CN106351626A - Method for oil extraction by utilizing alkaline electrolysis water drive - Google Patents

Method for oil extraction by utilizing alkaline electrolysis water drive Download PDF

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CN106351626A
CN106351626A CN201610862326.4A CN201610862326A CN106351626A CN 106351626 A CN106351626 A CN 106351626A CN 201610862326 A CN201610862326 A CN 201610862326A CN 106351626 A CN106351626 A CN 106351626A
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water
oil
alkaline
well
liquid
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CN106351626B (en
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高立红
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Gao Lihong
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Tianjin E Tech Energy Technology Development Co Ltd
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/20Displacing by water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mining & Mineral Resources (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Hydrology & Water Resources (AREA)
  • Electrochemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a method for oil extraction by utilizing alkaline electrolysis water drive. The alkaline electrolysis water drive is adopted: alkaline electrolysis water and injection water are mixed and directly injected into a water injection well to perform water drive, or alkaline electrolysis water single well huff and puff is adopted: alkaline electrolysis water with a concentration of 1-100% is injected into a production well, the well is shut and closed after injection, and then the well is opened to perform production. The method has the advantages that the method is high in activity and displacement efficiency, green, environmentally friendly, free of secondary pollution; raw materials are easy to obtain, the cost is low, and the process is simple and easy to construct.

