CN106366602A - Unsaturated polyester resin with excellent mechanical properties for anchoring agent - Google Patents
Unsaturated polyester resin with excellent mechanical properties for anchoring agent Download PDFInfo
- Publication number
- CN106366602A CN106366602A CN201610743504.1A CN201610743504A CN106366602A CN 106366602 A CN106366602 A CN 106366602A CN 201610743504 A CN201610743504 A CN 201610743504A CN 106366602 A CN106366602 A CN 106366602A
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- China
- Prior art keywords
- parts
- polyester resin
- unsaturated polyester
- excellent mechanical
- anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920006337 unsaturated polyester resin Polymers 0.000 title claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 27
- 238000004873 anchoring Methods 0.000 title abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 45
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 45
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 42
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 36
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 30
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims abstract description 21
- LNYYKKTXWBNIOO-UHFFFAOYSA-N 3-oxabicyclo[3.3.1]nona-1(9),5,7-triene-2,4-dione Chemical compound C1=CC(C(=O)OC2=O)=CC2=C1 LNYYKKTXWBNIOO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 16
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims abstract description 16
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 claims abstract description 16
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002113 nanodiamond Substances 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000000377 silicon dioxide Substances 0.000 claims abstract 2
- 239000002994 raw material Substances 0.000 claims description 19
- -1 phosphate ester Chemical class 0.000 claims description 16
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 claims description 16
- 238000010792 warming Methods 0.000 claims description 16
- 229910019142 PO4 Inorganic materials 0.000 claims description 15
- 239000010452 phosphate Substances 0.000 claims description 15
- 239000005543 nano-size silicon particle Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 235000009566 rice Nutrition 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229920000877 Melamine resin Polymers 0.000 abstract description 3
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000011176 polyphosphates Nutrition 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 241000209094 Oryza Species 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000002041 carbon nanotube Substances 0.000 description 4
- 229910003460 diamond Inorganic materials 0.000 description 4
- 239000010432 diamond Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- LLYXJBROWQDVMI-UHFFFAOYSA-N 2-chloro-4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1Cl LLYXJBROWQDVMI-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D20/00—Setting anchoring-bolts
- E21D20/02—Setting anchoring-bolts with provisions for grouting
- E21D20/025—Grouting with organic components, e.g. resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Structural Engineering (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses an unsaturated polyester resin with excellent mechanical properties for an anchoring agent. The unsaturated polyester resin is prepared from, by weight, 25-35 parts of maleic anhydride, 2-5 parts of isophthalic anhydride, 4-8 parts of tetrachlorophthalic anhydride, 1-5 parts of D-33 monomers, 2-6 parts of benzenetriol, 3-5 parts of hydroquinone, 1-4 parts of cobalt naphthenate styrene, 4-8 parts of melamine polyphosphate, 3-6 parts of methyl ethyl ketone peroxide, 1-6 parts of nano-silica, 3-5 parts of nano-diamond, 4-8 parts of modified carbon nanotubes, 5-15 parts of ethylene glycol, 3-5 parts of diethylene glycol and 4-9 parts of propylene glycol. The unsaturated polyester resin is applied to preparation of the anchoring agent, has excellent mechanical properties and can meet the requirement for mechanical properties in preparation of the anchoring agent.
Description
Technical field
The invention belongs to unsaturated polyester resin technical field, more particularly, to a kind of Anchor Agent excellent mechanical performance is not
Saturated polyester resin.
Background technology
Unsaturated polyester resin, usually by unsaturated dibasic acid dihydroxylic alcohols or monounsaturated dicarboxylic acid unsaturation dihydroxylic alcohols contracting
The poly- chain macromolecule compound with ester bond and unsaturated double-bond.Generally, polyesterification polycondensation reaction is in 190-220
DEG C carry out, until it reaches expected acid number, after polyesterification contracting reaction terminates, add a certain amount of vinyl monomer while hot, join
Become sticky liquid, such polymer solution is referred to as unsaturated polyester resin.
