CN106319430A - Preparation method of remanufactured coating for inner wall of air cylinder sleeve - Google Patents

Preparation method of remanufactured coating for inner wall of air cylinder sleeve Download PDF

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Publication number
CN106319430A
CN106319430A CN201610895013.9A CN201610895013A CN106319430A CN 106319430 A CN106319430 A CN 106319430A CN 201610895013 A CN201610895013 A CN 201610895013A CN 106319430 A CN106319430 A CN 106319430A
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China
Prior art keywords
coating
spraying
composite
preparation
internal wall
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Pending
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CN201610895013.9A
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Chinese (zh)
Inventor
张超
吴庆丹
刘黎明
徐海峰
肖金坤
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Yangzhou University
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Yangzhou University
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Priority to CN201610895013.9A priority Critical patent/CN106319430A/en
Publication of CN106319430A publication Critical patent/CN106319430A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material

Abstract

The invention relates to a preparation method of a remanufactured coating for the inner wall of an air cylinder sleeve. According to the preparation method, a thermal spraying mode is adopted; a base body of the inner wall of the air cylinder sleeve of a vehicle is remanufactured from a powdered material; the base body is made of carbon steel or stainless steel or other types of metal; the spraying powdered material is a metallic-nonmetallic composite and composite powder; after entering flame flow, the composite powder is deposited onto the base body through all or part of fusion and acceleration processes; and the composite powder is sprayed to the inner wall of the air cylinder sleeve of the vehicle, so that the composite coating is formed. By means of the method, defects existing in previous various air cylinder sleeve restoration methods are overcome. The thermal spraying method is adopted, and the high-performance composite coating is remanufactured on the inner wall of the cylinder sleeve; the service life of an engine of the vehicle is recovered; a mixed power gluing method is adopted in the spraying process, and the coating lamination phenomenon caused by density variation of the composite powder is effectively avoided; it is helpful to improve performance of the coating; and the service life of the coating is prolonged to a large extent.

