CN106368083A - High-glossiness spraying impregnation paper and production method thereof - Google Patents

High-glossiness spraying impregnation paper and production method thereof Download PDF

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Publication number
CN106368083A
CN106368083A CN201610753529.XA CN201610753529A CN106368083A CN 106368083 A CN106368083 A CN 106368083A CN 201610753529 A CN201610753529 A CN 201610753529A CN 106368083 A CN106368083 A CN 106368083A
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CN
China
Prior art keywords
bloom
resin
production method
value
drying
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Pending
Application number
CN201610753529.XA
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Chinese (zh)
Inventor
夏纪文
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SUZHOU JIANCHENG DECORATIVE MATERIAL CO Ltd
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SUZHOU JIANCHENG DECORATIVE MATERIAL CO Ltd
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Priority to CN201610753529.XA priority Critical patent/CN106368083A/en
Publication of CN106368083A publication Critical patent/CN106368083A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/22Structures being applied on the surface by special manufacturing processes, e.g. in presses
    • D21H27/26Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
    • D21H27/28Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/26Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08G12/30Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
    • C08G12/32Melamines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47Condensation polymers of aldehydes or ketones
    • D21H17/49Condensation polymers of aldehydes or ketones with compounds containing hydrogen bound to nitrogen
    • D21H17/51Triazines, e.g. melamine
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/26Aminoplasts
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • D21H19/824Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/84Paper comprising more than one coating on both sides of the substrate
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials

Abstract

The invention discloses high-glossiness spraying impregnation paper and a production method thereof, and relates to the field of impregnation paper. The high-glossiness spraying impregnation paper comprises a decorative paper base layer, a resin bottom layer, a wear-resistant mixed resin layer and a resin surface layer; the resin bottom layer is applied to the lower surface of the decorative paper base layer; the wear-resistant mixed resin layer is applied to the upper surface of the decorative paper base layer; the resin surface layer is applied to the wear-resistant mixed resin layer; the wear-resistant mixed resin layer is prepared from silicon carbide, aluminum oxide and high-glossiness MF resin.

