CN106319492A - Preparation method of surface complexation film coated FeCuNbSiB strip - Google Patents
Preparation method of surface complexation film coated FeCuNbSiB strip Download PDFInfo
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- CN106319492A CN106319492A CN201610945529.XA CN201610945529A CN106319492A CN 106319492 A CN106319492 A CN 106319492A CN 201610945529 A CN201610945529 A CN 201610945529A CN 106319492 A CN106319492 A CN 106319492A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0611—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by a single casting wheel, e.g. for casting amorphous metal strips or wires
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Abstract
The invention relates to a preparation method of a surface complexation film coated FeCuNbSiB strip, and belongs to the technical field of preparation of iron-based amorphous strips. The preparation method comprises the steps that walnut green seedcases are extracted; a tannin concentrated solution is collected and then subjected to esterification modification; a stable chelate can be formed by two adjacent phenolic hydroxyl groups in tannin and metal; and after a metal strip is exposed in air for a long time, tannin esterification matter is closely adsorbed to the surface of the strip by means of the water and oxidation corrosion function in air. The prepared surface complexation film coated FeCuNbSiB strip is high in durability; after the strip is placed at the room temperature for 6-8 months, epoxy resin wettability has no change; the combination degree of the strip and epoxy resin is high, and the service life is prolonged by 15%-20% relative to products of the same kind after combination with the epoxy resin; and the walnut green seedcases are used for preparation, and therefore the strip is green, safe and free of environment pollution.
Description
Technical field
The present invention relates to the preparation method of a kind of surface complexation overlay film FeCuNbSiB band, belong to Fe-based amorphous band system
Standby technical field.
Background technology
Compared with conventional soft magnetic materials MnZn ferrite, permalloy, Fe73.5Cu1Nb3Si13.5B9(being called for short FeCuNbSiB)
Nanocrystalline strip has high magnetic permeability (initial permeability can reach more than 80000, and maximum permeability can be more than 450000), height is satisfied
With advantages such as magnetic induction (Bs can reach 1.25T), low-coercivity, low iron loss and good thermal stabilities, it helps lend some impetus to
Miniaturization of electronic products, lighting, be widely used in sophisticated power transformer, high power switch current transformer, reactor,
Wave filter and other ultra-high frequency fields.FeCuNbSiB amorphous band is mainly obtained by liquid phase cooling method [7], its
Thermodynamically being in metastable state, soft magnet performance is poor.To improve the soft magnet performance of FeCuNbSiB amorphous band, it is right to need
FeCuNbSiB amorphous band carries out heat treatment, makes part non-product state be converted into crystalline state;But the FeCuNbSiB nanometer after heat treatment
Crystal zone material is more crisp and it is by under the effect of external carbuncle, and soft magnet performance can decline.In order to protect FeCuNbSiB nanocrystalline strip,
Production process needs FeCuNbSiB nanometer product band is carried out epoxy encapsulation.
FeCuNbSiB nanocrystalline strip surface is in amorphous/nanocrystalline state, there is substantial amounts of defect, FeCuNbSiB nanometer
There is substantial amounts of periodicity stomatal band and a rule obvious cold shut lines in brilliant strip surface, the existence of these defects causes epoxy
Resin is difficult to all infiltrate on FeCuNbSiB surface, it is impossible to reach to encapsulate the purpose of FeCuNbSiB nanometer band.So it is existing
Before epoxy encapsulation, FeCuNbSiB strip surface is carried out load thin film, due between chemical film to FeCuNbSiB
Substrate surface caking property is poor, and the longer basement membrane that is easily caused was peeled off and came off the time, reduced the performance of epoxy encapsulation, so system
Standby a kind of resistance to stripping, peel FeCuNbSiB area load membrane material is necessary.
