CN106349928A - Peeling antifouling paint of single-component propeller and preparing method thereof - Google Patents
Peeling antifouling paint of single-component propeller and preparing method thereof Download PDFInfo
- Publication number
- CN106349928A CN106349928A CN201610750413.0A CN201610750413A CN106349928A CN 106349928 A CN106349928 A CN 106349928A CN 201610750413 A CN201610750413 A CN 201610750413A CN 106349928 A CN106349928 A CN 106349928A
- Authority
- CN
- China
- Prior art keywords
- propeller
- antifouling
- copper
- fouling
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a peeling antifouling paint of a single-component propeller and relates to the field of the coating technology.The paint is prepared by the following raw materials, in quality percentage,15-65% of resin binder, 0-12% of thinner, 25-65% of copper antifouling agent,5-15% of zinc oxide, 0-10% of organic antifouling agent and 0.5-2% of thixotropicagent; and the resin binder is any one or more of barium petroleum sulfonate, butter,lanum, methylsilicone oil and hydroxyl silicone oil. The antifouling paint provided in the invention is obtained by mixing the above materials uniformly through a high-speed dispersing process. The antifouling paint can achieve temporary antifouling action on the propeller when the ship stops to avoid fouling bioattachment; if the bioattachment is available, marine organism can peel and fall along the coating under the effect of the centrifugal force and current scouring of the propeller when the ship sails; the propeller surface must keep clean without bioattachment;and the antifouling perid is above six months.
Description
Technical field
The present invention relates to technical field of coatings is and in particular to a kind of one pack system propeller strippable anti-fouling paint and its preparation
Method.
Background technology
At present, propeller for vessels material therefor is mainly ferromanganese pyrite and two kinds of rustless steel, and ferromanganese pyrite class propeller is certainly
Body can be electrolysed copper ion, has certain antifouling capacity, but the formation with corrosion product, screen layer can be formed on surface,
So that the precipitation quantity of copper ion is declined, lead to antifouling capacity to decline year by year.And propeller is in actual use because of anticorrosion
Requirement, be mounted with cathodic protection system, lead to ferromanganese pyrite class propeller copper ion cannot separate out so as to lose antifouling energy
Power；Stainless steel propellor itself no antifouling capacity.Ship in running, in the current scour of high speed and the effect of centrifugal force
Under, propeller surface will not produce sea marine organism pollution；When berthing, the propeller not doing antifouling process is easy to pollution by sea living
Damage.The sea marine organism pollution of propeller, particularly duricrust class sea marine organism pollution, can increase ship resistance and the fuel consumption of ship,
Reduce the speed of a ship or plane, the surface roughness of propeller can be increased simultaneously, reduce the delivery efficiency of propeller, accelerate the corruption of propeller
Erosion, makes ship need to frequently lie up maintenance because propeller is stained problem, increases maintenance cost, and reduction is sailed rate.
Multiple methods preventing sea marine organism pollution are researched and developed, including nonpolluting coating method, electrolysis both at home and abroad at present
Antifouling method, supercritical ultrasonics technology, radiochemical method and labor cleaning's method, but the stable method of current applied range, technical maturity is only
There are artificial method of cleaning, nonpolluting coating method and electrolysis anti-soil method, additive method is in the laboratory research stage, does not have correlation engineering
Application experience.Labor cleaning's method needs dockage cleaning spiral oar, adopt shovel remove marine growth and polish propeller surface with
Thoroughly remove marine growth, the method takes time and effort and can produce and huge accounts for depressed place expense；Electrolysis antifouling is mainly used in closing
Space, pipeline inner wall are antifouling, also develop corresponding propeller anti-fouler in recent years, but propeller is in open environment
In, the concentration of sodium hypochlorite is difficult to reach antifouling requirement it is difficult to realize effectively antifouling, and equipment investment is larger, is not subject to vast ship
The welcome in east.And the exploitation with regard to propeller nonpolluting coating is then less.
