CN106376992A - Agricultural protective mask material - Google Patents
Agricultural protective mask material Download PDFInfo
- Publication number
- CN106376992A CN106376992A CN201610944515.6A CN201610944515A CN106376992A CN 106376992 A CN106376992 A CN 106376992A CN 201610944515 A CN201610944515 A CN 201610944515A CN 106376992 A CN106376992 A CN 106376992A
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- CN
- China
- Prior art keywords
- layer
- zirconium dioxide
- material layer
- woven fabric
- zirconium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/02—Layered materials
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
Abstract
The invention discloses an agricultural protective mask material which comprises an ultra-thin polypropylene melt-blowing material layer, a hydrophobic spun-bonded non-woven fabric layer, a fiber melt-blowing non-woven fabric composite layer, a hydrophilic spun-bonded non-woven fabric layer, a zirconium dioxide micro-spherical material layer and a carbon fiber/nano-zero-valent iron composite material layer, wherein the ultra-thin polypropylene melt-blowing material layer, the hydrophobic spun-bonded non-woven fabric layer, the zirconium dioxide micro-spherical material layer, the carbon fiber/nano-zero-valent iron composite material layer, the fiber melt-blowing non-woven fabric composite layer and the hydrophilic spun-bonded non-woven fabric layer are laminated sequentially to form the mask material. The agricultural protective mask material has absorptive filtration and pesticide degradation effects, has an isolation protection effect on pesticide application staff, and can protect people from injury when pesticide is inhaled into a mouth.
Description
Technical field
The present invention relates to agricultural safety device technical field is and in particular to a kind of agricultural protective mask material.
Background technology
Mouth mask is the articles for daily use of people, and, with the breathing of people as power, customer service filtering layer resistance purifies to particulate matter for it
Mouth mask, open market mainly has cotton cloth respirator, textile mouth mask, medical surgical respirator, electret filtrate mouth mask etc., several years
Come, the absorption in order to improve mouth mask intercepts efficiency, and people are made that many improvement, counterpart to the structure of mask material and mouth mask
The absorption property of cover requires more and more higher, the requirement more and more higher to absorption contaminant particle fineness, and people are also directed to different
With cover crowd, use cap environment, develop the mouth mask with specific function, solve mouth mask performance Single-issue.But at present, for agriculture
Research with mouth mask is little, and common mouth mask can not solve the harm that applying pesticides bring human body very well.
Content of the invention
It is an object of the invention to, for prior art, provide a kind of agricultural protective mask material, solve peasant and spray agriculture
During medicine, the pesticide solution easily enters the mouth thus problem that human body is worked the mischief.
For achieving the above object, the present invention takes technical scheme below:A kind of agricultural protective mask material, including ultra-thin poly-
Propylene melt blown material layer, water repellent spun-bonded non-woven fabrics layer, the non-woven fabric compounded layer of fiber melt-blowing and hydrophilic spun-bond nonwoven fabric layer, titanium dioxide
Zirconium micro-sphere material layer and carbon fiber/nano zero valence iron composite layer;Described mask material is by ultra-thin polypropylene melt-blown material
Layer, water repellent spun-bonded non-woven fabrics layer, zirconium dioxide micro-sphere material layer, carbon fiber/nano zero valence iron composite layer, fiber melt-blowing are no
Spin cloth composite bed, hydrophilic spun-bond nonwoven fabric layer stacks gradually and forms.
Preferably, in described zirconium dioxide micro-sphere material layer, the mass percent of zirconium dioxide microballoon is 80~90%.
Preferably, in described carbon fiber/nano zero valence iron composite layer, carbon fiber/nano zero-valence iron complexes
Mass percent is 80~99%.
