CN106351626A - Method for oil extraction by utilizing alkaline electrolysis water drive - Google Patents
Method for oil extraction by utilizing alkaline electrolysis water drive Download PDFInfo
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- CN106351626A CN106351626A CN201610862326.4A CN201610862326A CN106351626A CN 106351626 A CN106351626 A CN 106351626A CN 201610862326 A CN201610862326 A CN 201610862326A CN 106351626 A CN106351626 A CN 106351626A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 118
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000000605 extraction Methods 0.000 title abstract description 4
- 238000006073 displacement reaction Methods 0.000 claims abstract description 27
- 239000007924 injection Substances 0.000 claims abstract description 17
- 238000002347 injection Methods 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 43
- 238000002474 experimental method Methods 0.000 claims description 25
- 238000004088 simulation Methods 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 6
- 239000008398 formation water Substances 0.000 claims description 6
- 230000000638 stimulation Effects 0.000 claims description 4
- 230000008595 infiltration Effects 0.000 claims description 3
- 238000001764 infiltration Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000004062 sedimentation Methods 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 21
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 57
- 238000001556 precipitation Methods 0.000 description 19
- 238000011084 recovery Methods 0.000 description 19
- 239000011435 rock Substances 0.000 description 17
- 239000010779 crude oil Substances 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011206 ternary composite Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000001376 precipitating effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/20—Displacing by water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
- C02F2001/4619—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Environmental & Geological Engineering (AREA)
- Mining & Mineral Resources (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
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- Hydrology & Water Resources (AREA)
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Abstract
The invention discloses a method for oil extraction by utilizing alkaline electrolysis water drive. The alkaline electrolysis water drive is adopted: alkaline electrolysis water and injection water are mixed and directly injected into a water injection well to perform water drive, or alkaline electrolysis water single well huff and puff is adopted: alkaline electrolysis water with a concentration of 1-100% is injected into a production well, the well is shut and closed after injection, and then the well is opened to perform production. The method has the advantages that the method is high in activity and displacement efficiency, green, environmentally friendly, free of secondary pollution; raw materials are easy to obtain, the cost is low, and the process is simple and easy to construct.
Description
Technical field
The invention belongs to oil field development technical field, more particularly to a kind of oil recovery side of utilization alkaline electrolysises water drive oil
Method.
Background technology
Oil exploitation, after primary oil recovery and secondary oil recovery, there is also about 2/3rds crude oil and is trapped in oil reservoir, by
In the effect of capillary force, this part trap is stayed in thinner hollow billet duct, this partly oily displacement out, depend merely on increase
Pressure reduction is difficult to accomplish.In tertiary oil recovery technology, chemical flooding is one of important oil recovery technique, and including polymer flooding, live in surface
Property agent drive, caustic waterflooding and three kinds of matching used ternary composite drivings.However, all there is certain technology limitation in all kinds of chemical floodings
Property.Surfactant flooding has that activating agent sweep efficiency is low, oil displacement efficiency is poor, adsorption losses are more serious, activating agent is used
Amount is big, high cost, pollution environment the shortcomings of.Alkali drive occurs in alkali drive evolution and destructively descends rock composition, easily form thing
Therefore and the basic residual excessively factor such as destruction equipment when meeting faintly acid crude oil, quickly caustic waterflooding be just eliminated.Polymer flooding
There is also this follow-up production fluid difficult, pollution the problems such as.After ternary composite driving enters fouling peak period, machine-pumped oil well is due to knot
Dirt, leads to frequent holddown, and operating cost increases;Alkali in injection liquid and the Ore in stratum and the fluid in stratum occur anti-
Should, produce substantial amounts of inorganic scale, in stratum accumulation, the sour gas producing during neutralization reaction knows from experience corrosion pipeline material;
Do not consider the surfactant that soda acid generates when adding surfactant, will result in process and repeat, and increased cost;
These all have a strong impact on ternary composite driving exploitation benefit.But chemical combined flooding either improves oil recovery in tertiary oil recovery method
Rate amplitude, or reduces cost has very big development potentiality, therefore, develops efficient, cheap, non-environmental-pollution surface and lives
Property agent and oil displacement system are extremely urgent, to adapt to the situation that high-water-cut stage old filed improves recovery ratio further.
