CN106373649B - A kind of composite core of grid power transmission conducting wire and preparation method thereof - Google Patents

A kind of composite core of grid power transmission conducting wire and preparation method thereof Download PDF

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Publication number
CN106373649B
CN106373649B CN201610866485.1A CN201610866485A CN106373649B CN 106373649 B CN106373649 B CN 106373649B CN 201610866485 A CN201610866485 A CN 201610866485A CN 106373649 B CN106373649 B CN 106373649B
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China
Prior art keywords
composite core
core
power transmission
layer
conducting wire
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201610866485.1A
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Chinese (zh)
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CN106373649A (en
Inventor
宋佩儒
王玥娜
姜晓阳
李伟
夏伟伟
李文祥
唐晓力
管卫卫
盛大泽
魏爱华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rongcheng Power Supply Co Of State Grid Shandong Electric Power Comany
State Grid Corp of China SGCC
Original Assignee
Rongcheng Power Supply Co Of State Grid Shandong Electric Power Comany
State Grid Corp of China SGCC
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Application filed by Rongcheng Power Supply Co Of State Grid Shandong Electric Power Comany, State Grid Corp of China SGCC filed Critical Rongcheng Power Supply Co Of State Grid Shandong Electric Power Comany
Priority to CN201610866485.1A priority Critical patent/CN106373649B/en
Publication of CN106373649A publication Critical patent/CN106373649A/en
Application granted granted Critical
Publication of CN106373649B publication Critical patent/CN106373649B/en
Expired - Fee Related legal-status Critical Current
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/1835Sheaths comprising abrasive charges
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/22Sheathing; Armouring; Screening; Applying other protective layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ropes Or Cables (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of composite core of grid power transmission conducting wire, the composite core is made of center carbon fiber core, intermediate buffer layer and outer resin layer;The intermediate buffer layer is made of resin material, fibre reinforced materials and antiwear additive, the resin material is one kind in Lauxite, polyurethane, the fibre reinforced materials is the one or more in carbon fiber, aramid fiber, silicon carbide fibre, glass fibre, and the antiwear additive is one kind in a nanometer molybdenum sulfide, carbon nanotubes;The outer resin layer is epoxy resin, a coating is also coated with the outer resin layer, the coating is polyalphaolefin.Due to the use of multi-layer compound structure and unique padded coaming, so that composite core prepared by the present invention has good bending property, bending radius is less than 30 times of compound core diameter, it is significantly better than similar product, shake performance with good mechanical tensile resistance and wind resistance, be particularly suitable for the use of coastal and western windy area.

