CN106380761A - Impact-resistant waterproof film and preparation method thereof - Google Patents
Impact-resistant waterproof film and preparation method thereof Download PDFInfo
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- CN106380761A CN106380761A CN201610779670.7A CN201610779670A CN106380761A CN 106380761 A CN106380761 A CN 106380761A CN 201610779670 A CN201610779670 A CN 201610779670A CN 106380761 A CN106380761 A CN 106380761A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses an impact-resistant waterproof film. The impact-resistant waterproof film comprises the following raw materials in parts by weight: 0.1-0.2 parts of azodiisobutyronitrile, 1-2 parts of fatty acid diethanol amide, 100-130 parts of polytetrafluoroethylene, 4-5 parts of pentaerythritol, 2-3 parts of polyvinyl butyral, 0.5-1 part of nickel aminosulfonate, 0.8-1 part of dodecafluoroheptyl-propyl-trimethoxylsilane, 6-10 parts of acrylamide, 1-2 parts of potassium tetraborate, 10-12 parts of diatomite, 2-3 parts of allylthiourea, 2-3 parts of methanamide, 3-4.8 parts of magnesium stearate, 0.6-1 part of 8-hydroxyquinoline, 0.1-0.2 parts of zinc naphthenate, and 5-7 parts of dibutyl maleate. The diatomite is subjected to methanamide processing, dodecafluoroheptyl-propyl-trimethoxylsilane is used for modification, surface hydrophobicity of the finished product is effectively increased, the film of the present invention has high waterproof impact-resistant intensity, good toughness, and long usage life.
Description
Technical field
The present invention relates to waterproofing membrane technical field, more particularly, to a kind of shock resistance waterproofing membrane and preparation method thereof.
Background technology
The anti-thin film of politef is a kind of synthetic macromolecule employing all hydrogen atoms in fluorine replacement polyethylene
Material.This material has the characteristics that antiacid alkali resistant, resists various organic solvents, is practically insoluble in all of solvent.Meanwhile, waterproof
Ventilated membrane has resistant to elevated temperatures feature, and its coefficient of friction is extremely low, so after lubrication being made, also become easy clean pot and
The preferable coating of water pipe internal layer;
Waterproof ventilated membrane is in a lot of sector applications widely:Modern society's automotive operation is universal, can meet in transportation
To different weather and road conditions.Car light is externally exposed in environment all the time, and cloud, sleet, mince in road surface and dirt all can affect
The illumination of car light, thus affect the degree of safety of the traveling process of vehicle.The rapid drawdown of external temperature can lead to the decline of internal pressure,
So that equipment is easily sucked pollutant and increase fogging, ultimately cause car light fault.Waterproof ventilated membrane can provide persistently to car light
Protection, from the intrusion of external moisture, dust, greasy dirt and other dirts.The unique airing function of product is with pressure simultaneously
Change carries out respiratory exchange, thus reducing the pressure on sealing member, extends the service life of product.In terms of sensor device:
Waterproof and breathable product can effectively resist adverse effect produced by the pressure reduction that temperature change leads to.Can be using waterproof ventilated membrane
Rapid equalisation housing external and internal pressure when ambient temperature and pressure change, in gas sensor and electrochemical sensor, waterproof is saturating
Gas product can prevent dust, dirt or liquid from invading sensing head.Meanwhile, waterproof ventilated membrane can allow gas pass through thin film immediately, from
And guarantee that sensor response speed keeps constant, prevent measurement result from mistake occurring and postpones.Communication equipment aspect out of doors:Family
After outer communication equipment is mounted with waterproof ventilated membrane product, the pressure reduction being caused due to temperature change will no longer be constituted to apparatus casing
Negative effect because waterproof and breathable product can in ambient temperature and pressure change rapid equalisation housing external and internal pressure;
But conventional waterproof ventilated membrane feature is more single, and have add the raw materials such as poisonous plasticizer, environmental protection
Property is poor, and the range of ventilated membrane is less, and some impact strengths are low, is easily damaged, and some resistances to ag(e)ing are poor, service life
Short, therefore, the waterproofing membrane of research higher performance just seems particularly necessary;.
Content of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of shock resistance waterproofing membrane and its preparation side
Method.
The present invention is achieved by the following technical solutions:
A kind of shock resistance waterproofing membrane, it is made up of the raw material of following weight parts:
Azodiisobutyronitrile 0.1-0.2, fatty diglycollic amide 1-2, politef 100-130, tetramethylolmethane 4-
5th, polyvinyl butyral resin 2-3, nickel sulfamic acid 0.5-1, ten difluoro heptyl propyl trimethoxy silicane 0.8-1, acrylamide
6-10, dipotassium tetraborate 1-2, kieselguhr 10-12, allylthiourea 2-3, Methanamide 2-3, magnesium stearate 3-4,8-hydroxyquinoline
0.6-1, zinc naphthenate 0.1-0.2, dibutyl maleate 5-7.
