CN106366768A - Novel metal series conductive ink - Google Patents
Novel metal series conductive ink Download PDFInfo
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- CN106366768A CN106366768A CN201610800983.6A CN201610800983A CN106366768A CN 106366768 A CN106366768 A CN 106366768A CN 201610800983 A CN201610800983 A CN 201610800983A CN 106366768 A CN106366768 A CN 106366768A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a novel metal series conductive ink. The novel metal series conductive ink is prepared from nano silver powder, nano copper powder, nano zinc powder, nano aluminum powder, nano nickel powder, nano vanadium carbide, nano titanium nitride, nano titanium carbide powder, nano boron carbide powder, nano tin powder, polyurethane modified epoxy resin, chloride vinyl acetate resin, Dama resin, petroleum resin, terpene resin, rosin modified resin, urea formaldehyde resin, melamine formaldehyde resin, styrene-acrylonitrile copolymer, ethanol, ethylene glycol, fatty alcohol ether sodium sulfate, sodium laureth sulfate and organic silicone oil. The components of the novel metal series conductive ink have a reasonable configuration, cost is low, and the prepared finished ink exhibits excellent conductive property, strong adhesion property and outstanding high-temperature oxidation resistance, and meets the molding needs of a printed circuit.
Description
Technical field
The present invention relates to a kind of technical field of electrically conductive ink, a kind of more particularly, to novel metal system electrically conductive ink.
Background technology
Electrically conductive ink refers to be printed on conductive stock, is allowed to have conduction electric current and exclusion accumulates electrostatic charge ability
Ink.Electrically conductive ink is usually imprinted on the non-conductive stock such as plastics, glass, pottery or cardboard.The printing side of electrically conductive ink
Method is very extensive, and such as silk screen printing, letterpress, flexible version printing, intaglio printing and offset printing etc. all can adopt.Can be according to film
Thick requirement and select different printing processes, then resistance, Solder resistance and rub resistance etc. are also different for thickness difference.Electrically conductive ink
There are thick film mill base and two kinds of resin type, the former is that the high temperature with frit as adhesive burns till type ink, and the latter is to synthesize tree
Fat is the cold drying of adhesive or the silk-screen ink of radiation (uv, eb) curing type.
Existing metal mold electrically conductive ink is broadly divided into gold system, silver system and copper system conductive ink.Gold system electrically conductive ink chemistry
Stable in properties, conduct electricity very well, but expensive;Silver system conductive ink is widely applied the conductive printing of thin film switch, but ink
The more difficult control of dried of film, leads to resistance value to increase, and price is partially expensive;Copper system electrically conductive ink low price, serviceability
Excellent, but have the shortcomings that oxidizable, printed circuit can be prevented oxidized the anti-oxidation process that copper powder is carried out in current art,
But shortcoming is printed circuit can not carry out high-temperature process, have impact on the practicality of copper system electrically conductive ink.
Content of the invention
The invention aims to overcoming the shortcoming of above-mentioned prior art, provide a kind of novel metal system electrically conductive ink,
Rationally, with low cost, finished product ink electric conductivity is excellent, adhesive force for the composition configuration of this novel metal system electrically conductive ink
By force, and there is prominent high-temperature oxidation resistance, the molding needs of printed circuit are met.
The technical solution adopted for the present invention to solve the technical problems is: a kind of novel metal system electrically conductive ink, by following
The composition of raw materials group of mass percent is grouped into: 10-15 part nanometer silver powder, 15-18 part copper nanoparticle, 15-16 part nano zinc powder,
16-18 part nanometer aluminium powder, 10-15 part nano-nickel powder, 10-12 part nano vanadium carbide, 10-12 part Nano titanium nitride, 8-10 part are received
Rice carbonized titanium powder, 6-8 part nano boron carbide powder, 8-10 part nanometer glass putty, 5-8 part polyurethane modified epoxy resin, 5-6 part chlorine vinegar
Resin, 6-8 part gum dammar, 8-10 part Petropols, 6-8 part terpene resin, 8-10 part modified rosin resin, 6-10 part ureaformaldehyde
Resin, 6-8 part melamine resin, 8-10 part acrylonitritrile-styrene resin, 4-5 part ethanol, 5-6 part ethylene glycol, 3-
5 parts of fatty alcohol-ether sodium sulfates, 6-8 part sodium lauryl tri(oxyethyl) sulfate, 15-20 part organic silicone oils.
