CN106368021A - Digital spray printing method for nylon-spandex swimming suit fabric - Google Patents

Digital spray printing method for nylon-spandex swimming suit fabric Download PDF

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Publication number
CN106368021A
CN106368021A CN201610763503.3A CN201610763503A CN106368021A CN 106368021 A CN106368021 A CN 106368021A CN 201610763503 A CN201610763503 A CN 201610763503A CN 106368021 A CN106368021 A CN 106368021A
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China
Prior art keywords
fabric
spray printing
printing method
swimming suit
digital spray
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Pending
Application number
CN201610763503.3A
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Chinese (zh)
Inventor
付春林
王�忠
孔令豪
常向真
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HOSA INDUSTRIAL (FUJIAN) Co Ltd
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HOSA INDUSTRIAL (FUJIAN) Co Ltd
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Priority to CN201610763503.3A priority Critical patent/CN106368021A/en
Publication of CN106368021A publication Critical patent/CN106368021A/en
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    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/78—Neutral esters of acids of phosphorus
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

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  • Wood Science & Technology (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
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Abstract

The invention discloses a digital spray printing method for a nylon-spandex swimming suit fabric. The method comprises the following steps: removing oil, modifying, sizing, performing spray printing, ageing, washing and drying, wherein low-temperature plasma treatment is performed during modifying; the sizing solution comprises the first treatment size containing cationic quaternary ammonium salts, a pH fluorescent probe and the second treatment size; steaming is performed under humidity saturation after spray printing; reaction endpoint is reached when fabric surface fibers present orange red fluorescence; insoluble color lakes are deposited inside and outside the fibers through the cationic quaternary ammonium salts, the dyes are coated on the fibers, and the color lakes can be reacted with available chlorine on the dyes so as to achieve high chlorine-resistant fastness. The first treatment size is combined with the low-temperature plasma treatment, so that the coloring effect and fixation rate of the fabric are improved, and the bleeding resistance is high; the clear outline of the flower type is improved by the second treatment size; the steaming reaction endpoint is accurately controlled by the pH fluorescent probe; a full coloring rate of the fabric is guaranteed, bleeding can be avoided, and the fabric is clear in outline and high in printing precision.

Description

The digital spray printing method of bright and beautiful ammonia swimming suit fabric
Technical field
The present invention relates to dope dyeing technical field, more particularly to a kind of digital spray printing method of brocade ammonia swimming suit fabric.
Background technology
Ink-jet printed, also known as digit printing, it is the stamp being carried out with digital technology, ink-jet printed production process is simply Say to be exactly by various digitized means such as: the various digitized patterns that scanning, digital photo, image or computing mechanism deal with Input computer, then by the process of computer color splitting printing system after, by special rip software by will be various to its sprayed printed system Dedicated dye (activity, dispersion, acid main coating) directly spray printing on various fabrics or other medium, then through processing Afterwards, required various high-precision Printing is obtained on various weaving face fabrics, have following several compared with traditional dyeing and finishing technique The advantage of individual aspect:
1. ink-jet printed production process makes original process route greatly shorten, and has broken away from Conventional decal and has divided in process of production Color retouches original text, film-making, network process processed, and order speed is fast, and cost of drawing a design substantially reduces.
2. the principle of ink-jet printed technology makes the set normal complexion that its product has broken traditional mode of production spend back the restriction of length, can So that weaving face fabric realizes the printing effect of high-grade printing, the pattern of Conventional decal suffers from the restriction of " spending back " length, and Can not there is the concept of " spending back ", thus being greatly expanded the sky of Textile Pattern Design in ink-jet printed technical process Between, improve the class of product.
3. ink-jet printed production is truly realized the production process of small lot, fast response, and production lot is unrestricted.
In the prior art, the direct-injection stamp of textile must carry out pre-treatment starching to textile before requiring stamp, on The purpose of slurry is to be coated with one layer of ink-jet ink absorbed layer on the surface of textile, and needed for dye fiber on the dyestuff being added thereto The chemical assistant wanted.But, current sizing technique can not accomplish existing certain viscosity, adsorbs ink, it is to avoid ink outline Fuzzy, again can be with fabric to be contaminated association reaction well, it is to avoid dyestuff imbibition, strengthen color fastness, and can not judge well Evaporate the reaction end of colour developing, or leading to fabric tinctorial yield not enough, or producing bleeding obfuscation, especially for the swimming of bright and beautiful ammonia Clothing blended yarn weaved fabric.
Content of the invention
For the technological deficiency overcoming prior art to exist, the digital spray printing method of the bright and beautiful ammonia swimming suit fabric of present invention offer, carry The tinctorial yield of high brocade polyurethane fabric and color fastness, printed mark is clearly full, and high chlorine-resistant.