A kind of preparation method of described shock resistance waterproofing membrane, comprises the following steps:
(1) above-mentioned 8-hydroxyquinoline is added in the dehydrated alcohol of its weight 10-13 times, stirs, add amino
Nickel sulphonic acid, insulated and stirred 4-7 minute at 50-60 DEG C, obtain alcohol dispersion liquid;
(2) soak 1-2 hour in the hydrochloric acid solution above-mentioned kieselguhr being sent into 10-17mol/l, filter, by precipitation washing
2-3 time, mix with magnesium stearate, be added in the deionized water of compound weight 17-20 times, add above-mentioned Methanamide, in 60-
Insulated and stirred 30-40 minute at 70 DEG C, filters, and is vacuum dried 1-2 hour, will obtain amide modifications filler at being deposited in 80-90 DEG C;
(3) take above-mentioned zinc naphthenate, be added in tetramethylolmethane, stir, mix with above-mentioned alcohol dispersion liquid, add even
Nitrogen bis-isobutyronitrile, stirs, and obtains initiator alcohol dispersion liquid;
(4) aforesaid propylene amide is added in the deionized water of its weight 30-40 times, stirs, add fatty acid
Diglycollic amide, amide modifications filler, insulated and stirred 20-30 minute at 47-50 DEG C, obtain initiator alcohol dispersion liquid;
(5) above-mentioned initiator alcohol dispersion liquid, initiator alcohol dispersion liquid are mixed, be passed through nitrogen, liter high-temperature is 70-76
DEG C, add above-mentioned ten difluoro heptyl propyl trimethoxy silicon, insulated and stirred 2-3 hour, add nickel sulfamic acid, stir to normal
Temperature, sucking filtration, precipitate with deionized water is washed 3-4 time, is vacuum dried 30-40 minute at 80-90 DEG C, obtains fluorinated modified material;
(6) above-mentioned fluorinated modified material is mixed with remaining each raw material, stir, through film blow molding machine blow molding,
Obtain final product described thin film.
It is an advantage of the invention that:
Kieselguhr is processed by the present invention by Methanamide, then with ten difluoro heptyl propyl trimethoxy Si modification, effectively
The surface hydrophobic that improve finished product, the membrane waterproofing of the present invention is excellent in cushion effect, good toughness, long service life.
Specific embodiment
A kind of shock resistance waterproofing membrane, it is made up of the raw material of following weight parts:
Azodiisobutyronitrile 0.1, fatty diglycollic amide 1, politef 100, tetramethylolmethane 4, polyvinyl alcohol contracting
Butyraldehyde 2, nickel sulfamic acid 0.5, ten difluoro heptyl propyl trimethoxy silicanes 0.8, acrylamide 6, dipotassium tetraborate 1, kieselguhr
10th, allylthiourea 2, Methanamide 2, magnesium stearate 3,8-hydroxyquinoline 0.6, zinc naphthenate 0.1, dibutyl maleate 5.
A kind of preparation method of described shock resistance waterproofing membrane, comprises the following steps:
(1) above-mentioned 8-hydroxyquinoline is added in the dehydrated alcohol of 10 times of its weight, stirs, add sulfamic acid
Nickel, insulated and stirred 4 minutes at 50 DEG C, obtain alcohol dispersion liquid;
(2) soak 1 hour in the hydrochloric acid solution above-mentioned kieselguhr being sent into 10mol/l, filter, precipitation is washed 2 times, with
Magnesium stearate mixes, and is added in the deionized water of 17 times of compound weight, adds above-mentioned Methanamide, insulated and stirred at 60 DEG C
30 minutes, filter, will be deposited in and be vacuum dried 1 hour at 80 DEG C, and obtain amide modifications filler;
(3) take above-mentioned zinc naphthenate, be added in tetramethylolmethane, stir, mix with above-mentioned alcohol dispersion liquid, add even
Nitrogen bis-isobutyronitrile, stirs, and obtains initiator alcohol dispersion liquid;
(4) aforesaid propylene amide is added in the deionized water of 30 times of its weight, stirs, add fatty acid diethyl
Alkylolamides, amide modifications filler, insulated and stirred 20 minutes at 47 DEG C, obtain initiator alcohol dispersion liquid;
(5) above-mentioned initiator alcohol dispersion liquid, initiator alcohol dispersion liquid are mixed, be passed through nitrogen, rise high-temperature and be 70 DEG C, plus
Enter above-mentioned ten difluoro heptyl propyl trimethoxy silicon, insulated and stirred 2 hours, add nickel sulfamic acid, stir to room temperature, sucking filtration,
Precipitate with deionized water is washed 3 times, is vacuum dried 30 minutes at 80 DEG C, obtains fluorinated modified material;
(6) above-mentioned fluorinated modified material is mixed with remaining each raw material, stir, through film blow molding machine blow molding,
Obtain final product described thin film.