Description

A kind of cylinder liner internal wall remanufactures the preparation method of coating
Technical field
The present invention relates to engineering and material science, remanufacture the preparation method of coating particularly to a kind of cylinder liner internal wall.
Background technology
Cylinder liner is most to be vulnerable to infringement as in electromotor important parts, reduces or reduces infringement and seem The most necessary.The modal failure mode of cylinder cylinder sleeve is wear out failure, mainly include abrasive wear, corrosive wear and Adhesive wear.It is taken as that the internal combustion engine of quovis modo, the requirement to its cylinder jacket is substantially consistent, i.e. cylinder jacket Inner surface must meet the low-friction coefficient between high abrasion resistance and piston ring, corrosion resistance, wearability and enough Tensile strength etc..
Before making the present invention, people use many ways to attempt to improve its wearability etc..Wherein, just there is plasma spray technology. Plasma spray technology is to utilize thermal source that sprayed on material is heated to melted or semi-molten state, makes it change by air-flow at a high speed former Some states, are molten into drop, are ejected into the material surface through pretreatment, form the surface layer of adhesion-tight.Thermal spraying is Cylinder jacket remanufactures one of technique, thermal spraying can at cylinder inner wall spray-on coating to recover cylinder jacket size, coating material with Coating structure can to a great extent in regulation and control, the hole in coating can realize oil storage function.
Ceramic powders adds the effect that can play hard phase in coating, improves the anti-wear performance of coating.Thermal jet is utilized to prepare Composite coating is an up the effective way of coating performance, and existing spraying method great majority are simple mixed-powders, when multiple When powder density difference is bigger, spraying process often cause coating to be divided because of mixed-powder acceleration difference in thermal spraying flame stream Layer phenomenon, this is also one of key factor restricting composite coating development, particularly evident when metal mixes with ceramic powders.At present Conventional solution is the non-ceramic powder product as an alternative using density difference less, and this method is difficult to reach preferable Abrasion resistant effect;Or spraying is through the cladding powder of processing, this method due to needs spraying front by metallic cover nonmetal Powder surface, powder preparation cost is higher.
CN101250698 invents a kind of composite corpuscle nickel base alloy manufacture or the method for repairing cylinder cover, for railway, Peculiar to vessel and large power diesel engine cylinder jacket is the reparation of inwall after using abrasion.Use chemical mode by alloy solution, be coated in Interior surface of cylinder liner, coating process is: goes out to add in the composite corpuscle nickel base alloy solution of a device imports cylinder jacket to be processed and Silicon-carbide particles in solution are coated with at interior surface of cylinder liner to be processed, then import condenser by row chemical reaction equably, Making solution lose activity, chemical reaction stops, and pumps into liquid pool dosing, is re-fed into heater, arrival outlet temperature 82~83 DEG C Rear importing adds a device, adds silicon-carbide particles and be configured to the circulation that composite corpuscle nickel base alloy solution entrance is following within adding a device System.Although this technology can manufacture reparation smoothly on workpiece, but there is the biggest defect of environmental pollution or problem, Additionally, due to technique this technology rehabilitation cost excessively complicated is too high, hardly result in extensively application.
CN103710660A relates to a kind of engine water-cooling cylinder jacket outer wall and inner wall size is recovered and intensifying method.The party Method is to use internal plasma spraying technology to prepare Ni-based anti-attrition, wear-resistant coating at cylinder liner internal wall, uses supersonic speed plasma Spraying technology prepares nickel Aluminium composite coating at cylinder jacket outer wall.Sprayed on material can only the high Ni bag Al powder of use cost, material Material wearability is limited, also without reference to the preparation of composite coating.
CN103132009A is the method for the inner surface of the cylinder sleeve that a kind of reparation is contained in engine cylinder-body.From inner surface Removing material, to produce the region that thickness reduces, the region that thickness reduces axially extends relative to cylinder, and not up to The end of cylinder sleeve stops, thus leaves initial diameter district between region and the end of cylinder body that thickness reduces.Then, such as The rough surface in the region making thickness reduce is brushed by hammer.This Patent Office is limited to the reparation of size, selects at material and adds It is not carried out in work technique breaking through.
Summary of the invention
It is an object of the invention to overcome drawbacks described above, develop a kind of cylinder liner internal wall and remanufacture the preparation method of coating.
The technical scheme is that
A kind of cylinder liner internal wall remanufactures the preparation method of coating, and it is mainly characterized by following steps:
(1) in thermal spraying mode, utilize dusty material that the matrix of automobile cylinder set inwall is remanufactured;
(2) material of matrix is carbon steel or rustless steel or other metal material;Dusty spray material used is metal-non- Metallic composite;
(3) dusty spray material is composite powder, and particle diameter is between 10-100 μm;
(4), after composite powder enters flame stream, through all processes melted and accelerate or partial routine, matrix is deposited to On;
(5) on cylinder liner internal wall, spraying forms composite coating.
In described step (1), heat spraying method includes but not limited to: air plasma spraying, HVAF, Asia Velocity of sound flame-spraying and flame-spraying.
Described step (2) composite include using two or more following material: NiCrBSi, FeCrBSi, One in FeCrC, Mo, as metal_based material, uses Al2O3、WC、WC-Co、Al2O3-TiO2In one as nonmetal Material.
Described step (4) needs when composite powder density contrast is bigger to utilize gluing to be bonded, process.
Described step (5) coating thickness can be between 200~500 μm, and coating if desired is thicker, then can be several times Implement spraying.
