CN106319206A - Method for producing ferro-nickel alloy with nickel laterite ore - Google Patents

Method for producing ferro-nickel alloy with nickel laterite ore Download PDF

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Publication number
CN106319206A
CN106319206A CN201610784647.7A CN201610784647A CN106319206A CN 106319206 A CN106319206 A CN 106319206A CN 201610784647 A CN201610784647 A CN 201610784647A CN 106319206 A CN106319206 A CN 106319206A
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CN
China
Prior art keywords
nickel
hearth furnace
rotary hearth
laterite ore
nickel ore
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610784647.7A
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Chinese (zh)
Inventor
柯雪利
黄玉鸿
蔡恒忠
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GANGXI SHENGLONG METALLURGICAL CO Ltd
Original Assignee
GANGXI SHENGLONG METALLURGICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by GANGXI SHENGLONG METALLURGICAL CO Ltd filed Critical GANGXI SHENGLONG METALLURGICAL CO Ltd
Priority to CN201610784647.7A priority Critical patent/CN106319206A/en
Publication of CN106319206A publication Critical patent/CN106319206A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/02Obtaining nickel or cobalt by dry processes
    • C22B23/021Obtaining nickel or cobalt by dry processes by reduction in solid state, e.g. by segregation processes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating
    • C22B1/2406Binding; Briquetting ; Granulating pelletizing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00Obtaining nickel or cobalt
    • C22B23/02Obtaining nickel or cobalt by dry processes
    • C22B23/023Obtaining nickel or cobalt by dry processes with formation of ferro-nickel or ferro-cobalt
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention relates to the field of metallurgy, in particular to a method for producing ferro-nickel alloy with nickel laterite ore. The method includes the steps that the nickel laterite ore is crushed and screened, and after reducing coal and limestone are matched to be added into the nickel laterite ore of being larger than 2mm, the mixture is directly distributed into a rotary hearth furnace; after reducing coal and limestone are matched to be added into the nickel laterite ore of being smaller than 2mm, the mixture is pressed into carbon-containing pellets through a ball press machine, and the carbon-containing pellets are distributed into a heat accumulating type coal-based rotary hearth furnace for quick high-temperature reduction after being dried by a grating machine; and products discharged out of the rotary hearth furnace are fed into melting equipment for slag-iron separation so that the ferro-nickel alloy can be produced. By means of the method for producing the ferro-nickel alloy with the nickel laterite ore, the raw materials can be treated in a classified mode, nickel resources can be recycled to the maximum degree, and the critical shortage dilemma of the nickel resources nowadays can be relieved.

Description

The method of laterite nickel ore and producing ferronickel alloy
Technical field
The present invention relates to field of metallurgy, specially the method for laterite nickel ore and producing ferronickel alloy.
Background technology
The iron smelting method that point stove melts point is melted in coal base rotary hearth furnace direct-reduction-combustion gas, by lateritic nickel ore, reducing agent coal, fluxes Agent is pressed into pelletizing according to a certain percentage, and pelletizing enters rotary hearth furnace after drying and reduces, then by rotary hearth furnace discharging product heat Tinning feeding coal gas makees the molten point stove of combustion gas of fuel and carries out molten point, finally gives dilval.But, said method is being carried out Carry out pressure ball after lateritic nickel ore being all crushed to relatively fine fraction during Feedstock treating, do not consider raw material is carried out staged care. And, during pressure ball, roller is easy to wear, causes pressure ball relatively costly, and this causes carrying of pressure ball cost to a certain extent Height and energy waste.When processing the lateritic nickel ore of nickel grade relatively low (such as nickel grade 1%-1.2%) in aforementioned manners, if not to molten Product after Fen carries out subsequent treatment, and the response rate of nickel is difficult to reach more than 90%, causes nickel resources to waste.
Summary of the invention
For above-mentioned technical problem, the present invention saves early stage pelletizing processing cost, improves the lateritic nickel ore of the response rate of nickel The method producing dilval.
Concrete technical scheme is:
The method of laterite nickel ore and producing ferronickel alloy, comprises the steps:
(1) lateritic nickel ore being carried out crushing and screening, the lateritic nickel ore more than 2mm is direct cloth after allocating reduction coal, limestone into Entering rotary hearth furnace, the lateritic nickel ore less than 2mm is pressed into carbonaceous pelletizing, carbonaceous pelletizing with ball press after allocating reduction coal, limestone into Heat accumulating type coal base rotary hearth furnace it is distributed into again after drying grate is dried;
(2) carrying out high temperature fast restore in stove after carbonaceous pelletizing is distributed into heat accumulating type coal base rotary hearth furnace, reduction temperature is 1230 DEG C~1300 DEG C, recovery time 30min~45min, the high-temperature flue gas of rotary hearth furnace output is sent into drying grate and is contained for drying Carbon pellets;
(3) rotary hearth furnace discharging product feeding fusion apparatus is carried out slag sluicing system and produce dilval, melting of fusion apparatus Melting temperature is 1550 DEG C~1650 DEG C, melting time 50min~70min;
(4) melting slag step (3) obtained is after break process, carries out mill ore magnetic selection process, the metal after magnetic separation Iron powder returns again to the described fusion apparatus of step (3) and carries out slag sluicing system, obtains dilval.
The method of the laterite nickel ore and producing ferronickel alloy that the present invention provides, carries out staged care to raw material, makes nickel resources obtain To farthest recycling, this can alleviate the predicament of current nickel resources critical shortage.
Detailed description of the invention
For the ease of understanding the present invention, by detailed description of the invention, the present invention will be described more fully below.But It is that the present invention can realize in many different forms, however it is not limited to embodiment described herein.On the contrary, provide this The purpose of a little embodiments is to make the understanding to the disclosure more thorough comprehensively.
The method of laterite nickel ore and producing ferronickel alloy, comprises the steps:
(1) lateritic nickel ore being carried out crushing and screening, the lateritic nickel ore more than 2mm is direct cloth after allocating reduction coal, limestone into Entering rotary hearth furnace, the lateritic nickel ore less than 2mm is pressed into carbonaceous pelletizing, carbonaceous pelletizing with ball press after allocating reduction coal, limestone into Heat accumulating type coal base rotary hearth furnace it is distributed into again after drying grate is dried;
(2) carrying out high temperature fast restore in stove after carbonaceous pelletizing is distributed into heat accumulating type coal base rotary hearth furnace, reduction temperature is 1230 DEG C~1300 DEG C, recovery time 30min~45min, the high-temperature flue gas of rotary hearth furnace output is sent into drying grate and is contained for drying Carbon pellets;
(3) rotary hearth furnace discharging product feeding fusion apparatus is carried out slag sluicing system and produce dilval, melting of fusion apparatus Melting temperature is 1550 DEG C~1650 DEG C, melting time 50min~70min;
(4) melting slag step (3) obtained is after break process, carries out mill ore magnetic selection process, the metal after magnetic separation Iron powder returns again to the described fusion apparatus of step (3) and carries out slag sluicing system, obtains dilval.
Embodiment described above only have expressed the several embodiments of the present invention, and it describes more concrete and detailed, but also Therefore the restriction to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that, for those of ordinary skill in the art For, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement, these broadly fall into the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (1)

