CN106365528A - Antibacterial self-cleaning ceramic coating and preparation method of same - Google Patents

Antibacterial self-cleaning ceramic coating and preparation method of same Download PDF

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Publication number
CN106365528A
CN106365528A CN201610716884.XA CN201610716884A CN106365528A CN 106365528 A CN106365528 A CN 106365528A CN 201610716884 A CN201610716884 A CN 201610716884A CN 106365528 A CN106365528 A CN 106365528A
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ceramic coating
nano titanium
self
powder
coating
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刘智曙
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FOSHAN DONGFANG ZHIBO NANO MATERIAL SCIENCE & TECHNOLOGY Co Ltd
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FOSHAN DONGFANG ZHIBO NANO MATERIAL SCIENCE & TECHNOLOGY Co Ltd
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Priority to CN201610716884.XA priority Critical patent/CN106365528A/en
Publication of CN106365528A publication Critical patent/CN106365528A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/022—Carbon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/06—Quartz; Sand
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/10—Clay
    • C04B14/104—Bentonite, e.g. montmorillonite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/30—Oxides other than silica
    • C04B14/305—Titanium oxide, e.g. titanates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04—Waste materials; Refuse
    • C04B18/0427—Dry materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08—Acids or salts thereof
    • C04B22/16—Acids or salts thereof containing phosphorus in the anion, e.g. phosphates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24—Macromolecular compounds
    • C04B24/38—Polysaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008—Obtaining or using nanotechnology related materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an antibacterial self-cleaning ceramic coating and a preparation method of same. The ceramic coating is mainly prepared from ceramic micro-powder, magnetic wave stone powder, cement, waste stainless steel powder, porous powdery quartz, nano titanium dioxide, nano montmorillonite, hydrophobic fumed silica, hydroxypropyl chitosan, (heptadecafluoro-1,1,2,2-tetradecyl)trimethoxysilane, etc. The ceramic coating is prepared by matching nano titanium dioxide and nano montmorillonite, wherein the special structure of the nano montmorillonite has adsorption effect on bacteria, and the nano titanium dioxide has strong killing effects on the bacteria due to photocatalysis. The two components are matched with each other to achieve strong antibacterial capability. Meanwhile, the added magnetic wave stone powder, algae carbon and the like can significantly improve the antibacterial performance of the coating; in addition, by addition of the nano titanium dioxide, the (heptadecafluoro-1,1,2,2-tetradecyl)trimethoxysilane, the nano titanium phosphate and the like, the coating has excellent self-cleaning performance; by addition of the waste stainless steel powder, the aluminum dihydrogen tripolyphosphate and the like, the ceramic coating is improved in anti-wear performance and high-temperature stability.

