CN106349532A - Additive capable of maintaining durable elasticity of rubber under alkali condition - Google Patents

Additive capable of maintaining durable elasticity of rubber under alkali condition Download PDF

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Publication number
CN106349532A
CN106349532A CN201610729925.9A CN201610729925A CN106349532A CN 106349532 A CN106349532 A CN 106349532A CN 201610729925 A CN201610729925 A CN 201610729925A CN 106349532 A CN106349532 A CN 106349532A
Authority
CN
China
Prior art keywords
rubber
additive
parts
elasticity
basic conditions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610729925.9A
Other languages
Chinese (zh)
Inventor
蒋士富
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BENGBU ZHENGZHONG RUBBER PRODUCTS Co Ltd
Original Assignee
BENGBU ZHENGZHONG RUBBER PRODUCTS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BENGBU ZHENGZHONG RUBBER PRODUCTS Co Ltd filed Critical BENGBU ZHENGZHONG RUBBER PRODUCTS Co Ltd
Priority to CN201610729925.9A priority Critical patent/CN106349532A/en
Publication of CN106349532A publication Critical patent/CN106349532A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/26Cellulose ethers
    • C08L1/28Alkyl ethers
    • C08L1/286Alkyl ethers substituted with acid radicals, e.g. carboxymethyl cellulose [CMC]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides an additive capable of maintaining the durable elasticity of rubber under an alkali condition, relating to the field of rubber additives. The additive is prepared from the following raw materials in parts by weight through blending: 0.1 part of erbium oxide, 2.1 parts of sodium carboxymethylcellulose, 5.2 parts of mica powder and 1.3 parts of polyacrylate. By taking paroline oil as a carrier in use, the additive has relatively good dispersity; and the additive is added into the rubber raw materials in a certain proportion, and a rubber product is prepared by plastication, mixing and vulcanization and has durable elasticity under the alkali condition.

Description

Rubber can be kept to have the additive of persistently elasticity in the basic conditions
Technical field
The present invention relates to rubber additive field, more particularly, to one kind can keep rubber to have lasting bullet in the basic conditions The additive of property.
Background technology
Material is material base and the guide of social production and technological progress, the macromolecular material that eighties of last century grows up Industry bring huge material progress to human society, rubber as the important component part of macromolecular material, in tire system Make aspect and there is the irreplaceable specific function of other materials, become indispensable important thing in national economy and daily life Matter.With the development of modern science and technology, to aspects such as the elasticity of rubber for tire, abrasion resistance, alkali resistance, alkali resistance, aging resistance Require more and more higher, and traditional rubber additive is limited to its mechanical property raising, present technology can not meet this Plant and require, be badly in need of the new rubber additive of exploitation, improve the serviceability of rubber.
Content of the invention
It is an object of the invention to provide a kind of additive keeping rubber to have persistently elasticity in the basic conditions, with Solve above-mentioned technical problem.
The technical problem to be solved employs the following technical solutions to realize:
A kind of keep rubber have in the basic conditions persistently elasticity additive it is characterised in that: by following weight The raw material mixture of part forms:
0.1 part of Erbia, 2.1 parts of sodium carboxymethyl cellulose, 5.2 parts of mica powder, 1.3 parts of polyacrylate.
Preferably, also containing 0.23 part of nano aluminium oxide in raw material.
Preferably, the granularity of described mica powder is 2-15 micron.
Can keep rubber have in the basic conditions persistently elasticity Rubber modification method it is characterised in that:
Additive is added in paraffin oil, makes additive dispersed in paraffin oil, obtain property-modifying additive, additive Quality be paraffin oil quality 82.5%;
Property-modifying additive is added in rubber raw materials, the addition of additive is the 1.25% of rubber quality, is moulded Refining, mixing, sulfidization molding, obtain final product the rubber product can in the basic conditions with persistently elasticity.
The invention has the beneficial effects as follows:
The additive of the present invention, with paraffin oil as carrier during use, has preferable dispersibility, adds according to certain ratio Enter in rubber raw materials, through over-mastication, mixing, sulfidization molding, the rubber product obtaining, can have lasting bullet in the basic conditions Property,
Erbia, sodium carboxymethyl cellulose, mica powder, polyacrylate,
Mica powder and polyacrylate synergism, make rubber be very easy to polymerization, and it contributes to sending out in the basic conditions Wave the performance of sodium carboxymethyl cellulose and Erbia, mechanical property, ageing resistace and the alkali resistance of rubber can be improved, so that Rubber has lasting elasticity in the basic conditions.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention realizes are easy to understand, tie below Close specific embodiment, the present invention is expanded on further, but following embodiment is only the preferred embodiments of the present invention, and not all. Based on the embodiment in embodiment, those skilled in the art are obtained other real on the premise of not making creative work Apply example, broadly fall into protection scope of the present invention.
A kind of additive keeping rubber to have persistently elasticity in the basic conditions, by the raw material mixture of following weight portion Form:
0.1 part of Erbia, 2.1 parts of sodium carboxymethyl cellulose, 4.6 parts of mica powder (granularity 2-15 micron), polyacrylate 1.3 parts, 0.23 part of nano aluminium oxide,
Rubber can be kept to have the Rubber modification method of persistently elasticity in the basic conditions,
(1) additive is added in paraffin oil, make additive dispersed in paraffin oil, obtain property-modifying additive, add Plus the quality of agent is the 82.5% of paraffin oil quality;
(2) property-modifying additive is added in rubber raw materials, the addition of additive is the 1.25% of rubber quality, carries out Plasticate, knead, sulfidization molding, obtain final product can have in the basic conditions persistently elasticity rubber product.
According to national standard, performance test is carried out to the rubber product prepared, result is as shown in the table:
Ultimate principle, principal character and the advantages of the present invention of the present invention have been shown and described above.The technology of the industry The only present invention it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description for the personnel Preference, be not intended to limit the present invention, without departing from the spirit and scope of the present invention, the present invention also has various Changes and improvements, these changes and improvements both fall within scope of the claimed invention.Claimed scope is by institute Attached claims and its equivalent thereof.