In the present invention, in described zirconium dioxide micro-sphere material layer, the preparation method of zirconium dioxide microballoon is:By shitosan
Powder and zirconium oxychloride are placed in mixing in distilled water, be placed in magnetic stirring apparatus and stir to mixing liquid in thoroughly after adding glacial acetic acid
Bright shape, mixing liquid is placed in reaction in sodium hydroxide solution and generates complex microsphere, stand 10h, go excess sodium hydroxide molten
Liquid, obtains zirconium dioxide microballoon 5 times with distillation water washing microballoon, zirconium dioxide microballoon again is placed in the hydrogen drying 3h in 60 DEG C of environment
Zirconium oxide microballoons, zirconium hydroxide ball are placed in calcining 8h in 600 DEG C and obtain zirconium dioxide microballoon.
The agricultural protective mask material of the present invention has adsorption filtration and the effect of degrading pesticide, and its principle is:Peasant applies
During medicine, pesticide activity component enters mouth mask mouth with spraying, and titanium dioxide white micro-sphere material layer can absorb enrichment organophosphor
In agricultural chemicals, prevent the Pesticide Infiltrations such as organophosphor to mouth mask nexine, be detrimental to health.Titanium dioxide white micro-sphere material layer bonding carbon is fine
Dimension/nano zero valence iron composite layer, further adsorbs to the agricultural chemicals in the spraying entering titanium dioxide white microballoon layer and degrades,
The agricultural chemicals entering outside mouth mask is carried out with second adsorption and filters degraded.
Each material layer between the agricultural protective mask material of the present invention cooperates, ultra-thin polypropylene melt-blown material and refusing
Water is put bonded non-woven fabrics layer and can be reduced entrance, zirconium dioxide micro-sphere material layer and carbon fiber/nano zero valence iron with spraying for the agricultural chemicals
Composite layer is adsorbed to the mouth mask Pesticides of infiltration and is degraded, and has agricultural chemicals filtration, and fiber melt-blowing non-woven fabrics is multiple
Close layer, hydrophilic spun-bond nonwoven fabric has the effect absorbing aqueous vapor, it is to avoid the steam such as sweat, in face accumulation, improves with cover personnel's
Comfort level.
The invention has the beneficial effects as follows:The agricultural protective mask material of the present invention has the work of adsorption filtration and degrading pesticide
With isolation protective effect is played to dispenser personnel, it is to avoid agricultural chemicals enters the mouth and causes human injury.
Brief description
Fig. 1 is the structural representation of the agricultural protective mask material of the present invention.
In accompanying drawing, the mark of each material layer is as follows:
Ultra-thin polypropylene melt-blown material layer 1;
Water repellent spun-bonded non-woven fabrics layer 2;
Zirconium dioxide micro-sphere material layer 3;
Carbon fiber/nano zero valence iron composite layer 4;
The non-woven fabric compounded layer of fiber melt-blowing 5;
Hydrophilic spun-bond nonwoven fabric layer 6.
Specific embodiment
Below in conjunction with the accompanying drawings, to further instruction of the present invention.
Embodiment 1
A kind of agricultural protective mask material of the present invention is successively by ultra-thin polypropylene melt-blown material layer 1, the spunbond nonwoven of water repellent
Layer of cloth 2, zirconium dioxide micro-sphere material layer 3, carbon fiber/nano zero valence iron composite layer 4, the non-woven fabric compounded layer of fiber melt-blowing 5
It is laminated with hydrophilic spun-bond nonwoven fabric layer 6.In application, ultra-thin polypropylene melt-blown material layer 1 is ultra-thin polypropylene outside mouth mask
Meltblown layer 1 and water repellent are put bonded non-woven fabrics layer 2 and can be reduced the entrance with spraying for the agricultural chemicals, zirconium dioxide micro-sphere material layer 3 He
Carbon fiber/nano zero valence iron composite layer 4 is adsorbed to the mouth mask Pesticides of infiltration and is degraded, and has agricultural chemicals and filters work
With hydrophilic spun-bond nonwoven fabric 6 is that inside mouth mask, the non-woven fabric compounded layer of fiber melt-blowing 5, hydrophilic spun-bond nonwoven fabric 6 have absorption water
The effect of gas, it is to avoid the steam such as sweat, in face accumulation, improves the comfort level with cover personnel.
