CN106376108A - High pressure-resistant carbon crystal plate and preparation method thereof - Google Patents
High pressure-resistant carbon crystal plate and preparation method thereof Download PDFInfo
- Publication number
- CN106376108A CN106376108A CN201610808215.5A CN201610808215A CN106376108A CN 106376108 A CN106376108 A CN 106376108A CN 201610808215 A CN201610808215 A CN 201610808215A CN 106376108 A CN106376108 A CN 106376108A
- Authority
- CN
- China
- Prior art keywords
- high pressure
- coating
- crystalline substance
- temperature
- resistant carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000013078 crystal Substances 0.000 title abstract 5
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 229920003023 plastic Polymers 0.000 claims abstract description 17
- 239000004033 plastic Substances 0.000 claims abstract description 16
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 13
- 238000005516 engineering process Methods 0.000 claims abstract description 11
- 238000000137 annealing Methods 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000008021 deposition Effects 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 28
- 239000007789 gas Substances 0.000 claims description 26
- 239000000126 substance Substances 0.000 claims description 16
- 239000003085 diluting agent Substances 0.000 claims description 11
- 239000001307 helium Substances 0.000 claims description 8
- 229910052734 helium Inorganic materials 0.000 claims description 8
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 8
- 238000009413 insulation Methods 0.000 claims description 7
- 239000012159 carrier gas Substances 0.000 claims description 6
- 238000005229 chemical vapour deposition Methods 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- HZBAVWLZSLOCFR-UHFFFAOYSA-N oxosilane Chemical compound [SiH2]=O HZBAVWLZSLOCFR-UHFFFAOYSA-N 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 4
- 238000005137 deposition process Methods 0.000 claims description 3
- 239000010410 layer Substances 0.000 claims 2
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000011247 coating layer Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 12
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000004567 concrete Substances 0.000 description 2
- 229920001587 Wood-plastic composite Polymers 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011155 wood-plastic composite Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/513—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using plasma jets
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/013—Heaters using resistive films or coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Plasma & Fusion (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Laminated Bodies (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
The invention discloses a high pressure-resistant carbon crystal plate and a preparation method thereof. The high pressure-resistant carbon crystal plate is characterized in that a rigid plastic plate and the surface are deposited with a 20-800nm coating; and the coating is prepared from the following raw materials in parts by weight: 20-60 parts of graphene, 5-10 parts of Cr, 5-10 parts of Zn, 5-15 parts of Ti and 10-15 parts of SiC. The invention further provides a method. The method comprises the following steps of ultrasonically cleaning the rigid plastic plate by deionized water and carrying out drying, deposition, high-temperature processing, and annealing. The high pressure-resistant carbon crystal plate is prepared by a dual-frequency capacitive coupled plasma discharge technology. The carbon crystal plate prepared by the method has high pressure resistance, the preparation method is simple and the raw materials are available.
Description
Technical field
The present invention relates to plastic cement production technical field, high pressure resistant and preparation method thereof in particular to one kind.
Background technology
Gradually severe with weather, China's most area winter becomes increasingly colder, and heating problem day by day becomes
The focus of society.With respect to traditional heating system, carbon trichite hot material have simple installation, environmental protection and energy saving, using flexibly etc.
Advantage, but carbon trichite hot material generally existing domestic at present with short life, heating rate be low, easy oxidation, using process
In apt to deteriorate.The domestic at present performance for electric hot plate to improve mostly be innovation by electrothermal plate structure and exothermic material is joined
The simple change of side and optimization, so the electric hot plate production preparation level in existing market is still relatively low.Prepare high performance
Electric hot plate, is necessary for preparing Stability Analysis of Structures, high pressure resistant material, and the method for plasma asistance technology prepares coating is full well
This requirement of foot, the heating board of preparation is not oxidizable, long service life.
Content of the invention
The present invention is intended to provide a kind of high pressure resistant carbon crystalline substance sheet material, this sheet material has excellent barotolerance.
To achieve these goals, the invention provides a kind of high pressure resistant carbon crystalline substance sheet material, its face coat is by following weight
The raw material of part is made: Graphene 20-60, cr 5-10, zn5-10, ti5-15, sic10-15.
