CN106336956A - Toilet cleaner and preparation method thereof - Google Patents
Toilet cleaner and preparation method thereof Download PDFInfo
- Publication number
- CN106336956A CN106336956A CN201610708158.3A CN201610708158A CN106336956A CN 106336956 A CN106336956 A CN 106336956A CN 201610708158 A CN201610708158 A CN 201610708158A CN 106336956 A CN106336956 A CN 106336956A
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- aeo
- carbon
- nonionic surfactant
- acid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the field of cleaners. A toilet cleaner is disclosed. The cleaner is composed of a water soluble membrane and a cleaning foil therein. The cleaning foil is prepared from the following ingredients (by weight): soda ash, tartrate, citric acid, sodium dichloroisocyanurate, anhydrous sodium sulphate, a low-foam nonionic surfactant and essence. The toilet cleaner has advantages as follows: storage space is small; the cleaner is convenient to take and use, will not pollute or corrode hands, has strong capability of removing urine stains, protects and brightens ceramic, and especially has good bactericidal performance.
Description
Technical field
The present invention relates to cleaning agent field, more particularly to a kind of Closestool cleanser and preparation method thereof.
Background technology
Traditional Closestool cleanser mostly is liquid, such as Chinese invention patent application (application number
Cn201310479781.2cn201510437124.0 applying date 2013.10.15) disclose a kind of Closestool cleanser, including such as
The composition of lower weight content: acetic acid 20-30 part, hypochlorous acid 1-2 part, surfactant 2-3 part, bleaching powder 5-15 part, essence
1-3 part, adds 100-150 part water, gets product.The deficiency that such liquid Closestool cleanser exists is that volume is big, cost of transportation
High.Also the Closestool cleanser having solid sheet on market is sold, and its deficiency needs hand-held plate detergent when being and using, and easily makes
Become hand skin pollution or corrode.
Content of the invention
First purpose of the present invention is to provide one kind to deposit to take up room little, takes conveniently, will not opponent pollute
Or corrosion, and the good Closestool cleanser of bactericidal effect.Second object of the present invention is to provide the preparation of above-mentioned bucket cleaning agent
Method.
In order to realize above-mentioned first purpose, present invention employs following technical scheme:
A kind of Closestool cleanser, this cleaning agent is made up of water soluble film and its interior cleansing tablet, and cleansing tablet is by mass percentage
Meter is prepared by following component:
Soda ash 10-20%
Tartaric acid 3-10%
Citric acid 6-15%
Sodium dichloro cyanurate 45-60%
Glauber salt 10-25%
Low bubble nonionic surfactant 2-15%
Essence 0.1-0.8%.
Preferably, low bubble nonionic surfactant include the APEO of alkyl phenol, AEO,
One or more of fatty acid methyl ester APEO and detergent 6501；Preferably, AEO selects bay
Alcohol APEO, 12-14 carbon primary alconol APEO, 12-14 carbon secondary alcohol APEO, collateralization 13 carbon Guerbet alcohols
APEO, collateralization 10 carbon Guerbet alcohol APEOs, 10 carbon alcohol APEOs of straight chain, straight chain 8 carbon pungent
One or more of alcohol APEO, 8 carbon isooctanol polyethoxylate of straight chain.
Preferably, aeo-7:aeo-9=1.7:1-2.3:1 or aeo-9:aeo-3 in low bubble nonionic surfactant
=1:1.2 1:2；The dirt-removing power that above-mentioned formulation actives bring is the strongest.
In order to realize above-mentioned second purpose, present invention employs following technical scheme:
A kind of method preparing the Closestool cleanser described in any one technical scheme above-mentioned, the method includes following step
Rapid:
1) soda ash, tartaric acid, citric acid, sodium dichloro cyanurate, glauber salt, low bubble nonionic surfactant and perfume (or spice) are pressed
Essence order feeds intake successively, stirs, tabletted；2) carry out water soluble film packaging.
