CN106318159A - Scratching-resistant mirror and preparation method thereof - Google Patents
Scratching-resistant mirror and preparation method thereof Download PDFInfo
- Publication number
- CN106318159A CN106318159A CN201610699041.3A CN201610699041A CN106318159A CN 106318159 A CN106318159 A CN 106318159A CN 201610699041 A CN201610699041 A CN 201610699041A CN 106318159 A CN106318159 A CN 106318159A
- Authority
- CN
- China
- Prior art keywords
- layer
- copper
- mirror
- scratch
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000006748 scratching Methods 0.000 title abstract 4
- 230000002393 scratching effect Effects 0.000 title abstract 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 70
- 229910052709 silver Inorganic materials 0.000 claims abstract description 70
- 239000004332 silver Substances 0.000 claims abstract description 70
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 65
- 229910052802 copper Inorganic materials 0.000 claims abstract description 65
- 239000010949 copper Substances 0.000 claims abstract description 65
- 239000011521 glass Substances 0.000 claims abstract description 48
- 239000000758 substrate Substances 0.000 claims abstract description 43
- 238000004140 cleaning Methods 0.000 claims abstract description 17
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims abstract description 13
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000001119 stannous chloride Substances 0.000 claims abstract description 13
- 235000011150 stannous chloride Nutrition 0.000 claims abstract description 13
- 238000007747 plating Methods 0.000 claims abstract description 11
- 239000002987 primer (paints) Substances 0.000 claims abstract description 10
- 238000000151 deposition Methods 0.000 claims abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 44
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 42
- 239000011248 coating agent Substances 0.000 claims description 37
- 238000000576 coating method Methods 0.000 claims description 37
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 27
- 239000003822 epoxy resin Substances 0.000 claims description 24
- 229920000647 polyepoxide Polymers 0.000 claims description 24
- 230000003678 scratch resistant effect Effects 0.000 claims description 24
- 239000004408 titanium dioxide Substances 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 239000000049 pigment Substances 0.000 claims description 18
- 229920000180 alkyd Polymers 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000012752 auxiliary agent Substances 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 claims description 11
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 11
- 239000011863 silicon-based powder Substances 0.000 claims description 11
- 239000000454 talc Substances 0.000 claims description 11
- 229910052623 talc Inorganic materials 0.000 claims description 11
- 235000012222 talc Nutrition 0.000 claims description 11
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 10
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 claims description 10
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 10
- ZWLIYXJBOIDXLL-UHFFFAOYSA-N decanedihydrazide Chemical compound NNC(=O)CCCCCCCCC(=O)NN ZWLIYXJBOIDXLL-UHFFFAOYSA-N 0.000 claims description 9
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 4
- 206010070834 Sensitisation Diseases 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 4
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 4
- 230000008313 sensitization Effects 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical class CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 claims 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims 1
- 230000008021 deposition Effects 0.000 claims 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical group OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 230000037452 priming Effects 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 12
- 238000001035 drying Methods 0.000 abstract description 11
- 230000003213 activating effect Effects 0.000 abstract 1
- 239000005002 finish coating Substances 0.000 abstract 1
- 238000005498 polishing Methods 0.000 abstract 1
- 230000001235 sensitizing effect Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 16
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 12
- 230000007797 corrosion Effects 0.000 description 11
- 229910021529 ammonia Inorganic materials 0.000 description 10
- 229920005749 polyurethane resin Polymers 0.000 description 10
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 10
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- BSRDNMMLQYNQQD-UHFFFAOYSA-N iminodiacetonitrile Chemical group N#CCNCC#N BSRDNMMLQYNQQD-UHFFFAOYSA-N 0.000 description 8
- 239000012948 isocyanate Substances 0.000 description 7
- 150000002513 isocyanates Chemical class 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000001103 potassium chloride Substances 0.000 description 6
- 235000011164 potassium chloride Nutrition 0.000 description 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000011630 iodine Substances 0.000 description 5
- 229910052740 iodine Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229910001961 silver nitrate Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 238000007790 scraping Methods 0.000 description 4
- 239000000176 sodium gluconate Substances 0.000 description 4
- 235000012207 sodium gluconate Nutrition 0.000 description 4
- 229940005574 sodium gluconate Drugs 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910000004 White lead Inorganic materials 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 150000001621 bismuth Chemical class 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical group CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- XUSLDCYELHANDT-UHFFFAOYSA-N bismuth;dodecanoic acid Chemical compound [Bi].CCCCCCCCCCCC(O)=O XUSLDCYELHANDT-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910001607 magnesium mineral Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003405 preventing effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- UPMFZISCCZSDND-JJKGCWMISA-M sodium gluconate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O UPMFZISCCZSDND-JJKGCWMISA-M 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G1/00—Mirrors; Picture frames or the like, e.g. provided with heating, lighting or ventilating means
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/3663—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties specially adapted for use as mirrors
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/48—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
- C03C2217/485—Pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to the technical field of mirrors, in particular to a scratching-resistant mirror and a preparation method thereof. The mirror comprises a glass substrate, a silver layer, a copper layer, a primer layer and a finish layer. The preparation method comprises the following steps; polishing and cleaning the surface of the glass substrate; sensitizing by using a stannous chloride solution, and activating by using a palladium chloride solution; depositing the silver layer by using a silver plating solution, and drying after cleaning; then depositing the copper layer, and drying after cleaning; and applying primer coating to form the primer layer, drying, applying finish coating to form the finish layer, and drying to obtain the scratching-resistant mirror. Glass is taken as the substrate of the mirror, anti-shear strength of the various layers is high, and the primer layer and the finish layer can protect the silver layer and the copper layer well. The mirror has excellent anti-corrosion property, mechanical durability and scratching resistance, and is firm and durable. A preparation process of the mirror is simple, and the prepared product is stable in quality and long in service life.
Description
Technical field
The present invention relates to mirror technical field, particularly relate to a kind of scratch-resistant mirror and preparation method thereof.