Present invention also offers a kind of manufacture method of high pressure resistant carbon crystalline substance sheet material, comprise the steps of
(1) deionized water is cleaned by ultrasonic hard plastic board 20min, 40~70 DEG C of drying, puts into chemical vapor deposition stove
In, remove surface residue through ar;
(2) sample having deposited Graphene is positioned at 150~220 DEG C in high-temperature vacuum tubular type stove, the bar of 2~20pa
Carry out under part making annealing treatment 2~10h;
(3) by double frequency capacitively coupled plasma discharge technology, with methyl trimethoxy oxosilane for source gas, helium is to carry
Gas, ar is diluent gas, in 120~200 DEG C of temperature, deposits 10~100h under 5~60pa pressure;In deposition process as needed
The flow of adjustment source gas, carrier gas and diluent gas.
(4) the carbon crystalline substance plate that deposited coating, then two surface-coated temperature-resistant insulation layer are taken out.
By technique scheme, the present invention after by the drying of individual composition, deposition, high temperature, annealing, the sheet material tool that obtains
There is barotolerance, and preparation method is simple, raw material is easy to get.
A kind of high pressure resistant sheet material of the present invention, it is convenient to manufacture, and traditional plastic production technology need not improve and can use
Produce and processing and fabricating in it, low production cost;Compare with common plasticses sheet material, pollution-free, nontoxic, have no side effect, reliably put
The heart.
Specific embodiment
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that it is described herein concrete
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that it is described herein concrete
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
, it is characterised in that being made up of hard plastic board and coating, coating is by following weight portion for a kind of high pressure resistant carbon crystalline substance plate
Raw material is made: Graphene 20-60, cr 5-10, zn5-10, ti5-15, sic10-15.
Present invention also offers a kind of manufacture method of anti-corrosion adsorptivity colour wood plastic composite board, comprise following step
Rapid:
A kind of preparation method of high pressure resistant carbon crystalline substance plate is it is characterised in that the step that includes following orders:
(1) deionized water is cleaned by ultrasonic hard plastic board 20min, 40~70 DEG C of drying, puts into chemical vapor deposition stove
In, remove surface residue through ar;
(2) sample having deposited Graphene is positioned at 150~220 DEG C in high-temperature vacuum tubular type stove, the bar of 2~20pa
Carry out under part making annealing treatment 2~10h;
(3) by double frequency capacitively coupled plasma discharge technology, with methyl trimethoxy oxosilane for source gas, helium is to carry
Gas, ar is diluent gas, in 120~200 DEG C of temperature, deposits 10~100h under 5~60pa pressure;In deposition process as needed
The flow of adjustment source gas, carrier gas and diluent gas.
(4) the carbon crystalline substance plate that deposited coating, then two surface-coated temperature-resistant insulation layer are taken out.
In the present invention, the time of deposition can select in wide in range scope, but so that the sheet material tool being obtained
There is barotolerance it is preferable that 40~70 DEG C of the temperature of deposition, the time is 7~50h.
In the present invention, pressure can select in wide in range scope, but so that the sheet material being obtained has resistance to height
It is preferable that pressure is 2~20pa, the time is 2~10h to pressure property.
In the present invention, gas can select in wide in range scope, but so that the sheet material being obtained has resistance to height
It is preferable that helium is carrier gas, ar is diluent gas to pressure property.
Embodiment 1
1) it is made up of hard plastic board and coating, by each for sheet material coating composition according to following weight portion: Graphene 20, cr
5、zn5、ti5、sic10.
2) deionized water is cleaned by ultrasonic hard plastic board and is dried with 40 DEG C, puts in chemical vapor deposition stove, through ar
Remove surface residue, then the sample having deposited Graphene is positioned at 150 DEG C in high-temperature vacuum tubular type stove, the condition of 2pa
Under carry out make annealing treatment 2h;
3) by double frequency capacitively coupled plasma discharge technology, with methyl trimethoxy oxosilane for source gas, helium is to carry
Gas, ar is diluent gas, in 120 DEG C of temperature, deposits 10h under 5pa pressure;Take out deposited coating carbon crystalline substance plate, then its two
Individual surface-coated temperature-resistant insulation layer, obtains sheet material a1.
Embodiment 2
1) it is made up of hard plastic board and coating, by each for sheet material coating composition according to following weight portion: Graphene 60,
cr10、zn10、ti15、sic15.
