CN106346919A - Negative-ion superelastic high-grade knitted denim fabric and preparation method thereof - Google Patents
Negative-ion superelastic high-grade knitted denim fabric and preparation method thereof Download PDFInfo
- Publication number
- CN106346919A CN106346919A CN201610935244.8A CN201610935244A CN106346919A CN 106346919 A CN106346919 A CN 106346919A CN 201610935244 A CN201610935244 A CN 201610935244A CN 106346919 A CN106346919 A CN 106346919A
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- Prior art keywords
- preparation
- treatment
- anion
- elasticity
- textle layers
- Prior art date
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- 239000004744 fabric Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title description 2
- 108090000790 Enzymes Proteins 0.000 claims abstract description 28
- 102000004190 Enzymes Human genes 0.000 claims abstract description 28
- 238000011282 treatment Methods 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 17
- 238000009940 knitting Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 229920000742 Cotton Polymers 0.000 claims abstract description 12
- 150000002500 ions Chemical class 0.000 claims abstract description 11
- -1 polypropylene Polymers 0.000 claims abstract description 10
- 239000004743 Polypropylene Substances 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 229920001155 polypropylene Polymers 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 7
- 238000004043 dyeing Methods 0.000 claims abstract description 4
- 150000001450 anions Chemical class 0.000 claims description 48
- 229940088598 enzyme Drugs 0.000 claims description 27
- 238000002203 pretreatment Methods 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 238000007789 sealing Methods 0.000 claims description 15
- 239000004902 Softening Agent Substances 0.000 claims description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- 239000011593 sulfur Substances 0.000 claims description 11
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 238000007493 shaping process Methods 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000004575 stone Substances 0.000 claims description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 7
- 238000007598 dipping method Methods 0.000 claims description 7
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920013822 aminosilicone Polymers 0.000 claims description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 108010059892 Cellulase Proteins 0.000 claims description 4
- 229940106157 cellulase Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920003225 polyurethane elastomer Polymers 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- 229960001484 edetic acid Drugs 0.000 claims description 2
- 238000004513 sizing Methods 0.000 claims 2
- 238000009941 weaving Methods 0.000 abstract description 5
- 239000004753 textile Substances 0.000 abstract description 3
- 229920002334 Spandex Polymers 0.000 abstract description 2
- 230000006870 function Effects 0.000 abstract description 2
- 239000004759 spandex Substances 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 230000035807 sensation Effects 0.000 abstract 1
- 239000002585 base Substances 0.000 description 5
- 239000000975 dye Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000009965 tatting Methods 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HVCNNTAUBZIYCG-UHFFFAOYSA-N ethyl 2-[4-[(6-chloro-1,3-benzothiazol-2-yl)oxy]phenoxy]propanoate Chemical compound C1=CC(OC(C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2S1 HVCNNTAUBZIYCG-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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- D06M13/332—Di- or polyamines
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a preparation method of a negative-ion superelastic high-grade knitted denim fabric. The method comprises the following steps: weaving: mutually looping and staggering 20-40S cotton yarn and 30-40D spandex stretch yarn to form a woven layer in a warp knitting or weft knitting mode, and forming an isolating layer from polypropylene fiber yarn or filament under the woven layer to obtain a base fabric; and sequentially carrying out pretreatment, dyeing, enzyme treatment, softening treatment, drying, stacking, setting, negative ion layer coating and drying for setting on the base fabric to obtain the negative-ion superelastic high-grade knitted denim fabric. The denim fabric has the advantages of soft tactile sensation in the thickness direction, high air permeability and high elasticity, and is comfortable, suitable and beautiful to wear. By adopting the specific textile processing and unique technique, the denim fabric has the function of generating negative ions and has the advantages of favorable all-around elasticity and the like.
Description
Technical field
The invention belongs to knitting fabric technical field, the high-grade knitted jean of more particularly, to a kind of anion super-elasticity and
Its preparation method.
Background technology
Jean stems from the U.S. of 1850, even to this day the favorite of always fashion, deep is subject to consuming public blue or green
The sportswear fabric looked at.Jean is star never withered throughout the year, is listed in " first of Joker clothing ".Mesh
The front fabric with cowboy and pattern get more and more, and the development of cowboy's style more has a diversification, fashion, the sending out of Leisure orchards
Exhibition trend.Substantial amounts of accessories five metals, leather, the manufacturing process such as knitting, painting cloth splicing quickly develops in China and uses.