Description

A kind of composite core of grid power transmission conducting wire and preparation method thereof
Technical field
The present invention relates to the preparation method of the core of power transmission cable in power grid, especially a kind of power transmission cable carbon fiber is compound Core and preparation method thereof.
Background technology
With the fast development of China's economy, some areas power load rapid growth, transmission line of electricity can't bear to bear to transmit The demand of the quick dilatation of capacity, power failure, disconnection fault occur again and again caused by overload, and power transmission has become power industry and sent out " bottleneck " of exhibition, low-loss, the economizing type advanced composite material (ACM) transmission pressure of large capacity cause each side's concern.With carbon fiber etc. Advanced composite material (ACM) core conducting wire made of steel core in the traditional twisted wire of composite material replacement is a kind of overhead power transmission of novel concept Circuit conducting wire.Carbon fiber composite core wire uses new composite technology, can eliminate magnetic resistance existing for aluminium steel conductor and show As and fuel factor, under identical traffic capacity, comprehensive line loss can reduce 6%~8%.By national annual electricity generating capacity 41413 in 2010 Hundred million kWh, line loss per unit 615% calculate, and can reduce about 160~21,500,000,000 kWh of line loss, are calculated by coal consumption for power generation 335g/kWh, equivalent to It is annual to save about 540~7,200,000 t of electric coal, reduce corresponding CO2Discharge capacity, effects of energy saving and emission reduction are notable.Obtained necessarily into In the advanced composite material (ACM) synthesis core conducting wire of fruit, with the aluminium twisted wire with carbon fiber composite core of complex technique company of the U.S. (CTC) production (ACCC) it is the most typical.
ACCC carbon fiber composite core wires have big light-weight, intensity, high temperature resistant, corrosion-resistant, anti-compared with conventional wires Creep, line loss is small, sag is low, thermal coefficient of expansion is small, with a series of excellent properties such as environment is affine, realize the section of power transmission Energy, environmental protection and safety, so as to cause the very big of various countries to be paid close attention to.Its cored wire is by layer centered on carbon fiber and glass fibre cladding system Into single plug, carbon fiber using polyamide refractory process, carbonization form;The epoxy resin tool of high intensity, high tenacity formula There are very strong impact resistance, resistance to tension stress and bending stress.The manufacturing technology of ACCC twisted wires is ripe day by day, main using continuous Extrusion, core technology are the manufactures of plug, and critical material is high temperature tough epoxy resin.In carbon fiber composite core rod, carbon Fiber accounts for 35%, and glass fibre accounts for 35%, and epoxy resin accounts for 30%.Carbon fiber used is high for tensile strength, and extension at break is big T700S grades, glass fibre is alkaline-resisting E types, and epoxy resin is the toughened resin of high temperature modification.
Cable using carbon fiber complex core as cable load-bearing core merely, due to being subject to steam, height in long-term use The long term of the conditions such as temperature, resin material can degrade, and cause the performance of the especially compound wicking surface of compound core performance to become Difference, in the case where hanging transmission line of electricity is chronically at wind shake operating mode, can rub between compound wicking surface and plain conductor so that multiple Close wicking surface and abrasion even mechanical destruction further occurs, cause composite core load-bearing and insulating properties hydraulic performance decline, ultimately result in Cable is damaged.
CN103578665A discloses the preparation method of overhead transmission line stranded fiber reinforced resin base composite core, Comprise the following steps:1. fiber is at the uniform velocity pulled out from creel, then dry through moisture separator;2. by the modified resin of different component It is driven into constant temperature steeping vat;3. the multiply fiber to have dried is then fed into constant temperature steeping vat respectively by the device aggregation of collection yarn Middle impregnation;4. precuring;5. by involving the composite core strand of semi-solid preparation, using winding machine outside each strand twining package tape Material;6. secondary precuring;7. each strand of composite core through secondary precuring is each passed through separated time mould, carried out subsequently into wire parallel module It is twisted;8. curing molding;9. take-up.The method effectively increases the bending strength of product, ensures product curved surface operating rate.
CN103646718A discloses a kind of fiber composite core conductive wire for power transmission line, and the conducting wire is by the fiber that sets gradually Composite core, coating and outer layer twisted wire composition, coating are in fluorocarbon resin coating, polyurea elastomer coating, polyurethane coating One or more coating coat.The fiber composite core conductive wire for power transmission line is wear-resisting, corrosion-resistant, wet-heat resisting, resistance to steam, Uvioresistant, coating protect fiber composite core to be worn from environmental corrosion and aluminum steel, improve fiber composite core anti-aging property.