Preferably, the optional material polyvinyl alcohol of described water soluble film, polyvinyl acetal, polyvinylpyrrolidone,
Polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthans, guar gum, hydroxypropyl methyl cellulose, and with
One or more of the homopolymerization of upper composition, copolymer and altered contents mix.Aeo-7 in low bubble nonionic surfactant:
Aeo-9=1.8:1.
The present invention, due to employing above-mentioned technical scheme, is compared with liquid Closestool cleanser, this Closestool cleanser excellent
Point is to deposit to take up room little, takes conveniently, cleansing tablet is coated by water soluble film, opponent will not pollute or corrode.Cleaning
Rationally, gross activity thing content is high for slice prescription, has very strong removal ability to urine stain, protection, light pottery, especially to golden yellow
The killing effect of staphylococcus, Escherichia coli and Candida albicans can exceed 99.9%.
Specific embodiment
Embodiment 1
A kind of Closestool cleanser, is made up of water soluble film and its interior cleansing tablet, cleansing tablet is by mass percentage by following
Component prepare: soda ash 15%, tartaric acid 5%, citric acid 8%, sodium dichloro cyanurate 50%, glauber salt 15%, low
Bubble nonionic surfactant 6.5% and essence 0.5%.
Above-mentioned soda ash and tartaric effect are cleaning, disintegration, citric acid effect be cleaning, disintegration, soft water, dichloro
The effect of sodium isocyanurate is disinfection, and the effect of glauber salt is figuration, and the effect of low bubble nonionic surfactant is
Dirt, the effect of essence is to eliminate the unusual smell.Aeo-7:aeo-9=1.8:1 in low bubble nonionic surfactant.
The preparation method of above-mentioned Closestool cleanser, the method comprises the following steps:
1) by soda ash, tartaric acid, citric acid, sodium dichloro cyanurate, glauber salt, low bubble nonionic surfactant with remove
Peculiar smell essence order feeds intake successively, stirs, tabletted；2) carry out water soluble film packaging.Water soluble film can material selection polyethylene
Alcohol, polyvinyl acetal, polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan
Glue, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can be
Above single component or the mixing of Multiple components.
Quantitative package of the present invention, easy to use, cleansing tablet will not be made to be stained with to hand.During use, take product a piece of, put into horse
In bucket, after half an hour, available brush gets wet inside cleaning toilet.
The Closestool cleanser test and evaluation report of embodiment 1 is as follows.
Sample: the Closestool cleanser of a. embodiment 1；
B. commercially available toilet cleaner.
Embodiment 2
A kind of Closestool cleanser, is made up of water soluble film and its interior cleansing tablet, cleansing tablet is by mass percentage by following
Component prepare: soda ash 12%, tartaric acid 4%, citric acid 8%, sodium dichloro cyanurate 53%, glauber salt 13%, low
Bubble nonionic surfactant 9.5% and essence 0.5%.Aeo-9:aeo-3=1:1.3 in low bubble nonionic surfactant.
Above-mentioned soda ash and tartaric effect are cleaning, disintegration, citric acid effect be cleaning, disintegration, soft water, dichloro
The effect of sodium isocyanurate is disinfection, and the effect of glauber salt is figuration, and the effect of low bubble nonionic surfactant is
Dirt, the effect of essence is to eliminate the unusual smell.
The preparation method of above-mentioned Closestool cleanser is same as Example 1.
Embodiment 3
A kind of Closestool cleanser, is made up of water soluble film and its interior cleansing tablet, cleansing tablet is by mass percentage by following
Component prepare: soda ash 10%, tartaric acid 6%, citric acid 10%, sodium dichloro cyanurate 48%, glauber salt 11%, low
Bubble nonionic surfactant 14.5% and essence 0.5%.Aeo-9:aeo-3=1:1.4 in low bubble nonionic surfactant.
Above-mentioned soda ash and tartaric effect are cleaning, disintegration, citric acid effect be cleaning, disintegration, soft water, dichloro
The effect of sodium isocyanurate is disinfection, and the effect of glauber salt is figuration, and the effect of low bubble nonionic surfactant is
Dirt, the effect of essence is to eliminate the unusual smell.
The preparation method of above-mentioned Closestool cleanser is same as Example 1.