But it is all that based on tatting jean, tatting jean elasticity is poor, fabric hardboard for a long time on market,
Even if multiple plus bullet jean occurs also being difficult to meet comfortable, soft, the well-pressed demand of consumer.This allows for having super
The exploitation of the relatively good high-grade knitted jean of elasticity, soft comfortable, regression color fastness is extremely urgent, gives cowboy face simultaneously
Material anion function, meets opportunity and health, the consumption concept of environmental protection of era development, has very big market prospect.
The present invention is directed to anion Fresh fats and the new fabric of knitted jean in prior art and is spinning, weaves, dyes, arranging
During, need the technical barrier solving and key problem in technology to provide specific technical scheme, and provide anion super-elasticity high-grade
The preparation method of knitting jeans fabric.Thus providing technically for textile industry popularization and application anion Fresh fats material further
Support, for consuming public provide have health care anion super-elasticity soft comfortable high-grade knitted jean facing
Material.
Content of the invention
The present invention is to solve the problems referred to above of the prior art, proposes a kind of high-grade knitted jean of anion super-elasticity
And preparation method thereof.
For current cowboy's functional fabric soft comfortable, there is the demand of four-side elastic, there is provided a kind of anion surpasses
The high-grade knitted jean of elasticity, by rational fabric texture, the weaving of science and dyeing and finishing processing method, makes fabric have
There is the continuous function of releasing anion substance, and increase while having given full play to functional treatment technology with reference to elastic fiber
Comfortable elasticity, makes the range of application of fabric more wide.
For achieving the above object, the present invention employs the following technical solutions:
The first aspect of the invention is the preparation method providing a kind of high-grade knitted jean of anion super-elasticity, bag
Include following steps:
(1) weave: the smart sulfur cotton yarn being propped up from 20~40 English and the polyurethane elastic filament of 30~40d are the mutual lasso of raw material
Staggered, form textle layers in the way of warp knit or weft knitting, and under textle layers, sealing coat is constituted by polypropylene fiber yarn or long filament, system
Obtain base fabric;
(2) base fabric is carried out successively pre-treatment, dyeing, ferment treatment, soft treatment, dry, bank up, shaping, coat bear from
Sublayer, drying and shaping, obtain final product the high-grade knitted jean of anion super-elasticity.
Further, described pre-treatment adopts 1~2%cleantech370 and 5~12%h2o2Carry out pre-treatment, containing alkali
Measure as 0.4~0.5%;Temperature is 70~80 DEG C, and the pre-treatment time is 40min.
Further, by weight percentage, the enzyme adopting described in described enzyme treatment process is by 40~50% celluloses
Enzyme, 20~30% transmethylases, 5~15% enzyme activity agent and 15~25% ethanol are formulated.
Further, described ferment treatment temperature is 55~60 DEG C, and enzyme processing time is 60min, the addition of enzyme is 2~
4%;Described enzyme activity agent is Ethylenedinitrilotetraacetic Acid.
Further, by weight percentage, the softening agent employed in described soft treatment technique is by 5~10% poly- ammonia
Ester elastomer, 10~15% myristamide propyl group hydroxypropyl sulfobetaines, 3~8% Tissuemat Es, 5~10 poly alkyl alcohols
Oxygen vinyl Ether, 20~30% polyether modified amino silicone, 5~15% dispersion emulsifiers, remaining is formulated for water.
Further, described soft treatment using dry after pad, 140~150 DEG C of drying and shaping or adopt 40~60
DEG C, 30min dipping, dewatered drying shape;Described using padding, the addition of softening agent is 5~10g/l;Using dipping, soft
The addition of agent is 5%.
Further, described coating anion layer technique is: coating anion layer is on textle layers and through weaving
Layer penetrates on sealing coat.
Further, described anion layer is configured to auxiliary agent by negative ion powder and forms, and described negative ion powder is strange ice
Stone, QICAISHI and silicate and Barium monoxide.
Preferably, by mass percentage, described negative ion powder by rare ice stone 30~40%, QICAISHI 20~30%,
Silicate 20~30% and 10~20% Barium monoxides are formulated, and wherein, described rare ice stone particle diameter is 50-200nm, described rare talent
Stone particle diameter is 60-100nm;Described silicate is preferably nanoscale and dodges keratite.
The second aspect of the invention is to provide a kind of high-grade knitted cattle of anion super-elasticity of employing said method preparation
Young fabric.