Description

A kind of oil production method of utilization alkaline electrolysises water drive oil
Technical field
The invention belongs to oil field development technical field, more particularly to a kind of oil recovery side of utilization alkaline electrolysises water drive oil Method.
Background technology
Oil exploitation, after primary oil recovery and secondary oil recovery, there is also about 2/3rds crude oil and is trapped in oil reservoir, by In the effect of capillary force, this part trap is stayed in thinner hollow billet duct, this partly oily displacement out, depend merely on increase Pressure reduction is difficult to accomplish.In tertiary oil recovery technology, chemical flooding is one of important oil recovery technique, and including polymer flooding, live in surface Property agent drive, caustic waterflooding and three kinds of matching used ternary composite drivings.However, all there is certain technology limitation in all kinds of chemical floodings Property.Surfactant flooding has that activating agent sweep efficiency is low, oil displacement efficiency is poor, adsorption losses are more serious, activating agent is used Amount is big, high cost, pollution environment the shortcomings of.Alkali drive occurs in alkali drive evolution and destructively descends rock composition, easily form thing Therefore and the basic residual excessively factor such as destruction equipment when meeting faintly acid crude oil, quickly caustic waterflooding be just eliminated.Polymer flooding There is also this follow-up production fluid difficult, pollution the problems such as.After ternary composite driving enters fouling peak period, machine-pumped oil well is due to knot Dirt, leads to frequent holddown, and operating cost increases;Alkali in injection liquid and the Ore in stratum and the fluid in stratum occur anti- Should, produce substantial amounts of inorganic scale, in stratum accumulation, the sour gas producing during neutralization reaction knows from experience corrosion pipeline material; Do not consider the surfactant that soda acid generates when adding surfactant, will result in process and repeat, and increased cost; These all have a strong impact on ternary composite driving exploitation benefit.But chemical combined flooding either improves oil recovery in tertiary oil recovery method Rate amplitude, or reduces cost has very big development potentiality, therefore, develops efficient, cheap, non-environmental-pollution surface and lives Property agent and oil displacement system are extremely urgent, to adapt to the situation that high-water-cut stage old filed improves recovery ratio further.
Content of the invention
It is an object of the invention to provide the oil recovery work of a kind of environmental protection, efficient, cheap utilization alkaline electrolysises water drive oil Process, the method is active strong, and displacement efficiency is high;Environmental protection, non-secondary pollution;Raw material is easy to get, with low cost;Work Skill simple it is easy to the advantages of construction.
The present invention is achieved through the following technical solutions:
A kind of method of utilization alkaline electrolysises water drive oil, using alkaline electrolysises water drive: electrolyzed alkaline water is mixed with water filling Obtain oil driving liquid and be directly injected into water injection well carrying out water drive.
A kind of method of utilization alkaline electrolysises water drive oil, using electrolyzed alkaline water single well stimulation: by electrolyzed alkaline water and note Water is mixed to get liquid injection producing well of handling up, the vexed well of closing well after injection, then opening well and making production again, and closed time is because of the viscosity of crude oil Different and different, needing to refer to core physical simulation oil displacement experiment determines throughput time, and general closing well closed time is 1h-6d.
In the method for the both the above displacement of reservoir oil, the interpolation concentration of described oil driving liquid or liquid neutral and alkali of handling up electrolysis water needs basis Oil driving liquid is determined with formation water salinity Experiment of Compatibility, on the basis of not producing alkaline sedimentation, real with the core physical simulation displacement of reservoir oil Test as reference frame, select optimum concentration, the ph of general oil driving liquid or liquid of handling up is more than or equal to 8.
Described closed time determines according to core physical simulation oil displacement experiment result, and described closed time is general 1h-6d.
Described injection rate is using remaining oil distribution radius as reference.
The preparation method of described electrolyzed alkaline water, comprises the steps:
Water, after electrolysis installation is electrolysed, obtains strong basicity electrolytic aqueous solution, alkaline electrolysises through infiltration membrance separation Water ph value is in 10-14.
Electrolysis water activity is stronger, needs sealing or airtight preservation during transport, and effect is unaffected substantially.Or Job site is prepared, to ensure its active effect.