Summary of the invention
The technical problem to be solved: after existing FeCuNbSiB band overlay film, owing to strip surface exists
Substantial amounts of periodicity stomatal band and cold shut lines, the overlay film permanent seal cooling making strip surface is poor, time length be easily peeled come off lack
Fall into, it is provided that the preparation method of a kind of surface complexation overlay film FeCuNbSiB band, the present invention is by carrying Exocarpium Juglandis Immaturus
Take, after collecting tannic acid concentrated solution, then to its esterification modification, can be formed surely with metal by tannic acid two phase ortho-phenolic hydroxyls
Fixed chelate, after sheet metal strip open-assembly time in atmosphere is longer, by moisture in air and oxide etch effect, makes tannin
Acid esters compound is tightly adsorbed in strip surface, and durability is greatly improved, and has wide prospect of the application.
For solving above-mentioned technical problem, the present invention uses the technical scheme as described below to be:
(1) collect Exocarpium Juglandis Immaturus, cleaned and be placed at 85~95 DEG C dry 6~8h, mill subsequently and cross 80~90 mesh, receiving
Collect to obtain Exocarpium Juglandis Immaturus powder, the most in mass ratio 1:10, by mixed with the stirring of mass fraction 45% ethanol solution for Exocarpium Juglandis Immaturus powder
Close, under 200~300W after sonic oscillation 10~15min, centrifugation 10~15min under 3500~4000r/min, collect
The supernatant is placed at 60~70 DEG C rotating and is evaporated to the 1/5 of original volume, is prepared into extraction concentrated solution;
(2) count by weight, respectively weigh the extraction concentrated solution of 45~50 parts of above-mentioned preparations, 10~15 parts of octadecanoyl chlorine and
1~2 part of toluenesulfonic acid is placed in there-necked flask, and logical nitrogen gets rid of air, in a nitrogen atmosphere, is placed on water at 70~80 DEG C
Bath heating 1~2h, filters subsequently and collects filtrate, rotates and is evaporated to the 1/10 of original volume, collect modified at 70~80 DEG C
Esterification concentrated solution, standby;
(3) count by weight, weigh respectively 45~50 parts of ferrum, the ferro-boron of 8~10 parts of boron contents 17%, 6~8 parts of copper, 7~8 parts
Niobium and 2~3 parts of silicon are placed in ball grinder, ball milling 3~5h under 350~400r/min, cross 120 mesh sieves subsequently, collect to obtain mixing
Ball-milled powder, is placed in mixing and ball milling powder in vacuum induction furnace, argon logical in stove is got rid of air, is subsequently vacuumed out to 5
~10Pa, at 1450~1500 DEG C after insulation melted 1~2h, stop heating and standing is cooled to room temperature, be prepared into
FeCuNbSiB foundry alloy;
(4) nozzle that slit width is 0.5~1.0mm is installed to nozzle bag, by the FeCuNbSiB foundry alloy of above-mentioned preparation
It is placed in nozzle bag, after nozzle bag is heated to 1400~1500 DEG C melted 45~60min, using the copper roller of surface cleaning as spray
Band basal plane, controlling copper roller rotating speed is 25~30r/min, and spray tape handling subsequently is also collected, and naturally cools to room temperature, is prepared into
FeCuNbSiB alloy strip steel rolled stock;
(5) the FeCuNbSiB alloy strip steel rolled stock both side surface after above-mentioned cooling is polished, after polishing completes, use anhydrous second
Alcohol is cleaned 3~5 times, the most naturally dries, and modified esterification concentrated solution step (2) prepared uniformly coats to FeCuNbSiB conjunction
Gold ribbon material both side surface, controlling coated weight is 60~80g/m2, coating thickness is 10~20 μm, after film completes, is put
At 65~70 DEG C, it is dried 6~8h, a kind of surface complexation overlay film FeCuNbSiB band can be prepared into.
The Fe-based amorphous strip width of FeCuNbSiB of the present invention is 9.5~10.5mm, and thickness is 28~32 μm, and density is
7.2~7.3g/cm3, resistivity is 135~145 μ Ω cm, and Curie temperature is 545~560 DEG C, and its initial permeability can reach
μ i=11 ten thousand, maximum saturation magnetic induction are Bs=1.28T, coercivity is Hc=0.83A/m.
