CN106349655A - Water conservancy and hydropower construction drainage and antifouling pipe material with good weather resistance - Google Patents

Water conservancy and hydropower construction drainage and antifouling pipe material with good weather resistance Download PDF

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CN106349655A
CN106349655A CN201610750322.7A CN201610750322A CN106349655A CN 106349655 A CN106349655 A CN 106349655A CN 201610750322 A CN201610750322 A CN 201610750322A CN 106349655 A CN106349655 A CN 106349655A
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parts
phenyl
tubing
hydropower construction
phosphate
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龚灿锋
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/18—Applications used for pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a water conservancy and hydropower construction drainage and antifouling pipe material with weather resistance, composed of the following components, by weight: epoxy acrylic resin, chloroprene rubber, polymethylvinylphenylsiloxane gum, MBS resin, styrenated alkyd resin, self-cross linking acrylic binder, Hexamethylphosphoramide, Acetic Styrene-acrylic Emulsion, crotonic acid methy, anthracene oil, limonene, chitin, acetylspiramycin, vancomycin, Portland cement, blue copperas, dibasic lead phosphite, nanometer titanium dioxide, Chromic acid lithium powder, magnesium sulfate, Phenyl containing hydrogen silicone, calcium thiocyanate, hexabromo-benzene, GUP, TCEP, Diethyl ethanephosphonate, sodium sulfite, 2-mercapto benzimidazole, Phenyl alkyl sulfonate, Ethoxylated Trimethyol propane Triacytate, benzimidazole and allyl methacrylate. The water conservancy and hydropower construction drainage and antifouling pipe material with weather resistance is mixed with multiple ingredients, to form a novel composite toughening and strengthening system, with better indexes of toughness, rigidity and elastic modulus. The water conservancy and hydropower construction drainage and antifouling pipe material with weather resistance greatly improves ageing resistance and use performance of products, with good corrosion resistance, antibacterial flame retardant, insulation performance, comprehensive performance and use effect.

Description

A kind of antifouling good weatherability tubing of WR and hydropower construction draining
Technical field
The present invention relates to a kind of antifouling good weatherability tubing of WR and hydropower construction draining, belong to water conservancy and hydropower technical field.
Background technology
It is often necessary to use multiple tubing during WR and hydropower construction, these tubing are deposited for WR and hydropower construction In significance.It is sometimes necessary to carry out drainage sunk well particularly during WR and hydropower construction, during this, having must Tubing to be used.Its performance of general tubing is limited by condition it is impossible to meet use requirement it is necessary to adopt suitable mode Improved.
Content of the invention
It is an object of the invention to provide a kind of antifouling good weatherability tubing of WR and hydropower construction draining, so that preferably real The use function of existing WR and hydropower construction draining antifouling good weatherability tubing, improves the toughness of product, rigidity, elastic modelling quantity, carries The ageing resistace of high product and serviceability, and make product have preferably corrosion-resistant, antibacterial flame-retardant effect.
To achieve these goals, technical scheme is as follows.
A kind of antifouling good weatherability tubing of WR and hydropower construction draining, is grouped into by the group of following mass fraction: epoxy third 28～32 parts of alkene acid ester resin, 26～30 parts of neoprene, 26～30 parts of methyl vinyl phenyl silicone rubber, mbs resin 24～ 28 parts, 26～30 parts of styrenated alkyd, 26～30 parts of polyacrylate emulsion, 24～28 parts of HMPA, 26～30 parts of acrylate and vinyl acetate emulsion, 26～30 parts of M Cr, 24～28 parts of carbolineum, 24～28 parts of limonene, chitin 24～28 Part, 26～30 parts of acetylspiramycin, 24～28 parts of vancomycin, 22～26 parts of portland cement, copper sulphate pentahydrate 26～30 Part, 24～28 parts of dibasic lead phosphite, 22～26 parts of nanometer titanium dioxide, 24～28 parts of chromic acid lithium powder, magnesium sulfate 22～26 Part, 22～26 parts of the hydrogeneous silicones of phenyl, 22～26 parts of Calcium rhodanate, 20～24 parts of HBB, guanyl-urea-phosphate 16～20 Part, 14～18 parts of trichloroethyl phosphate, 14～18 parts of diethyl ethylphosphate, 14～18 parts of sodium sulfite, 2- sulfydryl benzo miaow 14～18 parts of azoles, 14～18 parts of phenyl alkylsulf, 14～18 parts of ethoxylated trimethylolpropane triacrylate, benzo miaow 14～18 parts of azoles, 14～18 parts of allyl methacrylate.