Description

A kind of antibiosis and self-cleaning ceramic coating and preparation method thereof
Technical field
The present invention relates to ceramic coating technical field, more specifically a kind of antibiosis and self-cleaning ceramic coating and its preparation side Method.
Background technology
Ceramic coating belongs to field of functional coatings, is a kind of new aqueous inorganic paint.It is with nano inorganic chemical combination Thing is main component, generally goes through high-temperature heating mode and solidify after application, film as forming properties and ceramic phase.With coating Industrial expansion, some organic coatings can not meet the requirement to environmental protection, multifunction and premium properties for the people, and The development of ceramic coating opens the progress and research to high-new paint field, meets people further for lifting coating The vision of energy.
However, existing ceramic coating generally existing anti-microbial property is poor, and the height of some high-grade devices cannot be met simultaneously Wear-resisting, high temperature resistant, water boiling resistance and the requirement of corrosion resistance.
Content of the invention
The invention aims to making up the deficiencies in the prior art, provide a kind of antibiosis and self-cleaning ceramic coating and its preparation Method.
The purpose of the present invention is achieved through the following technical solutions:
A kind of antibiosis and self-cleaning ceramic coating, is made up of following raw material: ceramic 30-35, magnetic wave stone powder 8-12, cement 8-10, discarded stainless steel powder 3-5, porous konilite 2-4, nano titanium oxide 2-4, nanometer Montmorillonitum 3-5, hydrophobicity gas phase two Silicon oxide 1-3, hydroxypropyl chitosan 2-4,17 fluorine decyl triethoxysilane 1-3, sapindoside 1-2, organosilicon microsphere 1-3, aethiops vegetabilis 2-4, dehydrated alcohol 14-16, Adeps Bovis seu Bubali diamidogen two oleate 3-5, nanometer titanium phosphate 2-4, aluminium dihydrogen tripolyphosphate 1-3, inulin lauryl carbamate 1-2, methyl silicon sodium alcoholate 3-5.
A kind of preparation method of antibiosis and self-cleaning ceramic coating, comprises the following steps:
(1) weigh each raw material by weight；
(2) by magnetic wave stone powder, porous konilite, nanometer Montmorillonitum, 17 fluorine decyl triethoxysilanes, dehydrated alcohol, Adeps Bovis seu Bubali Diamidogen two oleate and appropriate water add in container and are stirred, then the material after stirring are carried out be crushed to fineness little 1um, obtains mixing slurry；
(3) discarded stainless steel powder, nano titanium oxide, hydrophobicity aerosil, hydroxypropyl are added in reactor Sugar, sapindoside, organosilicon microsphere, aethiops vegetabilis, nanometer titanium phosphate, inulin lauryl carbamate, methyl silicon sodium alcoholate and The mixing slurry that step (2) is obtained, adds aluminium dihydrogen tripolyphosphate and obtains mixed material after stirring；
(4) mixed material adding step (3) to prepare in homogenizer, adds the remaining materials such as ceramic, cement, Stir to after be sufficiently mixed, obtain final product antibiosis and self-cleaning ceramic coating.
It is an advantage of the current invention that:
The ceramic coating of the present invention adopts nano titanium oxide and nanometer Montmorillonitum cooperation, and the special construction of nanometer Montmorillonitum is to thin Bacterium has adsorption, nano titanium oxide then antibacterial is had under photocatalysiss very strong kill effect, the two cooperation, Sterilization capability is strong, the magnetic wave stone powder that simultaneously adds, hydroxypropyl chitosan, sapindoside, aethiops vegetabilis, can significantly improve coating Anti-microbial property, in addition, nano titanium oxide, 17 fluorine decyl triethoxysilanes, organosilicon microsphere, hydrophobicity gas phase dioxy The interpolation of the raw materials such as SiClx, nanometer titanium phosphate is so that coating has excellent self-cleaning performance, discarded stainless steel powder, trimerization phosphorus The compositions such as acid dihydride aluminum then increased wearability and the high-temperature stability of product.Product entirety strong antibacterial of the present invention, wear-resisting Property and resistance to elevated temperatures are excellent, and have good self-cleaning property.
Specific embodiment
Embodiment 1, a kind of antibiosis and self-cleaning ceramic coating, it is made up of following weight portion (kg) raw material: ceramic 30, magnetic wave Stone powder 8, cement 8, discarded stainless steel powder 3, porous konilite 2, nano titanium oxide 2, nanometer Montmorillonitum 3, hydrophobicity gas phase two Silicon oxide 1, hydroxypropyl chitosan 2,17 fluorine decyl triethoxysilanes 1, sapindoside 1, organosilicon microsphere 1, aethiops vegetabilis 2nd, dehydrated alcohol 14, Adeps Bovis seu Bubali diamidogen two oleate 3, nanometer titanium phosphate 2, aluminium dihydrogen tripolyphosphate 1, inulin lauryl aminocarbamic acid Ester 1, methyl silicon sodium alcoholate 3.
A kind of preparation method of antibiosis and self-cleaning ceramic coating, comprises the following steps:
(1) weigh each raw material by weight；
(2) by magnetic wave stone powder, porous konilite, nanometer Montmorillonitum, 17 fluorine decyl triethoxysilanes, dehydrated alcohol, Adeps Bovis seu Bubali Diamidogen two oleate and appropriate water add in container and are stirred, then the material after stirring are carried out be crushed to fineness little 1um, obtains mixing slurry；
(3) discarded stainless steel powder, nano titanium oxide, hydrophobicity aerosil, hydroxypropyl are added in reactor Sugar, sapindoside, organosilicon microsphere, aethiops vegetabilis, nanometer titanium phosphate, inulin lauryl carbamate, methyl silicon sodium alcoholate and The mixing slurry that step (2) is obtained, adds aluminium dihydrogen tripolyphosphate and obtains mixed material after stirring；
(4) mixed material adding step (3) to prepare in homogenizer, adds the remaining materials such as ceramic, cement, Stir to after be sufficiently mixed, obtain final product antibiosis and self-cleaning ceramic coating.
Embodiment 2, a kind of antibiosis and self-cleaning ceramic coating, it is made up of following weight portion (kg) raw material: ceramic 33, magnetic wave Stone powder 10, cement 9, discarded stainless steel powder 4, porous konilite 3, nano titanium oxide 3, nanometer Montmorillonitum 4, hydrophobicity gas phase two Silicon oxide 2, hydroxypropyl chitosan 3,17 fluorine decyl triethoxysilanes 2, sapindoside 2, organosilicon microsphere 2, aethiops vegetabilis 3rd, dehydrated alcohol 15, Adeps Bovis seu Bubali diamidogen two oleate 4, nanometer titanium phosphate 3, aluminium dihydrogen tripolyphosphate 2, inulin lauryl aminocarbamic acid Ester 1, methyl silicon sodium alcoholate 4.
A kind of preparation method of antibiosis and self-cleaning ceramic coating, comprises the following steps:
(1) weigh each raw material by weight；
(2) by magnetic wave stone powder, porous konilite, nanometer Montmorillonitum, 17 fluorine decyl triethoxysilanes, dehydrated alcohol, Adeps Bovis seu Bubali Diamidogen two oleate and appropriate water add in container and are stirred, then the material after stirring are carried out be crushed to fineness little 1um, obtains mixing slurry；
(3) discarded stainless steel powder, nano titanium oxide, hydrophobicity aerosil, hydroxypropyl are added in reactor Sugar, sapindoside, organosilicon microsphere, aethiops vegetabilis, nanometer titanium phosphate, inulin lauryl carbamate, methyl silicon sodium alcoholate and The mixing slurry that step (2) is obtained, adds aluminium dihydrogen tripolyphosphate and obtains mixed material after stirring；
(4) mixed material adding step (3) to prepare in homogenizer, adds the remaining materials such as ceramic, cement, Stir to after be sufficiently mixed, obtain final product antibiosis and self-cleaning ceramic coating.
Embodiment 3, a kind of antibiosis and self-cleaning ceramic coating, it is made up of following weight portion (kg) raw material: ceramic 35, magnetic wave Stone powder 12, cement 10, discarded stainless steel powder 5, porous konilite 4, nano titanium oxide 4, nanometer Montmorillonitum 5, hydrophobicity gas phase Silicon dioxide 3, hydroxypropyl chitosan 4,17 fluorine decyl triethoxysilanes 3, sapindoside 2, organosilicon microsphere 3, Sargassum Charcoal 4, dehydrated alcohol 16, Adeps Bovis seu Bubali diamidogen two oleate 5, nanometer titanium phosphate 4, aluminium dihydrogen tripolyphosphate 3, inulin lauryl Ji Anjijia Acid esters 2, methyl silicon sodium alcoholate 5.
A kind of preparation method of antibiosis and self-cleaning ceramic coating, comprises the following steps:
(1) weigh each raw material by weight；
(2) by magnetic wave stone powder, porous konilite, nanometer Montmorillonitum, 17 fluorine decyl triethoxysilanes, dehydrated alcohol, Adeps Bovis seu Bubali Diamidogen two oleate and appropriate water add in container and are stirred, then the material after stirring are carried out be crushed to fineness little 1um, obtains mixing slurry；
(3) discarded stainless steel powder, nano titanium oxide, hydrophobicity aerosil, hydroxypropyl are added in reactor Sugar, sapindoside, organosilicon microsphere, aethiops vegetabilis, nanometer titanium phosphate, inulin lauryl carbamate, methyl silicon sodium alcoholate and The mixing slurry that step (2) is obtained, adds aluminium dihydrogen tripolyphosphate and obtains mixed material after stirring；
(4) mixed material adding step (3) to prepare in homogenizer, adds the remaining materials such as ceramic, cement, Stir to after be sufficiently mixed, obtain final product antibiosis and self-cleaning ceramic coating.
The ceramic coating main performance testing result that above-described embodiment 1-3 is obtained is as shown in the table:
The ceramic coating main performance testing result that table 1 embodiment 1-3 is obtained
Embodiment 1 Embodiment 2 Embodiment 3
Hardness, h ≥4 ≥5 ≥4
Paint film appearance Flat smooth Flat smooth Flat smooth
Resistance to water, 30 days, 25 DEG C Paint film is unchanged Paint film is unchanged Paint film is unchanged
Wearability, g, (700g/500r) ≤0.04 ≤0.03 ≤0.04
Antibiotic rate/% 99.2 99.8 99.4