Electrolysis water be by water under electrolysis, with barrier film separate and generate acidic electrolytic water and electrolyzed alkaline water total Claim.Electrolyzed alkaline water is the electrolysis water that water generates through electrolysis, is made up of 5-6 micel, and normal water is by 13 micels Composition, this water activity is big, surface tension very little, and penetration is strong, dissolubility is high, has higher negative oxidation-reduction potential, is A kind of soda acid solvent of green, is a kind of reaction cosolvent again.Therefore, electrolyzed alkaline water can increase its infiltration on stratum and expand Scattered speed, reduce interfacial tension emulsified crude oil, strengthen crude oil fluidity, improve washing oil effect, with conventional surfactant drive and Ternary composite driving is compared, and oil displacement efficiency is higher;Although electrolyzed alkaline water is in alkalescence, not as Caustic soda has counter ion, tool There are stronger corrosion and fouling hidden danger, there is stronger rust inhibition, protection equipment and pipeline, alkali resistance Precipitation Potential on the contrary By force;In addition, this water does not pollute to oil reservoir and environment, eventually revert to conventional water, there is no chemical contamination and subsequently secondary place Reason cost.
The present invention has the advantages and positive effects that:
(1) electrolyzed alkaline water activity is high, and permeability is strong, big in oil reservoir diffusion rate, and washing oil displacement of reservoir oil degree is high.
(2) alkaline electrolysises water energy effectively reduces that crude oil surface tension is low, and emulsifying effectiveness is good.
(3) electrolyzed alkaline water is in strong basicity, but is different from conventional alkaline solution, does not have safety and corrosion hidden danger, after effect Revert to conventional water, there is no chemical contamination, environmental protection.
(4) electrolysis water source is universal, with low cost.
(5) process is simple is it is easy to construct.
Specific embodiment
The specific embodiment of the present invention is described more fully below, this be only used for explain the present invention, and can not be construed to right The restriction of the present invention.
Experimental technique used in following embodiments if no special instructions, is conventional method.
Material used, reagent etc. in following embodiments, if no special instructions, all can obtain from common commercial approach.
Embodiment 1:
A oil field adopts waterflooding extraction, is 99% because water drive producing well produces liquid moisture content all the year round, formation water salinity is 5160mg/l, viscosity of crude is 110mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 13.3, and electrolyzed alkaline water and water filling are mixed to get oil driving liquid, contrasts phase With the naoh solution of ph value, with stratum compatible test as follows:
Table 1 variable concentrations oil driving liquid and the compatibility phenomenon of stratum water
Sequence number Alkaline electrolysises water concentration Ph value Compatibility phenomenon Naoh solution Compatibility phenomenon
1 20% 10 No precipitation produces 20% Precipitation is had to produce
2 40% 12.5 No precipitation produces 40% Precipitation is had to produce
3 60% 12.8 No precipitation produces 60% Precipitation is had to produce
4 80% 13 No precipitation produces 80% Precipitation is had to produce
It can be seen that, the antisolvent precipitation Performance comparision of electrolyzed alkaline water is strong, different from highly basic.Ph value scope all >=8 meets water drive bar Part, concrete concentration is screened by core physical simulation oil displacement experiment effect expedition.
2) core physical simulation oil displacement experiment: water drive is carried out using electrolyzed alkaline water, parallel rock core is carried out water drive, displacement Reach 99% to aqueous, then carry out the displacement test of following oil driving liquids, experimental result is as follows:
The oil displacement efficiency of the different oil driving liquid of table 2
Sequence number Oil driving liquid Improve recovery ratio
1 Stratum water 0
2 Surfactant 2%
3 20% electrolyzed alkaline water 4%
4 40% electrolyzed alkaline water 10%
5 60% electrolyzed alkaline water 15%
6 80% electrolyzed alkaline water 26%
From above-mentioned experimental result, relative surfactant drives, using electrolyzed alkaline water oil driving liquid displacement efficiency more High.Consider oil displacement efficiency, the electrolyzed alkaline water using 80% carries out water drive, effect is more preferable.
Construction 1 month, field test results clearly, producing well aqueous average reduce by 8%, add up to increase oily 1.4 ten thousand m3.
Embodiment 2:
B oil field adopts waterflooding extraction, and it is 65% that producing well produces liquid moisture content, and formation water salinity is 10160mg/l, crude oil Viscosity is 20mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 13.9, electrolyzed alkaline water and water filling is mixed to get oil driving liquid, with stratum Compatible experiment is as follows:
Table 3 variable concentrations electrolyzed alkaline water and the compatibility phenomenon of stratum water
Sequence number Alkaline electrolysises water concentration Ph value Compatibility phenomenon
1 20% 12.8 No precipitation produces
2 40% 13 No precipitation produces
3 60% 13.2 No precipitation produces
4 80% 13.6 No precipitation produces