The technical solution that the present invention adopts is:
The digital spray printing method of bright and beautiful ammonia swimming suit fabric, concrete steps include:
Step one, oil removing: by fabric addition temperature be 65 DEG C～85 DEG C containing degreaser, refining agent and soda except oil solution In carry out oil removal treatment, bath raio be (10～15): 1, oil removing solution ph be 6～7；
Step 2, modified: the fabric after oil removing is dried carries out low-temperature plasma process；
Step 3, starching: include an immersing and rolling two and apply three bakings, specially first included have cationic quaternary amine first process Serosity pads, and pick-up controls 45%～65%, and after drying for the first time, on the first pulp layer surface of fabric, coating ph fluorescence is visited Pin, coating weight is 1g～2g/m2, then carry out second drying and coat second processing serosity in ph fluorescent probe layer surface again, Ph value is 6～7, and coating weight is 3g～5g/m2, then pull up width machine shaping and drying；
Step 4, spray printing: make mimeograph documents, using the second pulp layer table of the fabric to after process through step 3 for the Numerical Control Printer Face direct-injection acid dye ink is simultaneously dried；
Step 5, evaporates: decatize under moisture-saturated, and temperature is 100 DEG C～105 DEG C, is presented orange red with fabric surface fibre Fluorescence is reaction end；
Step 6, washing: be first impregnated with the fabric after processing through step 5 with cold water, then clean 8min with 70 DEG C～80 DEG C of hot water ～10min, then soap in 80 DEG C of liquid of soaping 15min～10min, is then cleaned with 30 DEG C～50 DEG C warm water, finally with cold Water rinsed clean；
Step 7, drying and shaping, dried with stenter, 90 DEG C～130 DEG C of temperature, speed 20m～40m/min, aridity controls Within 20%.
Beneficial effect using technique scheme:
1. the oil preparation on fabric is removed by deoiling step, reduce the dyeing kimonos of impact fabric when oil preparation is painted on follow-up spray printing With performance, as colour brightness, chromatic light deviation, dye uniformity, color flower, easily cause mottle white point；
2. utilize the high response of low temperature plasma, introduce hydrophilic group (such as-oh, so in fiber surface3H ,-cooh) and right Dyestuff has the group of affinity, using the high activity of low temperature plasma, generates free radical in fiber surface, thus causing list Body, in fiber surface glycerol polymerization, makes fiber surface grafting above and dyestuff has the group (as acrylic monomer) of affinity, Using the etching action of cold-plasma surfaces treated, so that textile surface is roughened, reduce the surface reflection to light, increase Absorption to dyestuff, improves Apparent Depth and the dyeing concentration of dyed fabric, and the etching action of plasma makes fiber surface thick Roughening, after overetch, the increase of fabric specific surface area causes fabric hydrophilic and the increase of dyestuff through-dyeing.
3. the fabric after the cationic quaternary plasma of the present invention is processed is arranged, can be with fiber surface Hydrophilic group and there is hydrophilic Interaction of substituents to dyestuff, and the positive charge that has of quaternary ammonium salt is tied with dyestuff Anionic group ionic bond in structure combines, and forms insoluble color lake and is deposited on inside and outside fiber, being printed after quaternary ammonium salt treatment In drying course, the reactive crosslinked group on its molecule is voluntarily cross-linked into macromole to fabric, thus coating dye in fibre In dimension, make dyestuff difficult for drop-off, the building stone of the close dyestuff on quaternary ammonium salt, it is allowed to be formed hydrogen bond and Van der Waals and dyestuff between Power, thus lifting the binding strength of dyestuff and fiber, and can be reacted with effective chlorine prior to dyestuff, so that dye molecule avoids dropping Solution and destruction, reach the effect of high color fastness to chlorine.
4., because the slurry of the present invention adopts separate operations, process serosity by first and make with reference to low-temperature plasma process Fabric color effect and degree of fixation higher, there is the effect of anti-bleeding well, air brushing adsorbed at it by second processing serosity On ink-jet ink, be allowed to become sticky, improve flower pattern contour sharpness, greatly improve percentage of A-class goods during stamp；And ph Fluorescent probe is to process between serosity and second processing serosity first, on the one hand ensures that ph fluorescent probe does not interfere with acidity Absorption on second processing serosity top layer for the dye ink and stamp, on the other hand ensure that ph fluorescent probe will not before and after spray printing Come off displacement and have influence on the judgement that the later stage evaporates reaction end.
5.ph fluorescent probe has extraordinary water solublity, its fluorescence response highly significant after ph is less than 6, high score simultaneously Sub- ph fluorescent probe can hot melt soften at 110 DEG C, migrates and adsorbs on cotton fiber surface, it is possible in steaming procedure Easily the web surface extent of reaction is tracked monitoring.Web surface when being evaporated by the monitoring of this ph fluorescent probe Ph value just can easily determine whether reaction can terminate in real time, thus accurately control evaporating reaction end, has both ensured fabric Sufficiently, can not bleeding, clear-cut, stamp precision is good again in color yield.
Preferably, described include following component: 25%～35% soda by weight percentage except oil solution, 8%～15% essence Refining agent tf-109,15%～25% oil base amine polyoxyethylene ether, 5%～10% alpha-olefin sodium sulfonate, 8%～15% lauryl sulphate acid Sodium, 15%～18% aliphatic alcohol polyoxyvinethene phosphate sodium.