Further, the antifouling good weatherability tubing of above-mentioned WR and hydropower construction draining, by the group packet of following mass fraction Become: 28 parts of Epocryl, 26 parts of neoprene, 26 parts of methyl vinyl phenyl silicone rubber, 24 parts of mbs resin, benzene 26 parts of ethylene modified alkyd resin, 26 parts of polyacrylate emulsion, 24 parts of HMPA, 26 parts of acrylate and vinyl acetate emulsion, butenoic acid 26 parts of methyl ester, 24 parts of carbolineum, 24 parts of limonene, 24 parts of chitin, 26 parts of acetylspiramycin, 24 parts of vancomycin, silicate 22 parts of cement, 26 parts of copper sulphate pentahydrate, 24 parts of dibasic lead phosphite, 22 parts of nanometer titanium dioxide, 24 parts of chromic acid lithium powder, sulphuric acid 22 parts of magnesium, 22 parts of the hydrogeneous silicones of phenyl, 22 parts of Calcium rhodanate, 20 parts of HBB, 16 parts of guanyl-urea-phosphate, tricresyl phosphate chloroethene 14 parts of ester, 14 parts of diethyl ethylphosphate, 14 parts of sodium sulfite, 14 parts of 2-mercaptobenzimidazole, 14 parts of phenyl alkylsulf, second 14 parts of epoxide trimethylolpropane trimethacrylate, 14 parts of benzimidazole, 14 parts of allyl methacrylate.
Further, the antifouling good weatherability tubing of above-mentioned WR and hydropower construction draining, by the group packet of following mass fraction Become: 30 parts of Epocryl, 28 parts of neoprene, 28 parts of methyl vinyl phenyl silicone rubber, 26 parts of mbs resin, benzene 28 parts of ethylene modified alkyd resin, 28 parts of polyacrylate emulsion, 26 parts of HMPA, 28 parts of acrylate and vinyl acetate emulsion, butenoic acid 28 parts of methyl ester, 26 parts of carbolineum, 26 parts of limonene, 26 parts of chitin, 28 parts of acetylspiramycin, 26 parts of vancomycin, silicate 24 parts of cement, 28 parts of copper sulphate pentahydrate, 26 parts of dibasic lead phosphite, 24 parts of nanometer titanium dioxide, 26 parts of chromic acid lithium powder, sulphuric acid 24 parts of magnesium, 24 parts of the hydrogeneous silicones of phenyl, 24 parts of Calcium rhodanate, 22 parts of HBB, 18 parts of guanyl-urea-phosphate, tricresyl phosphate chloroethene 16 parts of ester, 16 parts of diethyl ethylphosphate, 16 parts of sodium sulfite, 16 parts of 2-mercaptobenzimidazole, 16 parts of phenyl alkylsulf, second 16 parts of epoxide trimethylolpropane trimethacrylate, 16 parts of benzimidazole, 16 parts of allyl methacrylate.