Content of the invention
It is an object of the invention to provide the oil recovery work of a kind of environmental protection, efficient, cheap utilization alkaline electrolysises water drive oil
Process, the method is active strong, and displacement efficiency is high;Environmental protection, non-secondary pollution;Raw material is easy to get, with low cost;Work
Skill simple it is easy to the advantages of construction.
The present invention is achieved through the following technical solutions:
A kind of method of utilization alkaline electrolysises water drive oil, using alkaline electrolysises water drive: electrolyzed alkaline water is mixed with water filling
Obtain oil driving liquid and be directly injected into water injection well carrying out water drive.
A kind of method of utilization alkaline electrolysises water drive oil, using electrolyzed alkaline water single well stimulation: by electrolyzed alkaline water and note
Water is mixed to get liquid injection producing well of handling up, the vexed well of closing well after injection, then opening well and making production again, and closed time is because of the viscosity of crude oil
Different and different, needing to refer to core physical simulation oil displacement experiment determines throughput time, and general closing well closed time is 1h-6d.
In the method for the both the above displacement of reservoir oil, the interpolation concentration of described oil driving liquid or liquid neutral and alkali of handling up electrolysis water needs basis
Oil driving liquid is determined with formation water salinity Experiment of Compatibility, on the basis of not producing alkaline sedimentation, real with the core physical simulation displacement of reservoir oil
Test as reference frame, select optimum concentration, the ph of general oil driving liquid or liquid of handling up is more than or equal to 8.
Described closed time determines according to core physical simulation oil displacement experiment result, and described closed time is general 1h-6d.
Described injection rate is using remaining oil distribution radius as reference.
The preparation method of described electrolyzed alkaline water, comprises the steps:
Water, after electrolysis installation is electrolysed, obtains strong basicity electrolytic aqueous solution, alkaline electrolysises through infiltration membrance separation
Water ph value is in 10-14.
Electrolysis water activity is stronger, needs sealing or airtight preservation during transport, and effect is unaffected substantially.Or
Job site is prepared, to ensure its active effect.
Electrolysis water be by water under electrolysis, with barrier film separate and generate acidic electrolytic water and electrolyzed alkaline water total
Claim.Electrolyzed alkaline water is the electrolysis water that water generates through electrolysis, is made up of 5-6 micel, and normal water is by 13 micels
Composition, this water activity is big, surface tension very little, and penetration is strong, dissolubility is high, has higher negative oxidation-reduction potential, is
A kind of soda acid solvent of green, is a kind of reaction cosolvent again.Therefore, electrolyzed alkaline water can increase its infiltration on stratum and expand
Scattered speed, reduce interfacial tension emulsified crude oil, strengthen crude oil fluidity, improve washing oil effect, with conventional surfactant drive and
Ternary composite driving is compared, and oil displacement efficiency is higher;Although electrolyzed alkaline water is in alkalescence, not as Caustic soda has counter ion, tool
There are stronger corrosion and fouling hidden danger, there is stronger rust inhibition, protection equipment and pipeline, alkali resistance Precipitation Potential on the contrary
By force;In addition, this water does not pollute to oil reservoir and environment, eventually revert to conventional water, there is no chemical contamination and subsequently secondary place
Reason cost.
The present invention has the advantages and positive effects that:
(1) electrolyzed alkaline water activity is high, and permeability is strong, big in oil reservoir diffusion rate, and washing oil displacement of reservoir oil degree is high.
(2) alkaline electrolysises water energy effectively reduces that crude oil surface tension is low, and emulsifying effectiveness is good.
(3) electrolyzed alkaline water is in strong basicity, but is different from conventional alkaline solution, does not have safety and corrosion hidden danger, after effect
Revert to conventional water, there is no chemical contamination, environmental protection.
(4) electrolysis water source is universal, with low cost.
(5) process is simple is it is easy to construct.
Specific embodiment
The specific embodiment of the present invention is described more fully below, this be only used for explain the present invention, and can not be construed to right
The restriction of the present invention.
Experimental technique used in following embodiments if no special instructions, is conventional method.
Material used, reagent etc. in following embodiments, if no special instructions, all can obtain from common commercial approach.
