CN106373876A - Method of improving edge defect of etching chamber of asymmetric electrostatic chuck - Google Patents

Method of improving edge defect of etching chamber of asymmetric electrostatic chuck Download PDF

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Publication number
CN106373876A
CN106373876A CN201611028534.0A CN201611028534A CN106373876A CN 106373876 A CN106373876 A CN 106373876A CN 201611028534 A CN201611028534 A CN 201611028534A CN 106373876 A CN106373876 A CN 106373876A
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China
Prior art keywords
etching
electrostatic chuck
etch
edge defect
asymmetry
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CN201611028534.0A
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CN106373876B (en
Inventor
胡伟玲
聂钰节
唐在峰
吴智勇
任昱
吕煜坤
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Shanghai Huali Microelectronics Corp
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Shanghai Huali Microelectronics Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

The invention provides a method of improving the edge defect of an etching chamber of an asymmetric electrostatic chuck, comprising the following steps: S1, providing a plasma reaction chamber for implementing a polycrystalline silicon gate etching process and a semiconductor structure needing to be processed through a polycrystalline silicon gate etching process; S2, fixing an electrostatic chuck in an asymmetric way in the plasma reaction chamber; and S3, placing the semiconductor structure in the reaction chamber to implement a polycrystalline silicon gate etching process, wherein an additional cleaning step for reducing residual etching by-products in the etching chamber is implemented one or more steps before or after a predetermined step of polycrystalline silicon etching.

Description

A kind of method improving asymmetry electrostatic chuck etching cavity edge defect
Technical field
The present invention relates to field of semiconductor manufacture, it is more particularly related to one kind improves asymmetry electrostatic inhale The method of disk etching cavity edge defect.
Background technology
Enter the super large-scale integration epoch with integrated circuit technique, the process of integrated circuit towards 65nm with And smaller size of structural development, wafer manufacturing process is proposed with higher finer technical requirements simultaneously.Wherein, in etching The etching defect producing becomes more and more sensitive to the yield of wafer.In order to tackle integrated circuit to deep-submicron down to nanometer chi Degree development, the plasma dry etch process technology occupying critical role in semiconductor fabrication has also obtained constantly Development, wherein mainly has the film layer structure designing technique of the chip that is etched and the exploitation of etching technics optimisation technique itself.Due to Be etched pattern line miniaturization development, etch process parameters optimization also seems particularly significant.
Polycrystalline in large scale integrated circuit crosses using plasma etching in technical process at present, and also referred to as dry method is carved Erosion, is to carry out thin film lithographic technique using plasma.In the presence of gas is with plasma form, it possesses two features: One to be that aerochemistry activity ratio in plasma is eager to excel under normality a lot, and according to the difference of the material that is etched, it is suitable to select Gas, it is possible to quickly be reacted with material, realizes the purpose that etching removes;Two are available with electric field plasma Guide and accelerate so as to possess certain energy, when it bombards the surface of the thing that is etched, can be by the former of thing material that be etched Son hits, thus reaching the purpose realizing etching using energy transfer physically.Therefore, dry etching is wafer surface Physics and the result of chemical two kinds of process balances.
Dry etching is divided into three kinds again: physical property etching, and chemical etches, and physical chemistry etches.Wherein physical property is carved Erosion is also called physical sputter etch.It is obvious that this ise leans on the bombardment of energy to get process and the sputtering very phase of atom Seemingly.Chemical etching is with the material that is etched, chemical reaction to occur using the chemism atomic group in plasma, thus realizing Etching purpose.Due to core or the chemical reaction of etching, the therefore effect of etching and wet etching is a bit close, has preferably Selectivity, but anisotropy is poor.
Accordingly, it is desirable to a kind of asymmetry electrostatic chuck etching cavity edge defect of can improving can be provided Method.
Content of the invention
The technical problem to be solved is that there is drawbacks described above in prior art, provides one kind can improve The method of asymmetry electrostatic chuck etching cavity edge defect.
In order to realize above-mentioned technical purpose, according to the present invention, there is provided one kind improves asymmetry electrostatic chuck etch chamber The method of body edge defect, comprising:
First step: provide for the plasma reaction chamber of polycrystalline silicon gate grid etching process and need to execute polysilicon The semiconductor structure of grid etch PROCESS FOR TREATMENT;
Second step: fixing quiet in the way of making electrostatic chuck have asymmetry in described plasma reaction chamber Electric sucker;
Third step: described semiconductor structure is placed in reaction cavity and carries out polycrystalline silicon gate grid etching process;Wherein, exist Before or after the one or multi-step of the predetermined process of etching polysilicon, execution reduces the etch by-products of residual in etching cavity Additional removing step.
Preferably, in second step, using the fixing electrostatic chuck of single-cantilever so that electrostatic chuck has asymmetry.
Preferably, in third step, described additional step of removing reduces the etching remaining in etching cavity using gas By-product.
Preferably, the described additional gas that used of step of removing includes: noble gases and/or do not produce etch by-products Etching gas.
Preferably, in third step, in additional removing step, reduce etching by increasing in etching polysilicon formula The step of by-product is reducing the etch by-products of residual in etching cavity.
Preferably, described predetermined process includes: ARC etch step, hard mask etching step, etching polysilicon Step and etch step.
Preferably, described additional removing step includes: in the ARC etch step of polycrystalline silicon etching process process The step that the noble gases increasing afterwards dilute etch by-products.
Preferably, described additional removing step includes: increases after the hard mask etching step of polycrystalline silicon etching process process Plus noble gases dilute etch by-products step.
Preferably, described additional step of removing includes: increases after the etch step of polycrystalline silicon etching process process The step that noble gases dilute etch by-products.
Preferably, described additional removing step includes: after polycrystalline silicon etching process process terminates using noble gases or The step that non-reactive gas carry out gas dilution to etching cavity.
Using technical scheme, specific by adding before or after the committed step of etching polysilicon formula Gas dilution step and for this step carry out evacuation (pump down) to detach dilution etching process in produce by-product Thing gas, reduces deposition above cantilever for the polymer, effectively eliminates cantilever top edges etching defect, improves etching reaction The service efficiency of cavity, the electric property of wafer and the yield of product, reduce product rejection rate.
Brief description
In conjunction with accompanying drawing, and by reference to detailed description below, it will more easily have more complete understanding to the present invention And its adjoint advantages and features are more easily understood, wherein:
Fig. 1 schematically shows and according to the preferred embodiment of the invention improves asymmetry electrostatic chuck etching cavity side The flow chart of the method for edge defect.
It should be noted that accompanying drawing is used for the present invention is described, and the unrestricted present invention.Note, represent that the accompanying drawing of structure can Can be not necessarily drawn to scale.And, in accompanying drawing, same or like element indicates same or like label.
Specific embodiment
In order that present disclosure is more clear and understandable, with reference to specific embodiments and the drawings in the present invention Appearance is described in detail.
The invention discloses a kind of method improving asymmetry etching cavity etching edge defect, by carving in polysilicon The step that one or multi-step special gas reduce etch by-products residual is added to carry out the polymerization of minimizing electrostatic sucker edge in erosion formula The deposit of thing, thus solving the problems, such as the etching defect producing during etching polysilicon, improves the yield of product.The method is real Now simple, with low cost.
Fig. 1 schematically shows and according to the preferred embodiment of the invention improves asymmetry electrostatic chuck etching cavity side The flow chart of the method for edge defect.
As shown in figure 1, according to the preferred embodiment of the invention improve asymmetry electrostatic chuck etching cavity edge defect Method include:
First step s1: provide for the plasma reaction chamber of polycrystalline silicon gate grid etching process and need to execute polycrystalline The semiconductor structure that silicon gate etching technics is processed;
Second step s2: being fixed in the way of making electrostatic chuck have asymmetry in described plasma reaction chamber Electrostatic chuck;
Preferably, in second step s2, using the fixing electrostatic chuck of single-cantilever so that electrostatic chuck has asymmetry.
Third step s3: described semiconductor structure is placed in reaction cavity and carries out polycrystalline silicon gate grid etching process;Wherein, Before or after the one or multi-step of the predetermined process of etching polysilicon, execution reduces the etching by-product of residual in etching cavity The additional removing step of thing.
Preferably, in third step s3, in additional removing step, described additional removing step reduces quarter using gas The etch by-products of residual in erosion cavity.And preferably, the gas that described additional removing step is used includes but not only limits In: noble gases (as he, ar etc.) and/or the etching gas (n not producing etch by-products2Deng co etc.).
Or, in third step s3, in additional removing step, reduce etching by increasing in etching polysilicon formula The step of by-product is reducing the etch by-products of residual in etching cavity.
Specifically, described predetermined process refers to some key steps, for example, include: ARC (barc) etching step Suddenly, hard mask etching step, etching polysilicon step, etch step etc..Specifically, additional removing step can include as Under:
A) noble gases increasing after ARC (c-o) etch step of existing polycrystalline silicon etching process process are dilute The step releasing etch by-products;This process can dilute the organic by-products gas producing in ARC etching process, reduces Byproducts accumulation above cantilever;
B) in the hard mask (sio of existing polycrystalline silicon etching process process2/ sin) noble gases that increase after etch step The step of dilution etch by-products;This process can dilute hard mask (sio2/ sin) the organic by-products gas that produces in etching process Body, reduces the byproducts accumulation above cantilever;
C) the noble gases dilution etching increasing after silicon (si) etch step of existing polycrystalline silicon etching process process is secondary The step of product;This process can dilute the organic by-products gas producing in silicon (si) etching process, reduces the pair above cantilever Product accumulation;
D) after existing polycrystalline silicon etching process process terminates, using noble gases or non-reactive gas to etching cavity The step carrying out gas dilution, reduces remaining bi-products gas.
Using technical scheme, specific by adding before or after the committed step of etching polysilicon formula Gas dilution step and for this step carry out evacuation (pump down) to detach dilution etching process in produce by-product Thing gas, reduces deposition above cantilever for the polymer, effectively eliminates cantilever top edges etching defect, improves etching reaction The service efficiency of cavity, the electric property of wafer and the yield of product, reduce product rejection rate.
Furthermore, it is necessary to explanation, unless stated otherwise or point out, otherwise the term in description " first ", " the Two ", " 3rd " etc. describes each assembly being used only in differentiation description, element, step etc., rather than is used for representing each Logical relation between assembly, element, step or ordering relation etc..
Although it is understood that the present invention is disclosed as above with preferred embodiment, but above-described embodiment being not used to Limit the present invention.For any those of ordinary skill in the art, without departing under technical solution of the present invention ambit, The technology contents that the disclosure above all can be utilized are made many possible variations and modification, or are revised as to technical solution of the present invention Equivalent embodiments with change.Therefore, every content without departing from technical solution of the present invention, according to the technical spirit pair of the present invention Any simple modification made for any of the above embodiments, equivalent variations and modification, all still fall within the scope of technical solution of the present invention protection Interior.
And it should also be understood that the present invention is not limited to specific method described herein, compound, material, system Make technology, usage and application, they can change.It should also be understood that term described herein be used merely to describe specific Embodiment, rather than be used for limiting the scope of the present invention.Must be noted that herein and claims used in Singulative " one ", " a kind of " and " being somebody's turn to do " include complex reference, unless context explicitly indicates that contrary.Therefore, example As the citation of " element " meaned with the citation to one or more elements, and including known to those skilled in the art Its equivalent.Similarly, as another example, the citation of " step " or " device " is meaned to one or Multiple steps or the citation of device, and potentially include secondary step and second unit.Should be managed with broadest implication All conjunctions that solution uses.Therefore, word "or" should be understood that the definition with logical "or", rather than logical exclusive-OR Definition, unless context explicitly indicates that contrary.Structure described herein will be understood as also quoting from the function of this structure Equivalent.Can be interpreted that approximate language should be understood like that, unless context explicitly indicates that contrary.

Claims (10)

1. a kind of method improving asymmetry electrostatic chuck etching cavity edge defect is it is characterised in that include:
First step: provide for the plasma reaction chamber of polycrystalline silicon gate grid etching process and need to execute polysilicon gate The semiconductor structure that etching technics is processed;
Second step: in fixing electrostatic suction in the way of making electrostatic chuck have asymmetry in described plasma reaction chamber Disk;
Third step: described semiconductor structure is placed in reaction cavity and carries out polycrystalline silicon gate grid etching process;Wherein, in polycrystalline Before or after the one or multi-step of the predetermined process of silicon etching, execution reduces the attached of the etch by-products remaining in etching cavity Plus removing step.
2. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1, its feature exists In in second step, using the fixing electrostatic chuck of single-cantilever so that electrostatic chuck has asymmetry.
3. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1 and 2, its feature It is, in third step, described additional step of removing reduces the etch by-products remaining in etching cavity using gas.
4. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 3, its feature exists In the gas that described additional removing step is used includes: noble gases and/or the etching gas not producing etch by-products.
5. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1 and 2, its feature It is, in third step, in additional removing step, by increasing the step reducing etch by-products in etching polysilicon formula Suddenly the etch by-products of residual in etching cavity are reduced.
6. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1 and 2, its feature It is, described predetermined process includes: ARC etch step, hard mask etching step, etching polysilicon step and silicon are carved Erosion step.
7. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1 and 2, its feature It is, described additional step of removing includes: increase after the ARC etch step of polycrystalline silicon etching process process is lazy The step of property gas dilution etch by-products.
8. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1 and 2, its feature It is, described additional step of removing includes: the indifferent gas increasing after the hard mask etching step of polycrystalline silicon etching process process The step that body dilutes etch by-products.
9. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1 and 2, its feature It is, described additional step of removing includes: the noble gases increasing after the etch step of polycrystalline silicon etching process process are dilute The step releasing etch by-products.
10. the method improving asymmetry electrostatic chuck etching cavity edge defect according to claim 1 and 2, it is special Levy and be, described additional removing step includes: using noble gases or non-reacted after polycrystalline silicon etching process process terminates The step that gas carries out gas dilution to etching cavity.
CN201611028534.0A 2016-11-18 2016-11-18 A method of improving asymmetry electrostatic chuck etching cavity edge defect Active CN106373876B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030181027A1 (en) * 2002-03-25 2003-09-25 Chao-Hu Liang Method of forming a polysilicon layer
CN101290865A (en) * 2007-04-20 2008-10-22 中芯国际集成电路制造(上海)有限公司 Method for preventing generating surface blemish in etching process
CN105140115A (en) * 2015-07-22 2015-12-09 上海华力微电子有限公司 Method for improving spherical defect by optimizing charge releasing step process condition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030181027A1 (en) * 2002-03-25 2003-09-25 Chao-Hu Liang Method of forming a polysilicon layer
CN101290865A (en) * 2007-04-20 2008-10-22 中芯国际集成电路制造(上海)有限公司 Method for preventing generating surface blemish in etching process
CN105140115A (en) * 2015-07-22 2015-12-09 上海华力微电子有限公司 Method for improving spherical defect by optimizing charge releasing step process condition

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