Further, the antifouling good weatherability tubing of above-mentioned WR and hydropower construction draining, by the group packet of following mass fraction Become: 32 parts of Epocryl, 30 parts of neoprene, 30 parts of methyl vinyl phenyl silicone rubber, 28 parts of mbs resin, benzene 30 parts of ethylene modified alkyd resin, 30 parts of polyacrylate emulsion, 28 parts of HMPA, 30 parts of acrylate and vinyl acetate emulsion, butenoic acid 30 parts of methyl ester, 28 parts of carbolineum, 28 parts of limonene, 28 parts of chitin, 30 parts of acetylspiramycin, 28 parts of vancomycin, silicate 26 parts of cement, 30 parts of copper sulphate pentahydrate, 28 parts of dibasic lead phosphite, 26 parts of nanometer titanium dioxide, 28 parts of chromic acid lithium powder, sulphuric acid 26 parts of magnesium, 26 parts of the hydrogeneous silicones of phenyl, 26 parts of Calcium rhodanate, 24 parts of HBB, 20 parts of guanyl-urea-phosphate, tricresyl phosphate chloroethene 18 parts of ester, 18 parts of diethyl ethylphosphate, 18 parts of sodium sulfite, 18 parts of 2-mercaptobenzimidazole, 18 parts of phenyl alkylsulf, second 18 parts of epoxide trimethylolpropane trimethacrylate, 18 parts of benzimidazole, 18 parts of allyl methacrylate.
Further, above-mentioned WR and hydropower construction draining antifouling good weatherability tubing preparation method step is as follows:
(1) by the Epocryl of described mass fraction, neoprene, methyl vinyl phenyl silicone rubber, mbs tree Fat, styrenated alkyd, polyacrylate emulsion, HMPA, acrylate and vinyl acetate emulsion, M Cr, carbolineum, lemon Lemon alkene, chitin, acetylspiramycin, vancomycin, portland cement, copper sulphate pentahydrate, dibasic lead phosphite, nano-titanium White lead, chromic acid lithium powder, magnesium sulfate, the hydrogeneous silicones of phenyl, Calcium rhodanate are mixed, ultrasonic high speed dispersion, ultrasonic wave frequency Rate is 20～40khz, rate of dispersion 5000～5400r/min about, jitter time is 30～60min；
(2) HBB of the described mass fraction of addition, guanyl-urea-phosphate, trichloroethyl phosphate, diethyl ethylphosphate, sulfurous Sour sodium, ultrasonic high speed dispersion, ultrasonic frequency is 20～35khz, rate of dispersion 4800～5200r/min about, jitter time For 30～50min；
(3) 2-mercaptobenzimidazole of the described mass fraction of addition, phenyl alkylsulf, ethoxylated trimethylolpropane 3 third Olefin(e) acid ester, benzimidazole, allyl methacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 20～30khz, rate of dispersion 4600～4800r/min about, jitter time is 20～40min；Primary mix is obtained after mix homogeneously；Again by primary mixing Thing is added in double screw extruder and carries out melting mixing, obtains desired mixt raw material；
(4) mixture material obtaining step (3) is extruded in an extruder, obtains finished product, wherein, extrusion condition is: barrel Temperature: 184 ± 2 DEG C, merging core temperature: 176 ± 2 DEG C, head temperature: 190 ± 5 DEG C, traction: 0.6～0.9m/min, main frame turns Speed: 25～30 revs/min.
This beneficial effect of the invention is: the WR and hydropower construction draining antifouling good weatherability tubing in the present invention, by with The following group is grouped into: Epocryl, neoprene, methyl vinyl phenyl silicone rubber, mbs resin, phenylethene modified Alkyd resin, polyacrylate emulsion, HMPA, acrylate and vinyl acetate emulsion, M Cr, carbolineum, limonene, chitin, Acetylspiramycin, vancomycin, portland cement, copper sulphate pentahydrate, dibasic lead phosphite, nanometer titanium dioxide, lithium chromate The hydrogeneous silicones of powder, magnesium sulfate, phenyl, Calcium rhodanate, HBB, guanyl-urea-phosphate, trichloroethyl phosphate, ethylphosphonic acid Diethylester, sodium sulfite, 2-mercaptobenzimidazole, phenyl alkylsulf, ethoxylated trimethylolpropane triacrylate, benzene And imidazoles, allyl methacrylate.The multiple dispensing of the present invention is mutually mixed, and forms new composite toughening and strengthens system, tough Property, rigidity, elastic modelling quantity performance indications preferably, greatly improve ageing resistace and the serviceability of product, have preferably resistance to Burn into antibacterial flame-retardant effect is good, and insulating properties are good, and combination property is good, and using effect is good.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is described, to be better understood from the present invention.