Embodiment 1:
A oil field adopts waterflooding extraction, is 99% because water drive producing well produces liquid moisture content all the year round, formation water salinity is
5160mg/l, viscosity of crude is 110mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 13.3, and electrolyzed alkaline water and water filling are mixed to get oil driving liquid, contrasts phase
With the naoh solution of ph value, with stratum compatible test as follows:
Table 1 variable concentrations oil driving liquid and the compatibility phenomenon of stratum water
Sequence number | Alkaline electrolysises water concentration | Ph value | Compatibility phenomenon | Naoh solution | Compatibility phenomenon |
1 | 20% | 10 | No precipitation produces | 20% | Precipitation is had to produce |
2 | 40% | 12.5 | No precipitation produces | 40% | Precipitation is had to produce |
3 | 60% | 12.8 | No precipitation produces | 60% | Precipitation is had to produce |
4 | 80% | 13 | No precipitation produces | 80% | Precipitation is had to produce |
It can be seen that, the antisolvent precipitation Performance comparision of electrolyzed alkaline water is strong, different from highly basic.Ph value scope all >=8 meets water drive bar
Part, concrete concentration is screened by core physical simulation oil displacement experiment effect expedition.
2) core physical simulation oil displacement experiment: water drive is carried out using electrolyzed alkaline water, parallel rock core is carried out water drive, displacement
Reach 99% to aqueous, then carry out the displacement test of following oil driving liquids, experimental result is as follows:
The oil displacement efficiency of the different oil driving liquid of table 2
Sequence number | Oil driving liquid | Improve recovery ratio |
1 | Stratum water | 0 |
2 | Surfactant | 2% |
3 | 20% electrolyzed alkaline water | 4% |
4 | 40% electrolyzed alkaline water | 10% |
5 | 60% electrolyzed alkaline water | 15% |
6 | 80% electrolyzed alkaline water | 26% |
From above-mentioned experimental result, relative surfactant drives, using electrolyzed alkaline water oil driving liquid displacement efficiency more
High.Consider oil displacement efficiency, the electrolyzed alkaline water using 80% carries out water drive, effect is more preferable.
Construction 1 month, field test results clearly, producing well aqueous average reduce by 8%, add up to increase oily 1.4 ten thousand m3.
Embodiment 2:
B oil field adopts waterflooding extraction, and it is 65% that producing well produces liquid moisture content, and formation water salinity is 10160mg/l, crude oil
Viscosity is 20mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 13.9, electrolyzed alkaline water and water filling is mixed to get oil driving liquid, with stratum
Compatible experiment is as follows:
Table 3 variable concentrations electrolyzed alkaline water and the compatibility phenomenon of stratum water
Sequence number | Alkaline electrolysises water concentration | Ph value | Compatibility phenomenon |
1 | 20% | 12.8 | No precipitation produces |
2 | 40% | 13 | No precipitation produces |
3 | 60% | 13.2 | No precipitation produces |
4 | 80% | 13.6 | No precipitation produces |
It can be seen that, electrolyzed alkaline water interpolation concentration range is satisfied by no precipitating the water drive condition with ph >=8, and concrete concentration is by rock
Heart physical contradictions effect expedition screens.
2) core physical simulation oil displacement experiment: water drive is carried out using electrolyzed alkaline water, parallel rock core is carried out water drive, displacement
Reach 65% to aqueous, then carry out the displacement test of following oil driving liquids, experimental result is as follows:
The oil displacement efficiency of the different oil driving liquid of table 4
Sequence number | Oil driving liquid | Improve recovery ratio |
1 | Stratum water | 1.8% |
2 | 20% electrolyzed alkaline water | 18% |
3 | 40% electrolyzed alkaline water | 20% |
4 | 60% electrolyzed alkaline water | 28% |
5 | 80% electrolyzed alkaline water | 30% |
From above-mentioned experimental result, considering cost and oil displacement efficiency, the electrolyzed alkaline water using 20% carries out water
Drive, effect is more preferable.
Construction 1 month, field test results clearly, producing well aqueous average reduce by 6%, add up to increase oily 2.8 ten thousand m3.
Embodiment 3:
C oil field, no water filling, it is 98% that producing well produces liquid moisture content, and formation water salinity is 10000mg/l, viscosity of crude
For 40mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 11.8, electrolyzed alkaline water and water filling is mixed to get liquid of handling up, with stratum
Compatible experiment is as follows:
Table 5 variable concentrations electrolyzed alkaline water and the Experiment of Compatibility of stratum water
It can be seen that, electrolyzed alkaline water interpolation concentration range is satisfied by no precipitating the water drive condition with ph >=8, and concrete concentration is by rock
Heart physical contradictions effect expedition screens.