The processing performance of unsaturated polyester resin is excellent, and this is the maximum advantage of unsaturated polyester resin.Can be in room temperature
Lower solidification, molding under normal pressure, processing performance flexibly, is particularly suitable for large-scale and making in site glass fiber reinforced plastics product.Mechanical performance index
Slightly below epoxy resin, but it is better than phenolic resin.Corrosion resistance, electrical property and anti-flammability can be by selecting the tree of the suitable trade mark
Fat is shallow to meet requirement, color of resin, can make transparent article.Wide in variety, adapt to extensively, price is relatively low.
Unsaturated polyester resin used in Anchor Agent preparation process of the prior art, its mechanical property cannot meet anchor
Gu the demand of agent, the unsaturated polyester resin therefore needing a kind of design Anchor Agent excellent mechanical performance badly solves prior art
In problem.
Content of the invention
For solving technical problem present in background technology, the present invention proposes a kind of Anchor Agent excellent mechanical performance not
Saturated polyester resin.
A kind of Anchor Agent proposed by the present invention unsaturated polyester resin of excellent mechanical performance, its raw material wraps by weight
Include: maleic anhydride 25-35 part, isophthalic anhydride 2-5 part, tetrachlorophthalic anhydride 4-8 part, d-33 monomer 1-5 part, benzenetriol 2-
6 parts, hydroquinone 3-5 part, cobalt naphthenate styrene 1-4 part, phosphate ester tripolycyanamide 4-8 part, methyl ethyl ketone peroxide 3-6 part,
Nano silicon 1-6 part, Nano diamond 3-5 part, modified carbon nano-tube 4-8 part, ethylene glycol 5-15 part, diglycol
3-5 part, propylene glycol 4-9 part.
Preferably, modified carbon nano-tube is prepared by following technique: CNT and dichloroethanes mix homogeneously surpass
Sonication 1-3h, is subsequently added into thionyl chloride, magnetic agitation 20-40min, is then warming up to 80-90 DEG C, and flow back 20-30h, cold
But add 2- propylene -1- alcohol mix homogeneously to room temperature, be then warming up to 45-55 DEG C, stir 22-26h, then use washing with acetone
1-4 time, after centrifugation, solid is dried 6-12h in 40-50 DEG C, is cooled to room temperature and obtains modified carbon nano-tube.
Preferably, in the preparation process of modified carbon nano-tube, CNT, dichloroethanes, thionyl chloride and 2- propylene -1-
The weight of alcohol is than for 3-6:1-3:2-4:1-3.
Preferably, in the raw material of modified carbon nano-tube, specific surface area 40-300m of CNT2/ g, heat conductivity
1800-2200w/ (m k), external diameter is 30-50nm, and length is 3 μm.
Preferably, the mass fraction of solids of methyl ethyl ketone peroxide is 45-60%, and acid number is 10-14mgkoh/g, and viscosity is
320-340mpa·s.
Preferably, its raw material includes by weight: maleic anhydride 25-35 part, isophthalic anhydride 2-5 part, tetrachloro
Phthalic anhydride 4-8 part, d-33 monomer 1-5 part, benzenetriol 2-6 part, hydroquinone 3-5 part, cobalt naphthenate styrene 1-4 part, phosphate ester
Tripolycyanamide 4-8 part, methyl ethyl ketone peroxide 3-6 part, nano silicon 1-6 part, Nano diamond 3-5 part, modified carbon nano tube
Pipe 4-8 part, ethylene glycol 5-15 part, diglycol 3-5 part, propylene glycol 4-9 part.
Preferably, its raw material includes by weight: 30 parts of maleic anhydride, 3.5 parts of isophthalic anhydride, tetrachlorophthalic anhydride
6 parts, 3 parts of d-33 monomer, 4 parts of benzenetriol, 4 parts of hydroquinone, 2.5 parts of cobalt naphthenate styrene, 6 parts of phosphate ester tripolycyanamide,
4.5 parts of methyl ethyl ketone peroxide, 3.5 parts of nano silicon, 4 parts of Nano diamond, 6 parts of modified carbon nano-tube, 10 parts of ethylene glycol,
4 parts of diglycol, 6 parts of propylene glycol.