Wherein, in described zirconium dioxide micro-sphere material layer, the mass percent of zirconium dioxide microballoon is 90%.Described
In carbon fiber/nano zero valence iron composite layer, the mass percent of carbon fiber/nano zero-valence iron complexes is 99%;Described
Zirconium dioxide micro-sphere material layer in the preparation method of zirconium dioxide microballoon be:Chitosan powder and zirconium oxychloride are placed in distilled water
Middle mixing, is placed in after adding glacial acetic acid in magnetic stirring apparatus and stirs shape transparent to mixing liquid, mixing liquid is placed in hydrogen
In sodium hydroxide solution, reaction generates complex microsphere, stands 10h, removes excess sodium hydroxide solution, with distillation water washing microballoon 5 times
Obtain zirconium dioxide microballoon, zirconium dioxide microballoon again is placed in the zirconium hydroxide microballoon drying 3h in 60 DEG C of environment, by zirconium hydroxide
Ball is placed in calcining 8h in 600 DEG C and obtains zirconium dioxide microballoon.
Embodiment 2
A kind of agricultural protective mask material structure of the present invention and its preparation method of application process and zirconium dioxide microballoon
With embodiment 1.Difference with embodiment 1 is, zirconium dioxide micro-sphere material layer in the agricultural protective mask material of the present embodiment
In, the mass percent of zirconium dioxide microballoon is 80%.In described carbon fiber/nano zero valence iron composite layer, carbon fiber/
The mass percent of nano zero-valence iron complexes is 80%.
The embodiment of the present invention is that technical scheme is clearly and completely described with the reality it is clear that described
Apply a part of embodiment that example is only the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is general
All other embodiment that logical technical staff is obtained under the premise of not making creative work, broadly falls into present invention protection
Scope.
Claims (4)
1. a kind of agricultural protective mask material, including ultra-thin polypropylene melt-blown material layer, water repellent spun-bonded non-woven fabrics layer, fiber melt-blowing
Non-woven fabric compounded layer and hydrophilic spun-bond nonwoven fabric layer are it is characterised in that also include zirconium dioxide micro-sphere material layer and carbon fiber/receive
Rice zero-valent iron composite material layer;Described mask material is by ultra-thin polypropylene melt-blown material layer, water repellent spun-bonded non-woven fabrics layer, dioxy
Change zirconium micro-sphere material layer, carbon fiber/nano zero valence iron composite layer, the non-woven fabric compounded layer of fiber melt-blowing, hydrophilic spunbond nonwoven
Layer of cloth stacks gradually and forms.
2. a kind of agricultural protective mask material according to claim 1 is it is characterised in that described zirconium dioxide microballoon material
In the bed of material, the mass percent of zirconium dioxide microballoon is 80~90%.
3. a kind of agricultural protective mask material according to claim 1 is it is characterised in that described carbon fiber/nanometer zero
In valency iron composite material layer, the mass percent of carbon fiber/nano zero-valence iron complexes is 80~99%.
