CN106348469A - Efficient salt resistance scale inhibitor and application thereof - Google Patents

Efficient salt resistance scale inhibitor and application thereof Download PDF

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Publication number
CN106348469A
CN106348469A CN201610754872.6A CN201610754872A CN106348469A CN 106348469 A CN106348469 A CN 106348469A CN 201610754872 A CN201610754872 A CN 201610754872A CN 106348469 A CN106348469 A CN 106348469A
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China
Prior art keywords
parts
sodium
weight
salt resistance
water
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CN201610754872.6A
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Chinese (zh)
Inventor
王胜
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Shandong Sunway Garden Technology Co Ltd
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Shandong Sunway Garden Technology Co Ltd
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Priority to CN201610754872.6A priority Critical patent/CN106348469A/en
Publication of CN106348469A publication Critical patent/CN106348469A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/14Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
    • C02F5/145Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus combined with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/08Corrosion inhibition

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an efficient salt resistance scale inhibitor and an application thereof. The efficient salt resistance scale inhibitor is prepared from the raw materials: 20-30 parts by weight of biochar, 20-30 parts by weight of soda lime, 3-8 parts by weight of epoxy resin, 5-10 parts by weight of poly sodium metaphosphate, 4-7 parts by weight of amine resin, 10-15 parts by weight of acrylic acid, 6-11 parts by weight of sodium hydrogen sulfite, 10-20 parts by weight of sodium hydroxide solution, 10-15 parts by weight of phytic acid, 7-12 parts by weight of methanesulfonic acid, 10-12 parts by weight of sodium persulfate, 18-23 parts by weight of an antirust agent, 16-20 parts by weight of a preservative, 15-20 parts by weight of diethylene triamine penlaacetic acid, 12-16 parts by weight of acrylamide and 100-120 parts by weight of water. In the efficient salt resistance scale inhibitor and the application thereof, biochar and soda lime are added and mixed with water for salt resistance treatment of saline-alkali soil; sodium hydrogen sulfite and sodium persulfate are added so that the scale inhibitor can achieve the efficient scale removal effect; the antirust agent and the preservative are added so that water pipes cannot rusty spots and corrosion when spraying solution.