2) handle up liquid concentration experiment: single well stimulation logistics organizations are carried out using electrolyzed alkaline water, now variable concentrations is handled up
Liquid injection is aqueous to be reached in 98% parallel rock core, fixes tentatively simulation closing well vexed well 8h, then carries out reverse displacement, investigates the washing oil handled up
Effect, alkaline electrolysises water concentration chooses 20%, and Detailed Experimental result is as follows:
Table 6 variable concentrations are handled up the raising recovery ratio effect of liquid
Sequence number | Injection radius | Handle up liquid concentration | Improve recovery ratio |
1 | 1/2 rock core | 20% | 3.6% |
2 | 1/2 rock core | 40% | 4% |
3 | 1/2 rock core | 60% | 5.2% |
4 | 1/2 rock core | 80% | 5.5% |
3) closing well closed time experiment: the liquid of handling up from 20% carries out core experiment, different closed time experimental results
As follows, by effectiveness comparison, determine that 12h is optimal closed time.
The raising recovery ratio effect of the different closed time of table 7
Sequence number | Closed time | Improve recovery ratio |
1 | 4h | 2.3% |
2 | 8h | 3.6% |
3 | 12h | 4.6% |
4 | 16h | 3.4% |
To sum up experimental result, select 20% electrolyzed alkaline water handle up liquid injection producing well, injection rate be 5000m3, closing well
Vexed well 12h (0.5d), after driving a well, aqueous is 80%, adds up to increase oily 4890m3.
Embodiment 4:
D oil field, it is 99% that producing well produces liquid moisture content, and formation water salinity is 3200mg/l, and viscosity of crude is
113mpa.s.
1) Experiment of Compatibility: electrolyzed alkaline water ph is 13.9, as follows with the experiment of stratum compatible:
Table 8 variable concentrations electrolyzed alkaline water and the Experiment of Compatibility of stratum water
Sequence number | Alkaline electrolysises water concentration | Ph value | Compatibility phenomenon |
1 | 20% | 12.5 | No precipitation produces |
2 | 40% | 12.9 | No precipitation produces |
3 | 60% | 13.4 | No precipitation produces |
4 | 80% | 13.8 | No precipitation produces |
5 | 100% | 13.9 | No precipitation produces |
It can be seen that, electrolyzed alkaline water interpolation concentration range is satisfied by no precipitating the water drive condition with ph >=8, and concrete concentration is by rock
Heart physical contradictions effect expedition screens.
2) handle up liquid concentration experiment: single well stimulation logistics organizations are carried out using electrolysis water, now variable concentrations is handled up liquid note
Enter aqueous reach in 99% parallel rock core, fix tentatively simulation closing well vexed well 2d, then carry out reverse displacement, investigate the washing oil effect handled up
Really, Detailed Experimental result is as follows:
Table 9 variable concentrations are handled up the raising recovery ratio effect of liquid
Sequence number | Injection radius | Handle up liquid concentration | Improve recovery ratio |
1 | 1/2 rock core | 20% | 1.1% |
2 | 1/2 rock core | 40% | 1.3% |
3 | 1/2 rock core | 60% | 1.8% |
4 | 1/2 rock core | 80% | 3.6% |
5 | 1/2 rock core | 100% | 7.2% |
3) closing well closed time experiment: the liquid of handling up from 100% carries out core experiment, different closed time experimental results
As follows, by effectiveness comparison, determine that 4d is optimal material time.
The raising recovery ratio effect of the different closed time of table 10
Sequence number | Closed time | Improve recovery ratio |
1 | 1d | 2.6% |
2 | 2d | 7.2% |
3 | 4d | 8.9% |
4 | 6d | 7.8% |
To sum up experimental result, selects the liquid injection producing well of handling up of 100% electrolyzed alkaline water, injection rate is 3340m3,
Closing well vexed well 4d, after driving a well, aqueous is 84%, adds up to increase oily 6260m3.
Claims (7)
1. a kind of method of utilization alkaline electrolysises water drive oil it is characterised in that adopt alkaline electrolysises water drive: by electrolyzed alkaline water with
Water filling is mixed to get oil driving liquid and is directly injected into water injection well and carries out water drive.