It can be seen that, electrolyzed alkaline water interpolation concentration range is satisfied by no precipitating the water drive condition with ph >=8, and concrete concentration is by rock Heart physical contradictions effect expedition screens.
2) core physical simulation oil displacement experiment: water drive is carried out using electrolyzed alkaline water, parallel rock core is carried out water drive, displacement Reach 65% to aqueous, then carry out the displacement test of following oil driving liquids, experimental result is as follows:
The oil displacement efficiency of the different oil driving liquid of table 4
Sequence number Oil driving liquid Improve recovery ratio
1 Stratum water 1.8%
2 20% electrolyzed alkaline water 18%
3 40% electrolyzed alkaline water 20%
4 60% electrolyzed alkaline water 28%
5 80% electrolyzed alkaline water 30%
From above-mentioned experimental result, considering cost and oil displacement efficiency, the electrolyzed alkaline water using 20% carries out water Drive, effect is more preferable.
Construction 1 month, field test results clearly, producing well aqueous average reduce by 6%, add up to increase oily 2.8 ten thousand m3.
Embodiment 3:
C oil field, no water filling, it is 98% that producing well produces liquid moisture content, and formation water salinity is 10000mg/l, viscosity of crude For 40mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 11.8, electrolyzed alkaline water and water filling is mixed to get liquid of handling up, with stratum Compatible experiment is as follows:
Table 5 variable concentrations electrolyzed alkaline water and the Experiment of Compatibility of stratum water
It can be seen that, electrolyzed alkaline water interpolation concentration range is satisfied by no precipitating the water drive condition with ph >=8, and concrete concentration is by rock Heart physical contradictions effect expedition screens.
2) handle up liquid concentration experiment: single well stimulation logistics organizations are carried out using electrolyzed alkaline water, now variable concentrations is handled up Liquid injection is aqueous to be reached in 98% parallel rock core, fixes tentatively simulation closing well vexed well 8h, then carries out reverse displacement, investigates the washing oil handled up Effect, alkaline electrolysises water concentration chooses 20%, and Detailed Experimental result is as follows:
Table 6 variable concentrations are handled up the raising recovery ratio effect of liquid
Sequence number Injection radius Handle up liquid concentration Improve recovery ratio
1 1/2 rock core 20% 3.6%
2 1/2 rock core 40% 4%
3 1/2 rock core 60% 5.2%
4 1/2 rock core 80% 5.5%
3) closing well closed time experiment: the liquid of handling up from 20% carries out core experiment, different closed time experimental results As follows, by effectiveness comparison, determine that 12h is optimal closed time.
The raising recovery ratio effect of the different closed time of table 7
Sequence number Closed time Improve recovery ratio
1 4h 2.3%
2 8h 3.6%
3 12h 4.6%
4 16h 3.4%
To sum up experimental result, select 20% electrolyzed alkaline water handle up liquid injection producing well, injection rate be 5000m3, closing well Vexed well 12h (0.5d), after driving a well, aqueous is 80%, adds up to increase oily 4890m3.
Embodiment 4:
D oil field, it is 99% that producing well produces liquid moisture content, and formation water salinity is 3200mg/l, and viscosity of crude is 113mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 13.9, as follows with the experiment of stratum compatible:
Table 8 variable concentrations electrolyzed alkaline water and the Experiment of Compatibility of stratum water
Sequence number Alkaline electrolysises water concentration Ph value Compatibility phenomenon
1 20% 12.5 No precipitation produces
2 40% 12.9 No precipitation produces
3 60% 13.4 No precipitation produces
4 80% 13.8 No precipitation produces
5 100% 13.9 No precipitation produces
It can be seen that, electrolyzed alkaline water interpolation concentration range is satisfied by no precipitating the water drive condition with ph >=8, and concrete concentration is by rock Heart physical contradictions effect expedition screens.
2) handle up liquid concentration experiment: single well stimulation logistics organizations are carried out using electrolysis water, now variable concentrations is handled up liquid note Enter aqueous reach in 99% parallel rock core, fix tentatively simulation closing well vexed well 2d, then carry out reverse displacement, investigate the washing oil effect handled up Really, Detailed Experimental result is as follows:
Table 9 variable concentrations are handled up the raising recovery ratio effect of liquid
Sequence number Injection radius Handle up liquid concentration Improve recovery ratio
1 1/2 rock core 20% 1.1%
2 1/2 rock core 40% 1.3%
3 1/2 rock core 60% 1.8%
4 1/2 rock core 80% 3.6%
5 1/2 rock core 100% 7.2%
3) closing well closed time experiment: the liquid of handling up from 100% carries out core experiment, different closed time experimental results As follows, by effectiveness comparison, determine that 4d is optimal material time.
The raising recovery ratio effect of the different closed time of table 10
Sequence number Closed time Improve recovery ratio
1 1d 2.6%
2 2d 7.2%
3 4d 8.9%
4 6d 7.8%
To sum up experimental result, selects the liquid injection producing well of handling up of 100% electrolyzed alkaline water, injection rate is 3340m3, Closing well vexed well 4d, after driving a well, aqueous is 84%, adds up to increase oily 6260m3.