Beneficial effect using this preferred version: because oil base amine polyoxyethylene ether is nonionic surfactant, it is special Different fatty amine oleophylic based structures have stronger affinity to various oil preparationes, greasy dirt, therefore oil preparation, greasy dirt are shown well Emulsifying, washing, decontamination and peptizaiton；Due to alpha-olefin sodium sulfonate, sodium lauryl sulphate, fatty alcohol-polyoxyethylene ether phosphorus Acid esters sodium is anion surfactant, have good infiltration, emulsifying and a peptizaiton, therefore to greasy dirt, solid spot Removal ability is also very strong.Using anion surfactant and nonionic surfactant combinations, due to the surface tension of solution Lower when being used alone than both, therefore show higher surface activity.
Preferably, described low-temperature plasma processes and carries out surface modification using discharge plasma processing meanss to fabric, Discharge plasma processing meanss include two pieces of sparking electrodes, and two pieces of sparking electrodes embed the spacing in block media, between pole plate For 5cm, plasma working gas are o2, processing power is 50w～70w, and process time is 3min～8min.
Preferably, described first process serosity includes following component: 2%～4% tamarind gum by weight percentage, 2%～ 6% guar gum, 2.5%～3% rare earth chloride, 1%～2% sodium chloride, 0.5%～1% carboxymethyl cellulose, 2%～4% kieselguhr, 5%～ 10% cationic quaternary amine, balance of water.
Beneficial effect using this preferred version: the tamarind gum of the present invention and guar gum and carboxymethyl cellulose are in tool Have substantially anti-imbibition effect while additionally it is possible to stable, the synergism that so that its imbibition rate is changed near critical concentration value, can Effectively prevent pigment from producing diffusion with the capillary motion between fibre bundle, thus causing profile unintelligible, border is indefinite Problem, and high colour-fast rate and get Se effect can be reached while there is preferably anti-imbibition effect, and certain content chlorine The addition changing rare earth can promote to improve the degree of fixation of dyestuff.
Preferably, described second processing serosity includes following component: 15%～20% sodium alginate by weight percentage, 10%～15% etherification starch, 50%～60% dimethylformamide, 1%～2% hydroxypropyl cellulose, 2%～4% polyethylene pyrrole network alkane Ketone, 5%～15% glycerol, 2%～5% malic acid.
Beneficial effect using this preferred version: the effect of hydroxypropyl cellulose therein and polyethylene pyrrole network alkanone makes Second processing serosity assumes certain viscosity so that second processing serosity can smoothly be coated on ph fluorescent probe surface, and Two process serosity for second processing serosity can be made during liquid to keep certain viscosity, to avoid sodium alginate and etherification starch suspended Liquid aggregate and precipitate, and then become the binding agent of sodium alginate and etherification starch after the drying, sodium alginate and etherification starch are glued It is attached to the surface of the first process serosity and ph fluorescent probe, prevent from coming off.Due to the sodium alginate of the present invention and etherification starch because For not dissolving, it is uniformly suspended in molecule in the second processing serosity of the present invention only by grinding, can be big Improve greatly the content of sodium alginate and etherification starch in second processing serosity, so can substantially reduce starching amount, and ensure to make Ink-jet printed contour sharpness and surface tinctorial yield improve, the ink absorption amount of lifting direct-injection stamp is so that deep heavy colour simultaneously Can be achieved in the direct-injection stamp of bright and beautiful ammonia swimming suit fabric.
Preferably, the structural formula of described ph fluorescent probe is:
Wherein, n=6, x=317, y=39, z=25.
Preferably, described acid dye ink includes following component: 2%～10% acid stain by weight percentage, 0.5%～10% Polyvinylpyrrolidone, 5.0%～20% 1，2-ethandiol, 0.2%～5% tri ethylene glycol ethyl ether, 0.1%～2% 3 Ethanolamine, 0.1%～1% MIT, balance of deionized water.This acid dye ink may be used on Minute-pressure electricity, heat foamable printer；Quality stability by force can long-time storage, can be used for the materials such as real silk, Pilus Caprae seu Oviss, chinlon, leather Dyeing, and light fastness, washing fastness, crock fastness all can reach compared with high-tech require.
Preferably, comprise in described every liter liquid of soaping the disodium hydrogen phosphate of 2g～4g, the modified tea saponin of 3g～5g and The chlorine-resistant color fixing agent of 3g～5g.
Beneficial effect using this preferred version: chlorine-resistant color fixing agent of the present invention be cationic compound, can with dyestuff in Anionic reactive generates color lake, is deposited on fiber surface；The cross-linking reaction group of the color fixing agent of the present invention not only can be divided with dyestuff Some radical reactions in son, and energy and fibrin reaction, by forming polynary interconnected system, can effectively improve dyestuff Soaping fastness.Additionally, the imino group in product encloses chloride ion on dyestuff, greatly improve the chlorine resistance of product dyed thereby.? After fixation bakes process, various group crosslinking condensation in resin, define solid netted thin polymer film in fiber surface, Can effective organizational environment impact, the properties of lifting product dyed thereby.
The preparation method of ph fluorescent probe of the present invention, including following step:
1) by rhodamine b and hydration hydrazine reaction, rhodamine lactams are obtained: add rhodamine b in 100ml round-bottomed flask (2.4g, 5.01mmol) and 40ml dehydrated alcohol, then it is slowly added dropwise the hydrazine hydrate that 7ml mass fraction is 85% in round-bottomed flask (excessive), and start stirring at room temperature.After completion of dropping, under the conditions of 80 DEG C, reactant liquor is heated to reflux 2h.Reflux course In, solution gradually becomes the light orange of clear by darkviolet.After solution cooling, distillation removes etoh solvent.Then to Add the 1mol/lhcl of about 40ml in solid, dissolve to obtain red, transparent liquid, then it is molten to be slowly added dropwise 1mol/lnaoh in solution Liquid (about 50ml), and be stirred continuously, adjusting ph is 9～10, constantly separates out a large amount of white solids in period solution.Sucking filtration, with steaming Distilled water is washed till filtrate bleach.By dry for solid pink solid, i.e. compound 1 rhodamine lactams.
2) synthesis of the monomer of rhodamine group: add 0.912g (2mmol) compound 1 Luo Dan in 50ml there-necked flask Bright lactams, after the dissolving of 5ml oxolane, ice bath.0.2g (2.2mmol) acryloyl chloride is dissolved in 5ml oxolane, slowly It is added drop-wise in there-necked flask, continue room temperature reaction 6 hours.After reaction terminates, filter precipitation, be washed till filtrate with oxolane and become no Color, through distilling, purifying, be dried to obtain pink solid, i.e. the monomer of compound 2 rhodamine group, its structural formula is as follows:
3) synthesis of macromolecule ph fluorescent probe pdbar: in 50ml there-necked flask add 0.3256g rhodamine monomer, 2.0531g acrylamide monomer, 0.9690g n-butyl acrylate monomer and 0.3500g methylacryoyloxyethyl trimethyl chlorine Change ammonium monomer, be dissolved in the Ketohexamethylene of 30ml.Dissolving adds initiator aibn (addition is the 2% about of total amount) completely afterwards, Dissolving is completely.System evacuation, is filled with nitrogen.70 DEG C of aqueous solution reacts 3.5 hours, until occurring a large amount of in reaction bulb Terminate reaction after solid or the increase of reaction liquid viscosity.Reactant liquor is poured slowly into a large amount of dichloromethane, petroleum ether and ether volume Ratio separates out polymeric solid in the mixed solvent for 1:3:5.The solid of precipitation is filtered and is re-dissolved in a small amount of ether, then delay Slowly pour in substantial amounts of petroleum ether and separate out, sucking filtration obtains pure macromolecule product pdbar.
The synthetic method of the chlorine-resistant color fixing agent of the present invention, comprises the steps: 1) by the epoxychloropropane of 50-80g, 80- The diethylenetriamine of 110g, 80-110g diallylamine add equipped with mix and blend in the round-bottomed flask of water knockout drum and condensing tube It is heated to the water yield in 45-55 DEG C, and water knockout drum not to be further added by；2) temperature is heated to 55-70 DEG C, adds in reaction system 3.3-3.85g oxidizing agent solution and 3.3-3.85g reductant solution, after 25-40min by 29.7-34.65g oxidizing agent solution and 29.7-34.65g reductant solution Deca 2.5-3.5h at 70-95 DEG C, reaction terminates；3), after reaction terminates, use hydrogen peroxide Solution is bleached to product, obtains final product color fixing agent.
Specific embodiment
Embodiment one:
The present embodiment provides a kind of digital spray printing method of brocade ammonia swimming suit fabric, and concrete steps include:
Step one, oil removing: by fabric addition temperature be 65 DEG C～70 DEG C containing degreaser, refining agent and soda except oil solution In carry out oil removal treatment, bath raio be 12: 1, oil removing solution ph be 6～7.In the present embodiment, described except oil solution by weight Percentages include following component: 25% soda, 15% refining agent tf-109,23% oil base amine polyoxyethylene ether, 10% alpha-olefin sulphur Sour sodium, 12% sodium lauryl sulphate, 15% aliphatic alcohol polyoxyvinethene phosphate sodium.
Step 2, modified: the fabric after oil removing is dried carries out low-temperature plasma process, described low-temperature plasma processes and adopts With discharge plasma processing meanss, fabric is carried out with surface modification, discharge plasma processing meanss include two blocks of electric discharge electricity Pole, two pieces of sparking electrodes embed in block media, and the spacing between pole plate is 5cm, and plasma working gas are o2, processing power is 70w, process time is 3min.
Step 3, starching: include an immersing and rolling two and apply three bakings, specially first included have the first of cationic quaternary amine Process serosity to pad, pick-up controls 45%～50%, after drying for the first time, on the first pulp layer surface of fabric, coating ph is glimmering Light probe, coating weight is 1.0g～1.5g/m2, then carry out second drying again at ph fluorescent probe layer surface coating second Reason serosity, ph value is 6～7, and coating weight is 3g～4g/m2, then pull up width machine shaping and drying.
In the present embodiment, described first process serosity includes following component: 2% tamarind gum by weight percentage, and 5% Guar gum, 3% rare earth chloride, 1.5% sodium chloride, 1% carboxymethyl cellulose, 2% kieselguhr, 8% cationic quaternary amine, balance of Water.
In the present embodiment, described second processing serosity includes following component: 15% sodium alginate by weight percentage, 10% etherification starch, 57% dimethylformamide, 2% hydroxypropyl cellulose, 3% polyethylene pyrrole network alkanone, 10% glycerol, 3% malic acid.
In the present embodiment, the structural formula of described ph fluorescent probe is:
Wherein, n=6, x=317, y=39, z=25.
Step 4, spray printing: make mimeograph documents, using the second slurry of the fabric to after process through step 3 for the Numerical Control Printer Layer surface direct-injection acid dye ink is simultaneously dried.In the present embodiment, described acid dye ink includes by weight percentage Following component: 10% acid stain, 8% Polyvinylpyrrolidone, 10% 1，2-ethandiol, 5% tri ethylene glycol ethyl ether, 1% 3 ethanol Amine, 0.8% MIT, balance of deionized water.
Step 5, evaporates: decatize under moisture-saturated, and temperature is 100 DEG C～105 DEG C, assumes orange with fabric surface fibre Red fluorescence is reaction end；
Step 6, washing: be first impregnated with the fabric after processing through step 5 with cold water, then clean 8min with 70 DEG C～80 DEG C of hot water ～10min, then soap in 80 DEG C of liquid of soaping 15min～10min, is then cleaned with 30 DEG C～50 DEG C warm water, finally with cold Water rinsed clean.In the present embodiment, comprise in described every liter liquid of soaping the disodium hydrogen phosphate of 2g, the modified tea saponin of 5g and The chlorine-resistant color fixing agent of 5g.
Step 7, drying and shaping, dried with stenter, 90 DEG C～130 DEG C of temperature, speed 20m～40m/min, aridity Control within 20%.
Embodiment two:
The present embodiment provides a kind of digital spray printing method of brocade ammonia swimming suit fabric, and concrete steps include:
Step one, oil removing: by fabric addition temperature be 70 DEG C～80 DEG C containing degreaser, refining agent and soda except oil solution In carry out oil removal treatment, bath raio be 15: 1, oil removing solution ph be 6～7.In the present embodiment, described except oil solution by weight Percentages include following component: 30% soda, 10% refining agent tf-109,20% oil base amine polyoxyethylene ether, 8% alpha-olefin sulfonic acid Sodium, 15% sodium lauryl sulphate, 17% aliphatic alcohol polyoxyvinethene phosphate sodium.
Step 2, modified: the fabric after oil removing is dried carries out low-temperature plasma process, described low-temperature plasma processes and adopts With discharge plasma processing meanss, fabric is carried out with surface modification, discharge plasma processing meanss include two blocks of electric discharge electricity Pole, two pieces of sparking electrodes embed in block media, and the spacing between pole plate is 5cm, and plasma working gas are o2, processing power is 60w, process time is 5min.
Step 3, starching: include an immersing and rolling two and apply three bakings, specially first included have the first of cationic quaternary amine Process serosity to pad, pick-up controls 55%～65%, after drying for the first time, on the first pulp layer surface of fabric, coating ph is glimmering Light probe, coating weight is 1.5g～2g/m2, then carry out second drying and coat second processing in ph fluorescent probe layer surface again Serosity, ph value is 6～7, and coating weight is 3g～4g/m2, then pull up width machine shaping and drying.
In the present embodiment, described first process serosity includes following component: 4% tamarind gum by weight percentage, and 6% Guar gum, 2.5% rare earth chloride, 2% sodium chloride, 0.5% carboxymethyl cellulose, 3% kieselguhr, 10% cationic quaternary amine, surplus For water.
In the present embodiment, described second processing serosity includes following component: 15% sodium alginate by weight percentage, 14% etherification starch, 60% dimethylformamide, 1.5% hydroxypropyl cellulose, 2.5% polyethylene pyrrole network alkanone, 5% glycerol, 2% Herba Marsileae Quadrifoliae Fruit acid.
In the present embodiment, the structural formula of described ph fluorescent probe is:
Wherein, n=6, x=317, y=39, z=25.
Step 4, spray printing: make mimeograph documents, using the second slurry of the fabric to after process through step 3 for the Numerical Control Printer Layer surface direct-injection acid dye ink is simultaneously dried.In the present embodiment, described acid dye ink includes by weight percentage Following component: 8% acid stain, 5% Polyvinylpyrrolidone, 15% 1，2-ethandiol, 2.5% tri ethylene glycol ethyl ether, 2% 3 second Hydramine, 1% MIT, balance of deionized water.
Step 5, evaporates: decatize under moisture-saturated, and temperature is 100 DEG C～105 DEG C, assumes orange with fabric surface fibre Red fluorescence is reaction end；
Step 6, washing: be first impregnated with the fabric after processing through step 5 with cold water, then clean 8min with 70 DEG C～80 DEG C of hot water ～10min, then soap in 80 DEG C of liquid of soaping 15min～10min, is then cleaned with 30 DEG C～50 DEG C warm water, finally with cold Water rinsed clean.In the present embodiment, comprise in described every liter liquid of soaping the disodium hydrogen phosphate of 4g, the modified tea saponin of 3g and The chlorine-resistant color fixing agent of 3g.
Step 7, drying and shaping, dried with stenter, 90 DEG C～130 DEG C of temperature, speed 20m～40m/min, aridity Control within 20%.