Description

A kind of bloom spraying dipping paper and its production method
Technical field
The present invention relates to dipping paper field, more particularly to a kind of bloom spraying dipping paper and its production method.
Background technology
Melamine resin was invented in Europe the forties in last century, experienced from high-pressure process to low pressure short cycle Very long development course.Dipping uses melmac solution, is that polycondensation under firming agent effect forms with formaldehyde by tripolycyanamide Water white A-stage resin solution.Because it can form water-fast, heat-resisting, wear-resisting, anti-pollution, rich glossiness resin protection Film, with the facing paper of melmac dipping, for wood-based plate incrustation.Melamine impregnated paper wainscot decorative panel is extensive For furniture, floor, Men Ye, cabinet etc., it is related to the fields such as family, hotel, school, laboratory, stadiums.
Due to the excellent surface property of melamine decorative board, add the progress of printing technology, and tripolycyanamide decoration Plate is easy to process, and traditional wood furniture and the very big share of wood floors have changed into be manufactured by melamine decorative board.2000 Afterwards, melamine decorative board industry has obtained developing faster, and at present, national melamine impregnated paper production line is more than 5000 Bar, all kinds of melamine decorative board factories are countless." lumber " board melamine plate, " Europe group " cabinet, sage are as floor etc. All for melmac technology.
Concora crush bloom and molding bloom consolidated floor surface-brightening, soft and moist, improve grade, are greatly favored by consumers.But in fact, High finish surface easily exposes because of smooth, defect;Glossiness, typically in 75-85 degree, has bound to require, has special glossiness again Instrument can measure;The steel plate overlaying, typically in 600-630 degree, compares fixation, and the floor surface glossiness of extrusion only depends on Dipping paper, so bloom floor is very harsh to the prescription of spraying dipping paper.
Content of the invention
The invention mainly solves the technical problem of providing a kind of bloom spraying dipping paper and its production method, improve leaching The production technology level of stain paper.
For solving above-mentioned technical problem, one aspect of the present invention is to provide a kind of bloom spraying dipping paper, Including decoration paper substrate, resin bottom and wear-resisting compound tree lipid layer, resin surface layer;The lower surface of described decoration paper substrate is provided with institute State resin bottom;The upper surface of described decoration paper substrate is provided with described wear-resisting compound tree lipid layer;In wear-resisting compound tree lipid layer again Coated with resins top layer;The composition of wherein said wear-resisting compound tree lipid layer includes: carborundum, aluminium sesquioxide and bloom mf resin.
A kind of production method preparing above-mentioned bloom spraying dipping paper, its processing step includes successively: uncoiling, the back of the body apply, leaching Glue, liquid spray, put down, first drying, coating, secondary drying, shearing, stacking, packaging;In liquid spray and coating process In, using described bloom mf resin;The drying mode of low temperature high wind speed is adopted during described first drying and secondary drying.
Preferably, when the back of the body applies, resin bottom is first coated on the lower surface of decoration paper substrate;During impregnation, to decoration paper substrate The above and below of layer all carries out impregnation;During liquid spray, the upper surface only for decoration paper substrate is implemented, and decorates paper substrate when being coated with The above and below of layer is all implemented.
Preferably, the drying temperature adopting during described first drying and secondary drying is 125 ~ 138 DEG C;Dry wind Speed is the 90% of general dryer maximum wind velocity
Preferably, being modulated into point of described bloom mf resin includes virgin rubber, latent curing agent, penetrating agent, a releasing agent.
Preferably, in described bloom mf resin, the addition of latent curing agent was defined by hardening time, bloom mf tree The hardening time of fat be 4 points 30 seconds ~ 4 points 40 seconds;In described bloom mf resin, the addition of penetrating agent is the 0.2% of gross mass;Institute The addition stating releasing agent in bloom mf resin is also the 0.2% of gross mass.
Preferably, the quality of the composition of described virgin rubber and each composition is as follows:
Formaldehyde 1000kg;
Tripolycyanamide 850kg;
Water 450kg;
Sorbitol 100kg.
Preferably, the modulator approach of described virgin rubber includes:
1st, the Sorbitol of the formaldehyde of 1000kg, the water of 450kg, 75kg is mixed, and with the sodium hydroxide solution of content 30% ph Value is adjusted to 9.0 ~ 9.5;
2nd, heat up after the tripolycyanamide adding 850kg in above-mentioned mixed solution, be warming up to 90 ~ 92 DEG C and be incubated;During insulation Measurement ph value, if ph value less than 9.0, adjusts the now Acidity of Aikalinity of solution control ph value for 9.0;
3rd, the solution in insulating process is in the stage of reaction, measured once the ph value of now solution every 10 minutes, and keeps this When solution ph value be not less than 8.5, temperature retention time be 120 minutes;
4th, the solution after insulation is placed in reactor and is cooled to glue, determine water-soluble multiple when cooling and cloud point: putting During glue, water-soluble multiple is adjusted to 1:(1.5 ~ 1.6);When cooling, it is adjusted to Caustic soda terminating reaction and the ph value of glue 9.0~9.5;
5th, the glue obtaining the 4th step cools to after 60 DEG C, adds 25kg Sorbitol and stirs it is ensured that now glue Ph value be 9.0 ~ 9.5;
6th, the glue obtaining the 5th step is cooled to 40 DEG C and can blowing use.
The invention has the beneficial effects as follows: provide a kind of bloom spraying dipping paper and its production method, its formula is accurate, step Rationally, not only Storage period is long for prepared dipping paper out, and dipping paper is to the adaptability overlaying temperature when overlaying in the later stage Greatly.
Brief description
Fig. 1 is a kind of flow chart of present invention bloom spraying dipping paper production method;
Fig. 2 is the profile using this bloom spraying dipping paper production enhancement composite floor board.
Specific embodiment
Below in conjunction with the accompanying drawings presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention energy It is easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clearly defining.
The embodiment of the present invention includes:
A kind of bloom spraying dipping paper, including decoration paper substrate, resin bottom and wear-resisting compound tree lipid layer, resin surface layer;Resin Bottom is coated on the lower surface of described decoration paper substrate;The upper surface of decoration paper substrate coats wear-resisting compound tree lipid layer;Resistance to It is coated with resin surface layer in mill compound tree lipid layer;The composition of wherein wear-resisting compound tree lipid layer includes: carborundum, aluminium sesquioxide and Bloom mf resin.No longer overlay abrasion-proof paper using this bloom spraying dipping paper production enhancement composite floor board, so not only make floor The transparency on surface and definition are greatly improved, and also make the color and luster of printed decoration paper and pattern relatively sharp and true to nature, Because of the direct spraying composite of high abrasion on facing paper, the wear-resisting revolution of reinforced composite floorboard of production is greatly improved, and Other physical and chemical indexs are unaffected.
A kind of production method preparing above-mentioned bloom spraying dipping paper, its processing step includes successively: uncoiling, the back of the body apply, leaching Glue, liquid spray, put down, first drying, coating, secondary drying, shearing, stacking, packaging.Wherein, when the back of the body applies, resin bottom is first It is coated on the lower surface of decoration paper substrate;During impregnation, impregnation is all carried out to the above and below of decoration paper substrate;During liquid spray only Upper surface for decoration paper substrate is implemented, and the above and below decorating paper substrate when being coated with all is implemented.In liquid spray and coating During, using described bloom mf resin;The drying mode of low temperature high wind speed is adopted during first drying and secondary drying.Area Not in common conventional pickling process, the production method of this bloom spraying dipping paper is a kind of revolutionary dipping technique.Pass through Cement dipping machine carries out to general decor paper carrying on the back painting gluing, impregnation, liquid spray, coating so that the lower surface of decoration paper substrate scribbles Resin bottom, the upper surface of decoration paper substrate scribbles wear-resisting compound tree lipid layer, resin surface layer, wear-resisting compound tree from bottom to up successively Lipid layer is mixed with melmac by the ceramic material of the high-wearing features such as carborundum, aluminium sesquioxide and forms.
The temperature that first drying and secondary drying are adopted and wind speed are also different, and conventional impregnation uses the low wind speed of high temperature Technique, and in this production method, use low temperature high wind speed drying curve.Its contrast is as follows:
Being modulated into point of bloom mf resin includes virgin rubber, latent curing agent, penetrating agent, a releasing agent.The adding of latent curing agent Dosage was defined by hardening time, hardening time of bloom mf resin be 4 points 30 seconds ~ 4 points 40 seconds, penetrating agent in bloom mf resin Addition is the 0.2% of gross mass, and in bloom mf resin, the addition of releasing agent is also the 0.2% of gross mass.Latent curing agent The ca010 latent curing agent developed from our company 2013 annual proper motions, reaches the effect of higher latency.This latency is solid Agent is used for impregnating the production of paper, is not only greatly improved the Storage period of dipping paper, and dipping paper is to pressure when overlaying in the later stage The adaptability of patch temperature greatly enhances.
The quality of the composition of virgin rubber and each composition is as follows:
Formaldehyde 1000kg;
Tripolycyanamide 850kg;
Water 450kg;
Sorbitol 100kg.
Virgin rubber is modulated according to above-mentioned each composition quality, its modulator approach includes:
1st, the Sorbitol of the formaldehyde of 1000kg, the water of 450kg, 75kg is mixed, and with the sodium hydroxide solution of content 30% ph Value is adjusted to 9.0 ~ 9.5;
2nd, heat up after the tripolycyanamide adding 850kg in above-mentioned mixed solution, be warming up to 90 ~ 92 DEG C and be incubated;During insulation Measurement ph value, if ph value less than 9.0, adjusts the now Acidity of Aikalinity of solution control ph value for 9.0;
3rd, the solution in insulating process is in the stage of reaction, measured once the ph value of now solution every 10 minutes, and keeps this When solution ph value be not less than 8.5, temperature retention time be 120 minutes;
4th, the solution after insulation is placed in reactor and is cooled to glue, determine water-soluble multiple when cooling and cloud point: putting During glue, water-soluble multiple is adjusted to 1:(1.5 ~ 1.6);When cooling, it is adjusted to Caustic soda terminating reaction and the ph value of glue 9.0~9.5;
5th, the glue obtaining the 4th step cools to after 60 DEG C, adds 25kg Sorbitol and stirs it is ensured that now glue Ph value be 9.0 ~ 9.5;
6th, the glue obtaining the 5th step is cooled to 40 DEG C and can blowing use.
130 ~ 140%, 5.0 ~ 5.5%, procuring degree is 55 ~ 70% for fugitive constituent for the spread of this virgin rubber.
This bloom spraying dipping paper solves the requirement on user's high gloss floor, and other indexs of the floor of extrusion meet Gb/t 18102-2007(" impregnated paper laminated wood floor " GB) require;
This bloom spraying dipping paper spread is 220-240%, and volatilization is divided into 6.5-7.2%, and procuring degree is 40-50%, and other refer to Reference symbol closes gb/t28995-2012(" wood-based plate dedicated paper " GB) regulation.
The foregoing is only embodiments of the invention, not thereby limit the present invention the scope of the claims, every using this Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (8)