Embodiment 1
WR and hydropower construction draining antifouling good weatherability tubing in the present embodiment, is grouped into by the group of following mass fraction: ring 28 parts of oxypropylene acid ester resin, 26 parts of neoprene, 26 parts of methyl vinyl phenyl silicone rubber, 24 parts of mbs resin, styrene change 26 parts of alkyd resin of property, 26 parts of polyacrylate emulsion, 24 parts of HMPA, 26 parts of acrylate and vinyl acetate emulsion, M Cr 26 Part, 24 parts of carbolineum, 24 parts of limonene, 24 parts of chitin, 26 parts of acetylspiramycin, 24 parts of vancomycin, portland cement 22 Part, 26 parts of copper sulphate pentahydrate, 24 parts of dibasic lead phosphite, 22 parts of nanometer titanium dioxide, 24 parts of chromic acid lithium powder, magnesium sulfate 22 Part, 22 parts of the hydrogeneous silicones of phenyl, 22 parts of Calcium rhodanate, 20 parts of HBB, 16 parts of guanyl-urea-phosphate, trichloroethyl phosphate 14 Part, 14 parts of diethyl ethylphosphate, 14 parts of sodium sulfite, 14 parts of 2-mercaptobenzimidazole, 14 parts of phenyl alkylsulf, ethyoxyl Change 14 parts of trimethylolpropane trimethacrylate, 14 parts of benzimidazole, 14 parts of allyl methacrylate.
Above-mentioned WR and hydropower construction draining antifouling good weatherability tubing preparation method step is as follows:
(1) by the Epocryl of described mass fraction, neoprene, methyl vinyl phenyl silicone rubber, mbs tree Fat, styrenated alkyd, polyacrylate emulsion, HMPA, acrylate and vinyl acetate emulsion, M Cr, carbolineum, lemon Lemon alkene, chitin, acetylspiramycin, vancomycin, portland cement, copper sulphate pentahydrate, dibasic lead phosphite, nano-titanium White lead, chromic acid lithium powder, magnesium sulfate, the hydrogeneous silicones of phenyl, Calcium rhodanate are mixed, ultrasonic high speed dispersion, ultrasonic wave frequency Rate is 20khz, rate of dispersion 5400r/min about, jitter time is 60min；
(2) HBB of the described mass fraction of addition, guanyl-urea-phosphate, trichloroethyl phosphate, diethyl ethylphosphate, sulfurous Sour sodium, ultrasonic high speed dispersion, ultrasonic frequency is 20khz, rate of dispersion 5200r/min about, jitter time is 50min；
(3) 2-mercaptobenzimidazole of the described mass fraction of addition, phenyl alkylsulf, ethoxylated trimethylolpropane 3 third Olefin(e) acid ester, benzimidazole, allyl methacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 20khz, rate of dispersion 4800r/min about, jitter time is 40min；Primary mix is obtained after mix homogeneously；Again primary mix is added to double Carry out melting mixing in screw extruder, obtain desired mixt raw material；
(4) mixture material obtaining step (3) is extruded in an extruder, obtains finished product, wherein, extrusion condition is: barrel Temperature: 184 ± 2 DEG C, merging core temperature: 176 ± 2 DEG C, head temperature: 190 ± 5 DEG C, traction: 0.6～0.9m/min, main frame turns Speed: 25～30 revs/min.