Claims (7)

1. a kind of method of utilization alkaline electrolysises water drive oil it is characterised in that adopt alkaline electrolysises water drive: by electrolyzed alkaline water with Water filling is mixed to get oil driving liquid and is directly injected into water injection well and carries out water drive.
2. a kind of method of utilization alkaline electrolysises water drive oil is it is characterised in that adopt electrolyzed alkaline water single well stimulation: by alkaline electro Xie Shui and water filling are mixed to get liquid of handling up and are directly injected into producing well, the vexed well of closing well after injection, then opening well and making production again.
3. the method for utilization alkaline electrolysises water drive oil as claimed in claim 1 or 2, described electrolyzed alkaline water is adopted with the following method Preparation:
Water, after electrolysis installation is electrolysed, obtains strong basicity electrolytic aqueous solution, electrolyzed alkaline water ph through infiltration membrance separation Value is in 10-14.
4. the method for utilization alkaline electrolysises water drive oil as claimed in claim 1 or 2, described oil driving liquid or liquid neutral and alkali electricity of handling up The concentration of Xie Shui needs to be determined with formation water salinity Experiment of Compatibility according to oil driving liquid or liquid of handling up, and not produce alkaline sedimentation is Benchmark.
5. the method for the utilization alkaline electrolysises water drive oil as described in claim 1 or 2 or 4, the ph of described oil driving liquid or liquid of handling up Value is more than or equal to 8, and optium concentration is determined by core physical simulation oil displacement experiment result.
6. the method for utilization alkaline electrolysises water drive oil as claimed in claim 2, described closed time is according to core physical simulation Oil displacement experiment result determines.
7. the method for utilization alkaline electrolysises water drive oil as claimed in claim 6, described closed time is 1h-6d.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3929190A (en) * 1974-11-05 1975-12-30 Mobil Oil Corp Secondary oil recovery by waterflooding with extracted petroleum acids
US4008769A (en) * 1975-04-30 1977-02-22 Mobil Oil Corporation Oil recovery by microemulsion injection
CN1172867A (en) * 1996-08-01 1998-02-11 刘正立 Water pressure osmotic membrane electrolytic water device
CN1514106A (en) * 2003-01-24 2004-07-21 大庆油田有限责任公司 Method of optimizing trielement composite central displacement system interface tension and trielement system formulation
CN103224777A (en) * 2013-04-25 2013-07-31 中国石油天然气股份有限公司 Weak-base ternary composite oil displacement composition compounded with surfactant and application thereof
CN103937480A (en) * 2014-04-14 2014-07-23 中国石油大学(华东) Organic alkali/surfactant binary composite oil displacement system as well as preparation method and application thereof
CN104559985A (en) * 2013-10-28 2015-04-29 中国石油化工股份有限公司 Surfactant polymer composition for oil displacement and application thereof in tertiary oil recovery

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3929190A (en) * 1974-11-05 1975-12-30 Mobil Oil Corp Secondary oil recovery by waterflooding with extracted petroleum acids
US4008769A (en) * 1975-04-30 1977-02-22 Mobil Oil Corporation Oil recovery by microemulsion injection
CN1172867A (en) * 1996-08-01 1998-02-11 刘正立 Water pressure osmotic membrane electrolytic water device
CN1514106A (en) * 2003-01-24 2004-07-21 大庆油田有限责任公司 Method of optimizing trielement composite central displacement system interface tension and trielement system formulation
CN103224777A (en) * 2013-04-25 2013-07-31 中国石油天然气股份有限公司 Weak-base ternary composite oil displacement composition compounded with surfactant and application thereof
CN104559985A (en) * 2013-10-28 2015-04-29 中国石油化工股份有限公司 Surfactant polymer composition for oil displacement and application thereof in tertiary oil recovery
CN103937480A (en) * 2014-04-14 2014-07-23 中国石油大学(华东) Organic alkali/surfactant binary composite oil displacement system as well as preparation method and application thereof

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Effective date of registration: 20210329

Address after: No.2, Meiyuan Road, Huayuan Industrial Park, Nankai District, Tianjin

Patentee after: Gao Lihong

Address before: 300110 Haitai green industrial base m2, No.6 Haitai development road, Huayuan Industrial Zone, Nankai District, Tianjin

Patentee before: E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp.