CN106362642A - High-performance oil spill dispersant for exploration and development of oil and gas in deep sea, and preparation method thereof - Google Patents
High-performance oil spill dispersant for exploration and development of oil and gas in deep sea, and preparation method thereof Download PDFInfo
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- CN106362642A CN106362642A CN201610643785.3A CN201610643785A CN106362642A CN 106362642 A CN106362642 A CN 106362642A CN 201610643785 A CN201610643785 A CN 201610643785A CN 106362642 A CN106362642 A CN 106362642A
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- polyoxyethylene ether
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
- C09K23/018—Mixtures of two or more different organic oxygen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Public Health (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The invention discloses a high-performance oil spill dispersant for exploration and development of oil and gas in deep sea and a preparation method thereof. The high-performance oil spill dispersant comprises the following raw materials by weight: 8 to 12 parts of oleyl alcohol polyoxyethylene ether benzoate, 5 to 10 parts of methylglucose polyoxypropylene ether acetate, 6 to 11 parts of alkyl naphthalene sulfonate, 9 to 14 parts of sodium diol bisulfosuccinate diester, 10 to 15 parts of isocetyl palmitate, 5 to 10 parts of polyoxypropylene dioleate, 7 to 13 parts of polyoxypropylene polyoxyethylene ethylhexanol ether, 6 to 9 parts of avocado oil glycereth ester and 10 to 15 parts of polyoxyethylene sorbitol tetraoleate. The oil spill dispersant prepared through compounding of surfactants like oleyl alcohol polyoxyethylene ether benzoate, isocetyl palmitate, polyoxypropylene polyoxyethylene ethylhexanol ether and avocado oil glycereth ester has excellent emulsification and dispersion performance, and is rapid, convenient, energy-saving, environment-friendly and completely applicable to exploration and development of oil and gas in sea.
Description
Technical field
The present invention relates to a kind of deep-sea oil gas exploration and development high-performance oil-spill dispersant and preparation method thereof, belong to water body
Prevention and cure of pollution field.
Background technology
With growing to oil and its product demand in world wide, offshore oil exploitation amount and freight volume are significantly
Degree increases, and oil spill accident happens occasionally, and oil spill has become occurrence frequency highest, distribution in various marine pollution types
The widest and maximum one kind of the extent of injury.Oil spilling can take various emergency measure after occurring, and is such as contained using the oil fence, machinery returns
Receipts, combustion (of oil) insitu or sprinkling chemical agent etc., wherein, spraying oil-spill dispersant to oil spilling sea is the relatively early one kind side adopting
Method, particularly wind and waves or enter that extra large oil mass is very big, the response rate very low in the case of using oil-spill dispersant, be conventional should
One of anxious measure.
Oil-spill dispersant is commonly called as " detergent ", and it is that have reduction oil spilling viscosity and capillary characteristic, is conducive to overflowing
Oily emulsion dispersion, is conducive to being fully contacted and mix of oil and water, so that oil is easy to by the biodegradation in water, by water body only
Change.Reasonable employment oil-spill dispersant is a kind of important means reducing oil spill and harm.But it is used for deep on existing market
The oil-spill dispersant of extra large oil-gas exploration and development has the undesirable shortcoming of dispersion and emulsion effect, greatly limit it and applies model
Enclose.
Content of the invention
For the deficiencies in the prior art, it is high that the problem to be solved in the present invention is to provide a kind of deep-sea oil gas exploration and development
Performance oil-spill dispersant and preparation method thereof.
For solving prior art problem, the following technical scheme of present invention offer:
A kind of deep-sea oil gas exploration and development high-performance oil-spill dispersant, is made up of the raw material of following weight portion: oleyl alcohol polyoxy second
The double succinum of alkene ester benzoic ether 8-12, methyl glucoside polyethenoxy ether acetass 5-10, alkylnaphthalene sulfonate 6-11, dihydroxylic alcohols
Acid diester sodium sulfonate 9-14, different spermol cetylate 10-15, two Oleic acid polyoxypropylene ester 5-10, ethyl hexanol polyoxypropylene
Polyoxyethylene ether 7-13, American Avocado Tree oil glycerin polyoxyethylene ether ester 6-9, sorbitol polyoxyethylene ether four oleate 10-15.
A kind of deep-sea oil gas exploration and development preparation method of high-performance oil-spill dispersant, comprises the following steps:
(1) by oleic alcohol polyoxyethylene ether benzoate, dihydroxylic alcohols double sodium sulfosuccinic diester, different spermol cetylate, crocodile
Pear oil glycerin polyoxyethylene ether ester mix homogeneously, is then 250-450w in power, under conditions of rotating speed is 800-1200r/min
Magnetic agitation 5-10min, obtains compound a；
(2) by remaining raw material mix homogeneously, it is then 300-500w in microwave power, rotating speed is the bar of 1000-1500r/min
Under part, microwave stirring 4-8min, obtains compound b；
(3) compound obtaining a is mixed homogeneously with compound b, be then 400-500w in ultrasonic power, supersonic frequency is
Ultrasonic vibration 30-40min under conditions of 25-35khz, gets product.
The invention has the advantages that:
The present invention pass through oleic alcohol polyoxyethylene ether benzoate, methyl glucoside polyethenoxy ether acetass, the double succinum of dihydroxylic alcohols
Acid diester sodium sulfonate, different spermol cetylate, ethyl hexanol polyoxyethylene polyoxypropylene ether, American Avocado Tree oil glycerin polyoxyethylene ether
The oil-spill dispersant of the surfactant compounds such as ester has excellent emulsion dispersion property, and fast and convenient, energy-conserving and environment-protective,
It is completely suitable for extra large oil-gas exploration and development.