The preparation method of the present invention, comprises the steps:
S1, by ethylene glycol, diglycol, propylene glycol and isophthalic anhydride mix homogeneously, be warming up to 180-220 DEG C
Insulation 1-3h, is then cooled to 150-160 DEG C, adds maleic anhydride, tetrachlorophthalic anhydride and d-33 monomer mix homogeneously, then
It is warming up to 180-190 DEG C, be incubated 2-4h, be cooled to room temperature and obtain material a；
S2, in material a add benzenetriol, be warming up to 195-205 DEG C, be incubated 1-3h, controls vacuum be 0.1-
0.2gpa continuous evacuation 1-3h controls acid number to stop evacuation after 20-30mgkoh/g and start to be cooled to 175-185 DEG C of throwing
Enter hydroquinone mix homogeneously, cold go to obtain material b to room temperature；
S3, in material b add cobalt naphthenate styrene, be warming up to 125-145 DEG C, be incubated 0.5-1.5h, then in
400-600r/min stirs 30-50min, is then cooled to 60-80 DEG C, is incubated 0.5-1.5h, is subsequently added into phosphate ester melamine
Amine, stirs 15-25min in 250-350r/min, is cooled to room temperature and obtains material c；
S4, add nano silicon, Nano diamond and modified carbon nano-tube mix homogeneously in material c, in 1500-
2500r/min stirs 30-50min, is subsequently added into methyl ethyl ketone peroxide mix homogeneously, ultrasonic disperse 10-20min obtains Anchor Agent
Unsaturated polyester resin with excellent mechanical performance.
A kind of Anchor Agent of present invention unsaturated polyester resin of excellent mechanical performance, its raw material includes maleic acid
Acid anhydride, isophthalic anhydride, tetrachlorophthalic anhydride, d-33 monomer, benzenetriol, hydroquinone, cobalt naphthenate styrene, phosphate ester melamine
Amine, methyl ethyl ketone peroxide, nano silicon, Nano diamond, modified carbon nano-tube, ethylene glycol, diglycol and third
Glycol.Wherein using maleic anhydride, isophthalic anhydride and tetrachlorophthalic anhydride as primary response thing, with ethylene glycol, a contracting diethyl
Glycol and propylene glycol as alcohol reactant, with d-33 monomer, benzenetriol, hydroquinone, cobalt naphthenate styrene and phosphate ester three
Poly cyanamid as secondary response thing, using methyl ethyl ketone peroxide as initiator, with nano silicon, Nano diamond, carbon modified
Nanotube has excellent mechanical property, the wherein modification of interpolation as filler, the unsaturated polyester resin through preparing
CNT with CNT, dichloroethanes, thionyl chloride and 2- propylene -1- alcohol as raw material, through thionyl chloride by carbon nanometer
Hydroxyl on pipe is activated, and then dichloroethanes carry out chlorine atom replacement, is grafted to insatiable hunger in the presence of 2- propylene -1- alcohol
On polyester resin, effectively increase the mechanical property of unsaturated polyester resin.The unsaturated polyester resin of the present invention is applied to
The preparation of Anchor Agent, has excellent mechanical property, disclosure satisfy that the demand for mechanical property in Anchor Agent preparation process.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail it should be appreciated that embodiment is served only for this is described
Bright, rather than be used for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are all at this
In bright protection domain.
In specific embodiment, the weight portion of maleic anhydride can for 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30
Part, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts；The weight portion of isophthalic anhydride can for 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts；The weight portion of tetrachlorophthalic anhydride can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8
Part；The weight portion of d-33 monomer can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；The weight portion of benzenetriol can for 2 parts, 3 parts, 4 parts,
5 parts, 6 parts；The weight portion of hydroquinone can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The cinnamic weight portion of cobalt naphthenate
Can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of phosphate ester tripolycyanamide can for 4 parts, 4.5
Part, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The weight portion of methyl ethyl ketone peroxide can for 3 parts, 3.5 parts, 4 parts,
4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of nano silicon can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of Nano diamond can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Carbon modified
The weight portion of nanotube can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The weight of ethylene glycol
Part can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight of diglycol
Part can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of propylene glycol can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts,
6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts.