The content of the invention
The problem of composite core that the present invention is directed in carbon fiber composite core cable is easy to wear, there is provided a kind of improved carbon is fine Composite core is tieed up, performance that the cable prepared using the composite core has a good mechanical tensile resistance and wind resistance shakes is especially suitable In the use of coastal and western windy area, due to the use of multi-layer compound structure and unique padded coaming so that the present invention The composite core of preparation has good bending property, and bending radius is less than 30 times of compound core diameter, is significantly better than similar product, Achieve unexpected technique effect.
A kind of composite core of grid power transmission conducting wire, the composite core is by center carbon fiber core, intermediate buffer layer and outer layer tree Lipid layer forms;The intermediate buffer layer is made of resin material, fibre reinforced materials and antiwear additive, and the resin material is urea One kind in urea formaldehyde, polyurethane, the fibre reinforced materials are in carbon fiber, aramid fiber, silicon carbide fibre, glass fibre One or more, the antiwear additive is one kind in a nanometer molybdenum sulfide, carbon nanotubes;The outer resin layer is asphalt mixtures modified by epoxy resin Fat, is also coated with a coating on the outer resin layer, the coating is polyalphaolefin.
A diameter of 3-7mm of the center carbon fiber core, the thickness of intermediate buffer layer are 1-2mm, the thickness of outer resin layer Spend for 1-3mm.
The thickness of the coating is 150-300 microns, preferably 200-220 microns.
The composite core is cylinder, and a diameter of 10-30mm, is preferably 15-20mm.
The particle diameter of the antiwear additive is 50-200 nanometers.
The intermediate buffer layer is by the resin material of 70-90wt%, the fibre reinforced materials and 5-10wt% of 10-20wt% Antiwear additive composition, the preferably resin material of 80-85wt%, the fibre reinforced materials of 12-15wt% and 3-8wt%'s is wear-resistant Agent forms.
A kind of preparation method of grid power transmission conducting wire composite core, comprises the following steps:
Resin adhesive liquid is cured in grinding tool in leading portion and is gradually heated up, under the action of inner pattern releasing agent applicable, is pulled out by draw-gear Forming temperature is 140-200 DEG C, and hardening time is 30-90 seconds;
Center carbon fiber core by leading portion curing process passes through well-mixed intermediate buffering by quick cooling, coating Layer material, intermediate buffering layer thickness are 1-10mm;
The core material for being coated with intermediate layer is cured by 120-150 DEG C of processing;
Consolidate again at 190-210 DEG C after applying epoxy resin after quickly being cooled down to the core material for being coated with intermediate layer Change is handled;
A strata alhpa olefin is finally applied, obtains the grid power transmission conducting wire composite core.
Composite core of the present invention has a good tensile resistance, and with good wear-resisting, resistance to steam performance, can be with Avoid composite core from being worn by aluminum steel, effectively extend the service life of composite core.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Embodiment 1:
The composite core of grid power transmission conducting wire, the composite core are 2mm's by center carbon fiber core, the thickness of a diameter of 5mm Intermediate buffer layer and the outer resin layer that thickness is 1mm form;The intermediate buffer layer is by 70wt% Lauxites, 20wt% Aramid fiber, 10wt% nanometers of molybdenum sulfide compositions;The outer resin layer is epoxy resin, is also applied on the outer resin layer There is the polyalphaolefin that a layer thickness is 200 microns.
Embodiment 2:
The composite core of grid power transmission conducting wire, the composite core are 1mm's by center carbon fiber core, the thickness of a diameter of 5mm Intermediate buffer layer and the outer resin layer that thickness is 2mm form;The intermediate buffer layer is by 85wt% polyurethane, 10wt% virtues Synthetic fibre fiber, 5wt% carbon nanotubes composition;The outer resin layer is epoxy resin, and one is also coated with the outer resin layer Layer thickness is 150 microns of polyalphaolefin.
Comparative example 1:
The composite core of grid power transmission conducting wire, the composite core are 1mm's by center carbon fiber core, the thickness of a diameter of 5mm Outer resin layer forms;Also coated with the polyalphaolefin that a layer thickness is 200 microns on the outer resin layer..
It is detected for composite core made from embodiment and comparative example, specific data are as follows:
Tensile strength (MPa) Shear strength (MPa) Bending diameter (mm) Elongation at break (%)
Embodiment 1 3050 86 262 1.5
Embodiment 2 3240 89 235 1.6
Comparative example 1 2165 70 571 1.2
It the above is only the implementation example of the present invention, protection scope of the present invention be not limited in any way.It is every to use this Equivalent substitution known to field or the equivalent technical solution for exchanging formation, are within the scope of the present invention.

Claims (5)

1. a kind of composite core of grid power transmission conducting wire, the composite core is by center carbon fiber core, intermediate buffer layer and outermost resin Layer composition;The intermediate buffer layer is made of resin material, fibre reinforced materials and antiwear additive, and the resin material is ureaformaldehyde One kind in resin, polyurethane, the fibre reinforced materials are in carbon fiber, aramid fiber, silicon carbide fibre, glass fibre One or more, the antiwear additive are one kind in a nanometer molybdenum sulfide, carbon nanotubes;The outer resin layer is epoxy resin, A coating is also coated with the outer resin layer, the coating is polyalphaolefin;A diameter of 3- of the center carbon fiber core 7mm, the thickness of intermediate buffer layer is 1-2mm, and the thickness of outer resin layer is 1-3mm;The composite core is cylinder;In described Between cushion by the resin material of 80-85wt%, the antiwear additive composition of the fibre reinforced materials of 12-15wt% and 3-8wt%.
2. the composite core of grid power transmission conducting wire according to claim 1, it is characterised in that the thickness of the coating is 150- 300 microns.
3. the composite core of grid power transmission conducting wire according to claim 1, it is characterised in that the thickness of the coating is 200- 220 microns.
4. the composite core of grid power transmission conducting wire according to claim 1, it is characterised in that the particle diameter of the antiwear additive is 50- 200 nanometers.
5. the preparation method of grid power transmission conducting wire composite core, comprises the following steps described in claim 1:
(1) by resin adhesive liquid leading portion cure grinding tool in gradually heat up, under the action of inner pattern releasing agent applicable, by draw-gear pull out into Type temperature is 140-200 DEG C, and hardening time is 30-90 seconds;
(2) the center carbon fiber core Jing Guo leading portion curing process passes through well-mixed intermediate buffering by quick cooling, coating Layer material, intermediate buffering layer thickness are 1-10mm;
(3) core material for being coated with intermediate buffer layer is cured by 120-150 DEG C of processing;
(4) to be coated with intermediate buffer layer core material quickly cooling after apply epoxy resin after again at 190-210 DEG C into Row curing process;
(5) a strata alhpa olefin is finally applied, obtains the grid power transmission conducting wire composite core.
CN201610866485.1A 2016-09-29 2016-09-29 A kind of composite core of grid power transmission conducting wire and preparation method thereof Expired - Fee Related CN106373649B (en)

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CN109637722B (en) * 2018-11-06 2020-11-03 深圳烯湾科技有限公司 Carbon nanotube fiber wire
CN110343367B (en) * 2019-07-31 2021-11-12 国网河南省电力公司电力科学研究院 High-toughness carbon fiber composite core for overhead conductor
JP2021036495A (en) * 2019-08-30 2021-03-04 矢崎総業株式会社 Extrusion flexible flat cable and wire harness
CN113172971A (en) * 2020-06-22 2021-07-27 中国石化集团胜利石油管理局有限公司电力分公司 Carbon fiber composite material wire core and production method thereof
CN113329534A (en) * 2021-05-20 2021-08-31 湖北工业大学 Carbon fiber heating wire for road and bridge snow melting and deicing

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CN1152085A (en) * 1995-12-12 1997-06-18 宋春燕 Gasket for disc brake
CN101309056B (en) * 2008-05-30 2012-03-07 哈尔滨工业大学 Preparing method of antisotropic friction plate of ultrasonic motor and special preparing apparatus thereof
CN102516708B (en) * 2011-11-25 2014-07-02 中国电力科学研究院 Composite core for power grid transmission line wire and preparation method thereof
JP2014072039A (en) * 2012-09-28 2014-04-21 Kobe Steel Ltd PRECURSOR FOR MANUFACTURING Nb3Sn SUPERCONDUCTING WIRE ROD AND Nb3Sn SUPERCONDUCTING WIRE ROD

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