2) deionized water is cleaned by ultrasonic hard plastic board and is dried with 70 DEG C, puts in chemical vapor deposition stove, through ar
Remove surface residue, then the sample having deposited Graphene is positioned at 220 DEG C in high-temperature vacuum tubular type stove, the condition of 20pa
Under carry out make annealing treatment 10h;
3) by double frequency capacitively coupled plasma discharge technology, with methyl trimethoxy oxosilane for source gas, helium is to carry
Gas, ar is diluent gas, in 200 DEG C of temperature, deposits 100h under 60pa pressure;Take out the carbon crystalline substance plate that deposited coating, Ran Houqi
Two surface-coated temperature-resistant insulation layers, obtain sheet material a2.
Embodiment 3
1) it is made up of hard plastic board and coating, by each for sheet material coating composition according to following weight portion: Graphene 40, cr
8、zn8、ti10、sic12.
2) deionized water is cleaned by ultrasonic hard plastic board and is dried with 50 DEG C, puts in chemical vapor deposition stove, through ar
Remove surface residue, then the sample having deposited Graphene is positioned at 180 DEG C in high-temperature vacuum tubular type stove, the condition of 10pa
Under carry out make annealing treatment 5h;
3) by double frequency capacitively coupled plasma discharge technology, with methyl trimethoxy oxosilane for source gas, helium is to carry
Gas, ar is diluent gas, in 160 DEG C of temperature, deposits 50h under 20pa pressure;Take out deposited coating carbon crystalline substance plate, then its two
Individual surface-coated temperature-resistant insulation layer, obtains sheet material a3.
Comparative example 1
Method according to embodiment 1 carries out sheet material b1 is obtained, and except for the difference that, does not add cr.
Comparative example 2
Method according to embodiment 2 carries out sheet material b2 is obtained, and except for the difference that, does not add zn.
Comparative example 3
Method according to embodiment 3 carries out sheet material b3 is obtained, and except for the difference that, does not add sic.
Detection example 1
The barotolerance of above-mentioned sheet material is detected, result is: the barotolerance of sheet material a1-a3 is superior to sheet material b1-
The barotolerance of b3.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the range of the technology design of the present invention, multiple simple variant can be carried out to technical scheme, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy no longer separately illustrates.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it equally should be considered as content disclosed in this invention.
Claims (7)
1., it is characterised in that being made up of hard plastic board and coating, coating is former by following weight portion for a kind of high pressure resistant carbon crystalline substance plate
Material is made: Graphene 20-60, cr 5-10, zn5-10, ti5-15, sic10-15, the attached temperature-resistant insulation layer in two surfaces of coating.
2. high pressure resistant carbon crystalline substance plate according to claim 1 is it is characterised in that described coating layer thickness is 20-800nm.
3. high pressure resistant carbon crystalline substance plate according to claim 1 is it is characterised in that described rigid plastics material is polyamide.
4. a kind of preparation method of high pressure resistant carbon crystalline substance plate is it is characterised in that the step that includes following orders:
(1) deionized water is cleaned by ultrasonic hard plastic board 20min, 40~70 DEG C of drying, puts in chemical vapor deposition stove, warp
Ar removes surface residue;
(2) sample having deposited Graphene is positioned at 150~220 DEG C in high-temperature vacuum tubular type stove, under conditions of 2~20pa
Carry out making annealing treatment 2~10h;
(3) by double frequency capacitively coupled plasma discharge technology, with methyl trimethoxy oxosilane for source gas, helium is carrier gas,
Ar is diluent gas, in 120~200 DEG C of temperature, deposits 10~100h under 5~60pa pressure;Adjust as needed in deposition process
The flow of whole source gas, carrier gas and diluent gas.
(4) the carbon crystalline substance plate that deposited coating, then two surface-coated temperature-resistant insulation layer are taken out.
5. 40~70 DEG C of the temperature of deposition according to claim 4, the time is 7~50h.
6. pressure according to claim 4 is 2~20pa, and the time is 2~10h.
