CN106362344A - Cold-resistant highly-efficient environment-friendly water-based fire-extinguishing agent and preparation method thereof - Google Patents

Cold-resistant highly-efficient environment-friendly water-based fire-extinguishing agent and preparation method thereof Download PDF

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Publication number
CN106362344A
CN106362344A CN201610640213.XA CN201610640213A CN106362344A CN 106362344 A CN106362344 A CN 106362344A CN 201610640213 A CN201610640213 A CN 201610640213A CN 106362344 A CN106362344 A CN 106362344A
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CN
China
Prior art keywords
agent
cold
environment
based fire
friendly type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610640213.XA
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Chinese (zh)
Inventor
钟思礼
周贵云
蒋天国
陈仕刚
张贤
陈云刚
蒲秋岑
喻劲松
陈建钧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Province Mianyang City Jixing Fire-Fighting Medicament Co Ltd
Sichuan University
Original Assignee
Sichuan Province Mianyang City Jixing Fire-Fighting Medicament Co Ltd
Sichuan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Province Mianyang City Jixing Fire-Fighting Medicament Co Ltd, Sichuan University filed Critical Sichuan Province Mianyang City Jixing Fire-Fighting Medicament Co Ltd
Priority to CN201610640213.XA priority Critical patent/CN106362344A/en
Publication of CN106362344A publication Critical patent/CN106362344A/en
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/0035Aqueous solutions
    • A62D1/0042"Wet" water, i.e. containing surfactant
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The invention discloses a cold-resistant highly-efficient environment-friendly water-based fire-extinguishing agent and a preparation method thereof. The water-based fire-extinguishing agent is composed of a foaming agent, a thickening agent, an antifreezing agent, an antiseptic, a corrosion inhibitor, a fire retardant and water. The preparation method comprises the following steps: weighing the components and adding water into an agitating tank; then successively adding the thickening agent, the antifreezing agent, the antiseptic, the corrosion inhibitor and the foaming agent; carrying out uniform stirring until the above materials are completely dissolved; and filtering a solution obtained in the previous step so as to obtain the finished cold-resistant highly-efficient environment-friendly water-based fire-extinguishing agent. Due to good synergism of the antifreezing agent, the fire extinguishing performance of the fire-extinguishing agent produced in the invention is improved during fire extinguishing; the antifreezing agent does not support combustion during fire extinguishing and can resist a low temperature of -15 to -20 DEG C; and the antifreezing agent used in the invention has great solubility, so no extra solubiliser is needed.