Background technology
Mirror is a kind of smooth surface, and has the article of reflection light ability, and modal mirror is plane mirror, often
Utilized by people and arrange appearance.Existing mirror is typically silver-plated at the back side of glass substrate, and silver-plated glass mirror has height
Visible reflectance.But after silver-plated mirror uses a period of time, the minute surface of mirror and the enamelled coating not scratch-resistant at the mirror back side,
Easily cause mirror surface image smudgy, affect good looking appearance degree and the using effect of mirror, thus shorten service life, increase
Cost.Therefore, improving and design the mirror of scratch-resistant, improve service life, tool is of great significance.
Summary of the invention
The technical problem to be solved is to provide one and is difficult to blackening, has the mirror of good Corrosion Protection,
Its preparation method technique is simple, the constant product quality of preparation.
For achieving the above object, the technical solution used in the present invention is as follows.
A kind of scratch-resistant mirror, the silver layer including glass substrate, being covered in the glass substrate back side, is covered in silver layer surface and side
The layers of copper in face, it is covered in layers of copper surface and the prime coat of side, is covered in the top coat layer of primer coat surface and side.
Wherein, the coating that described prime coat uses is made up of the component of following weight portion:
Alkyd resin 40-60 part
Bisphenol A type epoxy resin 10-20 part
Firming agent 1-4 part
Ethyl acetate 10-20 part
Anticorrosive auxiliary agent 0.5-2 part
Pigment 40-60 part
Methyl ethyl ketone oxime 1-4 part.
Alkyd resin is formed by polyhydric alcohol, phthalic anhydride and fatty acid or oil (fatty acid triglyceride) condensation polymerization
Oily modified polyester resin.After alkyd resin film-forming, glossy and toughness, adhesive force is strong, and have good wearability,
Weatherability and insulating properties etc..
Bisphenol A type epoxy resin is thermoplastic resin, but has thermosetting, can be with multiple firming agent, catalyst and interpolation
Agent forms the solidfied material of multiple excellent performance, and hardness is high, does not the most produce little molecule volatile matter during solidification, can low pressure molding,
Can be dissolved in multi-solvents, the surface of metal and nonmetallic materials is had excellent adhesive strength, solidfied material has the highest intensity,
Corrosion resistance, dielectric properties are good, and deformation retract rate is little, product size good stability, to alkali and major part solvent-stable.
Ethyl acetate is colourless transparent liquid, hypotoxicity, has the dissolubility of excellence, quick-drying, forms body at prime coat
In system, the compatibility of each component, the viscosity of regulation prime coat compositional system can be promoted.
Methyl ethyl ketone oxime with dissolve in most organic most solvents such as alcohol, ether, ketone, hydrocarbon, have relatively with metal ion
Good complexing, can stabilizing polyol acid resin, bisphenol A type epoxy resin and polyurethane resin, prevent skinning, prevent prime coat from
Mirror comes off.
Alkyd resin, epoxy resin and polyurethane resin are matched by the present invention, and add other auxiliary agents, have excellence
Corrosion resistance, durability and adhesion strength, heat-resist, there is good mechanical performance and dimensional stability, coating good fluidity,
Layers of copper surface can be uniformly distributed in, silver layer and layers of copper can be realized good protection.
Wherein, the oil mass of described alkyd resin is 40-55%, and phthalic anhydride amount is 30-35%, does solid work very fast, glossiness and weather-proof
Property fine, can Self-dry, with layers of copper, there is good adhesion strength, the compatibility with other components of composition prime coat is good,
The mechanical performance that prime coat is good can be given.
Wherein, described anticorrosive auxiliary agent is Iminodiacetonitrile 1,1'-Imidodiacetonitrile.Iminodiacetonitrile 1,1'-Imidodiacetonitrile can be passivated layers of copper, reduces outer bound pair copper
The corrosion of layer, increases the cohesive of layers of copper and prime coat, and Iminodiacetonitrile 1,1'-Imidodiacetonitrile is unleaded anticorrosive auxiliary agent simultaneously, can less lead pair
The pollution of environment.
Wherein, described firming agent is sebacic dihydrazide or dicyandiamide.It is excellent that sebacic dihydrazide can give prime coat coating
Good pliability, resistance to water, against weather, anticorrosive property, hardening time is short, water-tolerant, adhesive strength high；Isocyanates is tied
Containing unsaturated bond in structure, therefore having high activity, easily the organic or inorganic thing with some band active groups reacts, and generates poly-
Urethane elastomer.The physical and chemical performance of the coating that prime coat uses is had a great impact by firming agent, the firming agent of the present invention
Combination can produce cross-linking reaction with resin combination, promotes the solidification of coating.
Wherein, described pigment includes the component of following weight portion:
Talcum 20-30 part
Muscovitum 10-20 part
Calcium molybdate 3-8 part
Bismuth hydrate. 2-6 part
Titanium dioxide 5-10 part.
Talcum is hydrothermal alteration mineral, and rich magnesium mineral often becomes Talcum through hydrothermal alteration, and for silicate mineral, it is the softest
And having satiny feel, Pulvis Talci can improve prime coat coating system abrasion resistance and greasy property.Muscovitum has very
High insulation, heat-insulating property, chemical stability is good, has anti-strong acid, highly basic and anti-pressure ability, can improve prime coat coating system
Chemical stability and insulating properties.Talcum and Muscovitum collectively as filler pigment, good dispersion in system, improve prime coat
Gloss.
Calcium molybdate matches with Bismuth hydrate. as rust resisting pigment, favorable rust preventing effect, can improve the corrosion resistant of prime coat coating
Erosion property, when the content of calcium molybdate and Bismuth hydrate. is too low simultaneously, corrosion resistance effect promoting is inconspicuous, during too high levels, molybdic acid
Calcium and Bismuth hydrate. difficulties in dispersion in system, and loss of adhesion with layers of copper.
Titanium dioxide is the amphoteric oxide of white solid or powder, is a kind of white inorganic pigment, has nontoxic,
Good opacity, optimal whiteness and brightness, it is considered to be current a kind of Chinese white that performance is best in the world, have good
Good covering power, similar with white lead, but unlike white lead can blackening；It has again the persistency that zinc white is the same, and its adhesion is strong,
Fusing point is high, has been difficult to chemical change, and titanium dioxide has preferable ultraviolet masking action simultaneously, improves the uvioresistant of prime coat
Ability.
Wherein, the thickness of described silver layer is 60-120nm, and the thickness of layers of copper is 20-40nm.By the selection to thickness, make
Silver layer makes, as emission layer, the visible reflectance that mirror is high, layers of copper be the prime coat of silver layer be also the supplemental layers in reflecting layer,
Also it is the bridge layer of silver layer and enamelled coating simultaneously.The visible reflectance of the present invention is more than 85%.
Wherein, the thickness of described prime coat is 40-70 μm, and the thickness of top coat layer is 30-60 μm.Prime coat and top coat layer can
Layers of copper and silver layer are realized good protection, and corrosion resistance is strong, and its edge not cracky makes layers of copper and silver layer appear and causes black surround,
The anti-scratch performance of top coat layer is good, big with the adhesive force of prime coat.
Wherein, the coating that described top coat layer uses is made up of the component of following weight portion:
Urethane acrylate 40-60 part
Bisphenol A type epoxy resin 5-10 part
Titanium dioxide 10-20 part
Silicon powder 5-10 part
γ-aminopropyl triethoxysilane 2-5 part
BTA 0.5-2 part
Fluorinated diphenyl titanium cyclopentadienyl 0.2-1 part
Antioxidant 0.2-1 part.
Containing acrylic-functional and amino-formate bond in the molecule of urethane acrylate, the adhesive after solidification has poly-
The high-wearing feature of urethane, adhesion, pliability, high-peeling strength and excellent resistance to low temperature and polyacrylate are remarkable
Optical property and weatherability.Urethane acrylate and bisphenol A type epoxy resin match, and have good mechanical strength and resistance to
Corrosivity.
Lauric acid bismuth is to be prepared by lauric acid and bismuth salt after chemical reaction, has polyurethane resin and is preferably catalyzed effect
Really, and bismuth salt is less to the injury of human body, is referred to as green metal, may replace lead hydrargyrum and the stannum abolished by legislation；Have more
Good stability to hydrolysis resistance, reduces the selectivity reacted with water, in aqueous polyurethane resin dispersion liquid, reduces water and NCO base
Side reaction, make the mechanical property of top coat layer more preferably, induction time is short.
Benzotriazole is good UV absorbers, can match with titanium dioxide, gives good top coat layer excellent
Uvioresistant performance, be simultaneously introduced in polyurethane and bisphenol A type epoxy resin system and can prevent copper and alloy corrosion blackening thereof,
Antirust for copper, silver, zinc, aluminum etc.；Titanium dioxide can be as top coat layer filler, Chinese white and UV absorbers.
γ-aminopropyl triethoxysilane is can to improve the dispersibility of titanium dioxide and improve glass, aluminum, ferrous metal
Cohesive, can improve, strengthen the physical and mechanical properties such as the dry and wet state bending strength of top coat layer, comprcssive strength, shear strength and
Hygrometric state electric property, and improve titanium dioxide and silicon powder wettability in the polymer and dispersibility.
Silicon powder is many through broken, ball milling, flotation, pickling purification, high purity water process etc. by natural quartz or vitreous silica
The micropowder of road processes, is a kind of Inorganic Non-metallic Materials nontoxic, tasteless, free of contamination, possesses temperature tolerance good, acidproof
The excellent performances such as caustic corrosion, poor thermal conductivity, high insulation, low bulk, stable chemical performance, hardness are big, can reduce epoxy resin
The exothermic peak temperature of curing reaction, reduces linear expansion coefficient and the shrinkage factor of top coat layer, thus eliminates the internal stress of top coat layer,
Prevent cracking；Through the silicon powder that γ-aminopropyl triethoxysilane processes, various types of resins is had good wellability, adsorptivity
Can be good, easily mix, without clustering phenomena, improve the wearability of top coat layer and anti-scratch ability.
Fluorinated diphenyl titanium cyclopentadienyl has prominent space charge force, storage stability and hypotoxicity, and its absorbing wavelength is prolonged
Extending 500nm, have bigger absorption in visible region, again because of the photobleaching effect under titanium cyclopentadienyl illumination, glued membrane yellowness index is little, and
Deeply-curing is good, beneficially top coat layer solidification, and fixed line efficiency is high.
Wherein, described antioxidant is double (2,2,6, the 6-tetramethyl-4-hydroxy piperidine) ester of decanedioic acid.
Double (2,2,6, the 6-tetramethyl-4-hydroxy piperidine) ester of decanedioic acid be a kind of efficient hindered amine light stabilizer, can be with
Benzotriazole use, have good cooperative effect, the light stability of top coat layer can be made to be greatly improved, and have good thermostability
With resistance to extractibility.
The top coat layer of the present invention and prime coat have good bonding strength, wearability and scraping and wiping resistance performance, simultaneously with soft
The aliphatic urethane acrylate major ingredient that toughness is good, and coordinate bisphenol A type epoxy resin to use, make top coat layer pliability and
Wearability is good.
The present invention also provides for the preparation method of a kind of scratch-resistant mirror, comprises the following steps:
Step 1, provide a glass substrate, glass baseplate surface is polished and cleans；
Step 2, use stannous chloride solution carry out sensitization to the back side of glass substrate, then use palladium chloride solution on the same face
Activate；
The back side of step 3, after activation glass substrate uses silver plating solution depositing silver layers, is dried after cleaning；Then sulphuric acid is used
Copper liquor copper layer, is dried after cleaning；
Step 4, it is coated with or spray-applied primer coating in the surface of layers of copper and side, forms prime coat, be dried, obtain scratch-resistant
Mirror.
Wherein, in described step 2, the concentration of stannous chloride solution is every liter of stannous chloride solution chloride containing stannous 30-
70g, hydrochloric acid 20-40mL；The concentration of palladium chloride solution is every liter of palladium chloride solution chloride containing palladium 0.4-0.8g, hydrochloric acid 2-5 mL.
Wherein, in described step 3, silver plating solution includes silver ammino solution and reducing solution, and silver ammino solution includes following concentration
Component: silver nitrate 1.5-2g/L, sodium hydroxide 1.5-2g/L, ammonia 0.8-1 g/L, iodine 0.01-0. 02g/L, potassium chloride 2-5
G/L, gelatin 6-10 g/L；Reducing solution includes the component of following mass percent: sodium gluconate 9-10%, sodium hydroxide 18-
22%, ammonia 2-4%, surplus is water.By same to silver ammino solution while of silver ammino solution and reducing solution and a certain amount of described reducing solution
In time, spray on the glass substrate that surface is activated, and through the redox reaction of 2-3min, the silver ion in silver ammino solution is also
Former one-tenth argent, is deposited on glass baseplate surface formation silver layer.The silver-colored utilization rate of silver plating solution of the present invention is high, potassium chloride and bright
The addition of glue improves the adhesive force of silver layer and glass substrate.
Wherein, in described step 3, deionized water after glass substrate copper layer, is used to clean, at 60-70 DEG C of bar after cleaning
Dry under part, subsequently into heating workshop section, make the temperature of silver layer and layers of copper reach more than 200 DEG C.Silver layer and copper is made by heating
Layer is finer and close, and the combination with glass substrate is more firm, makes coating mobility in layers of copper more preferable simultaneously, is more evenly distributed,
Surface and side is made all to obtain good protection.
The beneficial effects of the present invention is: the mirror of the present invention is using glass as substrate, the shear strength between each layer
Silver layer, layers of copper can be carried out good protection by height, prime coat and top coat layer, and it is durable that mirror has the anticorrosive property of excellence, machinery
Property and scraping and wiping resistance performance, durable；The preparation technology of mirror is simple, and the constant product quality of preparation, service life is long.
Accompanying drawing explanation
Utilize accompanying drawing that invention is described further, but the embodiment in accompanying drawing do not constitute any limitation of the invention,
For those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain it according to the following drawings
Its accompanying drawing.
Fig. 1 is the profile of scratch-resistant mirror of the present invention.
Reference includes:
1-glass substrate 2-silver layer
3-layers of copper 4-prime coat
5-top coat layer.
Detailed description of the invention
The present invention is further illustrated below in conjunction with the accompanying drawings, sees accompanying drawing 1.
Embodiment 1
As it is shown in figure 1, a kind of scratch-resistant mirror, the silver layer 2 including glass substrate 1, being covered in glass substrate 1 back side, it is covered in silver
Layer 2 surface and the layers of copper 3 of side, it is covered in the prime coat 4 of layers of copper 3 surface and side, is covered in prime coat 4 surface and side
Top coat layer 4.
Wherein, the coating that described prime coat 4 uses is made up of the component of following weight portion:
Alkyd resin 50 parts
Bisphenol A type epoxy resin 15 parts
2 parts of firming agent
Ethyl acetate 15 parts
Anticorrosive auxiliary agent 1 part
Pigment 50 parts
Methyl ethyl ketone oxime 2 parts.
Wherein, the oil mass of described alkyd resin is 40-55%, and phthalic anhydride amount is 30-35%.The alkyd resin of the present invention uses
Drying oil alkyd resin, the molecular weight of drying oil is relatively low, and forming macromole to cross-link through multistep, drying oil synthesize alkyd
After resin, be equivalent to add the molecular weight of drying oil, it is only necessary to less crosslinking points just curable film-forming, its paint film property is bright
Aobvious being better than drying oil paint film, it is strong that the resin formed with epoxy resin, polyurethane resin combination has good corrosion resistance, bonding
Degree and mechanical strength.
Wherein, described anticorrosive auxiliary agent is Iminodiacetonitrile 1,1'-Imidodiacetonitrile.
Wherein, described firming agent be weight ratio be sebacic dihydrazide and the isocyanates of 1.8:1.
Wherein, described pigment includes the component of following weight portion:
25 parts of Talcum
15 parts of Muscovitum
Calcium molybdate 6 parts
Bismuth hydrate. 4 parts
Titanium dioxide 8 parts.
Wherein, the coating that described top coat layer 5 uses is made up of the component of following weight portion:
Urethane acrylate 50 parts
Bisphenol A type epoxy resin 8 parts
Titanium dioxide 15 parts
Silicon powder 8 parts
γ-aminopropyl triethoxysilane 4 parts
BTA 1 part
Fluorinated diphenyl titanium cyclopentadienyl 0.6 part
Antioxidant 0.6 part.
Wherein, described antioxidant is double (2,2,6, the 6-tetramethyl-4-hydroxy piperidine) ester of decanedioic acid.
The thickness of described silver layer 2 is 90nm, and the thickness of layers of copper 3 is 30nm.
The thickness of described prime coat 4 is 60 μm, and the thickness of top coat layer 5 is 50 μm.
The present invention also provides for the preparation method of a kind of scratch-resistant mirror, comprises the following steps:
Step 1, provide a glass substrate 1, to glass substrate 1 surface finish and clean；
Step 2, use stannous chloride solution carry out sensitization to the back side of glass substrate 1, then use Palladous chloride. molten on the same face
Liquid activates；The concentration of stannous chloride solution is every liter of stannous chloride solution chloride containing stannous 50g, hydrochloric acid 30mL；Palladous chloride.
The concentration of solution is every liter of palladium chloride solution chloride containing palladium 0.5g, hydrochloric acid 3 mL；
The back side of step 3, after activation glass substrate 1 uses silver plating solution depositing silver layers 2, is dried after cleaning；Then sulfur is used
Acid copper liquor copper layer 3, is dried after cleaning；Silver plating solution includes silver ammino solution and reducing solution, and silver ammino solution includes following
The component of concentration: silver nitrate 1.8g/L, sodium hydroxide 1.8g/L, ammonia 0.9 g/L, iodine 0.015g/L, potassium chloride 4 g/L, bright
Glue 8 g/L；Reducing solution includes the component of following mass percent: sodium gluconate 9.5%, sodium hydroxide 20%, ammonia 3%,
Surplus is water.The step of copper layer 3 uses conventional method to carry out；
Step 4, being coated with or spray-applied primer layer 4 coating in layers of copper 3, form prime coat 4, be dried, coating or spray-coating surface enamelled coating 5 are coated with
Material, is dried, obtains scratch-resistant mirror.
In described step 3, use deionized water to clean after glass substrate 1 copper layer 3, dry under the conditions of 60 DEG C after cleaning
Dry, subsequently into heating workshop section, make the temperature of silver layer 2 and layers of copper 3 reach more than 200 DEG C.
In the present embodiment, the shear strength between silver layer 2 and glass substrate 1, and layers of copper 3 and prime coat 4 is all higher than
16N/cm2, the shear strength of prime coat 4 and top coat layer 5 is more than 20N/cm2。
Embodiment 2
As it is shown in figure 1, a kind of scratch-resistant mirror, the silver layer 2 including glass substrate 1, being covered in glass substrate 1 back side, it is covered in silver
Layer 2 surface and the layers of copper 3 of side, it is covered in the prime coat 4 of layers of copper 3 surface and side, is covered in prime coat 4 surface and side
Top coat layer 5.
The coating that described prime coat 4 uses is made up of the component of following weight portion:
Alkyd resin 40 parts
Bisphenol A type epoxy resin 20 parts
Polyurethane resin 8 parts
1 part of firming agent
Ethyl acetate 10 parts
Anticorrosive auxiliary agent 0.5 part
Pigment 45 parts
Methyl ethyl ketone oxime 1 part.
Wherein, described firming agent be weight ratio be sebacic dihydrazide and the isocyanates of 2:1.
Wherein, described pigment includes the component of following weight portion:
20 parts of Talcum
20 parts of Muscovitum
Calcium molybdate 3 parts
Bismuth hydrate. 6 parts
Titanium dioxide 10 parts.
Wherein, the coating that described top coat layer 5 uses is made up of the component of following weight portion:
Urethane acrylate 40 parts
Bisphenol A type epoxy resin 10 parts
Titanium dioxide 10 parts
Silicon powder 10 parts
γ-aminopropyl triethoxysilane 2 parts
BTA 0.5 part
Fluorinated diphenyl titanium cyclopentadienyl 0.2 part
Antioxidant 1 part.
Wherein, the thickness of described silver layer 2 is 60nm, and the thickness of layers of copper 3 is 20nm.
Wherein, the thickness of described prime coat 4 is 40 μm, and the thickness of top coat layer 5 is 40 μm.
Step 1, provide a glass substrate 1, to glass substrate 1 surface finish and clean；
Step 2, use stannous chloride solution carry out sensitization to the back side of glass substrate 1, then use Palladous chloride. molten on the same face
Liquid activates；The concentration of stannous chloride solution is every liter of stannous chloride solution chloride containing stannous 30g, hydrochloric acid 20mL；Palladous chloride.
The concentration of solution is every liter of palladium chloride solution chloride containing palladium 0.4g, hydrochloric acid 2 mL；
The back side of step 3, after activation glass substrate 1 uses silver plating solution depositing silver layers 2, is dried after cleaning；Then sulfur is used
Acid copper liquor copper layer 3, is dried after cleaning；Silver plating solution includes silver ammino solution and reducing solution, and silver ammino solution includes following
The component of concentration: silver nitrate 1.5g/L, sodium hydroxide 1.5g/L, ammonia 0.8 g/L, iodine 0.01g/L, potassium chloride 2 g/L, gelatin
6 g/L；Reducing solution includes the component of following mass percent: sodium gluconate 9%, sodium hydroxide 18%, ammonia 2%, surplus
For water；
Step 4, being coated with or spray-applied primer layer 4 coating in layers of copper 3, form prime coat 4, be dried, coating or spray-coating surface enamelled coating 5 are coated with
Material, is dried, obtains scratch-resistant mirror.
In described step 3, use deionized water to clean after glass substrate 1 copper layer 3, dry under the conditions of 70 DEG C after cleaning
Dry, subsequently into heating workshop section, make the temperature of silver layer 2 and layers of copper 3 reach more than 200 DEG C.
In the present embodiment, the shear strength between silver layer 2 and glass substrate 1, and layers of copper 3 and prime coat 4 is all higher than
16N/cm2, the shear strength of prime coat 4 and top coat layer 5 is more than 20N/cm2。
Remaining content of the present embodiment is same as in Example 1, repeats no more here.
Embodiment 3
The present embodiment is with the difference of embodiment 1:
The coating that described prime coat 4 uses is made up of the component of following weight portion:
Alkyd resin 60 parts
Bisphenol A type epoxy resin 10 parts
Polyurethane resin 15 parts
4 parts of firming agent
Ethyl acetate 25 parts
Anticorrosive auxiliary agent 2 parts
Pigment 60 parts
Methyl ethyl ketone oxime 4 parts.
Wherein, described firming agent be weight ratio be sebacic dihydrazide and the isocyanates of 1.5-1.
Wherein, described pigment includes the component of following weight portion:
30 parts of Talcum
10 parts of Muscovitum
Calcium molybdate 8 parts
Bismuth hydrate. 2 parts
Titanium dioxide 5 parts.
Wherein, the coating that described top coat layer 5 uses is made up of the component of following weight portion:
Urethane acrylate 60 parts
Bisphenol A type epoxy resin 5 parts
Titanium dioxide 20 parts
Silicon powder 5 parts
γ-aminopropyl triethoxysilane 2-5 part
BTA 2 parts
Fluorinated diphenyl titanium cyclopentadienyl 1 part
Antioxidant 0.2 part.
The thickness of described silver layer 2 is 120nm, and the thickness of layers of copper 3 is 20nm.
The thickness of described prime coat 4 is 70 μm, and the thickness of top coat layer 5 is 30 μm.
In the step 2 of mirror preparation process, the concentration of stannous chloride solution is every liter of stannous chloride solution chloride containing stannous
70g, hydrochloric acid 40mL；The concentration of palladium chloride solution is every liter of palladium chloride solution chloride containing palladium 0.8g, hydrochloric acid 5 mL.
In the step 3 of mirror preparation process, deionized water after glass substrate 1 copper layer 3, is used to clean, 70 after cleaning
Drying under the conditions of DEG C, subsequently into heating workshop section, make the temperature of silver layer 2 and layers of copper 3 reach more than 200 DEG C, silver plating solution includes
Silver ammino solution and reducing solution, silver ammino solution includes the component of following concentration: silver nitrate 2g/L, sodium hydroxide 2g/L, ammonia 1 g/
L, iodine 0. 02g/L, potassium chloride 5 g/L, gelatin 10 g/L；Reducing solution includes the component of following mass percent: sodium gluconate
10%, sodium hydroxide 22%, ammonia 4%, surplus is water.
In the present embodiment, the shear strength between silver layer 2 and glass substrate 1, and layers of copper 3 and prime coat 4 is all higher than
16N/cm2, the shear strength of prime coat 4 and top coat layer 5 is more than 20N/cm2。
Remaining content of the present embodiment is same as in Example 1, repeats no more here.
Embodiment 4
The present embodiment is with the difference of embodiment 1:
The coating that described prime coat 4 uses is made up of the component of following weight portion:
Alkyd resin 45 parts
Bisphenol A type epoxy resin 18 parts
Polyurethane resin 12 parts
3 parts of firming agent
Ethyl acetate 16 parts
Anticorrosive auxiliary agent 1.5 parts
Pigment 40 parts
Methyl ethyl ketone oxime 3 parts.
Wherein, described firming agent be weight ratio be sebacic dihydrazide and the isocyanates of 1.6:1.
Wherein, described pigment includes the component of following weight portion:
25 parts of Talcum
12 parts of Muscovitum
Calcium molybdate 6 parts
Bismuth hydrate. 5 parts
Titanium dioxide 5 parts.
Wherein, the coating that described top coat layer 5 uses is made up of the component of following weight portion:
Urethane acrylate 50 parts
Bisphenol A type epoxy resin 10 parts
Titanium dioxide 15 parts
Silicon powder 6 parts
γ-aminopropyl triethoxysilane 3 parts
BTA 1 part
Fluorinated diphenyl titanium cyclopentadienyl 0.5 part
Antioxidant 0.5 part.
Wherein, the thickness of described silver layer 2 is 100nm, and the thickness of layers of copper 3 is 25nm.
Wherein, the thickness of described prime coat 4 is 45 μm, and the thickness of top coat layer 5 is 60 μm.
In the step 3 of mirror preparation process, deionized water after glass substrate 1 copper layer 3, is used to clean, 65 after cleaning
Dry under the conditions of DEG C, subsequently into heating workshop section, make the temperature of silver layer 2 and layers of copper 3 reach more than 200 DEG C；Silver plating solution includes
Silver ammino solution and reducing solution, silver ammino solution includes the component of following concentration: silver nitrate 1.6g/L, sodium hydroxide 1.6g/L, ammonia 1
G/L, iodine 0.016g/L, potassium chloride 3 g/L, gelatin 7 g/L；Reducing solution includes the component of following mass percent: gluconic acid
Sodium 9%, sodium hydroxide 20%, ammonia 2.5%, surplus is water.
In the present embodiment, the shear strength between silver layer 2 and glass substrate 1, and layers of copper 3 and prime coat 4 is all higher than
16N/cm2, the shear strength of prime coat 4 and top coat layer 5 is more than 20N/cm2。
Remaining content of the present embodiment is same as in Example 1, repeats no more here.
Embodiment 5
The present embodiment is with the difference of embodiment 1:
The coating that described prime coat 4 uses is made up of the component of following weight portion:
Alkyd resin 55 parts
Bisphenol A type epoxy resin 12 parts
Polyurethane resin 12 parts
4 parts of firming agent
Ethyl acetate 20 parts
Anticorrosive auxiliary agent 1 part
Pigment yellow 155 part
Methyl ethyl ketone oxime 2 parts.
Wherein, described firming agent be weight ratio be sebacic dihydrazide and the isocyanates of 1.6:1.
Wherein, described pigment includes the component of following weight portion:
30 parts of Talcum
18 parts of Muscovitum
Calcium molybdate 7 parts
Bismuth hydrate. 3 parts
Titanium dioxide 7 parts.
Wherein, the coating that described top coat layer 5 uses is made up of the component of following weight portion:
Urethane acrylate 45 parts
Bisphenol A type epoxy resin 7 parts
Titanium dioxide 12 parts
Silicon powder 7 parts
γ-aminopropyl triethoxysilane 2 parts
BTA 2 parts
Fluorinated diphenyl titanium cyclopentadienyl 0.6 part
Antioxidant 0.6 part.
Wherein, the thickness of described silver layer 2 is 90nm, and the thickness of layers of copper 3 is 35nm.
Wherein, the thickness of described prime coat 4 is 50 μm, and the thickness of top coat layer 5 is 40 μm.
In the present embodiment, the shear strength between silver layer 2 and glass substrate 1, and layers of copper 3 and prime coat 4 is all higher than
16N/cm2, the shear strength of prime coat 4 and top coat layer 5 is more than 20N/cm2。
Remaining content of the present embodiment is same as in Example 1, repeats no more here.
Embodiment 6
The present embodiment is with the difference of embodiment 1:
The coating that described prime coat 4 uses is made up of the component of following weight portion:
Alkyd resin 50 parts
Bisphenol A type epoxy resin 16 parts
Polyurethane resin 10 parts
4 parts of firming agent
Ethyl acetate 18 parts
Anticorrosive auxiliary agent 1 part
Pigment 75 parts
Methyl ethyl ketone oxime 4 parts.
Wherein, the coating that described top coat layer 5 uses is made up of the component of following weight portion:
Urethane acrylate 55 parts
Bisphenol A type epoxy resin 8 parts
Titanium dioxide 18 parts
Silicon powder 9 parts
γ-aminopropyl triethoxysilane 4 parts
BTA 1 part
Fluorinated diphenyl titanium cyclopentadienyl 0.8 part
Antioxidant 0.8 part.
Wherein, described firming agent be weight ratio be sebacic dihydrazide and the isocyanates of 1.7:1.
Wherein, described pigment includes the component of following weight portion:
28 parts of Talcum
15 parts of Muscovitum
Calcium molybdate 5 parts
Bismuth hydrate. 5 parts
Titanium dioxide 7 parts.
Wherein, the thickness of described silver layer 2 is 110nm, and the thickness of layers of copper 3 is 30nm.
Wherein, the thickness of described prime coat 4 is 60 μm, and the thickness of top coat layer 5 is 45 μm.
In the present embodiment, the shear strength between silver layer 2 and glass substrate 1, and layers of copper 3 and prime coat 4 is all higher than
16N/cm2, the shear strength of prime coat 4 and top coat layer 5 is more than 20N/cm2。
The silver-plated mirror that common commercially available identical minute surface area, enamelled coating gross thickness are identical on market is as comparative example, with this
Bright mirror carries out the detection of anti-neutral salt spray performance by industry standard C/T871-2000, and result shows, the edge penalty of the present invention
Maximum development length inwards is less than 1mm, and the diameter number of spots less than 0.3mm is 0-2, the diameter speckle number less than 0.25mm
Mesh is 0-1；The edge penalty maximum development length inwards of comparative example is 2-3mm, and the diameter number of spots less than 0.3mm is 2-
4, the diameter number of spots less than 0.25mm is 1-2.Result shows, the mirror good corrosion resistance of the present invention, edge coating
It is difficult to be destroyed, makes mirror be difficult to blackening.
By pencil hardness, GB/T6739 measures, and the scraping and wiping resistance performance of the present invention is 5-6H, and comparative example is 3-4 H, shows this
The mirror of invention has good scraping and wiping resistance performance.
Last it should be noted that, above example is only in order to illustrate technical scheme, rather than the present invention is protected
Protecting the restriction of scope, although having made to explain to the present invention with reference to preferred embodiment, those of ordinary skill in the art should
Work as understanding, technical scheme can be modified or equivalent, without deviating from the reality of technical solution of the present invention
Matter and scope.
Claims (10)
1. a scratch-resistant mirror, it is characterised in that: include glass substrate, be covered in the silver layer at the glass substrate back side, be covered in silver
Layer surface and the layers of copper of side, it is covered in layers of copper surface and the prime coat of side, is covered in the finish paint of primer coat surface and side
Layer.
A kind of scratch-resistant mirror the most according to claim 1, it is characterised in that: the coating that described prime coat uses is by following heavy
The component composition of amount part:
Alkyd resin 40-60 part
Bisphenol A type epoxy resin 10-20 part
Firming agent 1-4 part
Ethyl acetate 10-20 part
Anticorrosive auxiliary agent 0.5-2 part
Pigment 40-60 part
Methyl ethyl ketone oxime 1-4 part.
A kind of scratch-resistant mirror the most according to claim 2, it is characterised in that: the oil mass of described alkyd resin is 40-55%,
Phthalic anhydride amount is 30-35%.
A kind of scratch-resistant mirror the most according to claim 2, it is characterised in that: described anticorrosive auxiliary agent is iminodiacetic acid (salt)
Nitrile.
A kind of scratch-resistant mirror the most according to claim 2, it is characterised in that: described firming agent is that sebacic dihydrazide is with double
At least one in cyanamide.
A kind of scratch-resistant mirror the most according to claim 2, it is characterised in that: described priming pigment includes following weight portion
Component:
Talcum 20-30 part
Muscovitum 10-20 part
Calcium molybdate 3-8 part
Bismuth hydrate. 2-6 part
Titanium dioxide 5-10 part.
A kind of scratch-resistant mirror the most according to claim 1, it is characterised in that: the coating that described top coat layer uses is by following heavy
The component composition of amount part:
Urethane acrylate 40-60 part
Bisphenol A type epoxy resin 5-10 part
Titanium dioxide 10-20 part
Silicon powder 5-10 part
γ-aminopropyl triethoxysilane 2-5 part
BTA 0.5-2 part
Fluorinated diphenyl titanium cyclopentadienyl 0.2-1 part
Antioxidant 0.2-1 part.
A kind of scratch-resistant mirror the most according to claim 7, it is characterised in that: described antioxidant be decanedioic acid double (2,2,
6,6-tetramethyl-4-hydroxy piperidines) ester.
9. the preparation method of the arbitrary described a kind of scratch-resistant mirror of claim 1-8, it is characterised in that: comprise the following steps:
Step 1, provide a glass substrate, glass baseplate surface is polished and cleans；
Step 2, use stannous chloride solution carry out sensitization to the back side of glass substrate, then use palladium chloride solution on the same face
Activate；
The back side of step 3, after activation glass substrate uses silver plating solution depositing silver layers, is dried after cleaning；Then sulphuric acid is used
Copper liquor copper layer, is dried after cleaning；
Step 4, at layers of copper coating or spray-applied primer coating, form prime coat, be dried, coating or spray paint coating, dry
Dry, obtain scratch-resistant mirror.