Embodiment 1
A kind of Anchor Agent proposed by the present invention unsaturated polyester resin of excellent mechanical performance, its raw material wraps by weight
Include: 30 parts of maleic anhydride, 3.5 parts of isophthalic anhydride, 6 parts of tetrachlorophthalic anhydride, 3 parts of d-33 monomer, 4 parts of benzenetriol, to benzene
4 parts of diphenol, 2.5 parts of cobalt naphthenate styrene, 6 parts of phosphate ester tripolycyanamide, 4.5 parts of methyl ethyl ketone peroxide, nano silicon
3.5 parts, 4 parts of Nano diamond, 6 parts of modified carbon nano-tube, 10 parts of ethylene glycol, 4 parts of diglycol, 6 parts of propylene glycol.
Embodiment 2
A kind of Anchor Agent proposed by the present invention unsaturated polyester resin of excellent mechanical performance, its raw material wraps by weight
Include: 25 parts of maleic anhydride, 5 parts of isophthalic anhydride, 4 parts of tetrachlorophthalic anhydride, 5 parts of d-33 monomer, 2 parts of benzenetriol, to benzene two
5 parts of phenol, 1 part of cobalt naphthenate styrene, 8 parts of phosphate ester tripolycyanamide, 3 parts of methyl ethyl ketone peroxide, 6 parts of nano silicon, receive
3 parts of diamond of rice, 8 parts of modified carbon nano-tube, 5 parts of ethylene glycol, 5 parts of diglycol, 4 parts of propylene glycol.
Modified carbon nano-tube is prepared by following technique: by weight by 3 parts of CNTs and 3 parts of dichloroethanes mixing
Uniformly, supersound process 1h, is subsequently added into 4 parts of thionyl chlorides, magnetic agitation 20min, is then warming up to 90 DEG C, and flow back 20h, cooling
Add 3 parts of 2- propylene -1- alcohol mix homogeneously to room temperature, be then warming up to 45 DEG C, stir 26h, then use washing with acetone 1 time,
After centrifugation, solid is dried 6h in 50 DEG C, is cooled to room temperature and obtains modified carbon nano-tube.
In the raw material of modified carbon nano-tube, specific surface area 40m of CNT2/ g, heat conductivity 2200w/ (m k), outward
Footpath is 30nm, and length is 3 μm.
The mass fraction of solids of methyl ethyl ketone peroxide is 45%, and acid number is 14mgkoh/g, and viscosity is 320mpa s.
Embodiment 3
A kind of Anchor Agent proposed by the present invention unsaturated polyester resin of excellent mechanical performance, its raw material wraps by weight
Include: 35 parts of maleic anhydride, 2 parts of isophthalic anhydride, 8 parts of tetrachlorophthalic anhydride, 1 part of d-33 monomer, 6 parts of benzenetriol, to benzene two
3 parts of phenol, 4 parts of cobalt naphthenate styrene, 4 parts of phosphate ester tripolycyanamide, 6 parts of methyl ethyl ketone peroxide, 1 part of nano silicon, receive
5 parts of diamond of rice, 4 parts of modified carbon nano-tube, 15 parts of ethylene glycol, 3 parts of diglycol, 9 parts of propylene glycol.
Modified carbon nano-tube is prepared by following technique: by weight by 6 parts of CNTs and 1 part of dichloroethanes mixing
Uniformly, supersound process 3h, is subsequently added into 2 parts of thionyl chlorides, magnetic agitation 40min, is then warming up to 80 DEG C, and flow back 30h, cooling
Add 1 part of 2- propylene -1- alcohol mix homogeneously to room temperature, be then warming up to 55 DEG C, stir 22h, then use washing with acetone 4 times,
After centrifugation, solid is dried 12h in 40 DEG C, is cooled to room temperature and obtains modified carbon nano-tube.
In the raw material of modified carbon nano-tube, specific surface area 300m of CNT2/ g, heat conductivity 1800w/ (m k),
External diameter is 50nm, and length is 3 μm.