1. a kind of bloom spraying dipping paper it is characterised in that: include decoration paper substrate, resin bottom and wear-resisting compound tree lipid layer, Resin surface layer;The lower surface of described decoration paper substrate is provided with described resin bottom;The upper surface of described decoration paper substrate is provided with institute State wear-resisting compound tree lipid layer;Wear-resisting compound tree lipid layer is coated with resin surface layer;The one-tenth of wherein said wear-resisting compound tree lipid layer Divide and include: carborundum, aluminium sesquioxide and bloom mf resin.
2. a kind of production method of the bloom spraying dipping paper prepared described in claim 1 it is characterised in that: its processing step Include successively: uncoiling, the back of the body painting, impregnation, liquid spray, put down, first drying, coating, secondary drying, shearing, stacking, packaging; In liquid spray with coating process, using described bloom mf resin;Adopt low during described first drying and secondary drying The drying mode of warm high wind speed.
3. a kind of bloom spraying dipping paper according to claim 2 and its production method it is characterised in that: when the back of the body applies, tree Fat bottom is first coated on the lower surface of decoration paper substrate;During impregnation, impregnation is all carried out to the above and below of decoration paper substrate;Liquid During spraying, the upper surface only for decoration paper substrate is implemented, and the above and below decorating paper substrate when being coated with all is implemented.
4. a kind of bloom spraying dipping paper according to claim 2 production method it is characterised in that: described first drying It is 125 ~ 138 DEG C with the drying temperature adopting during secondary drying;Dry wind speed for the 90% of general dryer maximum wind velocity.
5. a kind of bloom spraying dipping paper as claimed in any of claims 1 to 4 and its production method, its feature exists Point include virgin rubber, latent curing agent, penetrating agent, a releasing agent in being modulated into of: described bloom mf resin.
6. a kind of bloom spraying dipping paper according to claim 3 and its production method it is characterised in that: described bloom mf In resin, the addition of latent curing agent was defined by hardening time, and the hardening time of bloom mf resin is 4 points 30 seconds ~ 4 point 40 Second;In described bloom mf resin, the addition of penetrating agent is the 0.2% of gross mass;The interpolation of releasing agent in described bloom mf resin Amount is also the 0.2% of gross mass.
7. a kind of bloom spraying dipping paper according to claim 3 and its production method it is characterised in that: described virgin rubber The quality of composition and each composition is as follows:
Formaldehyde 1000kg;
Tripolycyanamide 850kg;
Water 450kg;
Sorbitol 100kg.
8. a kind of bloom spraying dipping paper according to claim 4 and its production method it is characterised in that: described virgin rubber Modulator approach includes:
1st, the Sorbitol of the formaldehyde of 1000kg, the water of 450kg, 75kg is mixed, and with the sodium hydroxide solution of content 30% ph Value is adjusted to 9.0 ~ 9.5;
2nd, heat up after the tripolycyanamide adding 850kg in above-mentioned mixed solution, be warming up to 90 ~ 92 DEG C and be incubated;During insulation Measurement ph value, if ph value less than 9.0, adjusts the now Acidity of Aikalinity of solution control ph value for 9.0;
3rd, the solution in insulating process is in the stage of reaction, measured once the ph value of now solution every 10 minutes, and keeps this When solution ph value be not less than 8.5, temperature retention time be 120 minutes;
4th, the solution after insulation is placed in reactor and is cooled to glue, determine water-soluble multiple when cooling and cloud point: putting During glue, water-soluble multiple is adjusted to 1:(1.5 ~ 1.6);When cooling, it is adjusted to Caustic soda terminating reaction and the ph value of glue 9.0~9.5;
5th, the glue obtaining the 4th step cools to after 60 DEG C, adds 25kg Sorbitol and stirs it is ensured that now glue Ph value be 9.0 ~ 9.5;
6th, the glue obtaining the 5th step is cooled to 40 DEG C and can blowing use.
CN201610753529.XA 2016-08-29 2016-08-29 High-glossiness spraying impregnation paper and production method thereof Pending CN106368083A (en)