1. the method for laterite nickel ore and producing ferronickel alloy, it is characterised in that comprise the steps:
(1) lateritic nickel ore being carried out crushing and screening, the lateritic nickel ore more than 2mm is directly distributed into after allocating reduction coal, limestone into and turns End stove, the lateritic nickel ore less than 2mm is pressed into carbonaceous pelletizing with ball press after allocating reduction coal, limestone into, and carbonaceous pelletizing is through chain Comb machine is distributed into heat accumulating type coal base rotary hearth furnace after drying again;
(2) carrying out high temperature fast restore in stove after carbonaceous pelletizing is distributed into heat accumulating type coal base rotary hearth furnace, reduction temperature is 1230 DEG C~1300 DEG C, recovery time 30min~45min, the high-temperature flue gas of rotary hearth furnace output is sent into drying grate and is used for drying carbon containing ball Group;
(3) rotary hearth furnace discharging product feeding fusion apparatus is carried out slag sluicing system and produce dilval, the melted temperature of fusion apparatus Degree is 1550 DEG C~1650 DEG C, melting time 50min~70min;
(4) melting slag step (3) obtained is after break process, carries out mill ore magnetic selection process, the metal iron powder after magnetic separation The described fusion apparatus returning again to step (3) carries out slag sluicing system, obtains dilval.
CN201610784647.7A 2016-08-31 2016-08-31 Method for producing ferro-nickel alloy with nickel laterite ore Pending CN106319206A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610784647.7A CN106319206A (en) 2016-08-31 2016-08-31 Method for producing ferro-nickel alloy with nickel laterite ore

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610784647.7A CN106319206A (en) 2016-08-31 2016-08-31 Method for producing ferro-nickel alloy with nickel laterite ore

Publications (1)

Publication Number Publication Date
CN106319206A true CN106319206A (en) 2017-01-11

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107177790A (en) * 2017-04-19 2017-09-19 广西盛隆冶金有限公司 A kind of sea sand ore deposit and lateritic nickel ore high intensity cold agglomerated pellet preparation method
CN107254620A (en) * 2017-04-19 2017-10-17 广西盛隆冶金有限公司 One kind is using sea sand ore deposit and lateritic nickel ore production vanadium titanium nichrome technique

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643997A (en) * 2012-04-09 2012-08-22 北京神雾环境能源科技集团股份有限公司 Laterite-nickel ore processing method for efficiently recovering nickel resources
CN104195279A (en) * 2014-09-03 2014-12-10 中南大学 Process for preparing ferric-nickel from laterite-nickel ore

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643997A (en) * 2012-04-09 2012-08-22 北京神雾环境能源科技集团股份有限公司 Laterite-nickel ore processing method for efficiently recovering nickel resources
CN104195279A (en) * 2014-09-03 2014-12-10 中南大学 Process for preparing ferric-nickel from laterite-nickel ore

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107177790A (en) * 2017-04-19 2017-09-19 广西盛隆冶金有限公司 A kind of sea sand ore deposit and lateritic nickel ore high intensity cold agglomerated pellet preparation method
CN107254620A (en) * 2017-04-19 2017-10-17 广西盛隆冶金有限公司 One kind is using sea sand ore deposit and lateritic nickel ore production vanadium titanium nichrome technique

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Application publication date: 20170111

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