Description

A kind of efficient salt resistance antisludging agent and its application
Technical field
The present invention relates to technical field of chemistry and chemical engineering, specially a kind of efficient salt resistance antisludging agent and its application.
Background technology
Antisludging agent be have can slightly solubility inorganic salt in disperse water, inhibit or interfere with slightly solubility inorganic salt in metal surface Precipitation, fouling function, and maintain hardware to have a class medicament of good heat-transfer effect, it has excellent shielding, anti- Ooze, the performance such as rustless property, good scale inhibition, heat conductivity, excellent weak acid resistant, highly basic and organic solvent.
Salt-soda soil is a species of salt aggregation, refers to that contained salinity inside soil has influence on the normal life of crop Long, according to UNESCO and food and agricultural organization's incomplete statistics, the area in whole world salt-soda soil is 9.5438 hundred million hectares, Wherein China is 99,130,000 hectares, the formation of China's alkaline earth and alkali-affected soil, most of accumulative relevant with Carbonates In Soil, Thus basicity is generally higher, serious salt affected soil regional plant can hardly be survived.
The existing improvement for salt-soda soil is often to spray some specific solvents with water pipe, therefore often can lead to water pipe Inside have thick dirty layer, so that the treatment cost of the company of improvement increases, and because the replacing often of water pipe also can be led Cause the continuous extension of control, and then the production environment of people cannot be improved, affect the orthobiosiss of people.
Content of the invention
It is an object of the invention to provide a kind of efficient salt resistance antisludging agent and its application, to solve to carry in above-mentioned background technology The improvement corporate governance costs going out increase, and because the replacing often of water pipe also results in the continuous extension of control, enter And the production environment of people cannot be improved, affect the problem of the orthobiosiss of people.
For achieving the above object, the present invention provides a kind of following technical scheme: efficient salt resistance antisludging agent, including following weight The raw material of number proportioning: charcoal 20-30 part, soda lime 20-30 part, epoxy resin 3-8 part, many Polymeric sodium metaphosphate ies 5-10 part, ammonia Base resin 4-7 part, acrylic acid 10-15 part, sodium sulfite 6-11 part, sodium hydroxide solution 10-20, phytic acid 10-15, in methyl Sulfonic acid 7-12 part, sodium peroxydisulfate 10-12 part, antirust agent 18-23 part, preservative 16-20 part, diethylene triamine pentamethylene phosphonic 15-20, acrylamide 12-16 part and water 100-120 part.
Preferably, including the raw material of following parts by weight proportioning: 30 parts of charcoal, 30 parts of soda lime, 8 parts of epoxy resin, 10 parts of many Polymeric sodium metaphosphate., 7 parts of amino resins, 15 parts of acrylic acid, 11 parts of sodium sulfite, sodium hydroxide solution 20, phytic acid 15, first 12 parts of sulfonic acid, 12 parts of sodium peroxydisulfate, 23 parts of antirust agent, 20 parts of preservative, diethylene triamine pentamethylene phosphonic 20, acryloyl in base 16 parts of amine and 120 parts of water.
Preferably, including the raw material of following parts by weight proportioning: 20 parts of charcoal, 20 parts of soda lime, 3 parts of epoxy resin, 5 parts of many Polymeric sodium metaphosphate., 4 parts of amino resins, 10 parts of acrylic acid, 6 parts of sodium sulfite, sodium hydroxide solution 10, phytic acid 10, methyl 7 parts of interior sulfonic acid, 10 parts of sodium peroxydisulfate, 18 parts of antirust agent, 16 parts of preservative, diethylene triamine pentamethylene phosphonic 15, acrylamide 12 parts and 100 parts of water.
Preferably, including the raw material of following parts by weight proportioning: 25 parts of charcoal, 25 parts of soda lime, 6 parts of epoxy resin, 7 parts of many Polymeric sodium metaphosphate., 5 parts of amino resins, 12 parts of acrylic acid, 8 parts of sodium sulfite, sodium hydroxide solution 15, phytic acid 13, methyl 9 parts of interior sulfonic acid, 11 parts of sodium peroxydisulfate, 21 parts of antirust agent, 18 parts of preservative, diethylene triamine pentamethylene phosphonic 18, acrylamide 14 parts and 110 parts of water.