Further, the high-grade knitted jean of described anion super-elasticity include by smart sulfur cotton yarn and polyurethane elastic filament with
The textle layers that the mode of warp knit or weft knitting is formed, described textle layers have polypropylene sealing coat, described anion layer is arranged at
Penetrate on sealing coat on textle layers and through textle layers.
The present invention adopts technique scheme, compared with prior art, has the following technical effect that
Textle layers in the high-grade knitted jean of anion super-elasticity of the present invention are by upper and lower two lower warp yarn position phases
The composition that mutually staggers twill structure, enhances the elasticity in fabric extension direction, due to passing through between warp knit structure wale to extend
Line connects, and Weft-knitted Structure belongs to fall arc and connects, and when being stretched by lateral external forces, warp knit structure elasticity is less, and Weft-knitted Structure
Sinker loop length release elasticity, therefore the dimensional stability of warp-knitted face fabric is better than weft-knitted product, and the four-side elastic of weft-knitted product is excellent
In warp knit product;And this jean thickness direction texture softness, breathability are strong, elasticity is big, comfortable and easy to wear, fit attractive in appearance;Adopt
With specific textile process and unique technique, have the advantages that generating negative ions function and four-side elastic are good.
Brief description
Fig. 1 is a kind of structural representation of the high-grade knitted jean of present invention anion super-elasticity;
Fig. 2 is the Weft-knitted Structure schematic diagram of textle layers in a kind of high-grade knitted jean of present invention anion super-elasticity.
Specific embodiment
As shown in figure 1, the invention provides a kind of high-grade knitted jean of anion super-elasticity, including by smart sulfur cotton yarn
The textle layers 1 being formed in the way of warp knit or weft knitting with polyurethane elastic filament, textle layers 1 have polypropylene fiber yarn or long filament every
Absciss layer 2, anion layer 3 is arranged on textle layers 1 and penetrates on sealing coat 2 through textle layers 1.
As shown in Fig. 2 described textle layers 1 include smart sulfur cotton yarn 4 and polyurethane elastic filament 5, and by delayed plaiting lopping
Mode interpolates polyurethane elastic filament 5 weaving below in smart sulfur cotton yarn 4 and forms.Specifically, every 3-4 circle essence sulfur cotton yarn adds 1 circle spandex bullet
Power silk 5 lopping weaving forms, and serves as a contrast an anion wire gauze 6 in each two row along row direction.
Preferably, described anion wire gauze 6 is using the polyester deformation long filament modified through anion;It is preferably 75d-200d's
Hollow polyester filament.
Below by specific embodiment, the present invention is described in more detail, for a better understanding of the present invention,
But following embodiments are not intended to limit the scope of the invention.
The preparation method of the high-grade knitted jean of embodiment 1 anion super-elasticity, comprises the following steps:
(1) weave: the smart sulfur cotton yarn being propped up from 40 English or the polyurethane elastic filament of strand and 40d are that the mutual lasso of raw material is handed over
Mistake, forms textle layers in the way of warp knit or weft knitting, and constitutes sealing coat by polypropylene fiber yarn or long filament under textle layers, is obtained
Base fabric;
(2) pre-treatment: using 2%cleantech370 and 12%h2o2Carry out pre-treatment, alkalinity is 0.4%;Temperature is
70 DEG C, the pre-treatment time is 40min;
(3) dye;
(4) ferment treatment: the enzyme of employing is prepared by 40% cellulase, 30 transmethylases, 5% enzyme activity agent and 25% ethanol
Form;Described ferment treatment temperature is 55 DEG C, and enzyme processing time is 60min, and the addition of enzyme is 4%;Described enzyme activity agent is second two
Amine triethylammonium tetrakis;
(5) soft treatment: the softening agent being adopted is by 10% polyurethane elastomer, 10% myristamide propyl group hydroxypropyl
Sulfobetaines, 3% Tissuemat E, 5 fatty alcohol-polyoxyethylene ether, 20% polyether modified amino silicone, 15% dispersion emulsifier,
Remaining is formulated for water;Soft treatment using dry after pad, 150 DEG C of drying and shaping or using 60 DEG C, 30min impregnate,
Dewatered drying is shaped;Described using padding, the addition of softening agent is 5g/l;Using dipping, the addition of softening agent is 5%;
(6) dry, shape;
(7) coat anion layer: coating anion layer on textle layers and through textle layers penetrate into sealing coat it
On;Negative ion powder is formulated by rare ice stone 30%, QICAISHI 30%, silicate 20% and 20% Barium monoxide;
(8) drying and shaping, obtains final product the high-grade knitted jean of anion super-elasticity.