Specific embodiment
Embodiment
A kind of deep-sea oil gas exploration and development high-performance oil-spill dispersant, is made up of the raw material of following weight (kg): oleyl alcohol
The double succinic acid of polyoxyethylene ether benzoate 10, methyl glucoside polyethenoxy ether acetass 8, alkylnaphthalene sulfonate 9, dihydroxylic alcohols
Dibasic acid esters sodium sulfonate 11, different spermol cetylate 12, two Oleic acid polyoxypropylene esters 8, ethyl hexanol polyoxyethylene polyoxypropylene ether
10th, American Avocado Tree oil glycerin polyoxyethylene ether ester 7, sorbitol polyoxyethylene ether four oleate 12.
A kind of deep-sea oil gas exploration and development preparation method of high-performance oil-spill dispersant, comprises the following steps:
(1) by oleic alcohol polyoxyethylene ether benzoate, dihydroxylic alcohols double sodium sulfosuccinic diester, different spermol cetylate, crocodile
Pear oil glycerin polyoxyethylene ether ester mix homogeneously, is then 350w in power, and rotating speed is magnetic agitation under conditions of 1000r/min
8min, obtains compound a；
(2) by remaining raw material mix homogeneously, it is then 400w in microwave power, rotating speed is microwave under conditions of 1200r/min
Stirring 6min, obtains compound b；
(3) compound obtaining a is mixed homogeneously with compound b, be then 450w in ultrasonic power, supersonic frequency is 30khz
Under conditions of ultrasonic vibration 35min, get product.
By the above-mentioned deep-sea oil gas exploration and development high-performance oil-spill dispersant preparing and crude oil according to 0.2:1 matter
Amount is than mixing, and is added in the artificial seawater of 50ml, after carrying out shaking emulsifying 3min, tests this deep-sea oil gas at 25 DEG C
Exploration and development high-performance oil-spill dispersant emulsion dispersion ability in the seawater to crude oil.Stand 5min and 20min respectively,
In 5min, emulsification rate reaches more than 76.2%, and in 20min, emulsification rate reaches 54.7%.
Claims (2)
1. a kind of deep-sea oil gas exploration and development with high-performance oil-spill dispersant it is characterised in that raw material group by following weight portion
Become: oleic alcohol polyoxyethylene ether benzoate 8-12, methyl glucoside polyethenoxy ether acetass 5-10, alkylnaphthalene sulfonate 6-
11st, dihydroxylic alcohols double sodium sulfosuccinic diester 9-14, different spermol cetylate 10-15, two Oleic acid polyoxypropylene ester 5-10, second
Base hexanol polyoxyethylene polyoxypropylene ether 7-13, American Avocado Tree oil glycerin polyoxyethylene ether ester 6-9, sorbitol polyoxyethylene ether four Oleic acid
Ester 10-15.
2. a kind of deep-sea oil gas exploration and development according to claim 1 preparation method of high-performance oil-spill dispersant, its
It is characterised by, comprise the following steps:
(1) by oleic alcohol polyoxyethylene ether benzoate, dihydroxylic alcohols double sodium sulfosuccinic diester, different spermol cetylate, crocodile
Pear oil glycerin polyoxyethylene ether ester mix homogeneously, is then 250-450w in power, under conditions of rotating speed is 800-1200r/min
Magnetic agitation 5-10min, obtains compound a；
(2) by remaining raw material mix homogeneously, it is then 300-500w in microwave power, rotating speed is the bar of 1000-1500r/min
Under part, microwave stirring 4-8min, obtains compound b；
(3) compound obtaining a is mixed homogeneously with compound b, be then 400-500w in ultrasonic power, supersonic frequency is
Ultrasonic vibration 30-40min under conditions of 25-35khz, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643785.3A CN106362642A (en) | 2016-08-08 | 2016-08-08 | High-performance oil spill dispersant for exploration and development of oil and gas in deep sea, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643785.3A CN106362642A (en) | 2016-08-08 | 2016-08-08 | High-performance oil spill dispersant for exploration and development of oil and gas in deep sea, and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106362642A true CN106362642A (en) | 2017-02-01 |
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ID=57879457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610643785.3A Pending CN106362642A (en) | 2016-08-08 | 2016-08-08 | High-performance oil spill dispersant for exploration and development of oil and gas in deep sea, and preparation method thereof |
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| Country | Link |
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| CN (1) | CN106362642A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832114A (en) * | 2017-03-10 | 2017-06-13 | 福建昆冈化学助剂科技有限公司 | The oil spilling detergent and its synthetic method of a kind of high-efficiency low-toxicity |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102335493A (en) * | 2010-07-29 | 2012-02-01 | 郑涵 | Biological oil spilling dispersing agent and preparation method thereof |
-
2016
- 2016-08-08 CN CN201610643785.3A patent/CN106362642A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102335493A (en) * | 2010-07-29 | 2012-02-01 | 郑涵 | Biological oil spilling dispersing agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832114A (en) * | 2017-03-10 | 2017-06-13 | 福建昆冈化学助剂科技有限公司 | The oil spilling detergent and its synthetic method of a kind of high-efficiency low-toxicity |
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Application publication date: 20170201 |