CN106349674A - A composite lining liner for railway box car - Google Patents

A composite lining liner for railway box car Download PDF

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Publication number
CN106349674A
CN106349674A CN201610759010.2A CN201610759010A CN106349674A CN 106349674 A CN106349674 A CN 106349674A CN 201610759010 A CN201610759010 A CN 201610759010A CN 106349674 A CN106349674 A CN 106349674A
Authority
CN
China
Prior art keywords
composite liner
box car
plate
liner
liner according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610759010.2A
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Chinese (zh)
Inventor
陆延保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Tongqing Vehicle Fittings Co Ltd
Original Assignee
Jiangsu Tongqing Vehicle Fittings Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Tongqing Vehicle Fittings Co Ltd filed Critical Jiangsu Tongqing Vehicle Fittings Co Ltd
Priority to CN201610759010.2A priority Critical patent/CN106349674A/en
Publication of CN106349674A publication Critical patent/CN106349674A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B61RAILWAYS
    • B61DBODY DETAILS OR KINDS OF RAILWAY VEHICLES
    • B61D17/00Construction details of vehicle bodies
    • B61D17/04Construction details of vehicle bodies with bodies of metal; with composite, e.g. metal and wood body structures
    • B61D17/18Internal lining, e.g. insulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a composite lining liner for railway box car, the material of the composite lining liner is plastic, the performance is as follows: tensile strength >= 120MPa, bending degree >= 120MPa, notched impact strength at 25 oC, kJ / m2 to 40 oC, KJ / m2, thermal deformation >= 130 oC; Aging conditions: radiation intensity 300w / m2. The invention adopts the plastic plate, has the advantages of light weight, and can use the recovered exhaust gas as the raw material to prepare the lining plate to solve the environmental protection problem; The plate surface with wave stripes improves the anti-skid performance, and the foam or sponge on the plate surface reduces the collision of the car wall on the cargo; The composite liner can be stitched into a fixed structure to solve the problems that the different size of the car need to customize the different liner, and a damaged part of the liner can be replaced with a new liner so as to make cost savings; The middle plate uses a variety of materials for compound preparation, which has the multiple effects of flame retardant, mildew, antibacterial and others.

Description

A kind of box car composite material as liner plate
Technical field
The present invention relates to box car adnexa, more particularly, to a kind of box car composite liner.
Background technology
Box car is with side wall, headwall, floor and roof, and has the railway freight-car of slide and vent window on side wall, in order to Shipment is valuable and is afraid of the goods exposing to the sun and rain.With quickly propelling of China's industrialization and urbanization, ecommerce flourishes, Tremendous influence is created to the consumption habit of people, promotes developing rapidly of China Logistics industry.The Internet+electric business+quick ferrum Road transport become new shipping and develops branch, safely, quickly, efficiently, the railway transportation of environmental protection can better conform to the modern times Developing Logistics demand, the research and development of box car will be the main vehicle answering the development of this demand, and still further aspect is with modern logistics Development, also heat-insulated, impact resistance, the wear-resisting antiskid of the built-in product of box car, environmental protection and the performance such as recyclable are proposed higher Require, existing interior lining panel mainly has steel and bamboo laminated board two class, although steel plate disclosure satisfy that strength and stiffness requirement, prevent Slip can be bad, there is potential safety hazard during handling goods or cargo transport;Bamboo laminated board has certain anti-skidding Performance, and lighter weight, but its insufficient strength, easily make moist and go mouldy, and then cause rotten, and mechanical property reduces, Easily fracture and interlaminar separation occur in cargo handling and transportation, there is potential safety hazard, the safety to transport goods is made Become to threaten it can be seen that existing liner panel material can not meet the growth requirement of current box car.
The defect existing in view of above-mentioned existing box car interior lining panel, the design people, actively in addition research and innovation, to wound If a kind of novel railway box car composite material as liner plate is so as to have more practicality.
Content of the invention
Present invention is primarily targeted at, overcome the defect that existing box car interior lining panel exists, and a kind of Novel iron is provided Road box car composite material as liner plate, improves fire resistance and antibacterial effect, thus more suitable for practicality, and has the profit in industry With being worth.
The object of the invention to solve the technical problems employs the following technical solutions to realize.Propose according to the present invention Box car composite liner, composite liner is made up of corner plate and intermediate plate, and the material of intermediate plate used is plastic plate, corner Plate is on one side or both sides smooth, remaining side can be fixedly connected with other plates, and the performance of intermediate plate plastic plate is as follows: tensile strength 120mpa, flexibility 120mpa, notch impact strength is in 25 DEG C, kj/m2Arrive -40 DEG C, kj/m2, 130 DEG C of thermal deformation degree;Always Change condition is: radiant intensity 300w/m2, include fire retardant 5-9%.
Aforesaid box car composite liner, described composite liner is made up of corner plate and intermediate plate, used by intermediate plate Material is plastic plate, and corner plate or both sides smooth, remaining side is fixedly connected with other corner plates or intermediate plate, composite liner Between can be spliced into fixed structure.
Aforesaid box car composite liner, described intermediate plate is grouped into by each group of following mass parts:
5 ~ 15% fire retardants
20 ~ 70% Merlon
1 ~ 15% stabilizer
3 ~ 18% antibacterial
1 ~ 8% glycoprotein
5 ~ 20% mildew removing agents
1 ~ 10% disinfectant
2 ~ 15% defoamer.
Aforesaid box car composite liner, described fire retardant is carborundum, zirconium oxide, aluminium oxide, magnesium oxide, hydroxide Magnesium or aluminium hydroxide therein any one.
Aforesaid box car composite liner, described stabilizer is nano-sized polyferric sulphate.
Aforesaid box car composite liner, described antibacterial is cocamido propyl betaine, polyquaternary ammonium salt, diethanol Amine or BIT therein any one.
Aforesaid box car composite liner, described disinfectant is ethanol, potassium permanganate, formaldehyde, glutaraldehyde, epoxy second Alkane, peracetic acid, hydrogen peroxide or chlorine dioxide therein any one.
Aforesaid box car composite liner, described mildew removing agent is alkali metal cyanate or cyanic acid ammonium salt.
Further, glycoprotein is Chinese potato glucoprotein, is a kind of protein extracting from Rhizoma Dioscoreae;Defoamer is nitre Sour gallium, gallium sulfate or gallium chloride one kind therein.
By technique scheme, the box car composite material as liner plate of the present invention at least has the advantage that
The interior lining panel of the present invention selects plastic plate, has the advantages that light weight, can be made from the waste gas plastics after reclaiming simultaneously Prepare interior lining panel for raw material, solve environmental issue;It is provided with wave band in plate surface and improve non-skid property, the bubble of setting Foam or sponge alleviate the collision to goods for the compartment wall;Composite liner can be spliced into fixed structure and solve different size compartment Need to customize different liner plate problems, also solve certain position of liner plate simultaneously and damage and can be replaced with new liner plate, save into This;Intermediate plate adopts multiple material to be combined preparation, has the multiple actions such as fire-retardant, mould proof, antibacterial.
Base material, from the waste plastic granule of conventional engineering plastics granule or recovery, wherein adds nanometer polymerization sulphuric acid Ferrum has good stability, and glycoprotein and antibacterial, mildew removing agent synergism are to strengthen its antibacterial, except mould effect;Froth breaking Agent ensures that the finished product intermediate plate of preparation has good performance it is ensured that each several part Performance comparision uniformly, excludes bubble to material The impact of energy.
, be applied to box car, as far as possible during minimizing transport goods, goods is damaged, mould for the interior lining panel of present invention preparation Become or occur burning etc. unexpected.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of description, after being described in detail such as with presently preferred embodiments of the present invention below.
Specific embodiment
For further illustrating that the present invention is to reach technological means and effect that predetermined goal of the invention is taken, below in conjunction with Preferred embodiment, after the specific embodiment detailed description such as of the present invention.
Embodiment 1
The box car composite liner of the present invention, intermediate plate is grouped into by each group of following mass parts:
12% nano zircite fire retardant, 38% Merlon, 13% nano-sized polyferric sulphate stabilizer, 15% cocamidopropyl propyl amide is sweet Dish alkali antibacterial, 2% Chinese potato glucoprotein, 6% cyanic acid ammonium salt mildew removing agent, 2% potassium permanganate disinfectant 12% gallium chloride defoamer.
Collect waste gas plastics it is processed obtain polycarbonate pellets, heating dissolve after stirring during, poly- carbonic acid Add fire retardant, stabilizer in ester solution, continue stirring after increasing the temperature to 550 DEG C, add glycoprotein, disinfectant, antibacterial Agent, mildew removing agent and defoamer, after stirring 2h, gradually lower the temperature, and then pelletize prepares intermediate plate.The intermediate plate tensile strength obtaining For 160mpa, flexibility 180mpa, thermal deformation degree is at 150 DEG C.By composite liner reprocess on one side smooth, remaining side can be with it Its corner plate or intermediate plate are fixedly connected, and composite liner is the plastic plate of hollow, is simultaneously provided with wave band, between composite liner It is spliced into fixed structure.According to the requirement to compartment, suitable composite liner is selected to be installed.
Embodiment 2
The box car composite liner of the present invention, intermediate plate is grouped into by each group of following mass parts:
5% flame retardant of magnesium hydroxide, 40% Merlon, 6% nano-sized polyferric sulphate stabilizer, 9% BIT antibacterial Agent, 7% Chinese potato glucoprotein, 13% cyanic acid magnesium salt mildew removing agent, 6% ethanol disinfection agent 14% gallium sulfate defoamer.
Collect waste gas plastics it is processed obtain polycarbonate pellets, heating dissolve after stirring during, poly- carbonic acid Add fire retardant, stabilizer in ester solution, continue stirring after increasing the temperature to 600 DEG C, add glycoprotein, disinfectant, antibacterial Agent, mildew removing agent and defoamer, after stirring 1.8h, gradually lower the temperature, and then pelletize prepares intermediate plate.The middle plate stretching obtaining is strong Spend for 170mpa, flexibility 190mpa, thermal deformation degree is at 160 DEG C.Composite liner is reprocessed can be with for smooth, remaining side on one side Other corners plate or intermediate plate are fixedly connected, composite liner be hollow plastic plate, be simultaneously provided with wave band, composite liner it Between be spliced into fixed structure.According to the requirement to compartment, suitable composite liner is selected to be installed.
Embodiment 3
The box car composite liner of the present invention, intermediate plate is grouped into by each group of following mass parts:
5% carborundum fire retardant, 35% Merlon, 7% nano-sized polyferric sulphate stabilizer, 13% cocamido propyl betaine resists Microbial inoculum, 5% Chinese potato glucoprotein, 15% cyanic acid potassium salt mildew removing agent, 8% ethylene oxide disinfectant 12% Ganite (Fujisawa). defoamer.
Collect waste gas plastics it is processed obtain polycarbonate pellets, heating dissolve after stirring during, poly- carbonic acid Add fire retardant, stabilizer in ester solution, continue stirring after increasing the temperature to 550 DEG C, add glycoprotein, disinfectant, antibacterial Agent, mildew removing agent and defoamer, after stirring 2h, gradually lower the temperature, and then pelletize prepares intermediate plate.The intermediate plate tensile strength obtaining For 160mpa, flexibility 180mpa, thermal deformation degree is at 150 DEG C.By composite liner reprocess on one side smooth, remaining side can be with it Its corner plate or intermediate plate are fixedly connected, and composite liner is the plastic plate of hollow, is simultaneously provided with wave band, between composite liner It is spliced into fixed structure.According to the requirement to compartment, suitable composite liner is selected to be installed.Carry out fire test checking, The fire resistance the result preparing material is as shown in table 1:
Table 1 fire resistance
Project Anti-flammability
Embodiment 1 Fall time 2.7s
Embodiment 2 Fall time 4.5s
Embodiment 3 Fall time 3.6s
, through degerming verification experimental verification, the effect removing antibacterial is as shown in table 2 for the material of preparation:
The degerming performance of table 2
Project Degerming property
Embodiment 1 Remove antibacterial time 6h
Embodiment 2 Remove antibacterial time 8.5h
Embodiment 3 Remove antibacterial time 5.5h
Good fire-retardant and bacteria-eliminating efficacy, performance are had by the intermediate plate that above-mentioned experimental result can be seen that present invention preparation The result shows its performance higher than existing material at present.
The above, be only presently preferred embodiments of the present invention, not the present invention is made with any pro forma restriction, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any is familiar with this professional technology people Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above make a little change or modification For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention Any simple modification, equivalent variations and the modification that above example is made, all still falls within the range of technical solution of the present invention.

Claims (10)

1., it is characterised in that the material of composite liner is plastics, performance is as follows: tensile strength for a kind of box car composite liner 120mpa, flexibility 120mpa, notch impact strength is in 25 DEG C, kj/m2 to -40 DEG C, kj/m2, thermal deformation degree 130 ℃;Aging condition is: radiant intensity 300w/m2.
2. box car composite liner according to claim 1 is it is characterised in that described composite liner is the plastics of hollow Plate.
3. box car composite liner according to claim 2 is it is characterised in that described composite liner one side is provided with wave Band, foam or sponge.
4. box car composite liner according to claim 1 it is characterised in that described composite liner by corner plate and in Between plate composition, the material used by intermediate plate is plastic plate, corner plate or both sides smooth, remaining side and other corner plates or in Between plate be fixedly connected, fixed structure can be spliced between composite liner.
5. box car composite liner according to claim 4 is it is characterised in that described intermediate plate is by following mass parts Each group is grouped into:
5 ~ 15% fire retardants
20 ~ 70% Merlon
1 ~ 15% stabilizer
3 ~ 18% antibacterial
1 ~ 8% glycoprotein
5 ~ 20% mildew removing agents
1 ~ 10% disinfectant
2 ~ 15% defoamer.
6. box car composite liner according to claim 5 is it is characterised in that described fire retardant is carborundum, oxidation Zirconium, aluminium oxide, magnesium oxide, magnesium hydroxide or aluminium hydroxide therein any one.
7. box car composite liner according to claim 5 is it is characterised in that described stabilizer is nanometer polymerization sulphuric acid Ferrum.
8. box car composite liner according to claim 5 is it is characterised in that described antibacterial is cocamidopropyl propyl amide Glycine betaine, polyquaternary ammonium salt, diethanolamine or BIT therein any one.
9. box car composite liner according to claim 5 is it is characterised in that described disinfectant is ethanol, permanganic acid Potassium, formaldehyde, glutaraldehyde, oxirane, peracetic acid, hydrogen peroxide or chlorine dioxide therein any one.
10. box car composite liner according to claim 5 is it is characterised in that described mildew removing agent is alkali metal cyanic acid Salt or cyanic acid ammonium salt.
CN201610759010.2A 2016-08-30 2016-08-30 A composite lining liner for railway box car Pending CN106349674A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610759010.2A CN106349674A (en) 2016-08-30 2016-08-30 A composite lining liner for railway box car

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610759010.2A CN106349674A (en) 2016-08-30 2016-08-30 A composite lining liner for railway box car

Publications (1)

Publication Number Publication Date
CN106349674A true CN106349674A (en) 2017-01-25

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610759010.2A Pending CN106349674A (en) 2016-08-30 2016-08-30 A composite lining liner for railway box car

Country Status (1)

Country Link
CN (1) CN106349674A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204623458U (en) * 2014-12-22 2015-09-09 江苏奇一科技有限公司 Lining of railway boxcar plate

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204623458U (en) * 2014-12-22 2015-09-09 江苏奇一科技有限公司 Lining of railway boxcar plate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
新闻: ""使用拜耳聚碳酸酯制造的时尚铁路车辆内饰"", 《HTTPS://WWW.PLASTICS.COVESTRO.COM/ZH-CN/NEWSANDEVENTS/NEWS/2014-09-05-STYLISH-RAIL-INTERIORS-WITH-BAYER-POLYCABONATES》 *

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SE01 Entry into force of request for substantive examination
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Application publication date: 20170125