Content of the invention
It is an object of the invention to provide a kind of one pack system propeller strippable anti-fouling paint, its when ship is suspended, to spiral shell
Rotation oar plays antifouling effect temporarily, it is to avoid fouling organism adheres to；Even and if having sea organism attachment, in ship's navigation, in spiral
In the presence of the centrifugal force of oar and current scour, marine growth can come off with coating is peeling-off, makes propeller surface keep clean,
No fouling organism attachment.
For achieving the above object, the technical scheme is that a kind of one pack system propeller strippable anti-fouling paint, its by
The raw material composition of following weight/mass percentage composition: resin binder 15～65%, diluent 0～12%, copper class anti-fouling agent 25～65%, oxygen
Change zinc 5～15%, organic anti-fouling agent 0～10%, thixotropic agent 0.5 ~ 2%；
Described resin binder is one or more of barium mahogany sulfonate, butter, lanoline, methyl-silicone oil, hydroxy silicon oil.Described
Butter is the grease in machinery.
Further, described diluent is one or more of Oleum Terebinthinae, benzyl alcohol, glycerol.
Described copper class anti-fouling agent is one of copper powder, Red copper oxide, Cuprous sulfocyanate, copper sulfate, copper naphthenate or many
Kind.
Described organic anti-fouling agent be Zinc Pyrithione, copper pyrithione, triphenylboron pyridine, tcpm, Bravo,
One or more of econea, diuron, carbendazim.
Described thixotropic agent is aerosil or byk410 or a combination of both.
A kind of preparation method of one pack system propeller strippable anti-fouling paint of the present invention is: first by resin binder, dilute
Release agent and thixotropic agent one superhigh speed dispersion 30min；It is subsequently adding zinc oxide and organic anti-fouling agent, at a high speed after dispersion 1h, using cold
But water cooling, is eventually adding copper class anti-fouling agent at a high speed dispersion 1h, fully dispersed uniformly after, you can discharging.
Beneficial effect:
The one pack system propeller strippable anti-fouling paint of the present invention can carry out underwater construction, one-pass film-forming thickness up to 150 μm with
On, salt water resistance, 6 months: coating is no bubbled, no comes off, propeller is corrosion-free；Paint spraying is suspended 6 months in propeller surface,
Propeller rotates 50h: coating fully stripped, propeller smooth surface, corrosion-free, no sea organism attachment, is expected antifouling by evaluation
Phase imitates as more than 6 months.
The antifouling paint of the present invention can be used for the propellers such as naval vessels, large ship, fishing boat, plays interim within a period of time
Antifouling effect is it is ensured that again the set sail precision of rear screw shaft and the speed of a ship or plane of ship.
Specific embodiment
A kind of one pack system propeller strippable anti-fouling paint, it is made up of the raw material of following weight/mass percentage composition: resin base
Material 15～65%, diluent 0～12%, copper class anti-fouling agent 25～65%, zinc oxide 5～15%, organic anti-fouling agent 0～10%, thixotropic agent
0.5~2%；
Described resin binder is one or more of barium mahogany sulfonate, butter, lanoline, methyl-silicone oil, hydroxy silicon oil.
Further, described diluent is one or more of Oleum Terebinthinae, benzyl alcohol, glycerol.
Described copper class anti-fouling agent is one of copper powder, Red copper oxide, Cuprous sulfocyanate, copper sulfate, copper naphthenate or many
Kind.
Described organic anti-fouling agent be Zinc Pyrithione, copper pyrithione, triphenylboron pyridine, tcpm, Bravo,
One or more of econea, diuron, carbendazim.
Described thixotropic agent is aerosil or byk410 or a combination of both.