The preparation method of a kind of scratch-resistant mirror the most according to claim 9, it is characterised in that: in described step 3, glass
Use deionized water to clean after substrate deposition layers of copper, dry under the conditions of 60-70 DEG C after cleaning, subsequently into heating workshop section, make
The temperature of silver layer and layers of copper reaches more than 200 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610699041.3A CN106318159B (en) | 2016-08-22 | 2016-08-22 | A kind of scratch-resistant mirror and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610699041.3A CN106318159B (en) | 2016-08-22 | 2016-08-22 | A kind of scratch-resistant mirror and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106318159A true CN106318159A (en) | 2017-01-11 |
| CN106318159B CN106318159B (en) | 2019-04-05 |
Family
ID=57741508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610699041.3A Active CN106318159B (en) | 2016-08-22 | 2016-08-22 | A kind of scratch-resistant mirror and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106318159B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109363451A (en) * | 2018-11-02 | 2019-02-22 | 合肥市老兵玻璃有限公司 | A kind of mirror with section self-protection function |
| CN109734328A (en) * | 2018-11-30 | 2019-05-10 | 江苏福坤玻璃有限公司 | A kind of preparation method of preparing low-emissivity coated hollow glass |
| CN111056748A (en) * | 2019-12-28 | 2020-04-24 | 平湖市偌俬电子有限公司 | Antirust lens for bathroom mirror and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258272A (en) * | 1997-05-27 | 2000-06-28 | 利利工业(美国)有限公司 | Iminodiacetonitrile mirror back coating corrosion inhibitor |
| CN1908098A (en) * | 2005-08-05 | 2007-02-07 | 中央硝子株式会社 | Composition for internal hanging coating and anti-corrosion mirror using same |
| CN102159119A (en) * | 2008-09-22 | 2011-08-17 | 法国圣戈班玻璃厂 | Corrosion-resistant mirror |
| CN102445853A (en) * | 2010-10-12 | 2012-05-09 | 京东方科技集团股份有限公司 | Photosensitive resin composition and color filter as well as preparation method thereof |
| CN103941318A (en) * | 2014-04-10 | 2014-07-23 | 武汉圣普太阳能科技有限公司 | Manufacturing method of solar thermal power generation light condensation silver mirror |
| CN104516035A (en) * | 2013-09-26 | 2015-04-15 | 青岛市首胜实业有限公司 | Manufacturing process of glass silver mirror |
-
2016
- 2016-08-22 CN CN201610699041.3A patent/CN106318159B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1258272A (en) * | 1997-05-27 | 2000-06-28 | 利利工业(美国)有限公司 | Iminodiacetonitrile mirror back coating corrosion inhibitor |
| CN1908098A (en) * | 2005-08-05 | 2007-02-07 | 中央硝子株式会社 | Composition for internal hanging coating and anti-corrosion mirror using same |
| CN102159119A (en) * | 2008-09-22 | 2011-08-17 | 法国圣戈班玻璃厂 | Corrosion-resistant mirror |
| CN102445853A (en) * | 2010-10-12 | 2012-05-09 | 京东方科技集团股份有限公司 | Photosensitive resin composition and color filter as well as preparation method thereof |
| CN104516035A (en) * | 2013-09-26 | 2015-04-15 | 青岛市首胜实业有限公司 | Manufacturing process of glass silver mirror |
| CN103941318A (en) * | 2014-04-10 | 2014-07-23 | 武汉圣普太阳能科技有限公司 | Manufacturing method of solar thermal power generation light condensation silver mirror |
Non-Patent Citations (3)
| Title |
|---|
| 梁水生: "《银镜反应的基本原理》", 《中国玻璃行业年会暨技术研讨会》 * |
| 王才: "《玻璃镀银制镜技术》", 《农村新技术》 * |
| 蔡积庆: "《镜制品化学镀银》", 《电镀和环保》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109363451A (en) * | 2018-11-02 | 2019-02-22 | 合肥市老兵玻璃有限公司 | A kind of mirror with section self-protection function |
| CN109734328A (en) * | 2018-11-30 | 2019-05-10 | 江苏福坤玻璃有限公司 | A kind of preparation method of preparing low-emissivity coated hollow glass |
| CN111056748A (en) * | 2019-12-28 | 2020-04-24 | 平湖市偌俬电子有限公司 | Antirust lens for bathroom mirror and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106318159B (en) | 2019-04-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101043527B1 (en) | Stainless steel out-case of home appliance having anti-fingerprint coating | |
| US5021091A (en) | Hard coating compositions | |
| CN106318159A (en) | Scratching-resistant mirror and preparation method thereof | |
| CN102766861A (en) | Process for producing a repair coating on a coated metallic surface | |
| CN101925457A (en) | Member with corrosion-resistant coating film, process for production of the same, and coating composition for production thereof | |
| CN101094937A (en) | Process for producing a repair coating on a coated metallic surface | |
| KR20090122195A (en) | Composition and process for coating metal surfaces | |
| JP2003160759A (en) | Silica-based coating liquid, silica-based coating film using it and base material coated with the same film | |
| AU2018204389B2 (en) | A chromium-free water based coating for treating a Galvannealed or galvanized steel surface | |
| US20080050601A1 (en) | Hard coating composition and plastic optical product | |
| JP2004307897A (en) | Surface-treated metal having silica-zirconia film, and method of manufacturing the same | |
| CN101255313B (en) | Paint for automobile reflecting layer | |
| WO2009055055A1 (en) | Corrosion and abrasion resistant coating | |
| CN106175298A (en) | A kind of mirror being difficult to blackening and preparation method thereof | |
| US20090108240A1 (en) | Friction reducing, corrosion resistant and abrasion resistant coating | |
| JP2805877B2 (en) | Composition for coating | |
| CN214390966U (en) | Water-based anticorrosive hardware baking paint coating | |
| CN100457841C (en) | Coating composition and resin product having light-transmitting property | |
| JPS624060B2 (en) | ||
| JP4842743B2 (en) | Regular reflection resin-coated aluminum material with excellent durability | |
| JP2006251413A (en) | Plastic lens using polycarbonate resin | |
| JP2764090B2 (en) | Ceramic coating metal material and its manufacturing method | |
| CN215970535U (en) | Water-based alcohol-resistant plastic paint coating | |
| CN1912030A (en) | High temperature coated acrylic acid resin paint and its manufacturing method | |
| US8075679B2 (en) | Corrosion and abrasion resistant coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A scratch resistant mirror and its preparation method Granted publication date: 20190405 Pledgee: Dongguan Rural Commercial Bank Co.,Ltd. Daojiao Branch Pledgor: DONGGUAN LAMXON TECHNOLOGY BUILDING MATERIAL Co.,Ltd. Registration number: Y2024980044370 |