Claims (2)

1. a kind of antibiosis and self-cleaning ceramic coating it is characterised in that: be made up of following raw material: ceramic 30-35, magnetic wave Stone powder 8-12, cement 8-10, discarded stainless steel powder 3-5, porous konilite 2-4, nano titanium oxide 2-4, nanometer Montmorillonitum 3- 5th, hydrophobicity aerosil 1-3, hydroxypropyl chitosan 2-4,17 fluorine decyl triethoxysilane 1-3, sapindoside 1-2, organosilicon microsphere 1-3, aethiops vegetabilis 2-4, dehydrated alcohol 14-16, Adeps Bovis seu Bubali diamidogen two oleate 3-5, nanometer titanium phosphate 2-4, Aluminium dihydrogen tripolyphosphate 1-3, inulin lauryl carbamate 1-2, methyl silicon sodium alcoholate 3-5.
2. a kind of antibiosis and self-cleaning ceramic coating according to claim 1 preparation method it is characterised in that: include following walking Rapid:
(1) weigh each raw material by weight；
(2) by magnetic wave stone powder, porous konilite, nanometer Montmorillonitum, 17 fluorine decyl triethoxysilanes, dehydrated alcohol, Adeps Bovis seu Bubali Diamidogen two oleate and appropriate water add in container and are stirred, then the material after stirring are carried out be crushed to fineness little 1um, obtains mixing slurry；
(3) discarded stainless steel powder, nano titanium oxide, hydrophobicity aerosil, hydroxypropyl are added in reactor Sugar, sapindoside, organosilicon microsphere, aethiops vegetabilis, nanometer titanium phosphate, inulin lauryl carbamate, methyl silicon sodium alcoholate and The mixing slurry that step (2) is obtained, adds aluminium dihydrogen tripolyphosphate and obtains mixed material after stirring；
(4) mixed material adding step (3) to prepare in homogenizer, adds the remaining materials such as ceramic, cement, Stir to after be sufficiently mixed, obtain final product antibiosis and self-cleaning ceramic coating.
CN201610716884.XA 2016-08-25 2016-08-25 Antibacterial self-cleaning ceramic coating and preparation method of same Pending CN106365528A (en)

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Publication number Priority date Publication date Assignee Title
CN107699086A (en) * 2017-10-11 2018-02-16 广东华兹卜新材料科技有限公司 A kind of flexible texture coating and preparation method thereof
CN109371780A (en) * 2018-11-23 2019-02-22 福建乐动体育场材料有限公司 A kind of luminous plastic runway
CN110194663A (en) * 2019-05-20 2019-09-03 陈海斗 A kind of preparation method of wearable ceramic coat layer
CN110734273A (en) * 2019-10-09 2020-01-31 安徽徽博先临三维云打印技术有限公司 3D printing-based cultural relic copying composite material and preparation method thereof

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CN102898092A (en) * 2012-09-06 2013-01-30 谭素珍 Eco-texture paint
CN105198360A (en) * 2015-11-14 2015-12-30 蒋文兰 Chlorite and montmorillonite mixed layer clay colored coating powder with air purification function
CN105418024A (en) * 2015-11-14 2016-03-23 蒋文兰 Colorized silica paint powder with air purifying function

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107699086A (en) * 2017-10-11 2018-02-16 广东华兹卜新材料科技有限公司 A kind of flexible texture coating and preparation method thereof
CN109371780A (en) * 2018-11-23 2019-02-22 福建乐动体育场材料有限公司 A kind of luminous plastic runway
CN109371780B (en) * 2018-11-23 2021-10-08 福建乐动体育场材料有限公司 Noctilucent plastic track
CN110194663A (en) * 2019-05-20 2019-09-03 陈海斗 A kind of preparation method of wearable ceramic coat layer
CN110734273A (en) * 2019-10-09 2020-01-31 安徽徽博先临三维云打印技术有限公司 3D printing-based cultural relic copying composite material and preparation method thereof

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Application publication date: 20170201