Embodiment 2
WR and hydropower construction draining antifouling good weatherability tubing in the present embodiment, is grouped into by the group of following mass fraction: ring 30 parts of oxypropylene acid ester resin, 28 parts of neoprene, 28 parts of methyl vinyl phenyl silicone rubber, 26 parts of mbs resin, styrene change 28 parts of alkyd resin of property, 28 parts of polyacrylate emulsion, 26 parts of HMPA, 28 parts of acrylate and vinyl acetate emulsion, M Cr 28 Part, 26 parts of carbolineum, 26 parts of limonene, 26 parts of chitin, 28 parts of acetylspiramycin, 26 parts of vancomycin, portland cement 24 Part, 28 parts of copper sulphate pentahydrate, 26 parts of dibasic lead phosphite, 24 parts of nanometer titanium dioxide, 26 parts of chromic acid lithium powder, magnesium sulfate 24 Part, 24 parts of the hydrogeneous silicones of phenyl, 24 parts of Calcium rhodanate, 22 parts of HBB, 18 parts of guanyl-urea-phosphate, trichloroethyl phosphate 16 Part, 16 parts of diethyl ethylphosphate, 16 parts of sodium sulfite, 16 parts of 2-mercaptobenzimidazole, 16 parts of phenyl alkylsulf, ethyoxyl Change 16 parts of trimethylolpropane trimethacrylate, 16 parts of benzimidazole, 16 parts of allyl methacrylate.
Above-mentioned WR and hydropower construction draining antifouling good weatherability tubing preparation method step is as follows:
(1) by the Epocryl of described mass fraction, neoprene, methyl vinyl phenyl silicone rubber, mbs tree Fat, styrenated alkyd, polyacrylate emulsion, HMPA, acrylate and vinyl acetate emulsion, M Cr, carbolineum, lemon Lemon alkene, chitin, acetylspiramycin, vancomycin, portland cement, copper sulphate pentahydrate, dibasic lead phosphite, nano-titanium White lead, chromic acid lithium powder, magnesium sulfate, the hydrogeneous silicones of phenyl, Calcium rhodanate are mixed, ultrasonic high speed dispersion, ultrasonic wave frequency Rate is 30khz, rate of dispersion 5200r/min about, jitter time is 45min；
(2) HBB of the described mass fraction of addition, guanyl-urea-phosphate, trichloroethyl phosphate, diethyl ethylphosphate, sulfurous Sour sodium, ultrasonic high speed dispersion, ultrasonic frequency is 27khz, rate of dispersion 5000r/min about, jitter time is 40min；
(3) 2-mercaptobenzimidazole of the described mass fraction of addition, phenyl alkylsulf, ethoxylated trimethylolpropane 3 third Olefin(e) acid ester, benzimidazole, allyl methacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 25khz, rate of dispersion 4700r/min about, jitter time is 30min；Primary mix is obtained after mix homogeneously；Again primary mix is added to double Carry out melting mixing in screw extruder, obtain desired mixt raw material；
(4) mixture material obtaining step (3) is extruded in an extruder, obtains finished product, wherein, extrusion condition is: barrel Temperature: 184 ± 2 DEG C, merging core temperature: 176 ± 2 DEG C, head temperature: 190 ± 5 DEG C, traction: 0.6～0.9m/min, main frame turns Speed: 25～30 revs/min.
Embodiment 3
WR and hydropower construction draining antifouling good weatherability tubing in the present embodiment, is grouped into by the group of following mass fraction: ring 32 parts of oxypropylene acid ester resin, 30 parts of neoprene, 30 parts of methyl vinyl phenyl silicone rubber, 28 parts of mbs resin, styrene change 30 parts of alkyd resin of property, 30 parts of polyacrylate emulsion, 28 parts of HMPA, 30 parts of acrylate and vinyl acetate emulsion, M Cr 30 Part, 28 parts of carbolineum, 28 parts of limonene, 28 parts of chitin, 30 parts of acetylspiramycin, 28 parts of vancomycin, portland cement 26 Part, 30 parts of copper sulphate pentahydrate, 28 parts of dibasic lead phosphite, 26 parts of nanometer titanium dioxide, 28 parts of chromic acid lithium powder, magnesium sulfate 26 Part, 26 parts of the hydrogeneous silicones of phenyl, 26 parts of Calcium rhodanate, 24 parts of HBB, 20 parts of guanyl-urea-phosphate, trichloroethyl phosphate 18 Part, 18 parts of diethyl ethylphosphate, 18 parts of sodium sulfite, 18 parts of 2-mercaptobenzimidazole, 18 parts of phenyl alkylsulf, ethyoxyl Change 18 parts of trimethylolpropane trimethacrylate, 18 parts of benzimidazole, 18 parts of allyl methacrylate.
Above-mentioned WR and hydropower construction draining antifouling good weatherability tubing preparation method step is as follows:
(1) by the Epocryl of described mass fraction, neoprene, methyl vinyl phenyl silicone rubber, mbs tree Fat, styrenated alkyd, polyacrylate emulsion, HMPA, acrylate and vinyl acetate emulsion, M Cr, carbolineum, lemon Lemon alkene, chitin, acetylspiramycin, vancomycin, portland cement, copper sulphate pentahydrate, dibasic lead phosphite, nano-titanium White lead, chromic acid lithium powder, magnesium sulfate, the hydrogeneous silicones of phenyl, Calcium rhodanate are mixed, ultrasonic high speed dispersion, ultrasonic wave frequency Rate is 40khz, rate of dispersion 5000r/min, and jitter time is 30min；
(2) HBB of the described mass fraction of addition, guanyl-urea-phosphate, trichloroethyl phosphate, diethyl ethylphosphate, sulfurous Sour sodium, ultrasonic high speed dispersion, ultrasonic frequency is 35khz, rate of dispersion 4800r/min, and jitter time is 30min；
(3) 2-mercaptobenzimidazole of the described mass fraction of addition, phenyl alkylsulf, ethoxylated trimethylolpropane 3 third Olefin(e) acid ester, benzimidazole, allyl methacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 30khz, rate of dispersion 4600r/min about, jitter time is 20min；Primary mix is obtained after mix homogeneously；Again primary mix is added to double Carry out melting mixing in screw extruder, obtain desired mixt raw material；
(4) mixture material obtaining step (3) is extruded in an extruder, obtains finished product, wherein, extrusion condition is: barrel Temperature: 184 ± 2 DEG C, merging core temperature: 176 ± 2 DEG C, head temperature: 190 ± 5 DEG C, traction: 0.6～0.9m/min, main frame turns Speed: 25～30 revs/min.
Carry out performance measurement for the product in embodiment 1, embodiment 2 and embodiment 3 and certain commercially available prod, measured Data is as shown in Table 1 and Table 2.Fire protection flame retarding level estimate adopts ul94 standard.
Table 1 the performance test results
From table 1, product of the present invention has preferably corrosion-resistant, fire protection flame retarding, anti-mildew, antibacterial insulating properties.
Table 2
From table 2, product of the present invention has preferable yield strength, tensile modulus of elasticity, and comprcssive strength is high, longitudinal extension rate Number, heat-conducting effect is good.
The above is the preferred embodiment of the present invention it is noted that for those skilled in the art For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (5)

1. a kind of antifouling good weatherability tubing of WR and hydropower construction draining it is characterised in that: by the group packet of following mass fraction Become: 28～32 parts of Epocryl, 26～30 parts of neoprene, 26～30 parts of methyl vinyl phenyl silicone rubber, mbs 24～28 parts of resin, 26～30 parts of styrenated alkyd, 26～30 parts of polyacrylate emulsion, HMPA 24 ～28 parts, 26～30 parts of acrylate and vinyl acetate emulsion, 26～30 parts of M Cr, 24～28 parts of carbolineum, 24～28 parts of limonene, chitin 24～28 parts, 26～30 parts of acetylspiramycin, 24～28 parts of vancomycin, 22～26 parts of portland cement, copper sulphate pentahydrate 26～30 parts, 24～28 parts of dibasic lead phosphite, 22～26 parts of nanometer titanium dioxide, 24～28 parts of chromic acid lithium powder, magnesium sulfate 22～26 parts, 22～26 parts of the hydrogeneous silicones of phenyl, 22～26 parts of Calcium rhodanate, 20～24 parts of HBB, guanyl-urea-phosphate 16～20 parts, 14～18 parts of trichloroethyl phosphate, 14～18 parts of diethyl ethylphosphate, 14～18 parts of sodium sulfite, 2- sulfydryl 14～18 parts of benzimidazole, 14～18 parts of phenyl alkylsulf, 14～18 parts of ethoxylated trimethylolpropane triacrylate, 14～18 parts of benzimidazole, 14～18 parts of allyl methacrylate.
2. the antifouling good weatherability tubing of WR and hydropower construction draining according to claim 1 it is characterised in that: described water conservancy Hydroelectric Project Construction draining antifouling good weatherability tubing is grouped into by the group of following mass fraction: 28 parts of Epocryl, chlorine 26 parts of buna, 26 parts of methyl vinyl phenyl silicone rubber, 24 parts of mbs resin, 26 parts of styrenated alkyd, polypropylene 26 parts of yogurt liquid, 24 parts of HMPA, 26 parts of acrylate and vinyl acetate emulsion, 26 parts of M Cr, 24 parts of carbolineum, limonene 24 Part, 24 parts of chitin, 26 parts of acetylspiramycin, 24 parts of vancomycin, 22 parts of portland cement, 26 parts of copper sulphate pentahydrate, two 24 parts of alkali formula lead phosphite, 22 parts of nanometer titanium dioxide, 24 parts of chromic acid lithium powder, 22 parts of magnesium sulfate, 22 parts of the hydrogeneous silicones of phenyl, 22 parts of Calcium rhodanate, 20 parts of HBB, 16 parts of guanyl-urea-phosphate, 14 parts of trichloroethyl phosphate, 14 parts of diethyl ethylphosphate, 14 parts of sodium sulfite, 14 parts of 2-mercaptobenzimidazole, 14 parts of phenyl alkylsulf, ethoxylated trimethylolpropane three acrylic acid 14 parts of ester, 14 parts of benzimidazole, 14 parts of allyl methacrylate.
3. the WR and hydropower construction draining antifouling good weatherability tubing according to claim 1 to 2 it is characterised in that: described WR and hydropower construction draining antifouling good weatherability tubing is grouped into by the group of following mass fraction: Epocryl 30 Part, 28 parts of neoprene, 28 parts of methyl vinyl phenyl silicone rubber, 26 parts of mbs resin, 28 parts of styrenated alkyd, 28 parts of polyacrylate emulsion, 26 parts of HMPA, 28 parts of acrylate and vinyl acetate emulsion, 28 parts of M Cr, 26 parts of carbolineum, Fructus Citri Limoniae 26 parts of alkene, 26 parts of chitin, 28 parts of acetylspiramycin, 26 parts of vancomycin, 24 parts of portland cement, copper sulphate pentahydrate 28 Part, 26 parts of dibasic lead phosphite, 24 parts of nanometer titanium dioxide, 26 parts of chromic acid lithium powder, 24 parts of magnesium sulfate, the hydrogeneous silicones of phenyl 24 parts, 24 parts of Calcium rhodanate, 22 parts of HBB, 18 parts of guanyl-urea-phosphate, 16 parts of trichloroethyl phosphate, diethyl ethylphosphate 16 parts, 16 parts of sodium sulfite, 16 parts of 2-mercaptobenzimidazole, 16 parts of phenyl alkylsulf, ethoxylated trimethylolpropane three 16 parts of acrylate, 16 parts of benzimidazole, 16 parts of allyl methacrylate.