7 embodiments are set forth below, the formulation for coating material of each embodiment is as follows:
The each formulation for coating material of table 1 embodiment 1 ~ 7
The method that the various embodiments described above prepare antifouling paint of the present invention is identical, taking embodiment 1 as a example, the one pack system spiral of the present invention
The preparation method of oar strippable anti-fouling paint is: first by resin binder (i.e. lanoline, hydroxy silicon oil and barium mahogany sulfonate), dilute
Release agent (i.e. Oleum Terebinthinae, benzyl alcohol and glycerol) and the dispersion of thixotropic agent (i.e. aerosil and byk410) superhigh speed
30min；It is subsequently adding zinc oxide and organic anti-fouling agent (i.e. Zinc Pyrithione), at a high speed after dispersion 1h, using cooling down water cooling,
Add copper class anti-fouling agent (i.e. Red copper oxide, Cuprous sulfocyanate and copper sulfate) at a high speed dispersion 1h afterwards, fully dispersed uniformly after, that is,
Can discharging.
Antifouling paint prepared by the present invention can carry out underwater construction, respond well, and prepared coating can directly be brushed
On propeller surface.The performance test results of the antifouling paint prepared by above-mentioned 7 embodiments are similar, the coating of 7 embodiments
Test result all can reach performance as shown in table 2 below:
Table 2 one pack system propeller strippable anti-fouling paint performance table
Claims (6)
1. a kind of one pack system propeller strippable anti-fouling paint it is characterised in that: it is by the raw material group of following weight/mass percentage composition
Become: resin binder 15～65%, diluent 0～12%, copper class anti-fouling agent 25～65%, zinc oxide 5～15%, organic anti-fouling agent 0～
10%th, thixotropic agent 0.5 ~ 2%；
Described resin binder is one or more of barium mahogany sulfonate, butter, lanoline, methyl-silicone oil, hydroxy silicon oil.
2. as claimed in claim 1 a kind of one pack system propeller strippable anti-fouling paint it is characterised in that: described diluent is
One or more of Oleum Terebinthinae, benzyl alcohol, glycerol.
3. as claimed in claim 1 a kind of one pack system propeller strippable anti-fouling paint it is characterised in that: described copper class is antifouling
Agent is one or more of copper powder, Red copper oxide, Cuprous sulfocyanate, copper sulfate, copper naphthenate.
4. as claimed in claim 1 a kind of one pack system propeller strippable anti-fouling paint it is characterised in that: described organic antifouling
Agent is Zinc Pyrithione, copper pyrithione, triphenylboron pyridine, tcpm, Bravo, econea, diuron, in carbendazim one
Plant or multiple.
5. as claimed in claim 1 a kind of one pack system propeller strippable anti-fouling paint it is characterised in that: described thixotropic agent is
Aerosil or byk410 or a combination of both.
6. as claimed in claim 1 a kind of preparation method of one pack system propeller strippable anti-fouling paint it is characterised in that: first
First resin binder, diluent and thixotropic agent one superhigh speed are disperseed 30min；It is subsequently adding zinc oxide and organic anti-fouling agent, at a high speed
After dispersion 1h, using cooling water cooling, be eventually adding copper class anti-fouling agent at a high speed dispersion 1h, fully dispersed uniformly after, you can go out
Material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610750413.0A CN106349928B (en) | 2016-08-29 | 2016-08-29 | A kind of one pack system propeller strippable anti-fouling paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610750413.0A CN106349928B (en) | 2016-08-29 | 2016-08-29 | A kind of one pack system propeller strippable anti-fouling paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106349928A true CN106349928A (en) | 2017-01-25 |
| CN106349928B CN106349928B (en) | 2018-08-10 |
Family
ID=57854794
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610750413.0A Active CN106349928B (en) | 2016-08-29 | 2016-08-29 | A kind of one pack system propeller strippable anti-fouling paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106349928B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106883758A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of environment-friendly type fishing net is without copper antifouling paint |
