CN106366768A - Novel metal series conductive ink - Google Patents

Novel metal series conductive ink Download PDF

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Publication number
CN106366768A
CN106366768A CN201610800983.6A CN201610800983A CN106366768A CN 106366768 A CN106366768 A CN 106366768A CN 201610800983 A CN201610800983 A CN 201610800983A CN 106366768 A CN106366768 A CN 106366768A
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China
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parts
nano
powder
resin
resins
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CN201610800983.6A
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Chinese (zh)
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李锦明
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Individual
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Individual
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Priority to CN201610800983.6A priority Critical patent/CN106366768A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/52Electrically conductive inks

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a novel metal series conductive ink. The novel metal series conductive ink is prepared from nano silver powder, nano copper powder, nano zinc powder, nano aluminum powder, nano nickel powder, nano vanadium carbide, nano titanium nitride, nano titanium carbide powder, nano boron carbide powder, nano tin powder, polyurethane modified epoxy resin, chloride vinyl acetate resin, Dama resin, petroleum resin, terpene resin, rosin modified resin, urea formaldehyde resin, melamine formaldehyde resin, styrene-acrylonitrile copolymer, ethanol, ethylene glycol, fatty alcohol ether sodium sulfate, sodium laureth sulfate and organic silicone oil. The components of the novel metal series conductive ink have a reasonable configuration, cost is low, and the prepared finished ink exhibits excellent conductive property, strong adhesion property and outstanding high-temperature oxidation resistance, and meets the molding needs of a printed circuit.

Description

A kind of novel metal system electrically conductive ink
Technical field
The present invention relates to a kind of technical field of electrically conductive ink, a kind of more particularly, to novel metal system electrically conductive ink.
Background technology
Electrically conductive ink refers to be printed on conductive stock, is allowed to have conduction electric current and exclusion accumulates electrostatic charge ability Ink.Electrically conductive ink is usually imprinted on the non-conductive stock such as plastics, glass, pottery or cardboard.The printing side of electrically conductive ink Method is very extensive, and such as silk screen printing, letterpress, flexible version printing, intaglio printing and offset printing etc. all can adopt.Can be according to film Thick requirement and select different printing processes, then resistance, Solder resistance and rub resistance etc. are also different for thickness difference.Electrically conductive ink There are thick film mill base and two kinds of resin type, the former is that the high temperature with frit as adhesive burns till type ink, and the latter is to synthesize tree Fat is the cold drying of adhesive or the silk-screen ink of radiation (uv, eb) curing type.
Existing metal mold electrically conductive ink is broadly divided into gold system, silver system and copper system conductive ink.Gold system electrically conductive ink chemistry Stable in properties, conduct electricity very well, but expensive;Silver system conductive ink is widely applied the conductive printing of thin film switch, but ink The more difficult control of dried of film, leads to resistance value to increase, and price is partially expensive;Copper system electrically conductive ink low price, serviceability Excellent, but have the shortcomings that oxidizable, printed circuit can be prevented oxidized the anti-oxidation process that copper powder is carried out in current art, But shortcoming is printed circuit can not carry out high-temperature process, have impact on the practicality of copper system electrically conductive ink.
Content of the invention
The invention aims to overcoming the shortcoming of above-mentioned prior art, provide a kind of novel metal system electrically conductive ink, Rationally, with low cost, finished product ink electric conductivity is excellent, adhesive force for the composition configuration of this novel metal system electrically conductive ink By force, and there is prominent high-temperature oxidation resistance, the molding needs of printed circuit are met.
The technical solution adopted for the present invention to solve the technical problems is: a kind of novel metal system electrically conductive ink, by following The composition of raw materials group of mass percent is grouped into: 10-15 part nanometer silver powder, 15-18 part copper nanoparticle, 15-16 part nano zinc powder, 16-18 part nanometer aluminium powder, 10-15 part nano-nickel powder, 10-12 part nano vanadium carbide, 10-12 part Nano titanium nitride, 8-10 part are received Rice carbonized titanium powder, 6-8 part nano boron carbide powder, 8-10 part nanometer glass putty, 5-8 part polyurethane modified epoxy resin, 5-6 part chlorine vinegar Resin, 6-8 part gum dammar, 8-10 part Petropols, 6-8 part terpene resin, 8-10 part modified rosin resin, 6-10 part ureaformaldehyde Resin, 6-8 part melamine resin, 8-10 part acrylonitritrile-styrene resin, 4-5 part ethanol, 5-6 part ethylene glycol, 3- 5 parts of fatty alcohol-ether sodium sulfates, 6-8 part sodium lauryl tri(oxyethyl) sulfate, 15-20 part organic silicone oils.
Further, it is grouped into by the composition of raw materials group of following mass percent: 10 parts of nanometer silver powder, 15 parts of Nanometer Coppers Powder, 15 parts of nano zinc powders, 16 parts of nanometer aluminium powders, 10 parts of nano-nickel powders, 10 parts of nano vanadium carbides, 10 parts of Nano titanium nitrides, 8 parts receive Rice carbonized titanium powder, 6 parts of nano boron carbide powder, 8 parts of nanometer glass puttys, 5 parts of polyurethane modified epoxy resins, 5 parts of vinyl chloride-vinyl acetate resins, 6 parts Gum dammar, 8 parts of Petropols, 6 parts of terpene resins, 8 parts of modified rosin resins, 6 parts of Lauxites, 6 parts of melamino-formaldehydes Resin, 8 parts of acrylonitritrile-styrene resins, 4 parts of ethanol, 5 parts of ethylene glycol, 3 parts of fatty alcohol-ether sodium sulfates, 6 parts of lauryl ethers Sodium sulfate, 15 parts of organic silicone oils.
Or, be grouped into by the composition of raw materials group of following mass percent: 15 parts of nanometer silver powder, 18 parts of copper nanoparticles, 16 parts of nano zinc powders, 18 parts of nanometer aluminium powders, 15 parts of nano-nickel powders, 12 parts of nano vanadium carbides, 12 parts of Nano titanium nitrides, 10 parts of nanometers Carbonized titanium powder, 8 parts of nano boron carbide powder, 10 parts of nanometer glass puttys, 8 parts of polyurethane modified epoxy resins, 6 parts of vinyl chloride-vinyl acetate resins, 8 parts reach Saqima resin, 10 parts of Petropols, 8 parts of terpene resins, 10 parts of modified rosin resins, 10 parts of Lauxites, 8 parts of melamino-formaldehydes Resin, 10 parts of acrylonitritrile-styrene resins, 5 parts of ethanol, 6 parts of ethylene glycol, 5 parts of fatty alcohol-ether sodium sulfates, 8 parts of dodecyls Ether sodium sulfate, 20 parts of organic silicone oils.
In sum, the invention has the beneficial effects as follows: the configuration of the composition of the novel metal system electrically conductive ink of the present invention rationally, With low cost, finished product ink electric conductivity is excellent, and adhesive force is strong, and has prominent high-temperature oxidation resistance, meets The molding of printed circuit needs.
Specific embodiment
Embodiment 1
A kind of novel metal system electrically conductive ink described by the present embodiment 1, by the composition of raw materials group packet of following mass percent Become: 10 parts of nanometer silver powder, 15 parts of copper nanoparticles, 15 parts of nano zinc powders, 16 parts of nanometer aluminium powders, 10 parts of nano-nickel powders, 10 parts of nanometers Vanadium carbide, 10 parts of Nano titanium nitrides, 8 parts of nano silicon carbide titanium valves, 6 parts of nano boron carbide powder, 8 parts of nanometer glass puttys, 5 parts of polyurethane change Property epoxy resin, 5 parts of vinyl chloride-vinyl acetate resins, 6 parts of gum dammars, 8 parts of Petropols, 6 parts of terpene resins, 8 parts of modified rosin resins, 6 Part Lauxite, 6 parts of melamine resins, 8 parts of acrylonitritrile-styrene resins, 4 parts of ethanol, 5 parts of ethylene glycol, 3 parts of fat Fat ether sulfate, 6 parts of sodium lauryl tri(oxyethyl) sulfates, 15 parts of organic silicone oils.
Embodiment 2
A kind of novel metal system electrically conductive ink described by the present embodiment 2, by the composition of raw materials group packet of following mass percent Become: 15 parts of nanometer silver powder, 18 parts of copper nanoparticles, 16 parts of nano zinc powders, 18 parts of nanometer aluminium powders, 15 parts of nano-nickel powders, 12 parts of nanometers Vanadium carbide, 12 parts of Nano titanium nitrides, 10 parts of nano silicon carbide titanium valves, 8 parts of nano boron carbide powder, 10 parts of nanometer glass puttys, 8 parts of polyurethane Modified epoxy, 6 parts of vinyl chloride-vinyl acetate resins, 8 parts of gum dammars, 10 parts of Petropols, 8 parts of terpene resins, 10 parts of Abietyl modified trees Fat, 10 parts of Lauxites, 8 parts of melamine resins, 10 parts of acrylonitritrile-styrene resins, 5 parts of ethanol, 6 parts of second two Alcohol, 5 parts of fatty alcohol-ether sodium sulfates, 8 parts of sodium lauryl tri(oxyethyl) sulfates, 20 parts of organic silicone oils.
The above, be only that presently preferred embodiments of the present invention, the not principle to the present invention and framework make any shape Restriction in formula.Any simple modification that every technical spirit according to the present invention is made to above example, equivalent variations with Modify, all still fall within the range of technical scheme.

Claims (3)

1. a kind of novel metal system electrically conductive ink is it is characterised in that be grouped into by the composition of raw materials group of following mass percent: 10-15 part nanometer silver powder, 15-18 part copper nanoparticle, 15-16 part nano zinc powder, 16-18 part nanometer aluminium powder, 10-15 part nano nickel Powder, 10-12 part nano vanadium carbide, 10-12 part Nano titanium nitride, 8-10 part nano silicon carbide titanium valve, 6-8 part nano boron carbide powder, 8-10 part nanometer glass putty, 5-8 part polyurethane modified epoxy resin, 5-6 part vinyl chloride-vinyl acetate resin, 6-8 part gum dammar, 8-10 part oil Resin, 6-8 part terpene resin, 8-10 part modified rosin resin, 6-10 part Lauxite, 6-8 part melamine resin, 8- 10 parts of acrylonitritrile-styrene resins, 4-5 part ethanol, 5-6 part ethylene glycol, 3-5 part fatty alcohol-ether sodium sulfate, 6-8 part dodecanes Base ether sodium sulfate, 15-20 part organic silicone oil.
2. a kind of novel metal system electrically conductive ink according to claim 1 is it is characterised in that by following mass percent Composition of raw materials group is grouped into: 10 parts of nanometer silver powder, 15 parts of copper nanoparticles, 15 parts of nano zinc powders, 16 parts of nanometer aluminium powders, 10 parts receive Rice nikel powder, 10 parts of nano vanadium carbides, 10 parts of Nano titanium nitrides, 8 parts of nano silicon carbide titanium valves, 6 parts of nano boron carbide powder, 8 parts of nanometers Glass putty, 5 parts of polyurethane modified epoxy resins, 5 parts of vinyl chloride-vinyl acetate resins, 6 parts of gum dammars, 8 parts of Petropols, 6 parts of terpene resins, 8 Part modified rosin resin, 6 parts of Lauxites, 6 parts of melamine resins, 8 parts of acrylonitritrile-styrene resins, 4 parts of second Alcohol, 5 parts of ethylene glycol, 3 parts of fatty alcohol-ether sodium sulfates, 6 parts of sodium lauryl tri(oxyethyl) sulfates, 15 parts of organic silicone oils.
3. a kind of novel metal system electrically conductive ink according to claim 1 is it is characterised in that by following mass percent Composition of raw materials group is grouped into: 15 parts of nanometer silver powder, 18 parts of copper nanoparticles, 16 parts of nano zinc powders, 18 parts of nanometer aluminium powders, 15 parts receive Rice nikel powder, 12 parts of nano vanadium carbides, 12 parts of Nano titanium nitrides, 10 parts of nano silicon carbide titanium valves, 8 parts of nano boron carbide powder, 10 parts receive Rice glass putty, 8 parts of polyurethane modified epoxy resins, 6 parts of vinyl chloride-vinyl acetate resins, 8 parts of gum dammars, 10 parts of Petropols, 8 parts of terpenes trees Fat, 10 parts of modified rosin resins, 10 parts of Lauxites, 8 parts of melamine resins, 10 parts of acrylonitritrile-styrene resins, 5 parts of ethanol, 6 parts of ethylene glycol, 5 parts of fatty alcohol-ether sodium sulfates, 8 parts of sodium lauryl tri(oxyethyl) sulfates, 20 parts of organic silicone oils.
CN201610800983.6A 2016-09-05 2016-09-05 Novel metal series conductive ink Pending CN106366768A (en)

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CN201610800983.6A CN106366768A (en) 2016-09-05 2016-09-05 Novel metal series conductive ink

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CN201610800983.6A CN106366768A (en) 2016-09-05 2016-09-05 Novel metal series conductive ink

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CN106366768A true CN106366768A (en) 2017-02-01

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109246920A (en) * 2017-06-08 2019-01-18 臻鼎科技股份有限公司 Cover film and preparation method thereof
TWI660859B (en) * 2017-06-07 2019-06-01 臻鼎科技股份有限公司 Cover layer and method for making the same
KR102175984B1 (en) * 2020-07-20 2020-11-06 김상분 Conductive ink composition for manufacturing planar heating film

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI660859B (en) * 2017-06-07 2019-06-01 臻鼎科技股份有限公司 Cover layer and method for making the same
CN109246920A (en) * 2017-06-08 2019-01-18 臻鼎科技股份有限公司 Cover film and preparation method thereof
CN109246920B (en) * 2017-06-08 2020-10-02 臻鼎科技股份有限公司 Covering film and manufacturing method thereof
KR102175984B1 (en) * 2020-07-20 2020-11-06 김상분 Conductive ink composition for manufacturing planar heating film

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Application publication date: 20170201

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