Claims (5)
1. it is characterised in that this cleaning agent is made up of water soluble film and its interior cleansing tablet, cleansing tablet presses matter to a kind of Closestool cleanser
Amount percentages are prepared by following component:
Soda ash 10-20%
Tartaric acid 3-10%
Citric acid 6-15%
Sodium dichloro cyanurate 45-60%
Glauber salt 10-25%
Low bubble nonionic surfactant 2-15%
Essence 0.1-0.8%.
2. a kind of Closestool cleanser according to claim 1, low bubble nonionic surfactant includes the polyoxy of alkyl phenol
One or more of vinethene, AEO, fatty acid methyl ester APEO and detergent 6501；Preferably,
AEO selects ethoxylated dodecyl alcohol, 12-14 carbon primary alconol APEO, 12-14 carbon secondary alcohol polyoxy second
Alkene ether, collateralization 13 carbon Guerbet alcohol APEOs, collateralization 10 carbon Guerbet alcohol APEOs, 10 carbon of straight chain
One or more of alcohol APEO, 8 carbon octanol APEOs of straight chain, 8 carbon isooctanol polyethoxylate of straight chain.
3. a kind of Closestool cleanser according to claim 1 is it is characterised in that aeo- in low bubble nonionic surfactant
7:aeo-9=1.7:1-2.3:1 or aeo-9:aeo-3=1:1.2 1:2；Described nonionic surfactant: dodecyl
Benzene sulfonic acid=2:8-3:7.
4. a kind of method preparing the Closestool cleanser described in claim 1-3 any one claim is it is characterised in that be somebody's turn to do
Method comprises the following steps: 1) by soda ash, tartaric acid, citric acid, sodium dichloro cyanurate, glauber salt, low bubble nonionic table
Face activating agent and essence order feed intake successively, stir, tabletted；2) carry out water soluble film packaging.
5. the preparation method of Closestool cleanser according to claim 4 is it is characterised in that water soluble film can material selection polyethylene
Alcohol, polyvinyl acetal, polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan
Glue, guar gum, hydroxypropyl methyl cellulose, and one or more of the homopolymerization of above composition, copolymer and altered contents
Mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610708158.3A CN106336956A (en) | 2016-08-23 | 2016-08-23 | Toilet cleaner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610708158.3A CN106336956A (en) | 2016-08-23 | 2016-08-23 | Toilet cleaner and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106336956A true CN106336956A (en) | 2017-01-18 |
Family
ID=57825103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610708158.3A Pending CN106336956A (en) | 2016-08-23 | 2016-08-23 | Toilet cleaner and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106336956A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096812A (en) * | 1993-06-19 | 1994-12-28 | 靳松 | Detergent for toilet |
| CN1608123A (en) * | 2001-12-20 | 2005-04-20 | 雷克特本克斯尔有限公司 | Water soluble container containing dry actives |
| CN103068959A (en) * | 2010-08-06 | 2013-04-24 | 雷利维股份公司 | A sanitary agent covered by a film |
| CN104450342A (en) * | 2014-11-10 | 2015-03-25 | 王海林 | Slow-release foaming agent for sanitary appliances |
| CN104903434A (en) * | 2013-01-07 | 2015-09-09 | 宝洁公司 | A process for recycling multicompartment unit dose articles |
-
2016
- 2016-08-23 CN CN201610708158.3A patent/CN106336956A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096812A (en) * | 1993-06-19 | 1994-12-28 | 靳松 | Detergent for toilet |
| CN1608123A (en) * | 2001-12-20 | 2005-04-20 | 雷克特本克斯尔有限公司 | Water soluble container containing dry actives |
| CN103068959A (en) * | 2010-08-06 | 2013-04-24 | 雷利维股份公司 | A sanitary agent covered by a film |
| CN104903434A (en) * | 2013-01-07 | 2015-09-09 | 宝洁公司 | A process for recycling multicompartment unit dose articles |
| CN104450342A (en) * | 2014-11-10 | 2015-03-25 | 王海林 | Slow-release foaming agent for sanitary appliances |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170118 |
|
| RJ01 | Rejection of invention patent application after publication |