Performance test:
Air transmission coefficient (ml/min/1PSI):400;
Aqueous vapor conductivity (g/24h):0.2058.
Claims (2)
1. a kind of shock resistance waterproofing membrane is it is characterised in that what it was made up of the raw material of following weight parts:
Azodiisobutyronitrile 0.1-0.2, fatty diglycollic amide 1-2, politef 100-130, tetramethylolmethane 4-5, poly-
Vinyl butyral 2-3, nickel sulfamic acid 0.5-1, ten difluoro heptyl propyl trimethoxy silicane 0.8-1, acrylamide 6-10,
Dipotassium tetraborate 1-2, kieselguhr 10-12, allylthiourea 2-3, Methanamide 2-3, magnesium stearate 3-4,8-hydroxyquinoline 0.6-1,
Zinc naphthenate 0.1-0.2, dibutyl maleate 5-7.
2. a kind of preparation method of shock resistance waterproofing membrane as claimed in claim 1 is it is characterised in that comprise the following steps:
(1) above-mentioned 8-hydroxyquinoline is added in the dehydrated alcohol of its weight 10-13 times, stirs, add sulfamic acid
Nickel, insulated and stirred 4-7 minute at 50-60 DEG C, obtain alcohol dispersion liquid;
(2) soak 1-2 hour in the hydrochloric acid solution above-mentioned kieselguhr being sent into 10-17mol/l, filter, by precipitation washing 2-3
Secondary, mix with magnesium stearate, be added in the deionized water of compound weight 17-20 times, add above-mentioned Methanamide, in 60-70
Insulated and stirred 30-40 minute at DEG C, filters, and is vacuum dried 1-2 hour, will obtain amide modifications filler at being deposited in 80-90 DEG C;
(3) take above-mentioned zinc naphthenate, be added in tetramethylolmethane, stir, mix with above-mentioned alcohol dispersion liquid, add azo two
Isopropyl cyanide, stirs, and obtains initiator alcohol dispersion liquid;
(4) aforesaid propylene amide is added in the deionized water of its weight 30-40 times, stirs, add fatty acid diethyl
Alkylolamides, amide modifications filler, insulated and stirred 20-30 minute at 47-50 DEG C, obtain initiator alcohol dispersion liquid;
(5) above-mentioned initiator alcohol dispersion liquid, initiator alcohol dispersion liquid are mixed, be passed through nitrogen, rise high-temperature and be 70-76 DEG C, plus
Enter above-mentioned ten difluoro heptyl propyl trimethoxy silicon, insulated and stirred 2-3 hour, add nickel sulfamic acid, stir to room temperature, take out
Filter, precipitate with deionized water is washed 3-4 time, is vacuum dried 30-40 minute, obtains fluorinated modified material at 80-90 DEG C;
(6) above-mentioned fluorinated modified material is mixed with remaining each raw material, stir, through film blow molding machine blow molding, obtain final product
Described thin film.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107474180A (en) * | 2017-09-06 | 2017-12-15 | 张永霞 | A kind of preparation method of silicon dioxide polyester emulsion |
CN109608793A (en) * | 2018-11-30 | 2019-04-12 | 朱莲华 | A kind of graphene cross-linked polytetrafluoroethylthrough hydrophobic film and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105838004A (en) * | 2016-06-21 | 2016-08-10 | 安庆市天虹新型材料科技有限公司 | Polytetrafluoroethylene-chitosan film |
-
2016
- 2016-08-30 CN CN201610779670.7A patent/CN106380761A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105838004A (en) * | 2016-06-21 | 2016-08-10 | 安庆市天虹新型材料科技有限公司 | Polytetrafluoroethylene-chitosan film |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107474180A (en) * | 2017-09-06 | 2017-12-15 | 张永霞 | A kind of preparation method of silicon dioxide polyester emulsion |
CN109608793A (en) * | 2018-11-30 | 2019-04-12 | 朱莲华 | A kind of graphene cross-linked polytetrafluoroethylthrough hydrophobic film and preparation method thereof |
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