The preparation method of the high-grade knitted jean of embodiment 2 anion super-elasticity, comprises the following steps:
(1) weave: the smart sulfur cotton yarn being propped up from 30 English or the polyurethane elastic filament of strand and 30d are that the mutual lasso of raw material is handed over
Mistake, forms textle layers in the way of warp knit or weft knitting, and constitutes sealing coat by polypropylene fiber yarn or long filament under textle layers, is obtained
Base fabric;
(2) pre-treatment: using 2%cleantech370 and 10%h2o2Carry out pre-treatment, alkalinity is 0.4%;Temperature is
80 DEG C, the pre-treatment time is 40min;
(3) dye;
(4) ferment treatment: the enzyme of employing is joined by 50% cellulase, 20 transmethylases, 10% enzyme activity agent and 20% ethanol
System forms;Described ferment treatment temperature is 60 DEG C, and enzyme processing time is 60min, and the addition of enzyme is 4%;Described enzyme activity agent is second
Diamidogen triethylammonium tetrakis;
(5) soft treatment: the softening agent being adopted is by 5% polyurethane elastomer, 15% myristamide propyl group hydroxypropyl
Sulfobetaines, 8% Tissuemat E, 10 fatty alcohol-polyoxyethylene ether, 30% polyether modified amino silicone, 10% dispersion and emulsion
Agent, remaining is formulated for water;Soft treatment using dry after pad, 150 DEG C of drying and shaping or using 60 DEG C, 30min leaching
Stain, dewatered drying is shaped;Described using padding, the addition of softening agent is 10g/l;Using dipping, the addition of softening agent is
5%;
(6) dry, shape;
(7) coat anion layer: coating anion layer on textle layers and through textle layers penetrate into sealing coat it
On;Described negative ion powder is formulated by rare ice stone 40%, QICAISHI 20%, silicate 20% and 20% Barium monoxide;
(8) drying and shaping, obtains final product the high-grade knitted jean of anion super-elasticity.
The preparation method of the high-grade knitted jean of embodiment 3 anion super-elasticity, comprises the following steps:
(1) weave: the smart sulfur cotton yarn being propped up from 20 English or the polyurethane elastic filament of strand and 30d are that the mutual lasso of raw material is handed over
Mistake, forms textle layers in the way of warp knit or weft knitting, and constitutes sealing coat by polypropylene fiber yarn or long filament under textle layers, is obtained
Base fabric;
(2) pre-treatment: using 2%cleantech370 and 5%h2o2Carry out pre-treatment, alkalinity is 0.5%;Temperature is
80 DEG C, the pre-treatment time is 40min;
(3) dye;
(4) ferment treatment: the enzyme of employing is prepared by 50% cellulase, 25 transmethylases, 5% enzyme activity agent and 20% ethanol
Form;Described ferment treatment temperature is 55 DEG C, and enzyme processing time is 60min, and the addition of enzyme is 4%;Described enzyme activity agent is second two
Amine triethylammonium tetrakis;
(5) soft treatment: the softening agent being adopted is by 10% polyurethane elastomer, 15% myristamide propyl group hydroxypropyl
Sulfobetaines, 6% Tissuemat E, 10 fatty alcohol-polyoxyethylene ether, 25% polyether modified amino silicone, 10% dispersion and emulsion
Agent, remaining is formulated for water;Soft treatment using dry after pad, 145 DEG C of drying and shaping or using 50 DEG C, 30min leaching
Stain, dewatered drying is shaped;Described using padding, the addition of softening agent is 8g/l;Using dipping, the addition of softening agent is
5%;
(6) dry, shape;
(7) coat anion layer: coating anion layer on textle layers and through textle layers penetrate into sealing coat it
On;This negative ion powder is formulated by rare ice stone 35%, QICAISHI 25%, silicate 25% and 15% Barium monoxide;
(8) drying and shaping, obtains final product the high-grade knitted jean of anion super-elasticity.
The high-grade knitted jean of anion super-elasticity that embodiment of the present invention 1-3 is obtained, its indices reaches: shrinks
Rate: directly to -1.5% horizontal -2.4%, 4 grades of fastness to light, wash resistant color fastness 4-5 level, fastness to perspiration 4-5 level, imitative cowboy
Dry fastness 3-4 level, fastness to wet rubbing 2-3 level, 4 grades of washing fastness, content of formaldehyde :≤50mg/kg, 4 grades of anti pilling;
Tensile elasticity and recovery characteristic, directly to stretching 95.8% cross directional stretch 100.5%, directly laterally replys to reply 95.5% after 1 hour
100.3%;1500/cm of anion3.
Above the specific embodiment of the present invention is described in detail, but it has been intended only as example, the present invention has not limited
It is formed on particular embodiments described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and
Substitute also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Modification, all should cover within the scope of the invention.
Claims (10)
1. a kind of preparation method of the high-grade knitted jean of anion super-elasticity is it is characterised in that comprise the following steps:
(1) weave: the smart sulfur cotton yarn being propped up from 20~40 English and the polyurethane elastic filament of 30~40d are that the mutual lasso of raw material is handed over
Mistake, forms textle layers in the way of warp knit or weft knitting, and constitutes sealing coat by polypropylene fiber yarn or long filament under textle layers, is obtained
Base fabric;
(2) base fabric is carried out successively pre-treatment, dyeing, ferment treatment, soft treatment, drying, sizing, coating anion layer, dry
Sizing, obtains final product the high-grade knitted jean of anion super-elasticity.
2. preparation method according to claim 1 is it is characterised in that described pre-treatment adopts 1~2%cleantech370
With 5~12%h2o2Carry out pre-treatment, alkalinity is 0.4~0.5%;Temperature is 70~80 DEG C, and the pre-treatment time is 40min.
3. preparation method according to claim 1 it is characterised in that by weight percentage, in described enzyme treatment process
The enzyme of described employing is joined by 40~50% cellulase, 20~30 transmethylases, 5~15% enzyme activity agent and 15~25% ethanol
System forms.
4. preparation method according to claim 3 it is characterised in that described ferment treatment temperature be 55~60 DEG C, ferment treatment
Time is 60min, and the addition of enzyme is 2~4%;Described enzyme activity agent is Ethylenedinitrilotetraacetic Acid.
5. preparation method according to claim 1 it is characterised in that by weight percentage, described soft treatment technique
Employed in softening agent by 5~10% polyurethane elastomers, 10~15% myristamide propyl group hydroxypropyl sulfobetaines,
3~8% Tissuemat Es, 5~10 fatty alcohol-polyoxyethylene ether, 20~30% polyether modified amino silicone, 5~15% dispersion and emulsions
Agent, remaining is formulated for water.
6. preparation method according to claim 5 it is characterised in that described soft treatment using dry after pad, 140~
150 DEG C of drying and shaping or using 40~60 DEG C, 30min dipping, dewatered drying shape;Described using padding, softening agent plus
Entering amount is 5~10g/l;Using dipping, the addition of softening agent is 5%.
7. preparation method according to claim 1 is it is characterised in that described coating anion layer technique is: coating bear from
Sublayer penetrates on sealing coat on textle layers and through textle layers.
8. preparation method according to claim 1 is it is characterised in that described anion layer is configured to help by negative ion powder
Agent forms, and described negative ion powder is rare ice stone, QICAISHI and silicate and Barium monoxide.
9. as the high-grade knitted jean of anion super-elasticity of claim 1-8 any one methods described preparation.
10. the high-grade knitted jean of anion super-elasticity according to claim 9 is it is characterised in that include by smart sulfur
The textle layers that cotton yarn and polyurethane elastic filament are formed in the way of warp knit or weft knitting, described textle layers have polypropylene sealing coat,
Anion layer is arranged on textle layers and penetrates on sealing coat through textle layers.
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CN106827709A (en) * | 2017-03-23 | 2017-06-13 | 上海题桥纺织染纱有限公司 | Three-dimensional wrinkle flower skin texture warming knitted composite fabric of embossment of a kind of high convergency and preparation method thereof |
CN107419559A (en) * | 2017-04-18 | 2017-12-01 | 广州锦兴纺织漂染有限公司 | A kind of new soft guarantor's type knitting jeans fabric production technology |
CN108396447A (en) * | 2018-05-14 | 2018-08-14 | 东华大学 | A kind of high machine one-side weft-knitted fabric |
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CN106827709A (en) * | 2017-03-23 | 2017-06-13 | 上海题桥纺织染纱有限公司 | Three-dimensional wrinkle flower skin texture warming knitted composite fabric of embossment of a kind of high convergency and preparation method thereof |
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CN108396447A (en) * | 2018-05-14 | 2018-08-14 | 东华大学 | A kind of high machine one-side weft-knitted fabric |
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