4. a kind of agricultural protective mask material according to claim 1 is it is characterised in that described zirconium dioxide microballoon material
In the bed of material, the preparation method of zirconium dioxide microballoon is:Chitosan powder and zirconium oxychloride are placed in mixing in distilled water, add ice
It is placed in after acetic acid in magnetic stirring apparatus and stirs shape transparent to mixing liquid, mixing liquid is placed in reaction in sodium hydroxide solution
Generate complex microsphere, stand 10h, take excess sodium hydroxide solution, obtain zirconium dioxide microballoon 5 times with distillation water washing microballoon,
Zirconium dioxide microballoon again is placed in the zirconium hydroxide microballoon drying 3h in 60 DEG C of environment, zirconium hydroxide ball is placed in 600 DEG C and forges
Burn 8h and obtain zirconium dioxide microballoon.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610944515.6A CN106376992A (en) | 2016-10-26 | 2016-10-26 | Agricultural protective mask material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610944515.6A CN106376992A (en) | 2016-10-26 | 2016-10-26 | Agricultural protective mask material |
Publications (1)
Publication Number | Publication Date |
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CN106376992A true CN106376992A (en) | 2017-02-08 |
Family
ID=57957119
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201610944515.6A Pending CN106376992A (en) | 2016-10-26 | 2016-10-26 | Agricultural protective mask material |
Country Status (1)
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CN (1) | CN106376992A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111436690A (en) * | 2020-04-22 | 2020-07-24 | 康业(江苏)医疗科技有限公司 | Protective mask |
WO2021206349A1 (en) * | 2020-04-09 | 2021-10-14 | 도레이첨단소재 주식회사 | Composite nonwoven and article comprising same |
WO2021212208A1 (en) * | 2020-04-22 | 2021-10-28 | Weining Tan | Electrically heated respirator |
TWI793815B (en) * | 2017-02-14 | 2023-02-21 | 日商優你 嬌美股份有限公司 | Face mask |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2102764U (en) * | 1991-10-17 | 1992-04-29 | 中国人民解放军济南军区后勤部军事医学研究所 | Pesticide gas protection gauze mask |
CN201085071Y (en) * | 2007-08-06 | 2008-07-16 | 李江波 | Ultraviolet preventing breathing mask |
CN102029734A (en) * | 2010-09-30 | 2011-04-27 | 吴江市元通纺织品有限公司 | Multifunctional compound nonwoven fabric |
CN102553523A (en) * | 2011-12-15 | 2012-07-11 | 南京大学 | Nano zero-valent iron-supported activated carbon fiber, and preparation method and application thereof |
CN103084138A (en) * | 2013-01-21 | 2013-05-08 | 华中师范大学 | Application of zirconium dioxide microspheres prepared by using microchannel injection auxiliary method to adsorptive enrichment of organophosphorus pesticide |
CN105054403A (en) * | 2015-08-20 | 2015-11-18 | 江苏广达医材集团有限公司 | Medical mask |
-
2016
- 2016-10-26 CN CN201610944515.6A patent/CN106376992A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2102764U (en) * | 1991-10-17 | 1992-04-29 | 中国人民解放军济南军区后勤部军事医学研究所 | Pesticide gas protection gauze mask |
CN201085071Y (en) * | 2007-08-06 | 2008-07-16 | 李江波 | Ultraviolet preventing breathing mask |
CN102029734A (en) * | 2010-09-30 | 2011-04-27 | 吴江市元通纺织品有限公司 | Multifunctional compound nonwoven fabric |
CN102553523A (en) * | 2011-12-15 | 2012-07-11 | 南京大学 | Nano zero-valent iron-supported activated carbon fiber, and preparation method and application thereof |
CN103084138A (en) * | 2013-01-21 | 2013-05-08 | 华中师范大学 | Application of zirconium dioxide microspheres prepared by using microchannel injection auxiliary method to adsorptive enrichment of organophosphorus pesticide |
CN105054403A (en) * | 2015-08-20 | 2015-11-18 | 江苏广达医材集团有限公司 | Medical mask |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI793815B (en) * | 2017-02-14 | 2023-02-21 | 日商優你 嬌美股份有限公司 | Face mask |
WO2021206349A1 (en) * | 2020-04-09 | 2021-10-14 | 도레이첨단소재 주식회사 | Composite nonwoven and article comprising same |
CN111436690A (en) * | 2020-04-22 | 2020-07-24 | 康业(江苏)医疗科技有限公司 | Protective mask |
WO2021212208A1 (en) * | 2020-04-22 | 2021-10-28 | Weining Tan | Electrically heated respirator |
CN115427114A (en) * | 2020-04-22 | 2022-12-02 | 谭玮宁 | Electronic heating breathing mask |
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PB01 | Publication | ||
C10 | Entry into substantive examination | ||
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WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170208 |
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WD01 | Invention patent application deemed withdrawn after publication |