The mass fraction of solids of methyl ethyl ketone peroxide is 60%, and acid number is 10mgkoh/g, and viscosity is 340mpa s.
Embodiment 4
A kind of Anchor Agent proposed by the present invention unsaturated polyester resin of excellent mechanical performance, its raw material wraps by weight
Include: 25 parts of maleic anhydride, 5 parts of isophthalic anhydride, 4 parts of tetrachlorophthalic anhydride, 5 parts of d-33 monomer, 2 parts of benzenetriol, to benzene two
5 parts of phenol, 1 part of cobalt naphthenate styrene, 8 parts of phosphate ester tripolycyanamide, 3 parts of methyl ethyl ketone peroxide, 6 parts of nano silicon, receive
3 parts of diamond of rice, 8 parts of modified carbon nano-tube, 5 parts of ethylene glycol, 5 parts of diglycol, 4 parts of propylene glycol.
Modified carbon nano-tube is prepared by following technique: mixes 4 parts of CNTs and 2.5 parts of dichloroethanes by weight
Close uniformly, supersound process 1.5h, it is subsequently added into 3.5 parts of thionyl chlorides, magnetic agitation 25min, be then warming up to 88 DEG C, backflow
22h, adds 2.5 parts of 2- propylene -1- alcohol mix homogeneously after being cooled to room temperature, is then warming up to 48 DEG C, stir 25h, then with third
Ketone washs 2 times, after centrifugation, solid is dried 7h in 48 DEG C, is cooled to room temperature and obtains modified carbon nano-tube.
In the raw material of modified carbon nano-tube, specific surface area 45m of CNT2/ g, heat conductivity 2150w/ (m k), outward
Footpath is 38nm, and length is 3 μm.
The mass fraction of solids of methyl ethyl ketone peroxide is 46%, and acid number is 13mgkoh/g, and viscosity is 325mpa s.
Embodiment 5
A kind of Anchor Agent proposed by the present invention unsaturated polyester resin of excellent mechanical performance, its raw material wraps by weight
Include: 35 parts of maleic anhydride, 2 parts of isophthalic anhydride, 8 parts of tetrachlorophthalic anhydride, 1 part of d-33 monomer, 6 parts of benzenetriol, to benzene two
3 parts of phenol, 4 parts of cobalt naphthenate styrene, 4 parts of phosphate ester tripolycyanamide, 6 parts of methyl ethyl ketone peroxide, 1 part of nano silicon, receive
5 parts of diamond of rice, 4 parts of modified carbon nano-tube, 15 parts of ethylene glycol, 3 parts of diglycol, 9 parts of propylene glycol.
Modified carbon nano-tube is prepared by following technique: mixes 5 parts of CNTs and 1.5 parts of dichloroethanes by weight
Close uniformly, supersound process 2.5h, it is subsequently added into 2.5 parts of thionyl chlorides, magnetic agitation 35min, be then warming up to 82 DEG C, backflow
28h, adds 1.5 parts of 2- propylene -1- alcohol mix homogeneously after being cooled to room temperature, is then warming up to 52 DEG C, stir 23h, then with third
Ketone washs 3 times, after centrifugation, solid is dried 11h in 42 DEG C, is cooled to room temperature and obtains modified carbon nano-tube.
In the raw material of modified carbon nano-tube, specific surface area 295m of CNT2/ g, heat conductivity 1850w/ (m k),
External diameter is 42nm, and length is 3 μm.
The mass fraction of solids of methyl ethyl ketone peroxide is 59%, and acid number is 11mgkoh/g, and viscosity is 325mpa s.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. a kind of unsaturated polyester resin of Anchor Agent excellent mechanical performance is it is characterised in that its raw material includes by weight:
Maleic anhydride 25-35 part, isophthalic anhydride 2-5 part, tetrachlorophthalic anhydride 4-8 part, d-33 monomer 1-5 part, benzenetriol 2-6
Part, hydroquinone 3-5 part, cobalt naphthenate styrene 1-4 part, phosphate ester tripolycyanamide 4-8 part, methyl ethyl ketone peroxide 3-6 part, receive
- 6 parts of silica 1 of rice, Nano diamond 3-5 part, modified carbon nano-tube 4-8 part, ethylene glycol 5-15 part, diglycol 3-
5 parts, propylene glycol 4-9 part.
