resisting Wood-plastic profiles, are made up of the raw material of following weight portion:50 parts of walnut shell powder (particle diameter is 130 mesh), peanut shell
22 parts of powder (particle diameter is 110 mesh), 25 parts of polyethylene, 10 parts of triacetyl glycerine, 6 parts of silicone powder, 7 parts of polytetrafluoroethylene powder, sub-
5 parts of phosphoric acid di-n-butyl, 6 parts of cyclohexanedicarboxyester ester, 4 parts of diethylene glycol dibenzoate, tetramethyl divinyl disiloxane 6
Part, 2 parts of vinyl trichlorosilane, 1,3- 3 parts of dimethyl -6- semicarbazides pyrimidine, 6 parts of APG, 2 parts of 1- vinyl imidazole,
2 parts of dialkyl diphenylamine.
The preparation method of wear-resisting Wood-plastic profiles, including following preparation process：Walnut shell powder and peanut shell powder are put into and is mixed
Machine, heats 5min at 85 DEG C, sequentially adds APG, 1,3- dimethyl -6- semicarbazides pyrimidine, the positive fourth of phosphorous acid two
Ester, dialkyl diphenylamine and 1- vinyl imidazole, under 105rpm rotating speed, mix 18min, then rise high-temperature to 130 DEG C, continue
Put into triacetyl glycerine, cyclohexanedicarboxyester ester and tetramethyl divinyl disiloxane, under 135rpm rotating speed, mixing
18min, continues to rise high-temperature to 190 DEG C, is eventually adding diethylene glycol dibenzoate, silicone powder, polytetrafluoroethylene powder, vinyl
Trichlorosilane and polyethylene, under 160rpm rotating speed, mix 35min, and being dried at 75 DEG C to water content is 2%, is often cooled to
Temperature, is extruded by double screw extruder melt blending, shaping, obtains final product wear-resisting Wood-plastic profiles.
Embodiment 3
Wear-resisting Wood-plastic profiles, are made up of the raw material of following weight portion:40 parts of walnut shell powder (particle diameter is 140 mesh), peanut shell
18 parts of powder (particle diameter is 120 mesh), 30 parts of polyethylene, 8 parts of triacetyl glycerine, 8 parts of silicone powder, 5 parts of polytetrafluoroethylene powder, phosphorous
6 parts of sour di-n-butyl, 5 parts of cyclohexanedicarboxyester ester, 5 parts of diethylene glycol dibenzoate, tetramethyl divinyl disiloxane 5
Part, 3 parts of vinyl trichlorosilane, 1,3- 5 parts of dimethyl -6- semicarbazides pyrimidine, 5 parts of APG, 3 parts of 1- vinyl imidazole,
3 parts of dialkyl diphenylamine.
The preparation method of wear-resisting Wood-plastic profiles, including following preparation process：Walnut shell powder and peanut shell powder are put into and is mixed
Machine, heats 6min at 90 DEG C, sequentially adds APG, 1,3- dimethyl -6- semicarbazides pyrimidine, the positive fourth of phosphorous acid two
Ester, dialkyl diphenylamine and 1- vinyl imidazole, under 110rpm rotating speed, mix 15min, then rise high-temperature to 135 DEG C, continue
Put into triacetyl glycerine, cyclohexanedicarboxyester ester and tetramethyl divinyl disiloxane, under 130rpm rotating speed, mixing
20min, continues to rise high-temperature to 185 DEG C, is eventually adding diethylene glycol dibenzoate, silicone powder, polytetrafluoroethylene powder, vinyl
Trichlorosilane and polyethylene, under 170rpm rotating speed, mix 30min, and being dried at 80 DEG C to water content is 3%, is often cooled to
Temperature, is extruded by double screw extruder melt blending, shaping, obtains final product wear-resisting Wood-plastic profiles.