The present invention is compared with additive method, and Advantageous Effects is:
(1) the surface complexation overlay film FeCuNbSiB band durability that prepared by the present invention is strong, at room temperature places 6~after 8 months,
Epoxy resin wellability is unchanged, and higher with epoxy resin conjugation, relatively like product in service life after epoxy resin combination
Improve 15~20%.
(2) present invention is prepared by Exocarpium Juglandis Immaturus, green safety, non-environmental-pollution.
Detailed description of the invention
First collect Exocarpium Juglandis Immaturus, cleaned and be placed at 85~95 DEG C dry 6~8h, mill subsequently and cross 80~90
Mesh, collects to obtain Exocarpium Juglandis Immaturus powder, the most in mass ratio 1:10, is stirred with mass fraction 45% ethanol solution by Exocarpium Juglandis Immaturus powder
Mix mixing, under 200~300W after sonic oscillation 10~15min, centrifugation 10~15min under 3500~4000r/min,
The collection supernatant is placed at 60~70 DEG C rotating and is evaporated to the 1/5 of original volume, is prepared into extraction concentrated solution;By weight
Meter, weighs the extraction concentrated solution of 45~50 parts of above-mentioned preparations, 10~15 parts of octadecanoyl chlorine and 1~2 part of toluenesulfonic acid respectively and puts
In there-necked flask, logical nitrogen gets rid of air, in a nitrogen atmosphere, is placed on heating in water bath 1~2h at 70~80 DEG C, subsequently
Filter and collect filtrate, rotating at 70~80 DEG C and be evaporated to the 1/10 of original volume, collect to obtain modified esterification concentrated solution, standby;
Count by weight, weigh respectively 45~50 parts of ferrum, the ferro-boron of 8~10 parts of boron contents 17%, 6~8 parts of copper, 7~8 parts of niobiums and 2~
3 parts of silicon are placed in ball grinder, ball milling 3~5h under 350~400r/min, cross 120 mesh sieves subsequently, collect to obtain mixing and ball milling powder
End, is placed in mixing and ball milling powder in vacuum induction furnace, argon logical in stove is got rid of air, is subsequently vacuumed out to 5~10Pa,
At 1450~1500 DEG C after insulation melted 1~2h, stop heating and standing is cooled to room temperature, be prepared into mother FeCuNbSiB and close
Gold;The nozzle that slit width is 0.5~1.0mm is installed to nozzle bag, the FeCuNbSiB foundry alloy of above-mentioned preparation is placed in
In nozzle bag, after nozzle bag is heated to 1400~1500 DEG C melted 45~60min, using the copper roller of surface cleaning as spray tape base
Face, controlling copper roller rotating speed is 25~30r/min, and spray tape handling subsequently is also collected, and naturally cools to room temperature, is prepared into
FeCuNbSiB alloy strip steel rolled stock;FeCuNbSiB alloy strip steel rolled stock both side surface after above-mentioned cooling is polished, treats that polishing completes
After, clean 3~5 times with dehydrated alcohol, the most naturally dry, prepared by step (2) modified be esterified concentrated solution uniformly coat to
FeCuNbSiB alloy strip steel rolled stock both side surface, controlling coated weight is 60~80g/m2, coating thickness is 10~20 μm, treats that film is complete
Cheng Hou, is placed at 65~70 DEG C and is dried 6~8h, can be prepared into a kind of surface complexation overlay film FeCuNbSiB band.