Embodiment three:
The present embodiment provides a kind of digital spray printing method of brocade ammonia swimming suit fabric, and concrete steps include:
Step one, oil removing: by fabric addition temperature be 70 DEG C～80 DEG C containing degreaser, refining agent and soda except oil solution In carry out oil removal treatment, bath raio be 10: 1, oil removing solution ph be 6～7.In the present embodiment, described except oil solution by weight Percentages include following component: 35% soda, 8% refining agent tf-109,22% oil base amine polyoxyethylene ether, 10% alpha-olefin sulphur Sour sodium, 8% sodium lauryl sulphate, 17% aliphatic alcohol polyoxyvinethene phosphate sodium.
Step 2, modified: the fabric after oil removing is dried carries out low-temperature plasma process, described low-temperature plasma processes and adopts With discharge plasma processing meanss, fabric is carried out with surface modification, discharge plasma processing meanss include two blocks of electric discharge electricity Pole, two pieces of sparking electrodes embed in block media, and the spacing between pole plate is 5cm, and plasma working gas are o2, processing power is 50w, process time is 8min.
Step 3, starching: include an immersing and rolling two and apply three bakings, specially first included have the first of cationic quaternary amine Process serosity to pad, pick-up controls 50%～55%, after drying for the first time, on the first pulp layer surface of fabric, coating ph is glimmering Light probe, coating weight is 1.0～1.5g/m2, then carry out second drying again at ph fluorescent probe layer surface coating second Reason serosity, ph value is 6～7, and coating weight is 4g～5g/m2, then pull up width machine shaping and drying.
In the present embodiment, described first process serosity includes following component: 3% tamarind gum by weight percentage, 6% guar gum, 3% rare earth chloride, 1% sodium chloride, 1% carboxymethyl cellulose, 4% kieselguhr, 5% cationic quaternary amine, surplus For water.
In the present embodiment, described second processing serosity includes following component: 18% sodium alginate by weight percentage, 12% etherification starch, 55% dimethylformamide, 1.5% hydroxypropyl cellulose, 2.5% polyethylene pyrrole network alkanone, 8% glycerol, 3% Fructus Mali pumilae Acid.
In the present embodiment, the structural formula of described ph fluorescent probe is:
Wherein, n=6, x=317, y=39, z=25.
Step 4, spray printing: make mimeograph documents, using the second slurry of the fabric to after process through step 3 for the Numerical Control Printer Layer surface direct-injection acid dye ink is simultaneously dried.In the present embodiment, described acid dye ink includes by weight percentage Following component: 2% acid stain, 0.5% Polyvinylpyrrolidone, 5.0% 1，2-ethandiol, 0.2% tri ethylene glycol ethyl ether, 0.15% triethanolamine, 0.1% MIT, balance of deionized water.
Step 5, evaporates: decatize under moisture-saturated, and temperature is 100 DEG C～105 DEG C, assumes orange with fabric surface fibre Red fluorescence is reaction end；
Step 6, washing: be first impregnated with the fabric after processing through step 5 with cold water, then clean 8min with 70 DEG C～80 DEG C of hot water ～10min, then soap in 80 DEG C of liquid of soaping 15min～10min, is then cleaned with 30 DEG C～50 DEG C warm water, finally with cold Water rinsed clean.In the present embodiment, comprise in described every liter liquid of soaping the disodium hydrogen phosphate of 2g, the modified tea saponin of 4g and The chlorine-resistant color fixing agent of 3g.
Step 7, drying and shaping, dried with stenter, 90 DEG C～130 DEG C of temperature, speed 20m～40m/min, aridity Control within 20%.
Example IV:
The present embodiment provides a kind of digital spray printing method of brocade ammonia swimming suit fabric, and concrete steps include:
Step one, oil removing: by fabric addition temperature be 65 DEG C～70 DEG C containing degreaser, refining agent and soda except oil solution In carry out oil removal treatment, bath raio be 13: 1, oil removing solution ph be 6～7.In the present embodiment, described except oil solution by weight Percentages include following component: 25% soda, 12% refining agent tf-109,25% oil base amine polyoxyethylene ether, 7% alpha-olefin sulphur Sour sodium, 13% sodium lauryl sulphate, 18% aliphatic alcohol polyoxyvinethene phosphate sodium.
Step 2, modified: the fabric after oil removing is dried carries out low-temperature plasma process, described low-temperature plasma processes and adopts With discharge plasma processing meanss, fabric is carried out with surface modification, discharge plasma processing meanss include two blocks of electric discharge electricity Pole, two pieces of sparking electrodes embed in block media, and the spacing between pole plate is 5cm, and plasma working gas are o2, processing power is 50w, process time is 7min.
Step 3, starching: include an immersing and rolling two and apply three bakings, specially first included have the first of cationic quaternary amine Process serosity to pad, pick-up controls 45%～50%, after drying for the first time, on the first pulp layer surface of fabric, coating ph is glimmering Light probe, coating weight is 1g～2g/m2, then carry out second drying again in ph fluorescent probe layer surface coating second processing slurry Liquid, ph value is 6～7, and coating weight is 4.5g～5g/m2, then pull up width machine shaping and drying.
In the present embodiment, described first process serosity includes following component: 2% tamarind gum by weight percentage, and 4% Guar gum, 2.5% rare earth chloride, 1.5% sodium chloride, 1% carboxymethyl cellulose, 2% kieselguhr, 5% cationic quaternary amine, surplus For water.