Embodiment 4
Wear-resisting Wood-plastic profiles, are made up of the raw material of following weight portion:30 parts of walnut shell powder (particle diameter is 150 mesh), peanut shell
14 parts of powder (particle diameter is 130 mesh), 35 parts of polyethylene, 7 parts of triacetyl glycerine, 8 parts of silicone powder, 4 parts of polytetrafluoroethylene powder, phosphorous
7 parts of sour di-n-butyl, 4 parts of cyclohexanedicarboxyester ester, 7 parts of diethylene glycol dibenzoate, tetramethyl divinyl disiloxane 3
Part, 4 parts of vinyl trichlorosilane, 1,3- 7 parts of dimethyl -6- semicarbazides pyrimidine, 4 parts of APG, 4 parts of 1- vinyl imidazole,
5 parts of dialkyl diphenylamine.
The preparation method of wear-resisting Wood-plastic profiles, including following preparation process：Walnut shell powder and peanut shell powder are put into and is mixed
Machine, heats 4min at 95 DEG C, sequentially adds APG, 1,3- dimethyl -6- semicarbazides pyrimidine, the positive fourth of phosphorous acid two
Ester, dialkyl diphenylamine and 1- vinyl imidazole, under 100rpm rotating speed, mix 12min, then rise high-temperature to 140 DEG C, continue
Put into triacetyl glycerine, cyclohexanedicarboxyester ester and tetramethyl divinyl disiloxane, under 125rpm rotating speed, mixing
22min, continues to rise high-temperature to 180 DEG C, is eventually adding diethylene glycol dibenzoate, silicone powder, polytetrafluoroethylene powder, vinyl
Trichlorosilane and polyethylene, under 180rpm rotating speed, mix 25min, and being dried at 85 DEG C to water content is 1%, is often cooled to
Temperature, is extruded by double screw extruder melt blending, shaping, obtains final product wear-resisting Wood-plastic profiles.
Embodiment 5
Wear-resisting Wood-plastic profiles, are made up of the raw material of following weight portion:20 parts of walnut shell powder (particle diameter is 160 mesh), peanut shell
10 parts of powder (particle diameter is 140 mesh), 40 parts of polyethylene, 5 parts of triacetyl glycerine, 10 parts of silicone powder, 3 parts of polytetrafluoroethylene powder, sub-
9 parts of phosphoric acid di-n-butyl, 3 parts of cyclohexanedicarboxyester ester, 8 parts of diethylene glycol dibenzoate, tetramethyl divinyl disiloxane 2
Part, 5 parts of vinyl trichlorosilane, 1,3- 8 parts of dimethyl -6- semicarbazides pyrimidine, 3 parts of APG, 5 parts of 1- vinyl imidazole,
6 parts of dialkyl diphenylamine.
The preparation method of wear-resisting Wood-plastic profiles, including following preparation process：Walnut shell powder and peanut shell powder are put into and is mixed
Machine, heats 3min at 85 DEG C, sequentially adds APG, 1,3- dimethyl -6- semicarbazides pyrimidine, the positive fourth of phosphorous acid two
Ester, dialkyl diphenylamine and 1- vinyl imidazole, under 105rpm rotating speed, mix 10min, then rise high-temperature to 150 DEG C, continue
Put into triacetyl glycerine, cyclohexanedicarboxyester ester and tetramethyl divinyl disiloxane, under 120rpm rotating speed, mixing
25min, continues to rise high-temperature to 175 DEG C, is eventually adding diethylene glycol dibenzoate, silicone powder, polytetrafluoroethylene powder, vinyl
Trichlorosilane and polyethylene, under 190rpm rotating speed, mix 20min, and being dried at 90 DEG C to water content is 2%, is often cooled to
Temperature, is extruded by double screw extruder melt blending, shaping, obtains final product wear-resisting Wood-plastic profiles.
Test example
Using GB/T24508-2009 method of testing to above-described embodiment 1, embodiment 3 and the wood moulding prepared by embodiment 5
Section bar carries out quantitative measurement, and result is expressed as below：
Claims (6)
1. wear-resisting Wood-plastic profiles are it is characterised in that be made up of the raw material of following weight portion:20～60 parts of walnut shell powder, peanut shell
10～26 parts of powder, 20～40 parts of polyethylene, 5～12 parts of triacetyl glycerine, 5～10 parts of silicone powder, polytetrafluoroethylene powder 3～8
Part, 4～9 parts of di-n-butyl phosphite, 3～7 parts of cyclohexanedicarboxyester ester, 3～8 parts of diethylene glycol dibenzoate, tetramethyl two
2～7 parts of vinyl disiloxane, 1～5 part of vinyl trichlorosilane, 1,3- 2～8 parts of dimethyl -6- semicarbazides pyrimidine, alkyl
3～8 parts of glucosides, 1～5 part of 1- vinyl imidazole, 1～6 part of dialkyl diphenylamine.