7. according to claim 4 with helium as carrier gas, ar be diluent gas.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610808215.5A CN106376108A (en) | 2016-09-08 | 2016-09-08 | High pressure-resistant carbon crystal plate and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610808215.5A CN106376108A (en) | 2016-09-08 | 2016-09-08 | High pressure-resistant carbon crystal plate and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106376108A true CN106376108A (en) | 2017-02-01 |
Family
ID=57899289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610808215.5A Pending CN106376108A (en) | 2016-09-08 | 2016-09-08 | High pressure-resistant carbon crystal plate and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106376108A (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080146427A1 (en) * | 2006-11-16 | 2008-06-19 | Bridgestone Corporation | Electrical conductive roller and imaging apparatus comprising the same |
CN202818640U (en) * | 2012-09-19 | 2013-03-20 | 张永利 | Far-infrared negative ion ceramic electrothermal substrate |
CN104144531A (en) * | 2014-08-08 | 2014-11-12 | 苏州宏久航空防热材料科技有限公司 | High heating carbon crystal plate and manufacturing method thereof |
CN203942654U (en) * | 2014-06-18 | 2014-11-12 | 泰阳电子(东莞)有限公司 | A kind of Anticreep heater device for Pediluvium apparatus |
CN105720259A (en) * | 2014-12-23 | 2016-06-29 | 三星Sdi株式会社 | Negative active material and lithium battery including negative active material |
-
2016
- 2016-09-08 CN CN201610808215.5A patent/CN106376108A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080146427A1 (en) * | 2006-11-16 | 2008-06-19 | Bridgestone Corporation | Electrical conductive roller and imaging apparatus comprising the same |
CN202818640U (en) * | 2012-09-19 | 2013-03-20 | 张永利 | Far-infrared negative ion ceramic electrothermal substrate |
CN203942654U (en) * | 2014-06-18 | 2014-11-12 | 泰阳电子(东莞)有限公司 | A kind of Anticreep heater device for Pediluvium apparatus |
CN104144531A (en) * | 2014-08-08 | 2014-11-12 | 苏州宏久航空防热材料科技有限公司 | High heating carbon crystal plate and manufacturing method thereof |
CN105720259A (en) * | 2014-12-23 | 2016-06-29 | 三星Sdi株式会社 | Negative active material and lithium battery including negative active material |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104005003B (en) | High temperature and salt spray resistance solar energy selective absorbing coating in atmosphere and preparation method of coating | |
CN104144531B (en) | Brilliant plate of a kind of high heating carbon and preparation method thereof | |
CN103162452B (en) | Inoxidizability solar spectrum selective absorbing coating and preparation method thereof | |
CN102534497A (en) | High temperature selective absorption coating based on stainless steel material and manufacture method thereof | |
CN103302917B (en) | A kind of double absorption layer TiON weatherability photo-thermal coating and preparation method thereof | |
CN105585326A (en) | Technology for diffusion connection of SiC ceramic matrix composite through nano foil | |
CN101700703B (en) | Chromium-plated plastic product | |
CN105908107A (en) | SiC fiber-reinforced TiAl-based composite with Mo coating and preparation method of SiC fiber-reinforced TiAl-based composite | |
CN107604340A (en) | Chemical vapor deposition stove | |
CN104089423A (en) | Full-glass high-temperature vacuum heat collecting tube and film coating method thereof | |
CN105605814B (en) | A kind of coating for selective absorption of sunlight spectrum and preparation method thereof | |
CN106376108A (en) | High pressure-resistant carbon crystal plate and preparation method thereof | |
CN106397816A (en) | High-pressure-resisting high heating carbon crystal plate and preparation method thereof | |
CN106231702A (en) | A kind of High-conductivity carbon crystalline substance plate and preparation method thereof | |
CN103849834A (en) | Compound cutting tool coating based on titanium diboride and preparation method thereof | |
CN106413147A (en) | High-pressure-resistant moisture-proof carbon crystal plate and preparation method thereof | |
CN103709814B (en) | A kind of sandwich antenna house surface-sealing agent and using method | |
CN106413146A (en) | High-temperature moisture-proof carbon crystal plate and preparation method thereof | |
CN102442024A (en) | High weatherability selective absorption coating based on aluminum materials and preparation method thereof | |
CN102734966A (en) | Tank type solar intermediate temperature selective absorption coating | |
CN104087911B (en) | A kind of preparation method of Parylene organic target | |
Lu et al. | Silicon Gradients-containing Films for Mid-high Temperature Non-vacuum Solar Absorber Coatings | |
CN106568207A (en) | High-temperature solar spectrum selective absorbing coating and preparation method thereof | |
CN207276698U (en) | A kind of heat safe titanium alloy milling cutter special-purpose coat structure | |
CN102954611A (en) | Medium-high temperature spectrum selective absorbing coating |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170201 |
|
RJ01 | Rejection of invention patent application after publication |