2. Anchor Agent according to claim 1 with the unsaturated polyester resin of excellent mechanical performance it is characterised in that modification
CNT is prepared by following technique: CNT and dichloroethanes mix homogeneously, supersound process 1-3h are subsequently added into
Thionyl chloride, magnetic agitation 20-40min, then it is warming up to 80-90 DEG C, flow back 20-30h, after being cooled to room temperature, add 2- third
Alkene -1- alcohol mix homogeneously, is then warming up to 45-55 DEG C, stirs 22-26h, then uses washing with acetone 1-4 time, after centrifugation,
Solid is dried 6-12h in 40-50 DEG C, is cooled to room temperature and obtains modified carbon nano-tube.
3. Anchor Agent according to claim 1 and 2 with the unsaturated polyester resin of excellent mechanical performance it is characterised in that
In the preparation process of modified carbon nano-tube, CNT, the weight of dichloroethanes, thionyl chloride and 2- propylene -1- alcohol are than for 3-
6:1-3:2-4:1-3.
4. the unsaturated polyester resin of excellent mechanical performance of the Anchor Agent according to any one of claim 1-3, its feature
It is, in the raw material of modified carbon nano-tube, specific surface area 40-300m of CNT2/ g, heat conductivity 1800-2200w/
(m k), external diameter is 30-50nm, and length is 3 μm.
5. the unsaturated polyester resin of excellent mechanical performance of the Anchor Agent according to any one of claim 1-4, its feature
It is, the mass fraction of solids of methyl ethyl ketone peroxide is 45-60%, and acid number is 10-14mgkoh/g, and viscosity is 320-
340mpa·s.
6. the unsaturated polyester resin of excellent mechanical performance of the Anchor Agent according to any one of claim 1-5, its feature
Be, its raw material includes by weight: maleic anhydride 25-35 part, isophthalic anhydride 2-5 part, tetrachlorophthalic anhydride 4-8 part,
D-33 monomer 1-5 part, benzenetriol 2-6 part, hydroquinone 3-5 part, cobalt naphthenate styrene 1-4 part, phosphate ester tripolycyanamide 4-8
Part, methyl ethyl ketone peroxide 3-6 part, nano silicon 1-6 part, Nano diamond 3-5 part, modified carbon nano-tube 4-8 part, second two
Alcohol 5-15 part, diglycol 3-5 part, propylene glycol 4-9 part.
7. the unsaturated polyester resin of excellent mechanical performance of the Anchor Agent according to any one of claim 1-6, its feature
It is, its raw material includes by weight: 30 parts of maleic anhydride, 3.5 parts of isophthalic anhydride, 6 parts of tetrachlorophthalic anhydride, d-33 are mono-
3 parts of body, 4 parts of benzenetriol, 4 parts of hydroquinone, 2.5 parts of cobalt naphthenate styrene, 6 parts of phosphate ester tripolycyanamide, peroxidating first and second
4.5 parts of ketone, 3.5 parts of nano silicon, 4 parts of Nano diamond, 6 parts of modified carbon nano-tube, 10 parts of ethylene glycol, a contracting diethyl two
4 parts of alcohol, 6 parts of propylene glycol.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111497274A (en) * | 2020-03-25 | 2020-08-07 | 福建安东实业有限公司 | Preparation method of impact-resistant strain-corrosion-resistant continuous winding glass reinforced plastic pipe |
| CN113652068A (en) * | 2021-08-19 | 2021-11-16 | 国能铁路装备有限责任公司 | Nano composite plastic, preparation method thereof and three-dimensional mark |
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| CN111497274A (en) * | 2020-03-25 | 2020-08-07 | 福建安东实业有限公司 | Preparation method of impact-resistant strain-corrosion-resistant continuous winding glass reinforced plastic pipe |
| CN113652068A (en) * | 2021-08-19 | 2021-11-16 | 国能铁路装备有限责任公司 | Nano composite plastic, preparation method thereof and three-dimensional mark |
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