2. a kind of method of utilization alkaline electrolysises water drive oil is it is characterised in that adopt electrolyzed alkaline water single well stimulation: by alkaline electro
Xie Shui and water filling are mixed to get liquid of handling up and are directly injected into producing well, the vexed well of closing well after injection, then opening well and making production again.
3. the method for utilization alkaline electrolysises water drive oil as claimed in claim 1 or 2, described electrolyzed alkaline water is adopted with the following method
Preparation:
Water, after electrolysis installation is electrolysed, obtains strong basicity electrolytic aqueous solution, electrolyzed alkaline water ph through infiltration membrance separation
Value is in 10-14.
4. the method for utilization alkaline electrolysises water drive oil as claimed in claim 1 or 2, described oil driving liquid or liquid neutral and alkali electricity of handling up
The concentration of Xie Shui needs to be determined with formation water salinity Experiment of Compatibility according to oil driving liquid or liquid of handling up, and not produce alkaline sedimentation is
Benchmark.
5. the method for the utilization alkaline electrolysises water drive oil as described in claim 1 or 2 or 4, the ph of described oil driving liquid or liquid of handling up
Value is more than or equal to 8, and optium concentration is determined by core physical simulation oil displacement experiment result.
6. the method for utilization alkaline electrolysises water drive oil as claimed in claim 2, described closed time is according to core physical simulation
Oil displacement experiment result determines.
7. the method for utilization alkaline electrolysises water drive oil as claimed in claim 6, described closed time is 1h-6d.
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US3929190A (en) * | 1974-11-05 | 1975-12-30 | Mobil Oil Corp | Secondary oil recovery by waterflooding with extracted petroleum acids |
US4008769A (en) * | 1975-04-30 | 1977-02-22 | Mobil Oil Corporation | Oil recovery by microemulsion injection |
CN1172867A (en) * | 1996-08-01 | 1998-02-11 | 刘正立 | Water pressure osmotic membrane electrolytic water device |
CN1514106A (en) * | 2003-01-24 | 2004-07-21 | 大庆油田有限责任公司 | Method of optimizing trielement composite central displacement system interface tension and trielement system formulation |
CN103224777A (en) * | 2013-04-25 | 2013-07-31 | 中国石油天然气股份有限公司 | Weak-base ternary composite oil displacement composition compounded with surfactant and application thereof |
CN103937480A (en) * | 2014-04-14 | 2014-07-23 | 中国石油大学(华东) | Organic alkali/surfactant binary composite oil displacement system as well as preparation method and application thereof |
CN104559985A (en) * | 2013-10-28 | 2015-04-29 | 中国石油化工股份有限公司 | Surfactant polymer composition for oil displacement and application thereof in tertiary oil recovery |
-
2016
- 2016-09-29 CN CN201610862326.4A patent/CN106351626B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3929190A (en) * | 1974-11-05 | 1975-12-30 | Mobil Oil Corp | Secondary oil recovery by waterflooding with extracted petroleum acids |
US4008769A (en) * | 1975-04-30 | 1977-02-22 | Mobil Oil Corporation | Oil recovery by microemulsion injection |
CN1172867A (en) * | 1996-08-01 | 1998-02-11 | 刘正立 | Water pressure osmotic membrane electrolytic water device |
CN1514106A (en) * | 2003-01-24 | 2004-07-21 | 大庆油田有限责任公司 | Method of optimizing trielement composite central displacement system interface tension and trielement system formulation |
CN103224777A (en) * | 2013-04-25 | 2013-07-31 | 中国石油天然气股份有限公司 | Weak-base ternary composite oil displacement composition compounded with surfactant and application thereof |
CN104559985A (en) * | 2013-10-28 | 2015-04-29 | 中国石油化工股份有限公司 | Surfactant polymer composition for oil displacement and application thereof in tertiary oil recovery |
CN103937480A (en) * | 2014-04-14 | 2014-07-23 | 中国石油大学(华东) | Organic alkali/surfactant binary composite oil displacement system as well as preparation method and application thereof |
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Effective date of registration: 20210329 Address after: No.2, Meiyuan Road, Huayuan Industrial Park, Nankai District, Tianjin Patentee after: Gao Lihong Address before: 300110 Haitai green industrial base m2, No.6 Haitai development road, Huayuan Industrial Zone, Nankai District, Tianjin Patentee before: E-TECH ENERGY TECHNOLOGY DEVELOPMENT Corp. |