In described step (5), size carries out turning, polishing to spraying reparation rear vehicle cylinder liner internal wall as required.
Advantages of the present invention and effect are:
Wearing and tearing for cylinder liner internal wall high temperature corrosion, the invalid characteristic of outer wall cavitation pitting, the present invention uses the method for thermal spraying Remanufacture high-performance composite coating at inboard wall of cylinder liner, recover vehicle motor service life.
Spraying process use gluing powder mixing method be prevented effectively from the coating layering phenomenon caused because of composite powder density variation, Being favorably improved the performance of coating, therefore compare Typical spray method, coating improves a lot service life.
In this patent, bonding method is applicable to the composite powder that powder density difference is bigger, it is to avoid use cladding powder, because of This can effectively save material cost.
Compared to CN101250698 introduce repair mode, plasma spray technology in terms of cost or feasibility all Have great advantage, it is not necessary to complicated chemical reaction, the easy steps such as this patent uses mixed-powder through heating, melting, deposition Reach the repairing effect being better than in CN101250698 showing, and operating procedure is relative to CN101250698 simple possible, owing to not having Having chemical reaction process, environmental pollution is less, and energy utilization rate is also improved.This patent is good to material selectivity, without pin Different materials is formulated different process.
The Ni bag Al powder high compared to use cost in CN103710660A, this patent utilizes gluing, solves smoothly The lamination certainly caused because of density difference, it is ensured that be substantially reduced production cost while coating quality.The method is also applied for Other analogue thermal spray process.
Compared to the Fe alloy even Ni alloy in CN103132009A, owing to adding hard ceramic powder, in the coating Adding hard particles, play main stress effect in friction process, anti-wear performance improves further, and some oxide ceramics is all right Form transfer membrane, improve greasy property.
Describe the present invention below in conjunction with the drawings and specific embodiments, but not as a limitation of the invention.
Accompanying drawing explanation
Fig. 1 spraying process of the present invention schematic diagram.
Fig. 2 NiCrBSi-Al of the present invention2O3The XRD figure spectrum schematic diagram of composite coating.
Fig. 3 plasma spraying of the present invention cylinder liner internal wall composite coating schematic cross-section.
Fig. 4 flame-spraying of the present invention cylinder liner internal wall composite coating schematic cross-section.
Fig. 5 plasma spraying of the present invention FeCrBSi-Al2O3The coating schematic diagram obtained.
In figure, each label represents that corresponding component names is as follows:
Turntable 1, support 2, (endoporus spray gun) nozzle 3, cylinder jacket 4, endoporus spray gun 5, flame stream 6, powder feeding pipe 7.
Detailed description of the invention
The technical thought of the present invention:
For vehicle engine set inwall because of the problem worn and torn or spot corrosion causes workpiece to be scrapped, use heat spraying method Obtain composite coating at cylinder liner internal wall, then make cylinder jacket recover initial inside diameter by machining, use gluing to solve spraying During occur coating layering phenomenon.Realize remanufacturing of cylinder jacket, while improving cylinder liner internal wall wearability, it is ensured that Coating quality and binding ability.The present invention can reduce cylinder jacket in use inevitable wear out failure, gives gas In the cylinder sleeve secondary life-span, extend air cylinder sleeve of engine service life.
Specification For Structure accompanying drawing illustrates the present invention below.
Structure as shown in Figure 1:
(joining servomotor) turntable 1 is fixed on ground, rotating speed controlled (depending on required reparation workpiece size), Frame 2 is arranged on above turntable 1, i.e. turntable 1 is separated by support 2 with cylinder jacket 4 to be repaired, and cylinder jacket 4 stands in support 2 On, endoporus spray gun 5 bottom is in cylinder jacket 4, and (endoporus spray gun) nozzle 3 is on the bottom of endoporus spray gun 5, the most just at cylinder In set 4, the endoporus spray gun 5 top other end, outside cylinder jacket 4, connects with powder feeding pipe 7.
Endoporus spray gun 5 is controlled by six-axis linkage mechanical arm, ensures the flame stream of nozzle 3 ejection during the most at the uniform velocity moving 6 can be evenly applied to cylinder jacket 4 inwall, and powder feeding pipe (including powder feeder (being not drawn in figure, omit)) 7 connects endoporus spray gun 5, Ensure that endoporus spray gun 5 powder delivery is uniform.
The concrete steps of the present invention include:
(1) material prepares: composite powder include using two or more following material: NiCrBSi, FeCrBSi, One in FeCrC, Mo, as metal_based material, uses Al2O3、WC、WC-Co、Al2O3-TiO2In one as nonmetal Material.Before spraying composite powder pretreatment included the steps such as mixed powder, gluing, mesh screen, drying, owing to powder diameter is too small easily Causing reunion plugging, the excessive then melting state of particle diameter is poor, and therefore composite powder size controlling is between 10-100 μm,.
(2) mixed powder process: by need the composite powder of spraying through batch mixer mixing 2h, with PVA glue with mix after powder Stir, be dried to micro-tacky state in being placed in baking oven, be sieved to suitable particle size with 130 eye mesh screens, be subsequently placed in 200 DEG C of baking ovens Within two hours, making glue thoroughly solidify, this mode can have effective adhesive difference powder, it is to avoid causes because of acceleration difference in spraying process The lamination of powder sedimentation state difference, in spraying process, glue can burn totally under plasma high temperature, will not be because of residual Stay foreign materials away composite coating.
(3) matrix prepares: spraying matrix uses finished product cylinder jacket, before spraying matrix carried out pretreatment include machining, The steps such as cleaning, dry, sandblasting, machining Main Function is unified reparation size, it is simple to the setting of spray procedure;Clean and dry Dry mainly for impurity such as the greasy dirts on removal automobile cylinder set inwall, in case spraying process coating material and automobile cylinder set Inwall adhesion is poor;Sandblasting step increases cylinder liner internal wall roughness, similarly helps to improve bond strength.