2. wear-resisting Wood-plastic profiles according to claim 1 are it is characterised in that be made up of the raw material of following weight portion:Walnut
40 parts of shell powder, 18 parts of peanut shell powder, 30 parts of polyethylene, 8 parts of triacetyl glycerine, 8 parts of silicone powder, 5 parts of polytetrafluoroethylene powder, sub-
6 parts of phosphoric acid di-n-butyl, 5 parts of cyclohexanedicarboxyester ester, 5 parts of diethylene glycol dibenzoate, tetramethyl divinyl disiloxane 5
Part, 3 parts of vinyl trichlorosilane, 1,3- 5 parts of dimethyl -6- semicarbazides pyrimidine, 5 parts of APG, 3 parts of 1- vinyl imidazole,
3 parts of dialkyl diphenylamine.
3. wear-resisting Wood-plastic profiles according to claim 1 and 2 it is characterised in that：The particle diameter of described walnut shell powder be 120～
160 mesh.
4. wear-resisting Wood-plastic profiles according to claim 1 and 2 it is characterised in that：The particle diameter of described peanut shell powder be 100～
140 mesh.
5. the preparation method of wear-resisting Wood-plastic profiles according to claim 4 is it is characterised in that include following preparation process：
Walnut shell powder and peanut shell powder are put into the machine that is mixed, at 80～95 DEG C, heat 3～8min, sequentially add APG, 1,
3- dimethyl -6- semicarbazides pyrimidine, di-n-butyl phosphite, dialkyl diphenylamine and 1- vinyl imidazole, in 100～110rpm
Under rotating speed, mix 10～20min, then rise high-temperature to 120～150 DEG C, continue to put into triacetyl glycerine, cyclohexane dicarboxylic acid
Ester and tetramethyl divinyl disiloxane, under 120～140rpm rotating speed, mix 15～25min, continue to rise high-temperature extremely
175～195 DEG C, it is eventually adding diethylene glycol dibenzoate, silicone powder, polytetrafluoroethylene powder, vinyl trichlorosilane and poly- second
Alkene, under 150～190rpm rotating speed, is mixed 20～40min, is cooled to normal temperature, is extruded by double screw extruder melt blending,
Shaping, obtains final product wear-resisting Wood-plastic profiles.
6. wear-resisting Wood-plastic profiles according to claim 5 preparation method it is characterised in that：Before being cooled to normal temperature,
Being dried at 70～90 DEG C to water content is 1%～3%.
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| WO2021025775A1 (en) * | 2019-08-07 | 2021-02-11 | Dow Silicones Corporation | Alkenyl-functional polydiorganosiloxane compositions and methods for use thereof in forming wood plastic composites |
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| CN112654679A (en) * | 2019-08-07 | 2021-04-13 | 美国陶氏有机硅公司 | Alkenyl-functionalized polydiorganosiloxane compositions and methods of use thereof in forming wood-plastic composites |
| CN112513169B (en) * | 2019-08-07 | 2021-06-22 | 美国陶氏有机硅公司 | Solid carrier component comprising liquid polydiorganosiloxane and methods of making and using the solid carrier component |
| US11312861B2 (en) | 2019-08-07 | 2022-04-26 | Dow Silicones Corporation | Solid carrier component including a liquid polyorganosiloxane and methods for preparation and use of the solid carrier component |
| US11312862B2 (en) | 2019-08-07 | 2022-04-26 | Dow Silicones Corporation | Solid carrier component including a liquid polydiorganosiloxane and methods for preparation and use of the solid carrier component |
| US11377561B2 (en) | 2019-08-07 | 2022-07-05 | Dow Silicones Corporation | Alkenyl-functional polydiorganosiloxane compositions and methods for use thereof in forming wood plastic composites |
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