Claims (3)

1. a kind of keep rubber have in the basic conditions persistently elasticity additive it is characterised in that: by following weight portion Raw material mixture form:
0.1 part of Erbia, 2.1 parts of sodium carboxymethyl cellulose, 5.2 parts of mica powder, 1.3 parts of polyacrylate.
2. the additive keeping rubber to have persistently elasticity in the basic conditions according to claim 1, its feature exists In: also contain 0.23 part of nano aluminium oxide in raw material.
3. the additive keeping rubber to have persistently elasticity in the basic conditions according to claim 1, its feature exists In: the granularity of described mica powder is 2-15 micron.
CN201610729925.9A 2016-08-25 2016-08-25 Additive capable of maintaining durable elasticity of rubber under alkali condition Pending CN106349532A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610729925.9A CN106349532A (en) 2016-08-25 2016-08-25 Additive capable of maintaining durable elasticity of rubber under alkali condition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610729925.9A CN106349532A (en) 2016-08-25 2016-08-25 Additive capable of maintaining durable elasticity of rubber under alkali condition

Publications (1)

Publication Number Publication Date
CN106349532A true CN106349532A (en) 2017-01-25

Family

ID=57854676

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610729925.9A Pending CN106349532A (en) 2016-08-25 2016-08-25 Additive capable of maintaining durable elasticity of rubber under alkali condition

Country Status (1)

Country Link
CN (1) CN106349532A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5233109A (en) * 1989-11-06 1993-08-03 National University Of Singapore Production of synthetic crude petroleum
CN101974181A (en) * 2010-11-17 2011-02-16 武汉工程大学 Method for preparing rare-earth oxide/rubber composite material for low-frequency sound absorption
CN104046407A (en) * 2014-04-24 2014-09-17 四川大学 Antiwear antifriction composite additive for lubricating oil (grease)

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5233109A (en) * 1989-11-06 1993-08-03 National University Of Singapore Production of synthetic crude petroleum
CN101974181A (en) * 2010-11-17 2011-02-16 武汉工程大学 Method for preparing rare-earth oxide/rubber composite material for low-frequency sound absorption
CN104046407A (en) * 2014-04-24 2014-09-17 四川大学 Antiwear antifriction composite additive for lubricating oil (grease)

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RJ01 Rejection of invention patent application after publication

Application publication date: 20170125

RJ01 Rejection of invention patent application after publication