In the present embodiment, described second processing serosity includes following component: 20% sodium alginate by weight percentage, 10% etherification starch, 50% dimethylformamide, 2% hydroxypropyl cellulose, 4% polyethylene pyrrole network alkanone, 10% glycerol, 4% Fructus Mali pumilae Acid.
In the present embodiment, the structural formula of described ph fluorescent probe is:
Wherein, n=6, x=317, y=39, z=25.
Step 4, spray printing: make mimeograph documents, using the second slurry of the fabric to after process through step 3 for the Numerical Control Printer Layer surface direct-injection acid dye ink is simultaneously dried.In the present embodiment, described acid dye ink includes by weight percentage Following component: 5% acid stain, 7% Polyvinylpyrrolidone, 13% 1，2-ethandiol, 3.5% tri ethylene glycol ethyl ether, 1% 3 second Hydramine, 0.4% MIT, balance of deionized water.
Step 5, evaporates: decatize under moisture-saturated, and temperature is 100 DEG C～105 DEG C, assumes orange with fabric surface fibre Red fluorescence is reaction end；
Step 6, washing: be first impregnated with the fabric after processing through step 5 with cold water, then clean 8min with 70 DEG C～80 DEG C of hot water ～10min, then soap in 80 DEG C of liquid of soaping 15min～10min, is then cleaned with 30 DEG C～50 DEG C warm water, finally with cold Water rinsed clean.In the present embodiment, comprise in described every liter liquid of soaping the disodium hydrogen phosphate of 4g, the modified tea saponin of 4g and The chlorine-resistant color fixing agent of 5g.
Step 7, drying and shaping, dried with stenter, 90 DEG C～130 DEG C of temperature, speed 20m～40m/min, aridity Control within 20%.
Embodiment five:
The present embodiment provides a kind of digital spray printing method of brocade ammonia swimming suit fabric, and concrete steps include:
Step one, oil removing: by fabric addition temperature be 80 DEG C～85 DEG C containing degreaser, refining agent and soda except oil solution In carry out oil removal treatment, bath raio be 10: 1, oil removing solution ph be 6～7.In the present embodiment, described except oil solution by weight Percentages include following component: 25% soda, 15% refining agent tf-109,25% oil base amine polyoxyethylene ether, 10% alpha-olefin sulphur Sour sodium, 10% sodium lauryl sulphate, 15% aliphatic alcohol polyoxyvinethene phosphate sodium.
Step 2, modified: the fabric after oil removing is dried carries out low-temperature plasma process, described low-temperature plasma processes and adopts With discharge plasma processing meanss, fabric is carried out with surface modification, discharge plasma processing meanss include two blocks of electric discharge electricity Pole, two pieces of sparking electrodes embed in block media, and the spacing between pole plate is 5cm, and plasma working gas are o2, processing power is 60w, process time is 5min.
Step 3, starching: include an immersing and rolling two and apply three bakings, specially first included have the first of cationic quaternary amine Process serosity to pad, pick-up controls 50%～55%, after drying for the first time, on the first pulp layer surface of fabric, coating ph is glimmering Light probe, coating weight is 1g～2g/m2, then carry out second drying again in ph fluorescent probe layer surface coating second processing slurry Liquid, ph value is 6～7, and coating weight is 3g～4g/m2, then pull up width machine shaping and drying.
In the present embodiment, described first process serosity includes following component: 3% tamarind gum by weight percentage, and 3% Guar gum, 2.5% rare earth chloride, 1% sodium chloride, 0.5% carboxymethyl cellulose, 3% kieselguhr, 7% cationic quaternary amine, surplus For water.
In the present embodiment, described second processing serosity includes following component: 15% sodium alginate by weight percentage, 14% etherification starch, 60% dimethylformamide, 1.5% hydroxypropyl cellulose, 2.5% polyethylene pyrrole network alkanone, 5% glycerol, 2% Herba Marsileae Quadrifoliae Fruit acid.
In the present embodiment, the structural formula of described ph fluorescent probe is:
Wherein, n=6, x=317, y=39, z=25.
Step 4, spray printing: make mimeograph documents, using the second slurry of the fabric to after process through step 3 for the Numerical Control Printer Layer surface direct-injection acid dye ink is simultaneously dried.In the present embodiment, described acid dye ink includes by weight percentage Following component: 10% acid stain, 5% Polyvinylpyrrolidone, 20% 1，2-ethandiol, 0.2% tri ethylene glycol ethyl ether, 2% 3 Ethanolamine, 0.5% MIT, balance of deionized water.
Step 5, evaporates: decatize under moisture-saturated, and temperature is 100 DEG C～105 DEG C, assumes orange with fabric surface fibre Red fluorescence is reaction end；
Step 6, washing: be first impregnated with the fabric after processing through step 5 with cold water, then clean 8min with 70 DEG C～80 DEG C of hot water ～10min, then soap in 80 DEG C of liquid of soaping 15min～10min, is then cleaned with 30 DEG C～50 DEG C warm water, finally with cold Water rinsed clean.In the present embodiment, comprise in described every liter liquid of soaping the disodium hydrogen phosphate of 4g, the modified tea saponin of 3g and The chlorine-resistant color fixing agent of 4g.
Step 7, drying and shaping, dried with stenter, 90 DEG C～130 DEG C of temperature, speed 20m～40m/min, aridity Control within 20%.
Ultimate principle and principal character and the advantages of the present invention of the invention have been shown and described above, the industry It should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description is to say to technical staff The principle of the bright present invention, on the premise of without departing from the invention spirit and scope, the present invention also has various change and changes Enter, these changes and improvements both fall within scope of the claimed invention, claimed scope is by appended right Claim and its equivalent thereof.

Claims (8)

1. the digital spray printing method of bright and beautiful ammonia swimming suit fabric is it is characterised in that concrete steps include:
Step one, oil removing: by fabric addition temperature be 65 DEG C～85 DEG C containing degreaser, refining agent and soda except oil solution In carry out oil removal treatment, bath raio be (10～15): 1, oil removing solution ph be 6～7；
Step 2, modified: the fabric after oil removing is dried carries out low-temperature plasma process；
Step 3, starching: include an immersing and rolling two and apply three bakings, specially first included have cationic quaternary amine first process Serosity pads, and pick-up controls 45%～65%, and after drying for the first time, on the first pulp layer surface of fabric, coating ph fluorescence is visited Pin, coating weight is 1g～2g/m2, then carry out second drying and coat second processing serosity in ph fluorescent probe layer surface again, Ph value is 6～7, and coating weight is 3g～5g/m2, then pull up width machine shaping and drying；
Step 4, spray printing: make mimeograph documents, using the second pulp layer table of the fabric to after process through step 3 for the Numerical Control Printer Face direct-injection acid dye ink is simultaneously dried；
Step 5, evaporates: decatize under moisture-saturated, and temperature is 100 DEG C～105 DEG C, is presented orange red with fabric surface fibre Fluorescence is reaction end；
Step 6, washing: be first impregnated with the fabric after processing through step 5 with cold water, then clean 8min with 70 DEG C～80 DEG C of hot water ～10min, then soap in 80 DEG C of liquid of soaping 15min～10min, is then cleaned with 30 DEG C～50 DEG C warm water, finally with cold Water rinsed clean；
Step 7, drying and shaping, dried with stenter, 90 DEG C～130 DEG C of temperature, speed 20m～40m/min, aridity controls Within 20%.
2. the digital spray printing method of brocade ammonia swimming suit fabric according to claim 1 is it is characterised in that described press except oil solution Percentage by weight meter includes following component: 25%～35% soda, 8%～15% refining agent tf-109,15%～25% oil base amine polyoxy Vinyl Ether, 5%～10% alpha-olefin sodium sulfonate, 8%～15% sodium lauryl sulphate, 15%～18% fatty alcohol-polyoxyethylene ether phosphoric acid Ester sodium.
3. the digital spray printing method of brocade ammonia swimming suit fabric according to claim 1 is it is characterised in that described low-temperature plasma Process, using discharge plasma processing meanss, fabric is carried out with surface modification, discharge plasma processing meanss include two pieces and put Electrode, two pieces of sparking electrodes embed in block media, and the spacing between pole plate is 5cm, and plasma working gas are o2, process work( Rate is 50w～70w, and process time is 3min～8min.
4. the digital spray printing method of brocade ammonia swimming suit fabric according to claim 1 is it is characterised in that described first processes slurry Liquid includes following component: 2%～4% tamarind gum by weight percentage, 2%～6% guar gum, 2.5%～3% rare earth chloride, and 1% ～2% sodium chloride, 0.5%～1% carboxymethyl cellulose, 2%～4% kieselguhr, 5%～10% cationic quaternary amine, balance of water.
5. the digital spray printing method of brocade ammonia swimming suit fabric according to claim 1 is it is characterised in that described second processing is starched Liquid includes following component: 15%～20% sodium alginate, 10%～15% etherification starch, 50%～60% dimethyl by weight percentage Methanamide, 1%～2% hydroxypropyl cellulose, 2%～4% polyethylene pyrrole network alkanone, 5%～15% glycerol, 2%～5% malic acid.
6. the digital spray printing method of brocade ammonia swimming suit fabric according to claim 1 is it is characterised in that described ph fluorescent probe Structural formula be:
Wherein, n=6, x=317, y=39, z=25.
7. the digital spray printing method of brocade ammonia swimming suit fabric according to claim 1 is it is characterised in that described acid stain is black Water includes following component: 2%～10% acid stain by weight percentage, 0.5%～10% Polyvinylpyrrolidone, 5.0%～ 20% 1，2-ethandiol, 0.2%～5% tri ethylene glycol ethyl ether, 0.1%～2% triethanolamine, 0.1%～1% different thiophene of 2- methyl -4- Oxazoline -3- ketone, balance of deionized water.
8. the digital spray printing method of brocade ammonia swimming suit fabric according to claim 1 is it is characterised in that described every liter liquid of soaping In comprise the chlorine-resistant color fixing agent of the disodium hydrogen phosphate of 2g～4g, the modified tea saponin of 3g～5g and 3g～5g.
CN201610763503.3A 2016-08-30 2016-08-30 Digital spray printing method for nylon-spandex swimming suit fabric Pending CN106368021A (en)

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