Description

A kind of cold-resistant efficient and environment-friendly type water based fire suppressant and preparation method thereof
Technical field
The present invention relates to a kind of water based fire suppressant, belong to fire control technology field.
Background technology
At present, the extinguishing chemical product that China produces mainly has powder extinguishing agent, gas extinguishing agent, water based fire suppressant.Water base Extinguishing chemical has that fire-fighting efficiency is high, anti-resume combustion performance strong, and extinguishing effect is better than other products, and no secondary pollution, nontoxic, stingless Sharp the features such as, do not result in environmental pollution.Therefore, water based fire suppressant obtains the weight of increasing research worker and user Depending on.
Eliminated to Halon extinguishing chemical in 2010 in China, China exists to the demand of efficient, environmental protection extinguishing chemical comprehensively It is continuously increased, especially for the extinguishing chemical of flammable liquid class fire.Therefore, one kind have efficiently, environmental protection, the cold-resistant, suitability Extensively, particularly to liquid fire, efficient extinguishing chemical has broad application prospects.Application number: 201510142887.2 China Patent provides a kind of cold-resistant aqueous film-forming foam extinguishing agent formula, and its composition includes: compound hc-surfactant 12%~ 30%, fluorocarbon surfactant 2%~5%, foam stabiliser 0.1%~1%, antifreeze 20%~50%, solubilizing agent 3%~ 5%, remaining is water.The extinguishing chemical that this formula produces needs when using to press the dilution proportion of 3:97 or 6:94, shape of putting out a fire with water Its freezing tolerance of weak solution under state will significantly decline, and far not reach -25 DEG C, therefore not be suitable for fill in extremely frigid zones and be Water base extinguisher uses, and in its raw material, antifreeze is ethylene glycol, and ethylene glycol is that combustibles can be to the intensity of a fire in fire extinguishing procedure in itself Play combustion-supporting effect.Application number: 201510142814.3 Chinese patent provides a kind of special foam fire-fighting agent prescription of f fire, Its composition includes: alkali metal salt 40%~70%, stabilizer 0.1%~0.5%, antifreeze 3%~5%, and thickening agent 1%~ 3% remaining be water.In this formula, alkali metal salt employs potassium carbonate in a large number, causes its solution ph to be higher than national standard, to going out The had corrosivity in the scene of a fire, and in this formula, antifreeze still adopts ethylene glycol, and the intensity of a fire can be played with combustion-supporting effect.
Technical scheme, present invention aims to the deficiency of prior art scheme, provides a kind of new water base fire extinguishing Agent and preparation method thereof, to meet it to cold-resistant, efficient and environmental protection requirement.
The technical scheme is that a kind of cold-resistant efficient and environment-friendly type water based fire suppressant, the weight of its component and each component Amount percentage composition is:
A kind of preparation method of cold-resistant efficient and environment-friendly type water based fire suppressant is it is characterised in that in turn include the following steps:
A, weigh each component according to quantity, first add water in agitator tank;Sequentially add thickening agent, antifreezing agent, preservative, delay Erosion agent, foaming agent;Uniform stirring is completely dissolved to material;
B, the solution obtaining upper step carry out filtering and obtain cold-resistant efficient and environment-friendly type water based fire suppressant product.
In such scheme: described foaming agent is sodium lauryl sulphate, dodecylbenzene sodium sulfonate, fatty alcohol polyoxy second One or more of alkene ether sodium sulfate, APG;Described thickening agent is xanthan gum, sodium alginate, guar gum, OK a karaoke club One or more of glue, pectin;Described antifreezing agent: sodium acetate, potassium acetate one or two;Described preservative: work One or more of the sodium benzoate of industry level, benzoic acid and potassium sorbate;Described corrosion inhibiter: mercaptobenzothiazoler, benzene And one or more of triazole and cetylamine;Described fire retardant: MAP, Diammonium phosphate (DAP) one or two.
Filter plant used by the present invention can adopt pressure filter, membrane filtration, vacuum filter, centrifuge etc..
The technology of the present invention has the advantage that
1. fire retardant of the present invention be MAP, Diammonium phosphate (DAP) one or two mixing, fire extinguishing when have with antifreeze Good synergism, improves extinguishing property;2. the antifreezing agent of traditional extinguishing chemical typically adopts ethylene glycol, and ethylene glycol is combustibles Matter, so there is combustion-supporting effect in fire extinguishing procedure.Antifreezing agent of the present invention adopts one or two mixing of sodium acetate, potassium acetate, Both materials are incombustible, not combustion-supporting in fire extinguishing procedure, also have the effect of fire extinguishing;3. the antifreeze acetic acid that the present invention adopts Sodium and potassium acetate, dissolubility is big, and in low concentration fire extinguishing agent solution, addition reaches 5~30%, can resist cold -15~-20 DEG C;4. originally The antifreeze that invention adopts, dissolubility is big, is not required to separately add solubilizing agent.
Specific embodiment
The each component of embodiments of the invention and content see table:
Weigh each material by above formula, first add water in agitator tank, sequentially add thickening agent, antifreezing agent, anti-corrosion Agent, corrosion inhibiter, foaming agent;Uniform stirring;Adopt vacuum filter after material is completely dissolved, filter and do not allow impurity, that is, obtain this Invention product resists cold efficient and environment-friendly type water based fire suppressant.Again the extinguishing chemical preparing is poured in fire extinguisher, packaged, pressurising 0.8mpa, installs special nozzle and generates complete fire extinguisher.
In the present invention, involved percentage composition is weight percentage as no really refer to.
Embodiments of the invention all can be implemented and can reach goal of the invention.
The invention is not restricted to these embodiments.

Claims (8)

1. a kind of cold-resistant efficient and environment-friendly type water based fire suppressant, the weight percentage of its component and each component is:
A, foaming agent 0.05 ~ 1.5%;
B, thickening agent 0.02 ~ 2%;
C, antifreezing agent 5 ~ 30%;
D, preservative 0.1 ~ 0.5%;
E, corrosion inhibiter 0.1 ~ 0.8%;
F, fire retardant 1.0 ~ 5.0%;
G, water surplus.
2. cold-resistant efficient and environment-friendly type water based fire suppressant according to claim 1 is it is characterised in that described foaming agent is ten One of sodium dialkyl sulfate, dodecylbenzene sodium sulfonate, polyoxyethylenated alcohol sodium sulfate, APG or many Kind.
3. cold-resistant efficient and environment-friendly type water based fire suppressant according to claim 1 is it is characterised in that described thickening agent is Huang One or more of virgin rubber, sodium alginate, guar gum, carrageenan, pectin.
4. cold-resistant efficient and environment-friendly type water based fire suppressant according to claim 1 is it is characterised in that described antifreezing agent is second Sour sodium, potassium acetate one or two.
5. cold-resistant efficient and environment-friendly type water based fire suppressant according to claim 1 is it is characterised in that described preservative is work One or more of the sodium benzoate of industry level, benzoic acid and potassium sorbate.
6. cold-resistant efficient and environment-friendly type water based fire suppressant according to claim 1 is it is characterised in that described corrosion inhibiter is mercapto One or more of base benzothiazole, benzotriazole and cetylamine.
7. cold-resistant efficient and environment-friendly type water based fire suppressant according to claim 1 is it is characterised in that described fire retardant is phosphorus A sour ammonium, Diammonium phosphate (DAP) one or two.
8. a kind of preparation method of cold-resistant efficient and environment-friendly type water based fire suppressant is it is characterised in that in turn include the following steps:
A, weigh each component according to quantity, first add water in agitator tank;Sequentially add thickening agent, antifreezing agent, preservative, inhibition Agent, foaming agent;Uniform stirring is completely dissolved to material;
B, the solution obtaining upper step carry out filtering and obtain cold-resistant efficient and environment-friendly type water based fire suppressant product.
CN201610640213.XA 2016-08-05 2016-08-05 Cold-resistant highly-efficient environment-friendly water-based fire-extinguishing agent and preparation method thereof Withdrawn CN106362344A (en)

Priority Applications (1)

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CN201610640213.XA CN106362344A (en) 2016-08-05 2016-08-05 Cold-resistant highly-efficient environment-friendly water-based fire-extinguishing agent and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610640213.XA CN106362344A (en) 2016-08-05 2016-08-05 Cold-resistant highly-efficient environment-friendly water-based fire-extinguishing agent and preparation method thereof

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CN106362344A true CN106362344A (en) 2017-02-01

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107376181A (en) * 2017-07-20 2017-11-24 北京久久神龙消防器材有限公司 Suitable for 20 DEG C ~ 55 DEG C water-based extinguishing agents and preparation method thereof
CN108042967A (en) * 2017-12-27 2018-05-18 广东自由能科技股份有限公司 A kind of fluorine-containing high-efficiency environment friendly extinguishing chemical and preparation method thereof
CN109224355A (en) * 2017-07-10 2019-01-18 南京市高淳消防药剂有限公司 A kind of water-based extinguishing agent and preparation method thereof
CN110102006A (en) * 2019-06-27 2019-08-09 江西圣辉生化科技有限公司 A kind of extinguishing chemical and preparation method thereof
CN110237480A (en) * 2018-06-10 2019-09-17 江苏锁龙消防科技股份有限公司 A kind of no PFOS non-fusibility aqueous film-forming foam extinguishing agent and preparation method thereof
CN110237479A (en) * 2018-06-10 2019-09-17 江苏锁龙消防科技股份有限公司 A kind of no PFOS aqueous film-forming foam extinguishing agent
CN110292739A (en) * 2019-07-29 2019-10-01 西安赛特实业有限公司 A kind of antifreeze fire-fighting liquid against corrosion of environmental protection and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5651416A (en) * 1995-08-22 1997-07-29 The United States Of America As Represented By The Secretary Of The Army Fire extinguishing method
CN102319499A (en) * 2011-07-19 2012-01-18 南京理工大学 Built-up synergetic class-A/B water extinguishing agent series
CN102350032A (en) * 2011-08-02 2012-02-15 英德市坤煌科技开发有限公司 Environmental-friendly water-based fire extinguishing agent and its preparation method
CN102274604B (en) * 2011-06-24 2013-03-27 南京理工大学 Water-base extinguishing agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5651416A (en) * 1995-08-22 1997-07-29 The United States Of America As Represented By The Secretary Of The Army Fire extinguishing method
CN102274604B (en) * 2011-06-24 2013-03-27 南京理工大学 Water-base extinguishing agent
CN102319499A (en) * 2011-07-19 2012-01-18 南京理工大学 Built-up synergetic class-A/B water extinguishing agent series
CN102350032A (en) * 2011-08-02 2012-02-15 英德市坤煌科技开发有限公司 Environmental-friendly water-based fire extinguishing agent and its preparation method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109224355A (en) * 2017-07-10 2019-01-18 南京市高淳消防药剂有限公司 A kind of water-based extinguishing agent and preparation method thereof
CN107376181A (en) * 2017-07-20 2017-11-24 北京久久神龙消防器材有限公司 Suitable for 20 DEG C ~ 55 DEG C water-based extinguishing agents and preparation method thereof
CN107376181B (en) * 2017-07-20 2020-07-24 北京久久神龙消防器材有限公司 Water-based fire extinguishing agent applicable to-20-55 ℃ and preparation method thereof
CN108042967A (en) * 2017-12-27 2018-05-18 广东自由能科技股份有限公司 A kind of fluorine-containing high-efficiency environment friendly extinguishing chemical and preparation method thereof
CN110237480A (en) * 2018-06-10 2019-09-17 江苏锁龙消防科技股份有限公司 A kind of no PFOS non-fusibility aqueous film-forming foam extinguishing agent and preparation method thereof
CN110237479A (en) * 2018-06-10 2019-09-17 江苏锁龙消防科技股份有限公司 A kind of no PFOS aqueous film-forming foam extinguishing agent
CN110102006A (en) * 2019-06-27 2019-08-09 江西圣辉生化科技有限公司 A kind of extinguishing chemical and preparation method thereof
CN110292739A (en) * 2019-07-29 2019-10-01 西安赛特实业有限公司 A kind of antifreeze fire-fighting liquid against corrosion of environmental protection and preparation method thereof

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