CN106366845A - Preparation method of high-bonding power impact-resistant epoxy terrace coating - Google Patents
Preparation method of high-bonding power impact-resistant epoxy terrace coating Download PDFInfo
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- CN106366845A CN106366845A CN201610746083.8A CN201610746083A CN106366845A CN 106366845 A CN106366845 A CN 106366845A CN 201610746083 A CN201610746083 A CN 201610746083A CN 106366845 A CN106366845 A CN 106366845A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Engineering & Computer Science (AREA)
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Floor Finish (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a preparation method of a high-bonding power impact-resistant epoxy terrace coating, and belongs to the technical field of coating preparation. The preparation method comprises the steps that gluten is self-made and then modified with natural resin to serve as filler, epoxy resin is modified with mixed plant juice to serve as a coating base material, finally, the filler, the coating base material and other auxiliary materials are compounded, and then the high-bonding power impact-resistant epoxy terrace coating can be obtained. According to the preparation method, the gluten is taken as a modifying agent by means of the characteristics of the high tenacity and the compression resistance, and by conducting compound modifying through natural peach gum and microorganisms, surface resin particles are increased, the compatibility of the coating and the epoxy resin base material is improved, and the defects that a traditional coating is brittle in texture and prone to crack are overcome; the epoxy resin base material is modified with the plant juice rich in active group and biogas fluid, therefore, the quantity of the active groups in resin is increased, the quantity of chemical bonds between the base material and an applying substrate is increased, the bonding power of the coating is enhanced, the problem that a traditional epoxy terrace coating is low in bonding power is solved, and a wide application prospect is achieved.
Description
Technical field
The invention discloses a kind of preparation method of strong bonding shock resistance type epoxy flooring coating, belong to coating preparation technology
Field.
Background technology
Floor coatings are to be invented in 1934 by Germany earliest, are mainly made up of oil plant, tree material, color, solvent etc..I
The floor coatings industry of state starts from phase early 1990s, with the fast development of China's economy, especially modern medicine, electricity
The rapid growth of the industries such as son, food, has driven the market demand of floor coatings.Floor coatings have become China and have applied in recent years
Material industry relaying building coating, vehicular traffic coating, after furniture woodwork coating and Marine Antifouling Paint, coating with fastest developing speed
One of kind.
Existing floor coatings are floor coatings is exactly to adopt epoxy source material to be host, adds pigment, solvent, auxiliary agent
Through the floor decorative material of allotment, epoxy oiliness floor paint researched and produced etc. all becomes terrace and applies firming agent
Material, floor coatings, for protection ground, play dust-proof, wear-resisting, cleaning, moistureproof effect, so by modern industry ground, commercially
Ground, garage floor etc. widely uses and promotes.Traditional floor coatings mainly have solvent-borne type, no-solvent type and water paint.
In recent years, with the fast development of epoxy Water-borne modification technology, aqueous epoxy floor coating obtains development and application, water
Property epoxy flooring coating is the environment-friendly type floor coatings occurring in recent years, and it not only has the physics of SOLVENT BASED EPOXY FLOOR COATINGS
Many advantages, such as good mechanical property, chemical resistance are strong, wearability is good, and do not contain organic solvent, volatile organic
Compound (voc) content is low, abnormal smells from the patient is little, coating surface is readily cleaned, environment friendly and pollution-free.However, existing aqueous epoxy floor applies
Material there is also many deficiencies, and existing aqueous epoxy floor coating cohesive force is poor, and matter is crisp easily to be split, rupture strength and comprcssive strength
Low, not impact resistance, these defect high degree limit the range of aqueous epoxy floor coating.
Content of the invention
Present invention mainly solves technical problem: there is cohesive force for existing aqueous epoxy floor coating at present
Difference, matter is crisp easily to be split, and rupture strength and comprcssive strength are low, not impact-resistant defect, provides a kind of strong shock resistance type epoxy ground that bonds
The preparation method of level ground coating, the method is used as filler with natural resin modification again by making gluten by oneself, then uses mixed plant juice
To epoxy resin modification as paint binder, last and other adjuvants can be prepared by strong bonding shock resistance type epoxide terrace after compounding
Coating, the present invention, by the use of the high tenacity of gluten and resistance to compression feature as modifying agent, is changed by natural Resina persicae and the compound of microorganism
Property, increase its surface resin granule, improve the compatibility of itself and epoxy resin bed material, make up traditional coating matter crisp easily split lack
Fall into, more modified to epoxy resin bed material by the water rich in active group and methane liquid, increase the active group in resin
Group's quantity, increases the chemical bond quantity between bed material and coated substrate, increases the cohesive force of coating, solves conventional epoxy terrace and applies
The low problem of material cohesive force, has broad application prospects.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1) weigh 500～600g Semen Tritici aestivi flour and add 250～300g distilled water, artificial with to become dough preservative film to cover quiet
Put 30～40min, then dough put in basin, adding distilled water until being totally submerged dough in basin, washing dough by rubbing with the hands by hand,
When water to be distilled becomes milky, again change water and repeatedly wash by rubbing with the hands till gluten diminishes and cannot wash out white distilled water again；
(2) it is filtrated to get gluten filtering residue after washing end by rubbing with the hands, filtering residue is put into steamer and steams 15～20min, pulverized with tissue after taking-up
Machine is pulverized and is crossed 100 mesh sieves, obtains wheat gluten, then is that 1:1 pours both total matter into by after wheat gluten and Resina persicae mixing in mass ratio
In the deionized water of 1～2 times of amount, after being heated to 70～80 DEG C of insulated and stirred 10～15min, obtain fermentation substrate；
(3) above-mentioned fermentation substrate is poured into fermentation tank, be 10% in substrate, to access bacillus subtilises by inoculum concentration, 30～
35 DEG C of bottom fermentation modifications 5～7 days, modification terminates rear filtration separation and obtains filtering residue, pulverizes and crosses 200 mesh sieves, obtain after vacuum freeze-drying
To natural resin modification gluten powder, standby；
(4) weigh 400～500g Folium Camptothecae Acuminatae and 200～300g Fructus Ananadis comosi is sequentially loaded into juice extractor and carries out process of squeezing the juice, filtration separation
Obtain mixing juice, for 5:1, Bisphenol-a Epoxy Resin and mixing juice are poured in ceramic pot successively in mass ratio, then to pottery
Add the methane liquid of mixing juice quality 10% in porcelain jar, ceramic pot is put in 30～40 DEG C of greenhouse, modified 7～9 days of insulation
Discharging afterwards, puts into the 10～15min that sterilizes at 100～120 DEG C in high temperature sterilize pot, obtains modified epoxy；
(5) by weight meter weigh 60～70 parts of above-mentioned modified epoxies, 10～15 parts of diglycidyl ether of ethylene glycol, 1～2
Part Polyethylene Glycol, 20～30 parts of standby natural resin modification gluten powder, 1～3 part of polydimethylsiloxane are added sequentially to
In Scattered Kettle, with 900～1000r/min rotating speed dispersed with stirring 1～2h, obtain coating a component；
(6) count by weight and weigh 3～5 parts of triethylamines again, 40～50 parts of modified epoxies are put in Scattered Kettle, with 600
～800r/min rotating speed disperses 30～40min to obtain coating b component, is mixed a, b component in mass ratio for 1:1 using front
After obtain final product strong bonding shock resistance type epoxy flooring coating.
The application process of the present invention is: the strong bonding shock resistance type epoxy flooring coating that the present invention is obtained by 0.1～
0.3kg/m2Consumption, coats ground after the cleaning with roller coating or brushing mode, constructed rear normal temperature cure 2～8h.Warp
Detection, after construction solidification, comprcssive strength reaches 30～50mpa to the strong bonding shock resistance type epoxy flooring coating of the present invention, anti-folding
Intensity reaches 5～8mpa, and adhesion strength reaches 30～50kg/cm2, cohesive force is strong, and the more traditional floor coatings of impact resistance exceed 2～
4 times.
The invention has the beneficial effects as follows:
(1) the strong bonding shock resistance type epoxy flooring coating of the present invention has that cohesive force is strong, wearability is good and bending and compressive strength
The features such as height, impact resistance are excellent, can be widely applied to terrace field of coating；
(2) the strong bonding shock resistance type epoxy flooring coating of the present invention has preferable workability, and adhesive force is strong, coating solidification
Quality is hard afterwards, and paint film is not easily broken, flat smooth, and spreading rate is high, practical.
Specific embodiment
Weigh 500～600g Semen Tritici aestivi flour first and add 250～300g distilled water, artificial with become dough preservative film cover
Live in standing 30～40min, then dough is put in basin, adding distilled water until being totally submerged dough in basin, washing by rubbing with the hands by hand
Dough, when water to be distilled becomes milky, again changes water and repeatedly washes by rubbing with the hands until gluten diminishes and cannot wash out white distilled water again and be
Only；Filter after washing end by rubbing with the hands, obtain gluten filtering residue, filtering residue is put into steamer and steams 15～20min, after taking-up, use tissue pulverizer
Pulverize and cross 100 mesh sieves, obtain wheat gluten, then be that 1:1 pours both gross masses 1 into by after wheat gluten and Resina persicae mixing in mass ratio
In～2 times of deionized water, after being heated to 70～80 DEG C of insulated and stirred 10～15min, obtain fermentation substrate；By above-mentioned fermentation
Substrate pours fermentation tank into, accesses bacillus subtilises for 10% by inoculum concentration, in 30～35 DEG C of bottom fermentation modifications 5～7 in substrate
My god, modification terminates rear filtration separation and obtains filtering residue, pulverizes and cross 200 mesh sieves after vacuum freeze-drying, obtains natural resin modification gluten
Powder, standby；Subsequently weigh 400～500g Folium Camptothecae Acuminatae and 200～300g Fructus Ananadis comosi is sequentially loaded into juice extractor and carries out process of squeezing the juice, mistake
Filter separates and obtains mixing juice, pours Bisphenol-a Epoxy Resin and mixing juice in ceramic pot successively into for 5:1 in mass ratio,
Add the methane liquid of mixing juice quality 10% again in ceramic pot, ceramic pot is put in 30～40 DEG C of greenhouse, insulation is modified
Discharging after 7～9 days, puts into the 10～15min that sterilizes at 100～120 DEG C in high temperature sterilize pot, obtains modified epoxy；Again
Meter weighs 60～70 parts of above-mentioned modified epoxies, 10～15 parts of diglycidyl ether of ethylene glycol, 1～2 part of poly- second by weight
Glycol, 20～30 parts of standby natural resin modification gluten powder, 1～3 part of polydimethylsiloxane are added sequentially to Scattered Kettle
In, with 900～1000r/min rotating speed dispersed with stirring 1～2h, obtain coating a component；Last counting by weight weighs 3～5 again
Part triethylamine, 40～50 parts of modified epoxies are put in Scattered Kettle, disperse 30～40min to obtain with 600～800r/min rotating speed
To coating b component, using front a, b component is mixed for 1:1 in mass ratio after obtain final product strong bonding shock resistance type epoxide terrace
Coating.
Example 1
Weigh 500g Semen Tritici aestivi flour first and add 250g distilled water, artificial and become dough preservative film to cover to stand 30min, then
Dough is put in basin, adding distilled water until being totally submerged dough in basin, washing dough by rubbing with the hands by hand, water to be distilled becomes breast
When white, again change water and repeatedly wash by rubbing with the hands till gluten diminishes and cannot wash out white distilled water again；Filter after washing end by rubbing with the hands,
Obtain gluten filtering residue, filtering residue is put into steamer and steams 15min, pulverized with tissue pulverizer after taking-up and cross 100 mesh sieves, obtain gluten
Powder, then be heat temperature raising in the deionized water pour into after wheat gluten and Resina persicae are mixed by 1:1 1 times of both gross masses in mass ratio
Fermentation substrate is obtained to 70 DEG C of insulated and stirred 10min；Above-mentioned fermentation substrate is poured into fermentation tank, is 10% to substrate by inoculum concentration
Middle access bacillus subtilises, in 30 DEG C of bottom fermentations modifications 5 days, modification terminated rear filtration separation and obtains filtering residue, after vacuum freeze-drying
Pulverize and cross 200 mesh sieves, obtain natural resin modification gluten powder, standby；Subsequently weigh 400g Folium Camptothecae Acuminatae and 200g Fructus Ananadis comosi according to
Secondary loading juice extractor carries out processs of squeezing the juice, and filtration separation obtains mixing juice, in mass ratio for 5:1 by Bisphenol-a Epoxy Resin
Pour in ceramic pot successively with mixing juice, then add the methane liquid of mixing juice quality 10% in ceramic pot, ceramic pot is put
Enter in 30 DEG C of greenhouse, be incubated discharging after modified 7 days, put into the 10min that sterilizes at 100 DEG C in high temperature sterilize pot, obtain modification
Epoxy resin；Meter weighs 60 parts of above-mentioned modified epoxies, 10 parts of diglycidyl ether of ethylene glycol, 1 part of poly- second by weight again
Glycol, 20 parts of standby natural resin modification gluten powder, 1 part of polydimethylsiloxane are added sequentially in Scattered Kettle, with
900r/min rotating speed dispersed with stirring 1h, obtains coating a component；Last counting by weight weighs 3 parts of triethylamines, 40 parts of modifications again
Epoxy resin is put in Scattered Kettle, obtains coating b component with 600r/min rotating speed dispersion 30min, using front, a, b component is pressed matter
Amount ratio obtains final product strong bonding shock resistance type epoxy flooring coating for 1:1 after being mixed.
This example operation is easy, and during use, the strong bonding shock resistance type epoxy flooring coating that the present invention is obtained is pressed
0.1kg/m2Consumption, coats ground after the cleaning with roller coating or brushing mode, constructed rear normal temperature cure 2h.Through inspection
Survey, after construction solidification, comprcssive strength reaches 30mpa to the strong bonding shock resistance type epoxy flooring coating of the present invention, and rupture strength reaches
5mpa, adhesion strength reaches 30kg/cm2, by force, the more original floor coatings of impact resistance exceed 2 times to cohesive force.
Example 2
Weigh 550g Semen Tritici aestivi flour first and add 275g distilled water, artificial and become dough preservative film to cover to stand 35min, then
Dough is put in basin, adding distilled water until being totally submerged dough in basin, washing dough by rubbing with the hands by hand, water to be distilled becomes breast
When white, again change water and repeatedly wash by rubbing with the hands till gluten diminishes and cannot wash out white distilled water again；Filter after washing end by rubbing with the hands,
Obtain gluten filtering residue, filtering residue is put into steamer and steams 18min, pulverized with tissue pulverizer after taking-up and cross 100 mesh sieves, obtain gluten
Powder, then be that in the deionized water pour into after wheat gluten and Resina persicae are mixed by 1:1 1.5 times of both gross masses, heating rises in mass ratio
Temperature obtains fermentation substrate to 75 DEG C of insulated and stirred 13min；Above-mentioned fermentation substrate is poured into fermentation tank, is 10% the bottom of to by inoculum concentration
Bacillus subtilises are accessed, in 33 DEG C of bottom fermentations modifications 6 days, modification terminated rear filtration separation and obtains filtering residue, vacuum freeze-drying in thing
After pulverize and cross 200 mesh sieves, obtain natural resin modification gluten powder, standby；Subsequently weigh 450g Folium Camptothecae Acuminatae and 250g Fructus Ananadis comosi
It is sequentially loaded into juice extractor and carries out process of squeezing the juice, filtration separation obtains mixing juice, in mass ratio for 5:1 by Bisphenol A Type asphalt mixtures modified by epoxy resin
Fat and mixing juice are poured in ceramic pot successively, then add the methane liquid of mixing juice quality 10% in ceramic pot, by ceramic pot
Put in 35 DEG C of greenhouse, be incubated discharging after modified 8 days, put into the 13min that sterilizes at 110 DEG C in high temperature sterilize pot, changed
Property epoxy resin；Again by weight meter weigh 65 parts of above-mentioned modified epoxies, 13 parts of diglycidyl ether of ethylene glycol, 1.5 parts
Polyethylene Glycol, 25 parts of standby natural resin modification gluten powder, 2 parts of polydimethylsiloxane are added sequentially in Scattered Kettle,
With 950r/min rotating speed dispersed with stirring 1.5h, obtain coating a component；Last count by weight weigh again 4 parts of triethylamines, 45 parts
Modified epoxy is put in Scattered Kettle, obtains coating b component with 700r/min rotating speed dispersion 35min, using front by a, b component
Strong bonding shock resistance type epoxy flooring coating is obtained final product for 1:1 after being mixed in mass ratio.
This example operation is easy, and during use, the strong bonding shock resistance type epoxy flooring coating that the present invention is obtained is pressed
0.2kg/m2Consumption, coats ground after the cleaning with roller coating or brushing mode, constructed rear normal temperature cure 5h.Through inspection
Survey, after construction solidification, comprcssive strength reaches 40mpa to the strong bonding shock resistance type epoxy flooring coating of the present invention, and rupture strength reaches
7mpa, adhesion strength reaches 40kg/cm2, by force, the more original floor coatings of impact resistance exceed 3 times to cohesive force.
Example 3
Weigh 600g Semen Tritici aestivi flour first and add 300g distilled water, artificial and become dough preservative film to cover to stand 40min, then
Dough is put in basin, adding distilled water until being totally submerged dough in basin, washing dough by rubbing with the hands by hand, water to be distilled becomes breast
When white, again change water and repeatedly wash by rubbing with the hands till gluten diminishes and cannot wash out white distilled water again；Filter after washing end by rubbing with the hands,
Obtain gluten filtering residue, filtering residue is put into steamer and steams 20min, pulverized with tissue pulverizer after taking-up and cross 100 mesh sieves, obtain gluten
Powder, then be heat temperature raising in the deionized water pour into after wheat gluten and Resina persicae are mixed by 1:1 2 times of both gross masses in mass ratio
Fermentation substrate is obtained to 80 DEG C of insulated and stirred 15min；Above-mentioned fermentation substrate is poured into fermentation tank, is 10% to substrate by inoculum concentration
Middle access bacillus subtilises, in 35 DEG C of bottom fermentations modifications 7 days, modification terminated rear filtration separation and obtains filtering residue, after vacuum freeze-drying
Pulverize and cross 200 mesh sieves, obtain natural resin modification gluten powder, standby；Subsequently weigh 500g Folium Camptothecae Acuminatae and 300g Fructus Ananadis comosi according to
Secondary loading juice extractor carries out processs of squeezing the juice, and filtration separation obtains mixing juice, in mass ratio for 5:1 by Bisphenol-a Epoxy Resin
Pour in ceramic pot successively with mixing juice, then add the methane liquid of mixing juice quality 10% in ceramic pot, ceramic pot is put
Enter in 40 DEG C of greenhouse, be incubated discharging after modified 9 days, put into the 15min that sterilizes at 120 DEG C in high temperature sterilize pot, obtain modification
Epoxy resin；Meter weighs 70 parts of above-mentioned modified epoxies, 15 parts of diglycidyl ether of ethylene glycol, 2 parts of poly- second by weight again
Glycol, 30 parts of standby natural resin modification gluten powder, 3 parts of polydimethylsiloxane are added sequentially in Scattered Kettle, with
1000r/min rotating speed dispersed with stirring 2h, obtains coating a component；Last count by weight weigh again 5 parts of triethylamines, 50 parts change
Property epoxy resin put in Scattered Kettle, with 800r/min rotating speed dispersion 40min obtain coating b component, using front, a, b component is pressed
Mass ratio obtains final product strong bonding shock resistance type epoxy flooring coating for 1:1 after being mixed.
This example operation is easy, and during use, the strong bonding shock resistance type epoxy flooring coating that the present invention is obtained is pressed
0.3kg/m2Consumption, coats ground after the cleaning with roller coating or brushing mode, constructed rear normal temperature cure 8h.Through inspection
Survey, after construction solidification, comprcssive strength reaches 50mpa to the strong bonding shock resistance type epoxy flooring coating of the present invention, and rupture strength reaches
8mpa, adhesion strength reaches 50kg/cm2, by force, the more original floor coatings of impact resistance exceed 4 times to cohesive force.
Claims (1)
1. a kind of preparation method of strong bonding shock resistance type epoxy flooring coating is it is characterised in that concrete preparation process is:
(1) weigh 500～600g Semen Tritici aestivi flour and add 250～300g distilled water, artificial with to become dough preservative film to cover quiet
Put 30～40min, then dough put in basin, adding distilled water until being totally submerged dough in basin, washing dough by rubbing with the hands by hand,
When water to be distilled becomes milky, again change water and repeatedly wash by rubbing with the hands till gluten diminishes and cannot wash out white distilled water again；
(2) it is filtrated to get gluten filtering residue after washing end by rubbing with the hands, filtering residue is put into steamer and steams 15～20min, pulverized with tissue after taking-up
Machine is pulverized and is crossed 100 mesh sieves, obtains wheat gluten, then is that 1:1 pours both total matter into by after wheat gluten and Resina persicae mixing in mass ratio
In the deionized water of 1～2 times of amount, after being heated to 70～80 DEG C of insulated and stirred 10～15min, obtain fermentation substrate；
(3) above-mentioned fermentation substrate is poured into fermentation tank, be 10% in substrate, to access bacillus subtilises by inoculum concentration, 30～
35 DEG C of bottom fermentation modifications 5～7 days, modification terminates rear filtration separation and obtains filtering residue, pulverizes and crosses 200 mesh sieves, obtain after vacuum freeze-drying
To natural resin modification gluten powder, standby；
(4) weigh 400～500g Folium Camptothecae Acuminatae and 200～300g Fructus Ananadis comosi is sequentially loaded into juice extractor and carries out process of squeezing the juice, filtration separation
Obtain mixing juice, for 5:1, Bisphenol-a Epoxy Resin and mixing juice are poured in ceramic pot successively in mass ratio, then to pottery
Add the methane liquid of mixing juice quality 10% in porcelain jar, ceramic pot is put in 30～40 DEG C of greenhouse, modified 7～9 days of insulation
Discharging afterwards, puts into the 10～15min that sterilizes at 100～120 DEG C in high temperature sterilize pot, obtains modified epoxy；
(5) by weight meter weigh 60～70 parts of above-mentioned modified epoxies, 10～15 parts of diglycidyl ether of ethylene glycol, 1～2
Part Polyethylene Glycol, 20～30 parts of standby natural resin modification gluten powder, 1～3 part of polydimethylsiloxane are added sequentially to
In Scattered Kettle, with 900～1000r/min rotating speed dispersed with stirring 1～2h, obtain coating a component；
(6) count by weight and weigh 3～5 parts of triethylamines again, 40～50 parts of modified epoxies are put in Scattered Kettle, with 600
～800r/min rotating speed disperses 30～40min to obtain coating b component, is mixed a, b component in mass ratio for 1:1 using front
After obtain final product strong bonding shock resistance type epoxy flooring coating.
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| CN201610746083.8A CN106366845A (en) | 2016-08-29 | 2016-08-29 | Preparation method of high-bonding power impact-resistant epoxy terrace coating |
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| CN201610746083.8A CN106366845A (en) | 2016-08-29 | 2016-08-29 | Preparation method of high-bonding power impact-resistant epoxy terrace coating |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107501862A (en) * | 2017-08-30 | 2017-12-22 | 常州苏达欧包装材料有限公司 | A kind of preparation method of steel bridge floor anti-slip pavement material |
| CN108483990A (en) * | 2018-04-04 | 2018-09-04 | 田秋珍 | A kind of preparation method of anti-hollowing high bond strength glue for tile |
| CN110922888A (en) * | 2019-11-14 | 2020-03-27 | 西安和光明宸科技有限公司 | Preparation method of electronic component coating |
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| JPH02238017A (en) * | 1989-03-13 | 1990-09-20 | Asahi Chem Ind Co Ltd | Epoxy resin composition |
| CN1220292A (en) * | 1998-11-17 | 1999-06-23 | 刘贵堂 | Method for preparing natural colour stone special spraying material and its products |
| CN101575477A (en) * | 2009-06-04 | 2009-11-11 | 无锡市艺博涂料有限公司 | High-solid terrace coating, preparation method and application thereof |
| CN105623472A (en) * | 2016-03-10 | 2016-06-01 | 广东耐迪化工有限公司 | Two-component thick-painted elastic self-leveling floor paint and preparation method thereof |
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2016
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02238017A (en) * | 1989-03-13 | 1990-09-20 | Asahi Chem Ind Co Ltd | Epoxy resin composition |
| CN1220292A (en) * | 1998-11-17 | 1999-06-23 | 刘贵堂 | Method for preparing natural colour stone special spraying material and its products |
| CN101575477A (en) * | 2009-06-04 | 2009-11-11 | 无锡市艺博涂料有限公司 | High-solid terrace coating, preparation method and application thereof |
| CN105623472A (en) * | 2016-03-10 | 2016-06-01 | 广东耐迪化工有限公司 | Two-component thick-painted elastic self-leveling floor paint and preparation method thereof |
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| Title |
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| 甘智荣: "《十分钟学会炒饭炒面》", 28 February 2015, 黑龙江科学技术出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107501862A (en) * | 2017-08-30 | 2017-12-22 | 常州苏达欧包装材料有限公司 | A kind of preparation method of steel bridge floor anti-slip pavement material |
| CN108483990A (en) * | 2018-04-04 | 2018-09-04 | 田秋珍 | A kind of preparation method of anti-hollowing high bond strength glue for tile |
| CN110922888A (en) * | 2019-11-14 | 2020-03-27 | 西安和光明宸科技有限公司 | Preparation method of electronic component coating |
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Application publication date: 20170201 |