Example 1
First collect Exocarpium Juglandis Immaturus, cleaned and be placed at 85 DEG C dry 6h, mill subsequently and cross 80 mesh, collect and to obtain Semen Juglandis green grass or young crops
Corium farinosum end, 1:10 the most in mass ratio, Exocarpium Juglandis Immaturus powder is mixed, under 200W with the stirring of mass fraction 45% ethanol solution
After sonic oscillation 10min, centrifugation 10min under 3500r/min, the collection supernatant is placed at 60 DEG C rotating and is evaporated to
The 1/5 of original volume, is prepared into extraction concentrated solution;Count by weight, respectively weigh the extraction concentrated solution of 45 parts of above-mentioned preparations, 10
Part octadecanoyl chlorine and 1 part of toluenesulfonic acid are placed in there-necked flask, and logical nitrogen gets rid of air, in a nitrogen atmosphere, is placed on
At 70 DEG C, heating in water bath 1h, filters subsequently and collects filtrate, rotates and is evaporated to the 1/10 of original volume, collect modified at 70 DEG C
Esterification concentrated solution, standby;Count by weight, weigh 45 parts of ferrum, the ferro-boron of 8 parts of boron contents 17%, 6 parts of copper, 7 parts of niobiums and 2 respectively
Part silicon is placed in ball grinder, ball milling 3 under 350r/min, crosses 120 mesh sieves subsequently, collects to obtain mixing and ball milling powder, will mix ball
Pulverizing end is placed in vacuum induction furnace, argon logical in stove is got rid of air, is subsequently vacuumed out to 5Pa, is incubated at 1450 DEG C
After melted 1h, stop heating and standing is cooled to room temperature, be prepared into FeCuNbSiB foundry alloy;It is the spray of 0.5mm by slit width
Mouth is installed to nozzle bag, is placed in nozzle bag by the FeCuNbSiB foundry alloy of above-mentioned preparation, treats that nozzle bag is heated to 1400 DEG C
After melted 45min, using the copper roller of surface cleaning as spray band basal plane, controlling copper roller rotating speed is 25r/min, and spray tape handling subsequently is also
Collect, naturally cool to room temperature, be prepared into FeCuNbSiB alloy strip steel rolled stock;By the FeCuNbSiB alloy strip steel rolled stock two after above-mentioned cooling
Side surface is polished, and after polishing completes, cleans 3 times with dehydrated alcohol, the most naturally dries, modification is esterified concentrated solution equal
Even coating is 60g/m to FeCuNbSiB alloy strip steel rolled stock both side surface, control coated weight2, coating thickness is 10 μm, treats that film is complete
Cheng Hou, is placed at 65 DEG C and is dried 6h, can be prepared into a kind of surface complexation overlay film FeCuNbSiB band.
Example 2
First collect Exocarpium Juglandis Immaturus, cleaned and be placed at 90 DEG C dry 7h, mill subsequently and cross 85 mesh, collect and to obtain Semen Juglandis green grass or young crops
Corium farinosum end, 1:10 the most in mass ratio, Exocarpium Juglandis Immaturus powder is mixed, under 250W with the stirring of mass fraction 45% ethanol solution
After sonic oscillation 12min, centrifugation 12min under 3750r/min, the collection supernatant is placed at 65 DEG C rotating and is evaporated to
The 1/5 of original volume, is prepared into extraction concentrated solution;Count by weight, respectively weigh the extraction concentrated solution of 47 parts of above-mentioned preparations, 12
Part octadecanoyl chlorine and 2 parts of toluenesulfonic acids are placed in there-necked flask, and logical nitrogen gets rid of air, in a nitrogen atmosphere, is placed on
At 75 DEG C, heating in water bath 2h, filters subsequently and collects filtrate, rotates and is evaporated to the 1/10 of original volume, collect modified at 75 DEG C
Esterification concentrated solution, standby;Count by weight, weigh 47 parts of ferrum, the ferro-boron of 9 parts of boron contents 17%, 7 parts of copper, 7 parts of niobiums and 2 respectively
Part silicon is placed in ball grinder, ball milling 4h under 375r/min, crosses 120 mesh sieves subsequently, collects to obtain mixing and ball milling powder, will mix ball
Pulverizing end is placed in vacuum induction furnace, argon logical in stove is got rid of air, is subsequently vacuumed out to 8Pa, is incubated at 1475 DEG C
After melted 2h, stop heating and standing is cooled to room temperature, be prepared into FeCuNbSiB foundry alloy;It is the spray of 0.7mm by slit width
Mouth is installed to nozzle bag, is placed in nozzle bag by the FeCuNbSiB foundry alloy of above-mentioned preparation, treats that nozzle bag is heated to 1450 DEG C
After melted 52min, using the copper roller of surface cleaning as spray band basal plane, controlling copper roller rotating speed is 27r/min, and spray tape handling subsequently is also
Collect, naturally cool to room temperature, be prepared into FeCuNbSiB alloy strip steel rolled stock;By the FeCuNbSiB alloy strip steel rolled stock two after above-mentioned cooling
Side surface is polished, and after polishing completes, cleans 4 times with dehydrated alcohol, the most naturally dries, modification is esterified concentrated solution equal
Even coating is 70g/m to FeCuNbSiB alloy strip steel rolled stock both side surface, control coated weight2, coating thickness is 15 μm, treats that film is complete
Cheng Hou, is placed at 67 DEG C and is dried 7h, can be prepared into a kind of surface complexation overlay film FeCuNbSiB band.
Example 3
First collect Exocarpium Juglandis Immaturus, cleaned and be placed at 95 DEG C dry 8h, mill subsequently and cross 90 mesh, collect and to obtain Semen Juglandis green grass or young crops
Corium farinosum end, 1:10 the most in mass ratio, Exocarpium Juglandis Immaturus powder is mixed, under 300W with the stirring of mass fraction 45% ethanol solution
After sonic oscillation 15min, centrifugation 15min under 4000r/min, the collection supernatant is placed at 70 DEG C rotating and is evaporated to
The 1/5 of original volume, is prepared into extraction concentrated solution;Count by weight, respectively weigh the extraction concentrated solution of 50 parts of above-mentioned preparations, 15
Part octadecanoyl chlorine and 2 parts of toluenesulfonic acids are placed in there-necked flask, and logical nitrogen gets rid of air, in a nitrogen atmosphere, is placed on
At 80 DEG C, heating in water bath 2h, filters subsequently and collects filtrate, rotates and is evaporated to the 1/10 of original volume, collect modified at 80 DEG C
Esterification concentrated solution, standby;Count by weight, weigh respectively 50 parts of ferrum, the ferro-boron of 10 parts of boron contents 17%, 8 parts of copper, 8 parts of niobiums and
3 parts of silicon are placed in ball grinder, ball milling 5h under 400r/min, cross 120 mesh sieves subsequently, collect to obtain mixing and ball milling powder, will mixing
Ball-milled powder is placed in vacuum induction furnace, argon logical in stove is got rid of air, is subsequently vacuumed out to 10Pa, protects at 1500 DEG C
After the melted 2h of temperature, stop heating and standing is cooled to room temperature, be prepared into FeCuNbSiB foundry alloy;It is 1.0mm's by slit width
Nozzle is installed to nozzle bag, is placed in nozzle bag by the FeCuNbSiB foundry alloy of above-mentioned preparation, treats that nozzle bag is heated to 1500
After DEG C melted 60min, using the copper roller of surface cleaning as spray band basal plane, controlling copper roller rotating speed is 30r/min, sprays tape handling subsequently
And collect, naturally cool to room temperature, be prepared into FeCuNbSiB alloy strip steel rolled stock;By the FeCuNbSiB alloy strip steel rolled stock after above-mentioned cooling
Both side surface is polished, and after polishing completes, cleans 5 times with dehydrated alcohol, the most naturally dries, modification is esterified concentrated solution
Uniformly coating is to FeCuNbSiB alloy strip steel rolled stock both side surface, and control coated weight is 80g/m2, coating thickness is 20 μm, treats film
After completing, it is placed at 70 DEG C and is dried 8h, a kind of surface complexation overlay film FeCuNbSiB band can be prepared into.
Claims (1)
1. the preparation method of a surface complexation overlay film FeCuNbSiB band, it is characterised in that concrete preparation process is:
(1) collect Exocarpium Juglandis Immaturus, cleaned and be placed at 85~95 DEG C dry 6~8h, mill subsequently and cross 80~90 mesh, receiving
Collect to obtain Exocarpium Juglandis Immaturus powder, the most in mass ratio 1:10, by mixed with the stirring of mass fraction 45% ethanol solution for Exocarpium Juglandis Immaturus powder
Close, under 200~300W after sonic oscillation 10~15min, centrifugation 10~15min under 3500~4000r/min, collect
The supernatant is placed at 60~70 DEG C rotating and is evaporated to the 1/5 of original volume, is prepared into extraction concentrated solution;
(2) count by weight, respectively weigh the extraction concentrated solution of 45~50 parts of above-mentioned preparations, 10~15 parts of octadecanoyl chlorine and
1~2 part of toluenesulfonic acid is placed in there-necked flask, and logical nitrogen gets rid of air, in a nitrogen atmosphere, is placed on water at 70~80 DEG C
Bath heating 1~2h, filters subsequently and collects filtrate, rotates and is evaporated to the 1/10 of original volume, collect modified at 70~80 DEG C
Esterification concentrated solution, standby;
(3) count by weight, weigh respectively 45~50 parts of ferrum, the ferro-boron of 8~10 parts of boron contents 17%, 6~8 parts of copper, 7~8 parts
Niobium and 2~3 parts of silicon are placed in ball grinder, ball milling 3~5h under 350~400r/min, cross 120 mesh sieves subsequently, collect to obtain mixing
Ball-milled powder, is placed in mixing and ball milling powder in vacuum induction furnace, argon logical in stove is got rid of air, is subsequently vacuumed out to 5
~10Pa, at 1450~1500 DEG C after insulation melted 1~2h, stop heating and standing is cooled to room temperature, be prepared into
FeCuNbSiB foundry alloy;
(4) nozzle that slit width is 0.5~1.0mm is installed to nozzle bag, by the FeCuNbSiB foundry alloy of above-mentioned preparation
It is placed in nozzle bag, after nozzle bag is heated to 1400~1500 DEG C melted 45~60min, using the copper roller of surface cleaning as spray
Band basal plane, controlling copper roller rotating speed is 25~30r/min, and spray tape handling subsequently is also collected, and naturally cools to room temperature, is prepared into
FeCuNbSiB alloy strip steel rolled stock;
(5) the FeCuNbSiB alloy strip steel rolled stock both side surface after above-mentioned cooling is polished, after polishing completes, use anhydrous second
Alcohol is cleaned 3~5 times, the most naturally dries, and modified esterification concentrated solution step (2) prepared uniformly coats to FeCuNbSiB conjunction
Gold ribbon material both side surface, controlling coated weight is 60~80g/m2, coating thickness is 10~20 μm, after film completes, is put
At 65~70 DEG C, it is dried 6~8h, a kind of surface complexation overlay film FeCuNbSiB band can be prepared into.
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Cited By (1)
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CN112023721A (en) * | 2020-07-31 | 2020-12-04 | 西华大学 | Visible light driven self-cleaning carbon nitride multifunctional composite film and preparation method and application thereof |
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CN102219810A (en) * | 2011-05-06 | 2011-10-19 | 叶城三诺农业科技开发有限公司 | Process method for preparing high-purity tannin from walnut green husk |
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CN102219810A (en) * | 2011-05-06 | 2011-10-19 | 叶城三诺农业科技开发有限公司 | Process method for preparing high-purity tannin from walnut green husk |
CN103524571A (en) * | 2013-10-08 | 2014-01-22 | 河北科技大学 | Recycling method for preparing tannic acid from walnut residues |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112023721A (en) * | 2020-07-31 | 2020-12-04 | 西华大学 | Visible light driven self-cleaning carbon nitride multifunctional composite film and preparation method and application thereof |
CN112023721B (en) * | 2020-07-31 | 2021-05-07 | 西华大学 | Visible light driven self-cleaning carbon nitride multifunctional composite film and preparation method and application thereof |
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