4. the WR and hydropower construction draining antifouling good weatherability tubing according to claims 1 to 3 it is characterised in that: described WR and hydropower construction draining antifouling good weatherability tubing is grouped into by the group of following mass fraction: Epocryl 32 Part, 30 parts of neoprene, 30 parts of methyl vinyl phenyl silicone rubber, 28 parts of mbs resin, 30 parts of styrenated alkyd, 30 parts of polyacrylate emulsion, 28 parts of HMPA, 30 parts of acrylate and vinyl acetate emulsion, 30 parts of M Cr, 28 parts of carbolineum, Fructus Citri Limoniae 28 parts of alkene, 28 parts of chitin, 30 parts of acetylspiramycin, 28 parts of vancomycin, 26 parts of portland cement, copper sulphate pentahydrate 30 Part, 28 parts of dibasic lead phosphite, 26 parts of nanometer titanium dioxide, 28 parts of chromic acid lithium powder, 26 parts of magnesium sulfate, the hydrogeneous silicones of phenyl 26 parts, 26 parts of Calcium rhodanate, 24 parts of HBB, 20 parts of guanyl-urea-phosphate, 18 parts of trichloroethyl phosphate, diethyl ethylphosphate 18 parts, 18 parts of sodium sulfite, 18 parts of 2-mercaptobenzimidazole, 18 parts of phenyl alkylsulf, ethoxylated trimethylolpropane three 18 parts of acrylate, 18 parts of benzimidazole, 18 parts of allyl methacrylate.
5. the antifouling good weatherability tubing of WR and hydropower construction draining according to claim 1 it is characterised in that: described water conservancy Hydroelectric Project Construction draining antifouling good weatherability tubing preparation method step is as follows:
(1) by the Epocryl of described mass fraction, neoprene, methyl vinyl phenyl silicone rubber, mbs tree Fat, styrenated alkyd, polyacrylate emulsion, HMPA, acrylate and vinyl acetate emulsion, M Cr, carbolineum, lemon Lemon alkene, chitin, acetylspiramycin, vancomycin, portland cement, copper sulphate pentahydrate, dibasic lead phosphite, nano-titanium White lead, chromic acid lithium powder, magnesium sulfate, the hydrogeneous silicones of phenyl, Calcium rhodanate are mixed, ultrasonic high speed dispersion, ultrasonic wave frequency Rate is 20～40khz, rate of dispersion about 5000～5400r/min, and jitter time is 30～60min；
(2) HBB of the described mass fraction of addition, guanyl-urea-phosphate, trichloroethyl phosphate, diethyl ethylphosphate, sulfurous Sour sodium, ultrasonic high speed dispersion, ultrasonic frequency is 20～35khz, and rate of dispersion is about 4800～5200r/min, jitter time For 30～50min about；
(3) 2-mercaptobenzimidazole of the described mass fraction of addition, phenyl alkylsulf, ethoxylated trimethylolpropane 3 third Olefin(e) acid ester, benzimidazole, allyl methacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 20～30khz, rate of dispersion It is about 4600～4800r/min, jitter time is 20～40min；Primary mix is obtained after mix homogeneously；Again by primary Mixture is added in double screw extruder and carries out melting mixing, obtains desired mixt raw material；
(4) mixture material obtaining step (3) is extruded in an extruder, obtains finished product, wherein, extrusion condition is: barrel Temperature: 184 ± 2 DEG C, merging core temperature: 176 ± 2 DEG C, head temperature: 190 ± 5 DEG C, traction: 0.6～0.9m/min, main frame turns Speed: 25～30 revs/min.
CN201610750322.7A 2016-08-30 2016-08-30 Water conservancy and hydropower construction drainage and antifouling pipe material with good weather resistance Pending CN106349655A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117762A (en) * 2017-11-30 2018-06-05 广东国立科技股份有限公司 A kind of nanometer titanium dioxide antibiotic plastics and its production technology

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117762A (en) * 2017-11-30 2018-06-05 广东国立科技股份有限公司 A kind of nanometer titanium dioxide antibiotic plastics and its production technology

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