Further, it is grouped into by the composition of raw materials group of following mass percent: 10 parts of nanometer silver powder, 15 parts of Nanometer Coppers
Powder, 15 parts of nano zinc powders, 16 parts of nanometer aluminium powders, 10 parts of nano-nickel powders, 10 parts of nano vanadium carbides, 10 parts of Nano titanium nitrides, 8 parts receive
Rice carbonized titanium powder, 6 parts of nano boron carbide powder, 8 parts of nanometer glass puttys, 5 parts of polyurethane modified epoxy resins, 5 parts of vinyl chloride-vinyl acetate resins, 6 parts
Gum dammar, 8 parts of Petropols, 6 parts of terpene resins, 8 parts of modified rosin resins, 6 parts of Lauxites, 6 parts of melamino-formaldehydes
Resin, 8 parts of acrylonitritrile-styrene resins, 4 parts of ethanol, 5 parts of ethylene glycol, 3 parts of fatty alcohol-ether sodium sulfates, 6 parts of lauryl ethers
Sodium sulfate, 15 parts of organic silicone oils.
Or, be grouped into by the composition of raw materials group of following mass percent: 15 parts of nanometer silver powder, 18 parts of copper nanoparticles,
16 parts of nano zinc powders, 18 parts of nanometer aluminium powders, 15 parts of nano-nickel powders, 12 parts of nano vanadium carbides, 12 parts of Nano titanium nitrides, 10 parts of nanometers
Carbonized titanium powder, 8 parts of nano boron carbide powder, 10 parts of nanometer glass puttys, 8 parts of polyurethane modified epoxy resins, 6 parts of vinyl chloride-vinyl acetate resins, 8 parts reach
Saqima resin, 10 parts of Petropols, 8 parts of terpene resins, 10 parts of modified rosin resins, 10 parts of Lauxites, 8 parts of melamino-formaldehydes
Resin, 10 parts of acrylonitritrile-styrene resins, 5 parts of ethanol, 6 parts of ethylene glycol, 5 parts of fatty alcohol-ether sodium sulfates, 8 parts of dodecyls
Ether sodium sulfate, 20 parts of organic silicone oils.
In sum, the invention has the beneficial effects as follows: the configuration of the composition of the novel metal system electrically conductive ink of the present invention rationally,
With low cost, finished product ink electric conductivity is excellent, and adhesive force is strong, and has prominent high-temperature oxidation resistance, meets
The molding of printed circuit needs.
Specific embodiment
Embodiment 1
A kind of novel metal system electrically conductive ink described by the present embodiment 1, by the composition of raw materials group packet of following mass percent
Become: 10 parts of nanometer silver powder, 15 parts of copper nanoparticles, 15 parts of nano zinc powders, 16 parts of nanometer aluminium powders, 10 parts of nano-nickel powders, 10 parts of nanometers
Vanadium carbide, 10 parts of Nano titanium nitrides, 8 parts of nano silicon carbide titanium valves, 6 parts of nano boron carbide powder, 8 parts of nanometer glass puttys, 5 parts of polyurethane change
Property epoxy resin, 5 parts of vinyl chloride-vinyl acetate resins, 6 parts of gum dammars, 8 parts of Petropols, 6 parts of terpene resins, 8 parts of modified rosin resins, 6
Part Lauxite, 6 parts of melamine resins, 8 parts of acrylonitritrile-styrene resins, 4 parts of ethanol, 5 parts of ethylene glycol, 3 parts of fat
Fat ether sulfate, 6 parts of sodium lauryl tri(oxyethyl) sulfates, 15 parts of organic silicone oils.
Embodiment 2
A kind of novel metal system electrically conductive ink described by the present embodiment 2, by the composition of raw materials group packet of following mass percent
Become: 15 parts of nanometer silver powder, 18 parts of copper nanoparticles, 16 parts of nano zinc powders, 18 parts of nanometer aluminium powders, 15 parts of nano-nickel powders, 12 parts of nanometers
Vanadium carbide, 12 parts of Nano titanium nitrides, 10 parts of nano silicon carbide titanium valves, 8 parts of nano boron carbide powder, 10 parts of nanometer glass puttys, 8 parts of polyurethane
Modified epoxy, 6 parts of vinyl chloride-vinyl acetate resins, 8 parts of gum dammars, 10 parts of Petropols, 8 parts of terpene resins, 10 parts of Abietyl modified trees
Fat, 10 parts of Lauxites, 8 parts of melamine resins, 10 parts of acrylonitritrile-styrene resins, 5 parts of ethanol, 6 parts of second two
Alcohol, 5 parts of fatty alcohol-ether sodium sulfates, 8 parts of sodium lauryl tri(oxyethyl) sulfates, 20 parts of organic silicone oils.
The above, be only that presently preferred embodiments of the present invention, the not principle to the present invention and framework make any shape
Restriction in formula.Any simple modification that every technical spirit according to the present invention is made to above example, equivalent variations with
Modify, all still fall within the range of technical scheme.
Claims (3)
1. a kind of novel metal system electrically conductive ink is it is characterised in that be grouped into by the composition of raw materials group of following mass percent:
10-15 part nanometer silver powder, 15-18 part copper nanoparticle, 15-16 part nano zinc powder, 16-18 part nanometer aluminium powder, 10-15 part nano nickel
Powder, 10-12 part nano vanadium carbide, 10-12 part Nano titanium nitride, 8-10 part nano silicon carbide titanium valve, 6-8 part nano boron carbide powder,
8-10 part nanometer glass putty, 5-8 part polyurethane modified epoxy resin, 5-6 part vinyl chloride-vinyl acetate resin, 6-8 part gum dammar, 8-10 part oil
Resin, 6-8 part terpene resin, 8-10 part modified rosin resin, 6-10 part Lauxite, 6-8 part melamine resin, 8-
10 parts of acrylonitritrile-styrene resins, 4-5 part ethanol, 5-6 part ethylene glycol, 3-5 part fatty alcohol-ether sodium sulfate, 6-8 part dodecanes
Base ether sodium sulfate, 15-20 part organic silicone oil.
2. a kind of novel metal system electrically conductive ink according to claim 1 is it is characterised in that by following mass percent
Composition of raw materials group is grouped into: 10 parts of nanometer silver powder, 15 parts of copper nanoparticles, 15 parts of nano zinc powders, 16 parts of nanometer aluminium powders, 10 parts receive
Rice nikel powder, 10 parts of nano vanadium carbides, 10 parts of Nano titanium nitrides, 8 parts of nano silicon carbide titanium valves, 6 parts of nano boron carbide powder, 8 parts of nanometers
Glass putty, 5 parts of polyurethane modified epoxy resins, 5 parts of vinyl chloride-vinyl acetate resins, 6 parts of gum dammars, 8 parts of Petropols, 6 parts of terpene resins, 8
Part modified rosin resin, 6 parts of Lauxites, 6 parts of melamine resins, 8 parts of acrylonitritrile-styrene resins, 4 parts of second
Alcohol, 5 parts of ethylene glycol, 3 parts of fatty alcohol-ether sodium sulfates, 6 parts of sodium lauryl tri(oxyethyl) sulfates, 15 parts of organic silicone oils.
3. a kind of novel metal system electrically conductive ink according to claim 1 is it is characterised in that by following mass percent
Composition of raw materials group is grouped into: 15 parts of nanometer silver powder, 18 parts of copper nanoparticles, 16 parts of nano zinc powders, 18 parts of nanometer aluminium powders, 15 parts receive
Rice nikel powder, 12 parts of nano vanadium carbides, 12 parts of Nano titanium nitrides, 10 parts of nano silicon carbide titanium valves, 8 parts of nano boron carbide powder, 10 parts receive
Rice glass putty, 8 parts of polyurethane modified epoxy resins, 6 parts of vinyl chloride-vinyl acetate resins, 8 parts of gum dammars, 10 parts of Petropols, 8 parts of terpenes trees
Fat, 10 parts of modified rosin resins, 10 parts of Lauxites, 8 parts of melamine resins, 10 parts of acrylonitritrile-styrene resins,
5 parts of ethanol, 6 parts of ethylene glycol, 5 parts of fatty alcohol-ether sodium sulfates, 8 parts of sodium lauryl tri(oxyethyl) sulfates, 20 parts of organic silicone oils.
Priority Applications (1)
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CN201610800983.6A CN106366768A (en) | 2016-09-05 | 2016-09-05 | Novel metal series conductive ink |
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CN201610800983.6A CN106366768A (en) | 2016-09-05 | 2016-09-05 | Novel metal series conductive ink |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109246920A (en) * | 2017-06-08 | 2019-01-18 | 臻鼎科技股份有限公司 | Cover film and preparation method thereof |
TWI660859B (en) * | 2017-06-07 | 2019-06-01 | 臻鼎科技股份有限公司 | Cover layer and method for making the same |
KR102175984B1 (en) * | 2020-07-20 | 2020-11-06 | 김상분 | Conductive ink composition for manufacturing planar heating film |
-
2016
- 2016-09-05 CN CN201610800983.6A patent/CN106366768A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI660859B (en) * | 2017-06-07 | 2019-06-01 | 臻鼎科技股份有限公司 | Cover layer and method for making the same |
CN109246920A (en) * | 2017-06-08 | 2019-01-18 | 臻鼎科技股份有限公司 | Cover film and preparation method thereof |
CN109246920B (en) * | 2017-06-08 | 2020-10-02 | 臻鼎科技股份有限公司 | Covering film and manufacturing method thereof |
KR102175984B1 (en) * | 2020-07-20 | 2020-11-06 | 김상분 | Conductive ink composition for manufacturing planar heating film |
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Application publication date: 20170201 |
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