The invention solves the problems that another technical problem be that a kind of efficient salt resistance antisludging agent application is provided, comprise the following steps:
1) by sulfonic acid 7-12 part in acrylic acid 10-15 part, sodium sulfite 6-11 part, acrylamide 12-16 part, methyl and Many Polymeric sodium metaphosphate ies 5-10 part is directed in water 30-50 part, carries out one hour heat under 85 degrees Celsius of temperature environment Dissolving, and accompany by stirring at a slow speed, until being completely dissolved, standby;
2) antirust agent 18-23 part, preservative 16-20 part, charcoal 20-30 part and soda lime 20-30 part are directed into water In 70-80 part, then quickly stirred so that charcoal 20-30 part and soda lime 20-30 part can be fully immersed into water In 40-50 part, standby;
3) by diethylene triamine pentamethylene phosphonic 15-20, epoxy resin 3-8 part, phytic acid 10-15, sodium peroxydisulfate 10-12 Part, amino resins 4-7 part, sodium sulfite 6-11 part are directed into 1) in, then under 85 degree celsius temperature environment again The stirring carrying out, standby;
4) by step 2) it is directed into step 3) in, carry out cold charge after low rate mixing, finally obtain a kind of efficient salt resistance scale inhibition Agent.
The invention has the beneficial effects as follows: this efficient salt resistance antisludging agent and its application, it is added with charcoal and soda lime, permissible Allow charcoal and soda lime that salt-soda soil can be carried out after being mixed into water with salt-resistance improvement, add sodium sulfite and persulfuric acid Sodium, can allow antisludging agent can reach the effect of efficient de-sludging, add antirust agent and preservative, water pipe can be made in spray solution Obtaining water pipe is not in rust staining and the situation of corrosion.
Specific embodiment
The enforcement it is clear that described will be clearly and completely described to the technical scheme in the embodiment of the present invention below Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained under the premise of not making creative work, broadly falls into the model of present invention protection Enclose.
Embodiment one:
A kind of efficient salt resistance antisludging agent, including the raw material of following parts by weight proportioning: 30 parts of charcoal, 30 parts of soda lime, 8 parts of epoxy resin, 10 parts of many Polymeric sodium metaphosphate ies, 7 parts of amino resins, 15 parts of acrylic acid, 11 parts of sodium sulfite, sodium hydroxide solution 20th, phytic acid 15,12 parts of sulfonic acid, 12 parts of sodium peroxydisulfate, 23 parts of antirust agent, 20 parts of preservative, diethylenetriamine five methene in methyl Phosphonic acids 20,16 parts of acrylamide and 120 parts of water.
A kind of efficient salt resistance antisludging agent application, comprises the following steps:
1) by 12 parts of sulfonic acid and many Polymeric sodium metaphosphate ies in 15 parts of acrylic acid, 11 parts of sodium sulfite, 16 parts of acrylamide, methyl 10 parts are directed in 50 parts of water, carry out the dissolving of heating of a hour, and accompany by a slow speed under 85 degrees Celsius of temperature environment Stirring, until be completely dissolved, standby;
2) 23 parts of antirust agent, 20 parts of preservative, 30 parts of charcoal and 30 parts of soda lime are directed in 80 parts of water, Ran Houjin Quickly stirring is so that 30 parts of charcoal and 30 parts of soda lime can be fully immersed into 80 parts of water, standby for row;
3) by diethylene triamine pentamethylene phosphonic 20,8 parts of epoxy resin, phytic acid 15,12 parts of sodium peroxydisulfate, amino resins 7 Part, 11 parts of sodium sulfite are directed into 1) in, the stirring then carrying out again under 85 degree celsius temperature environment, standby;
4) by step 2) it is directed into step 3) in, carry out cold charge after low rate mixing, finally obtain a kind of efficient salt resistance scale inhibition Agent.
Embodiment two:
A kind of efficient salt resistance antisludging agent, including the raw material of following parts by weight proportioning: 20 parts of charcoal, 20 parts of soda lime, 3 parts of epoxy resin, 5 parts of many Polymeric sodium metaphosphate ies, 4 parts of amino resins, 10 parts of acrylic acid, 6 parts of sodium sulfite, sodium hydroxide solution 10th, phytic acid 10,7 parts of sulfonic acid, 10 parts of sodium peroxydisulfate, 18 parts of antirust agent, 16 parts of preservative, diethylenetriamine five methene phosphine in methyl Acid 15,12 parts of acrylamide and 100 parts of water.
A kind of efficient salt resistance antisludging agent application, comprises the following steps:
1) by 7 parts of sulfonic acid and many Polymeric sodium metaphosphate ies 5 in 10 parts of acrylic acid, 6 parts of sodium sulfite, 12 parts of acrylamide, methyl Part is directed in 30 parts of water, carries out the dissolving of heating of a hour, and accompany by a slow speed under 85 degrees Celsius of temperature environment Stirring, until being completely dissolved, standby;
2) 18 parts of antirust agent, 16 parts of preservative, 20 parts of charcoal and 20 parts of soda lime are directed in 70 parts of water, Ran Houjin Quickly stirring is so that 20 parts of charcoal and 20 parts of soda lime can be fully immersed into 70 parts of water, standby for row;
3) by diethylene triamine pentamethylene phosphonic 15,3 parts of epoxy resin, phytic acid 10,10 parts of sodium peroxydisulfate, amino resins 4 Part, 6 parts of sodium sulfite are directed into 1) in, the stirring then carrying out again under 85 degree celsius temperature environment, standby;
4) by 2) it is directed into 3) in, carry out cold charge after low rate mixing, finally obtain a kind of efficient salt resistance antisludging agent.
Embodiment three:
A kind of efficient salt resistance antisludging agent, including the raw material of following parts by weight proportioning: 25 parts of charcoal, 25 parts of soda lime, 6 parts of epoxy resin, 7 parts of many Polymeric sodium metaphosphate ies, 5 parts of amino resins, 12 parts of acrylic acid, 8 parts of sodium sulfite, sodium hydroxide solution 15th, phytic acid 13,9 parts of sulfonic acid, 11 parts of sodium peroxydisulfate, 21 parts of antirust agent, 18 parts of preservative, diethylenetriamine five methene phosphine in methyl Acid 18,14 parts of acrylamide and 110 parts of water.
A kind of efficient salt resistance antisludging agent application, comprises the following steps:
1) by 9 parts of sulfonic acid and many Polymeric sodium metaphosphate ies 7 in 12 parts of acrylic acid, 8 parts of sodium sulfite, 14 parts of acrylamide, methyl Part is directed in 40 parts of water, carries out the dissolving of heating of a hour, and accompany by a slow speed under 85 degrees Celsius of temperature environment Stirring, until being completely dissolved, standby;
2) 21 parts of antirust agent, 18 parts of preservative, 25 parts of charcoal and 25 parts of soda lime are directed in 75 parts of water, Ran Houjin Quickly stirring is so that 25 parts of charcoal and 25 parts of soda lime can be fully immersed into 75 parts of water, standby for row;
3) by diethylene triamine pentamethylene phosphonic 18,6 parts of epoxy resin, phytic acid 13,11 parts of sodium peroxydisulfate, amino resins 5 Part, 8 parts of sodium sulfite are directed into 1) in, the stirring then carrying out again under 85 degree celsius temperature environment, standby;
4) by 2) it is directed into 3) in, carry out cold charge after low rate mixing, finally obtain a kind of efficient salt resistance antisludging agent.
The invention has the beneficial effects as follows: this efficient salt resistance antisludging agent and its application, it is added with charcoal and soda lime, permissible Allow charcoal and soda lime that salt-soda soil can be carried out after being mixed into water with salt-resistance improvement, add sodium sulfite and persulfuric acid Sodium, can allow antisludging agent can reach the effect of efficient de-sludging, add antirust agent and preservative, water pipe can be made in spray solution Obtaining water pipe is not in rust staining and the situation of corrosion.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, permissible Understand and can carry out multiple changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention And modification, the scope of the present invention be defined by the appended.