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Application Number Priority Date Filing Date Title
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385996A (en) * 2017-08-10 2017-11-24 浙江宜佳新材料股份有限公司 A kind of production technology of the short cycle dipping paper of hot pressing
CN108486959A (en) * 2018-03-27 2018-09-04 江苏建丰装饰纸有限公司 The preparation method of resistance to cigarette calcination facing paper
CN108486952A (en) * 2018-03-27 2018-09-04 江苏建丰装饰纸有限公司 The preparation method of resistance to cracking wear-resistant decorative paper
CN108560313A (en) * 2018-03-27 2018-09-21 江苏建丰装饰纸有限公司 The preparation method of wet-heat resisting wear-resistant decorative paper
CN108867193A (en) * 2017-05-10 2018-11-23 中国林业科学研究院林业新技术研究所 A kind of environment-friendly type applied decorative paper and preparation method thereof
CN109403139A (en) * 2018-11-08 2019-03-01 河北盛林装饰纸有限公司 A kind of production method of impregnating resin and bloom impregnated bond paper
CN114164712A (en) * 2021-12-21 2022-03-11 湖北鸿连实业有限公司 Preparation method of spray paper
CN114182575A (en) * 2021-12-09 2022-03-15 华电电力科学研究院有限公司 Wear-resistant paper, preparation method thereof and floor

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CN202055113U (en) * 2011-03-04 2011-11-30 苏州市建诚装饰材料有限公司 Abrasion resistant paper impregnated thermosetting resins
CN103911916A (en) * 2014-03-28 2014-07-09 苏州市建诚装饰材料有限公司 Wear-resistant scratch-resistant impregnated paper
CN103910843A (en) * 2014-03-28 2014-07-09 苏州市建诚装饰材料有限公司 Formula and preparation method of resin for primary impregnation
CN103911906A (en) * 2014-03-28 2014-07-09 苏州市建诚装饰材料有限公司 Method for manufacturing pearl bond paper through dipping, spraying and coating

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202055113U (en) * 2011-03-04 2011-11-30 苏州市建诚装饰材料有限公司 Abrasion resistant paper impregnated thermosetting resins
CN103911916A (en) * 2014-03-28 2014-07-09 苏州市建诚装饰材料有限公司 Wear-resistant scratch-resistant impregnated paper
CN103910843A (en) * 2014-03-28 2014-07-09 苏州市建诚装饰材料有限公司 Formula and preparation method of resin for primary impregnation
CN103911906A (en) * 2014-03-28 2014-07-09 苏州市建诚装饰材料有限公司 Method for manufacturing pearl bond paper through dipping, spraying and coating

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108867193A (en) * 2017-05-10 2018-11-23 中国林业科学研究院林业新技术研究所 A kind of environment-friendly type applied decorative paper and preparation method thereof
CN107385996A (en) * 2017-08-10 2017-11-24 浙江宜佳新材料股份有限公司 A kind of production technology of the short cycle dipping paper of hot pressing
CN108486959A (en) * 2018-03-27 2018-09-04 江苏建丰装饰纸有限公司 The preparation method of resistance to cigarette calcination facing paper
CN108486952A (en) * 2018-03-27 2018-09-04 江苏建丰装饰纸有限公司 The preparation method of resistance to cracking wear-resistant decorative paper
CN108560313A (en) * 2018-03-27 2018-09-21 江苏建丰装饰纸有限公司 The preparation method of wet-heat resisting wear-resistant decorative paper
CN109403139A (en) * 2018-11-08 2019-03-01 河北盛林装饰纸有限公司 A kind of production method of impregnating resin and bloom impregnated bond paper
CN114182575A (en) * 2021-12-09 2022-03-15 华电电力科学研究院有限公司 Wear-resistant paper, preparation method thereof and floor
CN114182575B (en) * 2021-12-09 2022-10-21 华电电力科学研究院有限公司 Wear-resistant paper, preparation method thereof and floor
CN114164712A (en) * 2021-12-21 2022-03-11 湖北鸿连实业有限公司 Preparation method of spray paper
CN114164712B (en) * 2021-12-21 2023-02-10 湖北鸿连实业有限公司 Preparation method of spray paper

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