CN106318286A - Adhesive for fracture surface of connection position of rattans, and preparation method of adhesive - Google Patents
Adhesive for fracture surface of connection position of rattans, and preparation method of adhesive Download PDFInfo
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- CN106318286A CN106318286A CN201610688099.8A CN201610688099A CN106318286A CN 106318286 A CN106318286 A CN 106318286A CN 201610688099 A CN201610688099 A CN 201610688099A CN 106318286 A CN106318286 A CN 106318286A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
- C09J133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
- C09D181/04—Polysulfides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to an adhesive for a fracture surface of the connection position of rattans, and a preparation method of the adhesive. The adhesive mainly comprises polyacrylamide, thermoplastic phenolic resin, glycerinum, liquid low-molecular-weight polyamide, ethylene thiourea, epoxy resin, tetramethylthiuram tetrasulfide, polylactic acid, paraffin, epoxy chloropropane, an organic silane coupling agent, nano-silicon dioxide, zinc stearate, oxidized thermoplastic phenolic resin wax, ethyl silicon oil, calcium carbonate, glutaraldehyde, octadecanol, chloromethyloxirane, sodium hydroxide, modified epoxy resin, isoamylol, isobutanol, castor oil polyoxyethylene ether, dibutyl phthalate, ash, urea, potassium chloride, cane sugar, peanuts, dry mushrooms, forage, fresh milk, cold water, boiled water, rheum officinale, mangnolia officinalis, fructus aurantii, casein, costustoot, liquid polysulfide rubber, maltose, diacyl-oxygen heptanes dibutyltin, monochloroacetic acid and ginger juice. The adhesive prepared with the method has a good adhesion effect and no corrosion, and can enhance the strength and the toughness of a softening part.
Description
Technical field:
The present invention relates to artware and prepare adjuvant technical field, be specifically related to rattan and rattan junction section adhesive and
Its preparation method.
Background technology:
Existing rattan artware is worked out many pitch of the laps and is given a discount, and the intensity of rattan and toughness directly affect the aesthetics of artware
And ruggedness, but existing hardening agent mostly is strengthening surface, although surface increases intensity, but becomes more crisp, and toughness reduces,
The most existing hardening agent scribbles one layer on surface, non-watertight, for a long time, occurs coming off, invalid.
Summary of the invention:
The technical problem to be solved is to overcome the defect of prior art, it is provided that a kind of waterproof hardening agent of rattan
And preparation method thereof.
The technical problem to be solved realizes by the following technical solutions.
Rattan and rattan junction section adhesive, it is characterised in that: mainly include that following mass parts component is prepared from:
Polyacrylamide 100-110 part, thermoplastic phenolic resin 2-3 part, glycerol 3-5 part, liquid low-molecular polyamide
5-10 part, ethylene thiourea 2-3 part, epoxy resin 15-20 part, four sulfuration tetramethyl thiuram 2-5 part, polylactic acid 60-70 part, paraffin
15-20 part, epoxychloropropane 12-18 part, organo silane coupling agent 7-15 part, nano silicon 13-16 part, zinc stearate
15-20 part, heat of oxidation plastic phenolic resin wax 14-18 part, ethyl silicon oil 12-17 part, calcium carbonate 13-15 part, glutaraldehyde 4-10
Part, octadecanol 13-15 part, 20-30 part chloromethyloxirane, 30-40 part sodium hydroxide, 20-25 part modified epoxy,
25-30 part isoamyl alcohol, 20-25 part isobutanol, 8-10 part castor oil polyoxyethylene ether, 6-8 part dibutyl phthalate, ash
20-25 part, carbamide 12-15 part, potassium chloride 12-15 part, sucrose 100-110 part, Semen arachidis hypogaeae 50-60 part, Lentinus Edodes do 50-60 part, grass
Material 200-210 part, fresh milk 40-50 part, cold water 100-110 part, boiled water 50-60 part, Radix Et Rhizoma Rhei 5-10 part, Cortex Magnoliae Officinalis 5-10 part, Fructus Aurantii
5-10 part, casein 5-10 part, Radix Aucklandiae 5-10 part, liquid polysulphide rubber 10-20 part, maltose 60-68 part, two acyl-oxygen heptane two
Butyl tin 3-5 part, monochloroacetic acid 3-5 part, Sucus Zingberis 3-5 part.
Its preparation method includes:
Chloromethyloxirane, sodium hydroxide, modified epoxy, isoamyl alcohol, isobutanol, castor oil polyoxyethylene ether,
Dibutyl phthalate, being placed in agitator tank, mixing speed is 2500r/mim, and whipping temp is 80-90 DEG C, the time 5 points
Clock；
Take Radix Et Rhizoma Rhei, Cortex Magnoliae Officinalis, Fructus Aurantii, casein, the Radix Aucklandiae, grinds, add boiled water and distill；
While distillation, take Lentinus Edodes dry absorption distilled water, until the moisture during Lentinus Edodes is dry is to 65%-70%, stop
Only distillation, takes out Lentinus Edodes, diced；
Joining in agitator tank by diced Lentinus Edodes, soak 10 minutes, be then stirred, mixing speed is 2500r/
Mim, whipping temp is 60-70 DEG C, 10 minutes time；
Filter, take liquid one；
Meanwhile, take Semen arachidis hypogaeae grinds, with fresh milk and cold water mix, obtain mixture；
Forage is placed in case, Lentinus Edodes fourth and mixed liquor are simultaneously introduced in forage, close 24-36 hour；
Take out forage, be cut into the billet of 5-10cm；
Sprinkling Calx, carbamide and sucrose, be then stirred, mixing speed is 2500r/mim, and whipping temp is 60-70
DEG C, 10 minutes time；
Filter, take liquid two；
Select polyacrylamide, thermoplastic phenolic resin, glycerol, add reactor, be simultaneously introduced the liquid one of 60% deal,
It is mixed and made into 50% toluene solution, selects liquid low-molecular polyamide, four sulfuration tetramethyl thiuram, ethylene thioureas, be simultaneously introduced
The liquid one of 40% deal, is mixed and made into 85% toluene solution, takes the toluene solution of 50% toluene solution and 85%, adds reaction
Still heats, heating-up temperature 160 DEG C, 1 hour time, be cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, obtain hot glue；
Poly-by hot glue and epoxychloropropane, glutaraldehyde, the heat of oxidation plastic phenolic resin wax of 1/3-1/2 and 1/4-1/3
Lactic acid is put in baking oven and is dried, and then prepares biodegradable master batch after double screw extruder extrusion, water-cooled, cutting；
By organo silane coupling agent, nano silicon, zinc stearate, octadecanol mix homogeneously, it is placed in sealing bag, will
Sealing bag is placed under mud and buries, and takes out and seals bag, punctured by sealing bag after 3 days, then by the polylactic acid of 1/4-1/3 at cut
Add, after 1 hour, be placed under sunlight and be exposed to the sun 1 hour, the mixture sealed in bag is mixed homogeneously with paraffin, then through double spiral shells
Light degradation masterbatch is prepared after bar extruder extrusion, water-cooled, cutting；
Ethyl silicon oil, calcium carbonate, remaining oxidation thermoplastic is added in prepared biodegradable master batch and light degradation masterbatch
Property phenolic resin wax and polylactic acid, then with preparing mother raw material degradable after double screw extruder extrusion, water-cooled, cutting；
Mixing with liquid two, filter, strengthened agent, and at rattan mainspring cock jewel aperture, the glue after filtering spreads upon rattan
On, after cooling, scrape off excess surface glue；
In bamboo dustpan, heap puts liquid polysulphide rubber well, rapidly the most well-done maltose is watered in heap, then with the fastest
Speed is mixed popped rice, two acyl-oxygen heptane dibutyl tins, monochloroacetic acid thoroughly with maltose, and after heating 60 DEG C, uniform application is at rattan
On.
The beneficial effects of the present invention is: at rattan mainspring cock jewel aperture, the glue after filtering spreads upon on rattan, after cooling,
Scraping off excess surface glue, by injecting inside rattan by glue, in rattan Forging Process, glue plays interconnection function, increases rattan
Flexibility, it is ensured that toughness, after the surface agent of preparation is heated 60 DEG C, uniform application is on rattan, plays high waterproof action, simultaneously
Also enhance the intensity of rattan.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot
Close specific embodiment, the present invention is expanded on further.
Embodiment 1: rattan and rattan junction section adhesive, mainly includes that following mass parts component is prepared from:
Polyacrylamide 100 parts, thermoplastic phenolic resin 2 parts, glycerol 3 parts, liquid low-molecular polyamide 5 parts, ethylene
Thiourea 2 parts, epoxy resin 15 parts, four sulfuration tetramethyl thiurams 2 parts, polylactic acid 60 parts, 15 parts of paraffin, epoxychloropropane 12 parts,
Organo silane coupling agent 7 parts, nano silicon 13 parts, zinc stearate 15 parts, heat of oxidation plastic phenolic resin wax 14 parts, ethyl
Silicone oil 12 parts, calcium carbonate 13 parts, glutaraldehyde 4 parts, 13 parts, 20 parts chloromethyloxiranes of octadecanol, 30 parts of sodium hydroxide, 20 parts
Modified epoxy, 25 parts of isoamyl alcohol, 20 parts of isobutanol, 8 parts of castor oil polyoxyethylene ethers, 6 parts of dibutyl phthalates, ashes
20 parts, 12 parts of carbamide, 12 parts of potassium chloride, sucrose 100 parts, Semen arachidis hypogaeae 50 parts, Lentinus Edodes do 50 parts, forage 200 parts, fresh milk 40 parts, cold
100 parts of water, 50 parts of boiled water, Radix Et Rhizoma Rhei 5 parts, Cortex Magnoliae Officinalis 5 parts, Fructus Aurantii 5 parts, casein 5 parts, the Radix Aucklandiae 5 parts, liquid polysulphide rubber 10 parts,
Maltose 60 parts, two acyl-oxygen heptane dibutyl tins 3 parts, monochloroacetic acid 3 parts, Sucus Zingberis 3 parts.
Its preparation method includes:
Chloromethyloxirane, sodium hydroxide, modified epoxy, isoamyl alcohol, isobutanol, castor oil polyoxyethylene ether,
Dibutyl phthalate, being placed in agitator tank, mixing speed is 2500r/mim, and whipping temp is 80-90 DEG C, the time 5 points
Clock；
Take Radix Et Rhizoma Rhei, Cortex Magnoliae Officinalis, Fructus Aurantii, casein, the Radix Aucklandiae, grinds, add boiled water and distill；
While distillation, take Lentinus Edodes dry absorption distilled water, until the moisture during Lentinus Edodes is dry is to 65%-70%, stop
Only distillation, takes out Lentinus Edodes, diced；
Joining in agitator tank by diced Lentinus Edodes, soak 10 minutes, be then stirred, mixing speed is 2500r/
Mim, whipping temp is 60-70 DEG C, 10 minutes time；
Filter, take liquid one；
Meanwhile, take Semen arachidis hypogaeae grinds, with fresh milk and cold water mix, obtain mixture；
Forage is placed in case, Lentinus Edodes fourth and mixed liquor are simultaneously introduced in forage, close 24-36 hour；
Take out forage, be cut into the billet of 5-10cm；
Sprinkling Calx, carbamide and sucrose, be then stirred, mixing speed is 2500r/mim, and whipping temp is 60-70
DEG C, 10 minutes time；
Filter, take liquid two；
Select polyacrylamide, thermoplastic phenolic resin, glycerol, add reactor, be simultaneously introduced the liquid one of 60% deal,
It is mixed and made into 50% toluene solution, selects liquid low-molecular polyamide, four sulfuration tetramethyl thiuram, ethylene thioureas, be simultaneously introduced
The liquid one of 40% deal, is mixed and made into 85% toluene solution, takes the toluene solution of 50% toluene solution and 85%, adds reaction
Still heats, heating-up temperature 160 DEG C, 1 hour time, be cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, obtain hot glue；
Poly-by hot glue and epoxychloropropane, glutaraldehyde, the heat of oxidation plastic phenolic resin wax of 1/3-1/2 and 1/4-1/3
Lactic acid is put in baking oven and is dried, and then prepares biodegradable master batch after double screw extruder extrusion, water-cooled, cutting；
By organo silane coupling agent, nano silicon, zinc stearate, octadecanol mix homogeneously, it is placed in sealing bag, will
Sealing bag is placed under mud and buries, and takes out and seals bag, punctured by sealing bag after 3 days, then by the polylactic acid of 1/4-1/3 at cut
Add, after 1 hour, be placed under sunlight and be exposed to the sun 1 hour, the mixture sealed in bag is mixed homogeneously with paraffin, then through double spiral shells
Light degradation masterbatch is prepared after bar extruder extrusion, water-cooled, cutting；
Ethyl silicon oil, calcium carbonate, remaining oxidation thermoplastic is added in prepared biodegradable master batch and light degradation masterbatch
Property phenolic resin wax and polylactic acid, then with preparing mother raw material degradable after double screw extruder extrusion, water-cooled, cutting；
Mixing with liquid two, filter, strengthened agent, and at rattan mainspring cock jewel aperture, the glue after filtering spreads upon rattan
On, after cooling, scrape off excess surface glue；
In bamboo dustpan, heap puts liquid polysulphide rubber well, rapidly the most well-done maltose is watered in heap, then with the fastest
Speed is mixed popped rice, two acyl-oxygen heptane dibutyl tins, monochloroacetic acid thoroughly with maltose, and after heating 60 DEG C, uniform application is at rattan
On.
Embodiment 2: rattan and rattan junction section adhesive, it is characterised in that: mainly include following mass parts component
It is prepared from:
Polyacrylamide 110 parts, thermoplastic phenolic resin 3 parts, glycerol 5 parts, liquid low-molecular polyamide 10 parts, ethylene
Thiourea 3 parts, epoxy resin 20 parts, four sulfuration tetramethyl thiurams 5 parts, polylactic acid 70 parts, 20 parts of paraffin, epoxychloropropane 18 parts,
Organo silane coupling agent 15 parts, nano silicon 16 parts, zinc stearate 20 parts, heat of oxidation plastic phenolic resin wax 18 parts, second
Base silicone oil 17 parts, calcium carbonate 15 parts, glutaraldehyde 10 parts, 15 parts, 30 parts chloromethyloxiranes of octadecanol, 40 parts of sodium hydroxide,
25 parts of modified epoxies, 30 parts of isoamyl alcohol, 25 parts of isobutanol, 10 parts of castor oil polyoxyethylene ethers, 8 parts of phthalic acid two fourths
Ester, ash 25 parts, 15 parts of carbamide, 15 parts of potassium chloride, sucrose 110 parts, Semen arachidis hypogaeae 60 parts, Lentinus Edodes do 60 parts, forage 210 parts, fresh milk 50
Part, 110 parts of cold water, 60 parts of boiled water, Radix Et Rhizoma Rhei 10 parts, Cortex Magnoliae Officinalis 10 parts, Fructus Aurantii 10 parts, casein 10 parts, the Radix Aucklandiae 10 parts, liquid polysulfide
Rubber 20 parts, maltose 68 parts, two acyl-oxygen heptane dibutyl tins 5 parts, monochloroacetic acid 5 parts, Sucus Zingberis 5 parts.
Its preparation method includes:
Chloromethyloxirane, sodium hydroxide, modified epoxy, isoamyl alcohol, isobutanol, castor oil polyoxyethylene ether,
Dibutyl phthalate, being placed in agitator tank, mixing speed is 2500r/mim, and whipping temp is 80-90 DEG C, the time 5 points
Clock；
Take Radix Et Rhizoma Rhei, Cortex Magnoliae Officinalis, Fructus Aurantii, casein, the Radix Aucklandiae, grinds, add boiled water and distill；
While distillation, take Lentinus Edodes dry absorption distilled water, until the moisture during Lentinus Edodes is dry is to 65%-70%, stop
Only distillation, takes out Lentinus Edodes, diced；
Joining in agitator tank by diced Lentinus Edodes, soak 10 minutes, be then stirred, mixing speed is 2500r/
Mim, whipping temp is 60-70 DEG C, 10 minutes time；
Filter, take liquid one；
Meanwhile, take Semen arachidis hypogaeae grinds, with fresh milk and cold water mix, obtain mixture；
Forage is placed in case, Lentinus Edodes fourth and mixed liquor are simultaneously introduced in forage, close 24-36 hour；
Take out forage, be cut into the billet of 5-10cm；
Sprinkling Calx, carbamide and sucrose, be then stirred, mixing speed is 2500r/mim, and whipping temp is 60-70
DEG C, 10 minutes time；
Filter, take liquid two；
Select polyacrylamide, thermoplastic phenolic resin, glycerol, add reactor, be simultaneously introduced the liquid one of 60% deal,
It is mixed and made into 50% toluene solution, selects liquid low-molecular polyamide, four sulfuration tetramethyl thiuram, ethylene thioureas, be simultaneously introduced
The liquid one of 40% deal, is mixed and made into 85% toluene solution, takes the toluene solution of 50% toluene solution and 85%, adds reaction
Still heats, heating-up temperature 160 DEG C, 1 hour time, be cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, obtain hot glue；
Poly-by hot glue and epoxychloropropane, glutaraldehyde, the heat of oxidation plastic phenolic resin wax of 1/3-1/2 and 1/4-1/3
Lactic acid is put in baking oven and is dried, and then prepares biodegradable master batch after double screw extruder extrusion, water-cooled, cutting；
By organo silane coupling agent, nano silicon, zinc stearate, octadecanol mix homogeneously, it is placed in sealing bag, will
Sealing bag is placed under mud and buries, and takes out and seals bag, punctured by sealing bag after 3 days, then by the polylactic acid of 1/4-1/3 at cut
Add, after 1 hour, be placed under sunlight and be exposed to the sun 1 hour, the mixture sealed in bag is mixed homogeneously with paraffin, then through double spiral shells
Light degradation masterbatch is prepared after bar extruder extrusion, water-cooled, cutting；
Ethyl silicon oil, calcium carbonate, remaining oxidation thermoplastic is added in prepared biodegradable master batch and light degradation masterbatch
Property phenolic resin wax and polylactic acid, then with preparing mother raw material degradable after double screw extruder extrusion, water-cooled, cutting；
Mixing with liquid two, filter, strengthened agent, and at rattan mainspring cock jewel aperture, the glue after filtering spreads upon rattan
On, after cooling, scrape off excess surface glue；
In bamboo dustpan, heap puts liquid polysulphide rubber well, rapidly the most well-done maltose is watered in heap, then with the fastest
Speed is mixed popped rice, two acyl-oxygen heptane dibutyl tins, monochloroacetic acid thoroughly with maltose, and after heating 60 DEG C, uniform application is at rattan
On.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The technology of the industry
Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and
Equivalent defines.
Claims (2)
1. rattan and rattan junction section adhesive, it is characterised in that: mainly include that following mass parts component is prepared from:
Polyacrylamide 100-110 part, thermoplastic phenolic resin 2-3 part, glycerol 3-5 part, liquid low-molecular polyamide 5-10
Part, ethylene thiourea 2-3 part, epoxy resin 15-20 part, four sulfuration tetramethyl thiuram 2-5 part, polylactic acid 60-70 part, paraffin 15-
20 parts, epoxychloropropane 12-18 part, organo silane coupling agent 7-15 part, nano silicon 13-16 part, zinc stearate 15-20
Part, heat of oxidation plastic phenolic resin wax 14-18 part, ethyl silicon oil 12-17 part, calcium carbonate 13-15 part, glutaraldehyde 4-10 part, ten
Eight alcohol 13-15 parts, 20-30 part chloromethyloxirane, 30-40 part sodium hydroxide, 20-25 part modified epoxy, 25-30 part
Isoamyl alcohol, 20-25 part isobutanol, 8-10 part castor oil polyoxyethylene ether, 6-8 part dibutyl phthalate, ash 20-25 part,
Carbamide 12-15 part, potassium chloride 12-15 part, sucrose 100-110 part, Semen arachidis hypogaeae 50-60 part, Lentinus Edodes do 50-60 part, forage 200-210
Part, fresh milk 40-50 part, cold water 100-110 part, boiled water 50-60 part, Radix Et Rhizoma Rhei 5-10 part, Cortex Magnoliae Officinalis 5-10 part, Fructus Aurantii 5-10 part, dry
Casein 5-10 part, Radix Aucklandiae 5-10 part, liquid polysulphide rubber 10-20 part, maltose 60-68 part, two acyl-oxygen heptane dibutyl tin 3-5
Part, monochloroacetic acid 3-5 part, Sucus Zingberis 3-5 part.
Rattan the most according to claim 1 and rattan junction section adhesive, it is characterised in that: its preparation method bag
Include:
Chloromethyloxirane, sodium hydroxide, modified epoxy, isoamyl alcohol, isobutanol, castor oil polyoxyethylene ether, adjacent benzene
Dibutyl carboxylic acid, being placed in agitator tank, mixing speed is 2500r/mim, and whipping temp is 80-90 DEG C, 5 minutes time；
Take Radix Et Rhizoma Rhei, Cortex Magnoliae Officinalis, Fructus Aurantii, casein, the Radix Aucklandiae, grinds, add boiled water and distill；
While distillation, take Lentinus Edodes dry absorption distilled water, until the moisture during Lentinus Edodes is dry is to 65%-70%, stop steaming
Evaporate, take out Lentinus Edodes, diced；
Joining in agitator tank by diced Lentinus Edodes, soak 10 minutes, be then stirred, mixing speed is 2500r/mim,
Whipping temp is 60-70 DEG C, 10 minutes time；
Filter, take liquid one；
Meanwhile, take Semen arachidis hypogaeae grinds, with fresh milk and cold water mix, obtain mixture；
Forage is placed in case, Lentinus Edodes fourth and mixed liquor are simultaneously introduced in forage, close 24-36 hour；
Take out forage, be cut into the billet of 5-10cm；
Sprinkling Calx, carbamide and sucrose, be then stirred, mixing speed is 2500r/mim, and whipping temp is 60-70 DEG C, time
Between 10 minutes；
Filter, take liquid two；
Select polyacrylamide, thermoplastic phenolic resin, glycerol, add reactor, be simultaneously introduced the liquid one of 60% deal, mixing
Make 50% toluene solution, select liquid low-molecular polyamide, four sulfuration tetramethyl thiuram, ethylene thioureas, be simultaneously introduced 40%
The liquid one of deal, is mixed and made into 85% toluene solution, takes the toluene solution of 50% toluene solution and 85%, adds in reactor
Heating, heating-up temperature 160 DEG C, 1 hour time, it is cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, obtain hot glue；
By hot glue and epoxychloropropane, glutaraldehyde, the heat of oxidation plastic phenolic resin wax of 1/3-1/2 and the polylactic acid of 1/4-1/3
Put in baking oven and dry, after double screw extruder extrusion, water-cooled, cutting, then prepare biodegradable master batch；
By organo silane coupling agent, nano silicon, zinc stearate, octadecanol mix homogeneously, it is placed in sealing bag, will seal
Bag is placed under mud and buries, and takes out and seals bag, punctured by sealing bag, then added at cut by the polylactic acid of 1/4-1/3 after 3 days
Enter, after 1 hour, be placed under sunlight and be exposed to the sun 1 hour, the mixture sealed in bag is mixed homogeneously with paraffin, then through twin screw
Light degradation masterbatch is prepared after extruder extrusion, water-cooled, cutting；
Ethyl silicon oil, calcium carbonate, remaining heat of oxidation plasticity phenol is added in prepared biodegradable master batch and light degradation masterbatch
Urea formaldehyde wax and polylactic acid, then with preparing mother raw material degradable after double screw extruder extrusion, water-cooled, cutting；
Mixing with liquid two, filter, strengthened agent, and at old bamboo mainspring cock jewel aperture, the glue after filtering spreads upon old age
In bamboo cane, after cooling, scrape off excess surface glue；
In bamboo dustpan, heap puts liquid polysulphide rubber well, rapidly the most well-done maltose is watered in heap, then with the fastest speed
Popped rice, two acyl-oxygen heptane dibutyl tins, monochloroacetic acid are mixed thoroughly with maltose, and after heating 60 DEG C, uniform application is in old bamboo cane
On.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107692616A (en) * | 2017-11-24 | 2018-02-16 | 广西博白焕发工艺品有限公司 | A kind of method of rattan softening |
| CN109047774A (en) * | 2018-08-22 | 2018-12-21 | 扬州海昌新材股份有限公司 | A kind of method for sealing of injection moulding stainless steel products |
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| CN102417783A (en) * | 2011-10-10 | 2012-04-18 | 漳州市奈特新型建材有限责任公司 | Waterproof/sealing paint with aqueous resin as main body |
| CN104293271A (en) * | 2014-09-28 | 2015-01-21 | 王璐 | Novel solid wood adhesive |
| CN104861899A (en) * | 2015-05-30 | 2015-08-26 | 张家港市山牧新材料技术开发有限公司 | Adhesive composition for plywood and preparation process of adhesive composition |
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| CN101195735A (en) * | 2007-12-28 | 2008-06-11 | 深圳市神竹科技有限公司 | Fireproof glue and method for producing the same |
| CN102417783A (en) * | 2011-10-10 | 2012-04-18 | 漳州市奈特新型建材有限责任公司 | Waterproof/sealing paint with aqueous resin as main body |
| CN104293271A (en) * | 2014-09-28 | 2015-01-21 | 王璐 | Novel solid wood adhesive |
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| CN107692616A (en) * | 2017-11-24 | 2018-02-16 | 广西博白焕发工艺品有限公司 | A kind of method of rattan softening |
| CN109047774A (en) * | 2018-08-22 | 2018-12-21 | 扬州海昌新材股份有限公司 | A kind of method for sealing of injection moulding stainless steel products |
| CN109047774B (en) * | 2018-08-22 | 2021-01-08 | 扬州海昌新材股份有限公司 | Hole sealing method for injection molding stainless steel product |
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Application publication date: 20170111 |