(4) prepared by coating: utilizes powder feeding pipe to be sent into by composite powder and uses spray gun, complete through heat, melt and accelerate Portion's process or partial routine, deposit on matrix.
(5) process control: calculate spray deposited efficiency, according to cylinder jacket workpiece required size, utilizes mechanical arm and watches Take motor and coordinate control spraying particle bundle movement locus, scale error can be controlled within 10 μm by accurate calculating, side The machining operation such as the most ensuing turning, polishing.
Embodiment 1:
By 20g particle diameter 20 μm left and right Al2O3Powder uniformly mixes with the NiCrBSi powder of 180g particle diameter 40-50 μm, with glue Putting into powder feeder pipe 7 after bonding is bonding, controlling powder sending quantity is that 30g/min sends in plasma flame flow, is deposited on cylinder liner internal wall Forming composite coating, powder sending quantity too much or is crossed that I haven't seen you for ages and is caused the molten or peroxidating situation during powder feeding and occur, and directly affects Coating quality and coating layer thickness.Spray parameters is set as H2Flow 7L/min, Ar flow 40L/min, electric current 500A, voltage 56V.Controlled for ensureing coating uniform and thickness, spray gun translational speed is set to 200mm/s, moves down 3mm every time, sprays continuously It is coated with 6 times.Phase structure is observed with X-ray diffractometer.As in figure 2 it is shown, there is γ-Ni, α-Al in coating2O3、γ-Al2O3Etc. phase, Al2O3Presented in strengthening mutually, in gained coating, effectively strengthen coating wear resistance, about coating layer thickness 150 μm, meet Prepare cylinder liner internal wall and repair dimensional requirement.
Embodiment 2:
By 40g particle diameter 20 μm left and right Al2O3Powder uniformly mixes with the NiCrBSi powder of 160g particle diameter 40-50 μm, due to Al2O3Density is little compared with alloy powders such as NiCrBSi, Al2O3Mass ratio controls to prevent content from too much causing gained at 10%-30% Coating self-fluxing nature is relatively deteriorated, reduce coating quality, with gluing bonding after send into spray equipment, control powder sending quantity is 35g/min Send in plasma flame flow, be deposited on cylinder liner internal wall and form composite coating.H2Flow 5L/min, Ar flow 40L/min, electric current 500A, voltage 56V.Spray gun translational speed is 200mm/s, moves down 3mm every time, owing to powder sending quantity is relatively big, suitably reduces spray It is coated with number of times to control gained coating layer thickness, continuous spray 5 times.Coating cross sections pattern is observed with dish card microscope.As it is shown on figure 3, Coating is well combined, porosity about 5%, Al2O3Being uniformly dispersed, coating layer thickness is about 120 μm, and i.e. sedimentation rate is at 20-30 μm/secondary, is suitable for preparing cylinder liner internal wall coating.
Embodiment 3:
FeCrBSi is lower compared to NiCrBSi material cost, is more suitable for industrial mass production, by FeCrBSi and Al2O3 Uniformly mix with 8: 2 mass ratios, gluing after be sent in flame gun flame stream, be deposited on matrix formation ceramic metal be combined Coating.Spray gun is gases used for oxygen with acetylene, and its ignition temperature can reach 3000 DEG C, fully meet FeCrBSi and Al2O3Material Material fusion temperature, spray gun translational speed is 150mm/s, moves down 2mm, continuous spray 15 times every time.Use dish Ka Xianweijingguan Examining Cross Section Morphology, as shown in Figure 4, about coating layer thickness 150 μm, be uniformly dispersed, layer base junction is closed all right, meets high intensity resistance to Mill test.
Embodiment 4:
By the FeCrBSi powder of particle diameter 40-50 μm and particle diameter 20 μm left and right Al2O3Powder respectively with 19: 1,18: 2,16: 4, 14: 6 mass ratioes uniformly mix, and contrast the coating product that 4 kinds of heterogeneities are more optimum to find combination property than experiment, with gluing Sending into spray equipment after bonding, controlling powder sending quantity is that 30g/min sends in plasma flame flow, is deposited on 304 stainless steel surfaces shapes Become composite coating.H2Flow 5L/min, Ar flow 40L/min, electric current 500A, voltage 56V.Spray gun translational speed is 200mm/s, Move down 3mm, continuous spray 5 times every time.Gained composite coating sample is as it is shown in figure 5, display quality ratio is 16: 4 these ginsengs The Coating Surface Roughness of number is moderate, zero defect, is suitable for cylinder sleeve processing.
Embodiment 5:
By 20g particle diameter 20 μm left and right TiO2Powder uniformly mixes with the NiCrBSi powder of 180g particle diameter 40-50 μm, TiO2Powder End is known for inorganic pigment, but can play certain dispersion-strengthened action the most equally, with glue as adding in the coating Sending into spray equipment after bonding is bonding, controlling powder sending quantity is that 30g/min sends in plasma flame flow, is deposited on cylinder jacket section shape Become composite coating.H2Flow 5L/min, Ar flow 42L/min, electric current 550A, voltage 60V.Spray gun translational speed is 200mm/s, Move down 3mm, continuous spray 6 times every time.Coating cross sections, Plasma Sprayed Composite Coatings table is observed with scanning electron microscope FE-SEM Face is melted good, particle sufficiently flatization, and conjugation is high, and has certain oil storage hole, is suitable for cylinder sleeve processing.
Instant invention overcomes metal-ceramic in conventional plasma spraying coating process, easy during the spraying of the composite powder such as metal-metal Layering a difficult problem, by by composite powder through gluing processing method, by powder even application bigger for density difference in matrix, with Time deposition efficiency be guaranteed, combination rate is good, and anti-wear performance is outstanding, and remanufacturing aspect at automobile cylinder set has well application Prospect.It is especially suitable for the un-densified wear-resistant coating preparing thickness requirement after 100 μm~300 μm.
Certainly, the present invention also can have other various embodiments, in the case of without departing substantially from present invention spirit and essence thereof, ripe Know those skilled in the art to work as and can make various corresponding change and deformation according to the present invention, but these change accordingly and become Shape all should belong to the protection domain of appended claims of the invention.

Claims (6)

1. a cylinder liner internal wall remanufactures the preparation method of coating, it is characterised in that following steps:
(1) in thermal spraying mode, utilize dusty material that the matrix of automobile cylinder set inwall is remanufactured;
(2) material of matrix is carbon steel or rustless steel or other metal material;Dusty spray material used is metal-non-metal Composite;
(3) dusty spray material is composite powder, and particle diameter is between 10-100 μm;
(4), after composite powder enters flame stream, through all processes melted and accelerate or partial routine, deposit on matrix;
(5) on cylinder liner internal wall, spraying forms composite coating.
A kind of cylinder liner internal wall the most according to claim 1 remanufactures the preparation method of coating, it is characterised in that described step Suddenly in (1), heat spraying method includes but not limited to: air plasma spraying, HVAF, sub-concordant convergence and Flame-spraying.
A kind of cylinder liner internal wall the most according to claim 1 remanufactures the preparation method of coating, it is characterised in that described step Suddenly (2) composite includes using two or more following material: the one in NiCrBSi, FeCrBSi, FeCrC, Mo As metal_based material, use Al2O3、WC、WC-Co、Al2O3-TiO2In one as nonmetallic materials.
A kind of cylinder liner internal wall the most according to claim 1 remanufactures the preparation method of coating, it is characterised in that described step Suddenly (4) need when composite powder density contrast is bigger to utilize gluing to be bonded, process.
A kind of cylinder liner internal wall the most according to claim 1 remanufactures the preparation method of coating, it is characterised in that described step Suddenly (5) coating thickness can be between 200~500 μm, and coating if desired is thicker, then can implement spraying several times.
A kind of cylinder liner internal wall the most according to claim 1 remanufactures the preparation method of coating, it is characterised in that described step Suddenly in (5), size carries out turning, polishing to spraying reparation rear vehicle cylinder liner internal wall as required.
CN201610895013.9A 2016-10-10 2016-10-10 Preparation method of remanufactured coating for inner wall of air cylinder sleeve Pending CN106319430A (en)

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CN107338408A (en) * 2017-04-11 2017-11-10 滨州渤海活塞有限公司 A kind of cermet composite coating for steel pistons
CN108034915A (en) * 2017-12-19 2018-05-15 浙江威肯特泵业有限公司 A kind of preparation method of grinding machine disc surface wear-resistant coating
CN109778104A (en) * 2019-03-06 2019-05-21 扬州大学 A kind of cylinder liner internal wall heat insulation and wear resistance composite coating and preparation method
CN111893418A (en) * 2020-08-08 2020-11-06 桂林电子科技大学 Method for improving high-temperature oxidation resistance of nickel-based alloy surface
CN112126885A (en) * 2020-08-18 2020-12-25 江苏南钢通恒特材科技有限公司 Preparation method of high-temperature-resistant insulating coating of electromagnetic induction heating coil
CN112695318A (en) * 2020-12-22 2021-04-23 天津修船技术研究所(中国船舶重工集团公司第六三一三研究所) Maintenance method for nozzle flow channel of rotary drum in disc type separator

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107338408A (en) * 2017-04-11 2017-11-10 滨州渤海活塞有限公司 A kind of cermet composite coating for steel pistons
CN107338408B (en) * 2017-04-11 2019-06-14 滨州渤海活塞有限公司 A kind of metal-ceramic composite coatings for steel pistons
CN108034915A (en) * 2017-12-19 2018-05-15 浙江威肯特泵业有限公司 A kind of preparation method of grinding machine disc surface wear-resistant coating
CN109778104A (en) * 2019-03-06 2019-05-21 扬州大学 A kind of cylinder liner internal wall heat insulation and wear resistance composite coating and preparation method
CN111893418A (en) * 2020-08-08 2020-11-06 桂林电子科技大学 Method for improving high-temperature oxidation resistance of nickel-based alloy surface
CN111893418B (en) * 2020-08-08 2022-06-07 桂林电子科技大学 Method for improving high-temperature oxidation resistance of surface of nickel-based alloy
CN112126885A (en) * 2020-08-18 2020-12-25 江苏南钢通恒特材科技有限公司 Preparation method of high-temperature-resistant insulating coating of electromagnetic induction heating coil
CN112695318A (en) * 2020-12-22 2021-04-23 天津修船技术研究所(中国船舶重工集团公司第六三一三研究所) Maintenance method for nozzle flow channel of rotary drum in disc type separator

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Application publication date: 20170111