Claims (5)

1. a kind of efficient salt resistance antisludging agent is it is characterised in that include the raw material of following parts by weight proportioning: charcoal 20-30 part, Soda lime 20-30 part, epoxy resin 3-8 part, many Polymeric sodium metaphosphate ies 5-10 part, amino resins 4-7 part, acrylic acid 10-15 part, sulfurous Sour hydrogen sodium 6-11 part, sodium hydroxide solution 10-20, phytic acid 10-15, sulfonic acid 7-12 part in methyl, sodium peroxydisulfate 10-12 part, anti- Rust agent 18-23 part, preservative 16-20 part, diethylene triamine pentamethylene phosphonic 15-20, acrylamide 12-16 part and water 100- 120 parts.
2. a kind of efficient salt resistance antisludging agent according to claim 1 is it is characterised in that include following parts by weight proportioning Raw material: 30 parts of charcoal, 30 parts of soda lime, 8 parts of epoxy resin, 10 parts of many Polymeric sodium metaphosphate ies, 7 parts of amino resins, 15 parts of acrylic acid, 12 parts of sulfonic acid in 11 parts of sodium sulfite, sodium hydroxide solution 20, phytic acid 15, methyl, 12 parts of sodium peroxydisulfate, 23 parts of antirust agent, 20 parts of preservative, diethylene triamine pentamethylene phosphonic 20,16 parts of acrylamide and 120 parts of water.
3. a kind of efficient salt resistance antisludging agent according to claim 1 is it is characterised in that include following parts by weight proportioning Raw material: 20 parts of charcoal, 20 parts of soda lime, 3 parts of epoxy resin, 5 parts of many Polymeric sodium metaphosphate ies, 4 parts of amino resins, 10 parts of acrylic acid, 7 parts of sulfonic acid in 6 parts of sodium sulfite, sodium hydroxide solution 10, phytic acid 10, methyl, 10 parts of sodium peroxydisulfate, 18 parts of antirust agent, anti- 16 parts of rotten agent, diethylene triamine pentamethylene phosphonic 15,12 parts of acrylamide and 100 parts of water.
4. a kind of efficient salt resistance antisludging agent according to claim 1 is it is characterised in that include following parts by weight proportioning Raw material: 25 parts of charcoal, 25 parts of soda lime, 6 parts of epoxy resin, 7 parts of many Polymeric sodium metaphosphate ies, 5 parts of amino resins, 12 parts of acrylic acid, 9 parts of sulfonic acid in 8 parts of sodium sulfite, sodium hydroxide solution 15, phytic acid 13, methyl, 11 parts of sodium peroxydisulfate, 21 parts of antirust agent, anti- 18 parts of rotten agent, diethylene triamine pentamethylene phosphonic 18,14 parts of acrylamide and 110 parts of water.
5. a kind of efficient salt resistance antisludging agent is applied it is characterised in that comprising the following steps:
1) by sulfonic acid 7-12 part in acrylic acid 10-15 part, sodium sulfite 6-11 part, acrylamide 12-16 part, methyl and how inclined Sodium phosphate 5-10 part is directed in water 30-50 part, carries out the dissolving of heating of a hour under 85 degrees Celsius of temperature environment, And accompany by stirring at a slow speed, until being completely dissolved, standby;
2) antirust agent 18-23 part, preservative 16-20 part, charcoal 20-30 part and soda lime 20-30 part are directed into water 70-80 In part, then quickly stirred so that charcoal 20-30 part and soda lime 20-30 part can be fully immersed into water 40-50 part In, standby;
3) by diethylene triamine pentamethylene phosphonic 15-20, epoxy resin 3-8 part, phytic acid 10-15, sodium peroxydisulfate 10-12 part, ammonia Base resin 4-7 part, sodium sulfite 6-11 part are directed into 1) in, then carry out again under 85 degree celsius temperature environment Stirring, standby;
4) by step 2) it is directed into step 3) in, carry out cold charge after low rate mixing, finally obtain a kind of efficient salt resistance antisludging agent.
CN201610754872.6A 2016-08-29 2016-08-29 Efficient salt resistance scale inhibitor and application thereof Withdrawn CN106348469A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115340874A (en) * 2022-08-29 2022-11-15 陕西科技大学 Saline-alkali soil treatment agent using waste resources and preparation method thereof

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CN101125715A (en) * 2007-08-16 2008-02-20 樊桂修 Composite corrosion-retarding antisludging agent for treating high-concentration multiple circulating water
CN101746902A (en) * 2008-12-03 2010-06-23 成都澳贝龙科技发展有限公司 Green compound corrosion and scale inhibitor
US20110017677A1 (en) * 2009-06-04 2011-01-27 Evans Thomas S Oil field water recycling system and method
CN104609579A (en) * 2013-11-01 2015-05-13 湖州欧美新材料有限公司 Multi-component corrosion and scale inhibitor
CN104230016A (en) * 2014-09-07 2014-12-24 无棣华信石油技术服务有限公司 Oilfield reinjection water scale inhibitor and preparation method thereof
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115340874A (en) * 2022-08-29 2022-11-15 陕西科技大学 Saline-alkali soil treatment agent using waste resources and preparation method thereof

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Application publication date: 20170125