| CN106883725A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of double-component propeller antifouling paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225136A (en) * | 2008-01-26 | 2008-07-23 | 中国船舶重工集团公司第七二五研究所 | Method for preparing antifouling hydroxyl silicon oil modified acrylic resin |
| CN102898756A (en) * | 2011-07-29 | 2013-01-30 | 许秀峰 | Peelable composite protective film |
| CN103748157A (en) * | 2011-08-18 | 2014-04-23 | 阿克佐诺贝尔国际涂料股份有限公司 | Fouling-resistant composition comprising sterols and/or derivatives thereof |
| CN104789123A (en) * | 2015-04-30 | 2015-07-22 | 国网四川省电力公司电力科学研究院 | One-component anti-pollution flashover coating for inhibiting chlorococcum growth and preparation method thereof |
| CN105670446A (en) * | 2016-03-22 | 2016-06-15 | 湖州国信物资有限公司 | Preparation method of organosilicone ocean antifouling paint |
-
2016
- 2016-08-29 CN CN201610750413.0A patent/CN106349928B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225136A (en) * | 2008-01-26 | 2008-07-23 | 中国船舶重工集团公司第七二五研究所 | Method for preparing antifouling hydroxyl silicon oil modified acrylic resin |
| CN102898756A (en) * | 2011-07-29 | 2013-01-30 | 许秀峰 | Peelable composite protective film |
| CN103748157A (en) * | 2011-08-18 | 2014-04-23 | 阿克佐诺贝尔国际涂料股份有限公司 | Fouling-resistant composition comprising sterols and/or derivatives thereof |
| CN104789123A (en) * | 2015-04-30 | 2015-07-22 | 国网四川省电力公司电力科学研究院 | One-component anti-pollution flashover coating for inhibiting chlorococcum growth and preparation method thereof |
| CN105670446A (en) * | 2016-03-22 | 2016-06-15 | 湖州国信物资有限公司 | Preparation method of organosilicone ocean antifouling paint |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106883758A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of environment-friendly type fishing net is without copper antifouling paint |
| CN106883725A (en) * | 2017-02-17 | 2017-06-23 | 中国船舶重工集团公司第七二五研究所 | A kind of double-component propeller antifouling paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106349928B (en) | 2018-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106883725A (en) | A kind of double-component propeller antifouling paint | |
| CN107400421B (en) | A kind of corrosion resistant metal coating layer material and preparation method thereof | |
| CN101696340B (en) | Strippable anti-fouling paint | |
| CN102732122A (en) | Long-acting self-polishing antifouling coating and preparation method thereof | |
| CN106349928B (en) | A kind of one pack system propeller strippable anti-fouling paint and preparation method thereof | |
| CN104449223A (en) | Aluminum-zinc-silicon epoxy composite powder anticorrosive coating and preparation method thereof | |
| CN101974281B (en) | Anticorrosive emulsion paint | |
| CN107541129A (en) | A kind of nano combined antifouling paint and preparation method thereof | |
| CN105754383A (en) | Preparation method and application of graphene-based coating for marine device | |
| LaQue | The Behavior of Nickel Copper Alloys in Sea Water | |
| CN106947391B (en) | Antifouling paint and application thereof in antifouling of cooling seawater circulating pipeline of nuclear power station | |
| CN102504697B (en) | High-efficiency tin-free self-polishing antifouling paint composition and application thereof | |
| CN108189992B (en) | Drilling platform propeller | |
| JP6535842B1 (en) | Antifouling paint | |
| US20150259542A1 (en) | Copper-based antifouling composition | |
| Cong et al. | An experimental investigation of the composite coating for marine propellers on cavitation characteristics and fouling release property | |
| CN110951333A (en) | Environment-friendly antifouling paint | |
| CN104845467B (en) | Environment-friendly type anti-fouling anti-drag composite functional coating and preparation method thereof | |
| JP4496390B2 (en) | Thiocyanate antifouling agent and antifouling paint | |
| CN102408807B (en) | High performance bionic antifouling composite paint and synthetic method thereof | |
| CN105543828A (en) | Activated rust layer rust converting agent for electric transmission and transformation equipment and preparation method and application of rust converting agent | |
| CN106519837B (en) | A kind of hull bottom long-acting and anti-fouling coating and preparation method thereof | |
| CN104745054A (en) | Polyaspartic acid ester polyurea titanium alloy nanometer heavy anti-corrosion coating | |
| CN108841171B (en) | Nylon composite material capable of preventing marine organism fouling for long time and preparation method thereof | |
| CN107090225A (en) | A kind of low-surface-energy type is from polishing marine antifouling coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |