CN106317868A - String for badminton racket - Google Patents
String for badminton racket Download PDFInfo
- Publication number
- CN106317868A CN106317868A CN201610766338.7A CN201610766338A CN106317868A CN 106317868 A CN106317868 A CN 106317868A CN 201610766338 A CN201610766338 A CN 201610766338A CN 106317868 A CN106317868 A CN 106317868A
- Authority
- CN
- China
- Prior art keywords
- parts
- fiber
- modified polyolefin
- acid
- netting twine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a string for a badminton racket. The string is prepared from the following raw materials: polyhexamethylene adipamide, poly[imino(1-oxo-1,12-dodecanediyl)], a polymer of dodecanoic acid and 1,6-diaminohexane, carbon fibers, graphene, modified polyolefin fibers, hydroxypropyl cellulose, diatomite, sodium 2,2'-methylene-bis-(4,6-di-tert-butylphenyl)phosphate, dilauryl thiodipropionate, diphenyl isopropylphenyl phosphate and 3-(2-amino-ethylamine) propyl dimethoxy silane. According to the string for the badminton racket, by means of rational proportion and combined action of the raw materials, the string has outstanding strength and better elasticity compared with a traditional nylon string, and the characteristics are enhanced particularly through the addition of the modified polyolefin fibers.
Description
Technical field
The present invention relates to a kind of racket netting twine, belong to Material Field.
Background technology
Racket netting twine, is racket this thing required.Plumage line in plumage clap, just as arrow in bow.Just do not have without arrow
Have saying of " arrow string have to send out ", wireless just cannot heterodyne, therefore the importance of plumage line is unknown, and a good bat need to prepare
Line.
Traditional plumage line is mainly sheep, nylon, tendon Bovis seu Bubali string and chemical fibre Intestinum caprae seu ovis four kinds of string of synthesis.Wherein nylon wire is used
Amount maximum, the most extensively, but he has individual shortcoming, it is simply that elasticity is the best.
Summary of the invention
For overcoming above-mentioned deficiency, it is an object of the present invention to provide a kind of racket netting twine, there is reasonable hot strength
While, also there is excellent elasticity.
The solution of the present invention is as follows: a kind of racket netting twine, following raw material prepare: poly hexamethylene adipamide oneself two
Amine 80-90 part, poly-[imino group (1-oxo-1,12-Asia dodecyl)] 45-55 part, lauric acid/dodecanoic acid are polymerized with 1,6-hexamethylene diamine
Thing 22-30 part, carbon fiber 5-10 part, Graphene 2-6 part, modified polyolefin are through fiber 4-6 part, hydroxypropyl cellulose 1-3 part, diatom
Soil 0.5-0.9 part, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) sodium phosphate 1-3 part, dilauryl thiodipropionate 1-
3 parts, p isopropylbenzoic acid base benzene diphenyl ester 0.2-0.8 part, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 1-4 part;
Described modified polyolefin is prepared by following methods through fiber:
By polyene through fiber 12-18g, polycaprolactam 5-8g, tetraethyl orthosilicate polyvinyl chloride fibre chopped fiber 4-6g, ethenyl pyrrolidone
Ketone-vinyl acetate copolymer 2-5g, ethyl dimethylchlorosilane 1-3g, tetraethyl orthosilicate 0.4-0.9g, hydroxypropyl methyl are fine
Dimension element 0.3-0.8g, attapulgite clay 0.5-1g mix homogeneously, heat 35-45min at 940-980 DEG C, cool down, dry, grind
Mill, to obtain final product;
Described polyhexamethylene adipamide and modified polyolefin are 1:0.05-0.06 through the weight ratio of fiber.
Further, following raw material prepare: polyhexamethylene adipamide 85 parts, poly-[imino group (1-oxo-1,12-
Sub-dodecyl)] 46 parts, lauric acid/dodecanoic acid and 28 parts of the polymer of 1,6-hexamethylene diamine, 8 parts of carbon fiber, Graphene 4 parts, modified polyolefin
Through fiber 5 parts, hydroxypropyl cellulose 1.8 parts, 0.6 part of kieselguhr, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) phosphate ester
2 parts of sodium, dilauryl thiodipropionate 1.8 parts, p isopropylbenzoic acid base benzene diphenyl ester 0.6 part, 3-(2-aminoethyl) hydroxypropyl methyl
Dimethoxysilane 3 parts.
Further, following raw material prepare: polyhexamethylene adipamide 88 parts, poly-[imino group (1-oxo-1,12-
Sub-dodecyl)] 46 parts, lauric acid/dodecanoic acid and 28 parts of the polymer of 1,6-hexamethylene diamine, 6 parts of carbon fiber, Graphene 5 parts, modified polyolefin
Through fiber 4.4 parts, hydroxypropyl cellulose 1.6 parts, 0.7 part of kieselguhr, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) phosphoric acid
2.2 parts of ester sodium, dilauryl thiodipropionate 2 parts, p isopropylbenzoic acid base benzene diphenyl ester 0.45 part, 3-(2-aminoethyl) propyl group first
Base dimethoxysilane 2.3 parts.
Further, following raw material prepare: polyhexamethylene adipamide 83 parts, poly-[imino group (1-oxo-1,12-
Sub-dodecyl)] 51 parts, lauric acid/dodecanoic acid and 26 parts of the polymer of 1,6-hexamethylene diamine, 6 parts of carbon fiber, Graphene 4 parts, modified polyolefin
Through fiber 4.15 parts, hydroxypropyl cellulose 2.1 parts, 0.66 part of kieselguhr, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) phosphorus
2.4 parts of acid esters sodium, dilauryl thiodipropionate 3 parts, p isopropylbenzoic acid base benzene diphenyl ester 0.8 part, 3-(2-aminoethyl) propyl group
Methyl dimethoxysilane 3 parts.
A kind of production method of racket netting twine, each raw material mixed, melt extrude, cool down, wire drawing, winding.
Racket netting twine of the present invention, is acted on the most jointly by the Reasonable of raw material so that netting twine have excellent
While intensity, compare conventional nylon netting twine, have more preferably elastic.Especially modified polyolefin is through the addition of fiber, enhances
State characteristic.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
Modified polyolefin is prepared through fiber:
By polyene through fiber 13g, polycaprolactam 6g, tetraethyl orthosilicate polyvinyl chloride fibre chopped fiber 5g, vinyl pyrrolidone-acetic acid second
Enoate copolymer 3g, ethyl dimethylchlorosilane 2g, tetraethyl orthosilicate 0.6g, hydroxypropyl methyl cellulose 0.4g, attapulgite are viscous
Soil 0.8g mix homogeneously, heats 35-45min at 940-980 DEG C, cools down, dries, grinds, to obtain final product.
Embodiment 1
A kind of racket netting twine, is prepared by following raw material: polyhexamethylene adipamide 85 parts, poly-[imino group (1-oxygen
Generation-1,12-Asia dodecyl)] 46 parts, lauric acid/dodecanoic acid and 28 parts of the polymer of 1,6-hexamethylene diamine, 8 parts of carbon fiber, Graphene 4 parts,
Modified polyolefin is through fiber 5 parts, hydroxypropyl cellulose 1.8 parts, 0.6 part of kieselguhr, 2,2' methylene bis (4,6-di-tert-butyl
Base) sodium phosphate 2 parts, dilauryl thiodipropionate 1.8 parts, p isopropylbenzoic acid base benzene diphenyl ester 0.6 part, 3-(2-aminoethyl)
Hydroxypropyl methyl dimethoxysilane 3 parts.
Racket with netting twine according to a conventional method, raw material mixes, melt extrudes, cools down, wire drawing, winding, to obtain final product.
Embodiment 2
A kind of racket netting twine, is prepared by following raw material: polyhexamethylene adipamide 88 parts, poly-[imino group (1-oxygen
Generation-1,12-Asia dodecyl)] 46 parts, lauric acid/dodecanoic acid and 28 parts of the polymer of 1,6-hexamethylene diamine, 6 parts of carbon fiber, Graphene 5 parts,
Modified polyolefin is through fiber 4.4 parts, hydroxypropyl cellulose 1.6 parts, 0.7 part of kieselguhr, 2,2' methylene bis (4,6-di-t-butyl
Phenyl) sodium phosphate 2.2 parts, dilauryl thiodipropionate 2 parts, p isopropylbenzoic acid base benzene diphenyl ester 0.45 part, 3-(2-amino second
Amine) hydroxypropyl methyl dimethoxysilane 2.3 parts.
Racket with netting twine according to a conventional method, raw material mixes, melt extrudes, cools down, wire drawing, winding, to obtain final product.
Embodiment 3
A kind of racket netting twine, is prepared by following raw material: polyhexamethylene adipamide 83 parts, poly-[imino group (1-oxygen
Generation-1,12-Asia dodecyl)] 51 parts, lauric acid/dodecanoic acid and 26 parts of the polymer of 1,6-hexamethylene diamine, 6 parts of carbon fiber, Graphene 4 parts,
Modified polyolefin is through fiber 4.15 parts, hydroxypropyl cellulose 2.1 parts, 0.66 part of kieselguhr, 2,2' methylene bis (the tertiary fourth of 4,6-bis-
Base phenyl) sodium phosphate 2.4 parts, dilauryl thiodipropionate 3 parts, p isopropylbenzoic acid base benzene diphenyl ester 0.8 part, 3-(2-amino
Ethamine) hydroxypropyl methyl dimethoxysilane 3 parts.
Racket with netting twine according to a conventional method, raw material mixes, melt extrudes, cools down, wire drawing, winding, to obtain final product.
Comparative example 1
Compared with Example 1, it is at difference, does not contains modified polyolefin through fiber.
Comparative example 2
Compared with Example 2, it is at difference, does not contains modified polyolefin through fiber.
Comparative example 3
Compared with Example 3, it is at difference, does not contains modified polyolefin through fiber.
The racket netting twine being fabricated to above-described embodiment 1-3, comparative example 1-3 carries out performance test, and result is as follows
Shown in table:
Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Commercially available nylon netting twine | |
Ultimate strength (N) | 291 | 288 | 290 | 275 | 269 | 273 | 220-250 |
Elastic modelling quantity (MP) | 645 | 650 | 642 | 622 | 628 | 625 | 500-600 |
Although above the detailed description of the invention to the present invention give detailed description and explanation, but it should be noted that we
According to the conception of the present invention, above-mentioned embodiment can be carried out various equivalence to change and amendment, produced by it, function is still
Without departing from description contained spiritual time, all should be within protection scope of the present invention.
Claims (5)
1. a racket netting twine, it is characterised in that prepared by following raw material:
Polyhexamethylene adipamide 80-90 part, poly-[imino group (1-oxo-1,12-Asia dodecyl)] 45-55 part, lauric acid/dodecanoic acid with
Polymer 22-30 part of 1,6-hexamethylene diamine, carbon fiber 5-10 part, Graphene 2-6 part, modified polyolefin are through fiber 4-6 part, hydroxypropyl
Cellulose 1-3 part, kieselguhr 0.5-0.9 part, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) sodium phosphate 1-3 part, sulfur generation
Dipropionic acid dilauryl 1-3 part, p isopropylbenzoic acid base benzene diphenyl ester 0.2-0.8 part, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxy
Base silane 1-4 part;
Described modified polyolefin is prepared by following methods through fiber:
By polyene through fiber 12-18g, polycaprolactam 5-8g, tetraethyl orthosilicate polyvinyl chloride fibre chopped fiber 4-6g, ethenyl pyrrolidone
Ketone-vinyl acetate copolymer 2-5g, ethyl dimethylchlorosilane 1-3g, tetraethyl orthosilicate 0.4-0.9g, hydroxypropyl methyl are fine
Dimension element 0.3-0.8g, attapulgite clay 0.5-1g mix homogeneously, heat 35-45min at 940-980 DEG C, cool down, dry, grind
Mill, to obtain final product;
Described polyhexamethylene adipamide and modified polyolefin are 1:0.05-0.06 through the weight ratio of fiber.
A kind of racket netting twine the most according to claim 1, it is characterised in that prepared by following raw material:
Polyhexamethylene adipamide 85 parts, poly-[imino group (1-oxo-1,12-Asia dodecyl)] 46 parts, lauric acid/dodecanoic acid and 1,6-are own
28 parts of the polymer of diamidogen, 8 parts of carbon fiber, Graphene 4 parts, modified polyolefin are through fiber 5 parts, hydroxypropyl cellulose 1.8 parts, diatom
0.6 part of soil, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) sodium phosphate 2 parts, dilauryl thiodipropionate 1.8 parts, phosphorus
Acid cumene diphenyl ester 0.6 part, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 3 parts.
A kind of racket netting twine the most according to claim 1, it is characterised in that prepared by following raw material:
Polyhexamethylene adipamide 88 parts, poly-[imino group (1-oxo-1,12-Asia dodecyl)] 46 parts, lauric acid/dodecanoic acid and 1,6-are own
28 parts of the polymer of diamidogen, 6 parts of carbon fiber, Graphene 5 parts, modified polyolefin are through fiber 4.4 parts, hydroxypropyl cellulose 1.6 parts, silicon
Diatomaceous earth 0.7 part, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) sodium phosphate 2.2 parts, dilauryl thiodipropionate 2 parts,
P isopropylbenzoic acid base benzene diphenyl ester 0.45 part, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 2.3 parts.
A kind of racket netting twine the most according to claim 1, it is characterised in that prepared by following raw material:
Polyhexamethylene adipamide 83 parts, poly-[imino group (1-oxo-1,12-Asia dodecyl)] 51 parts, lauric acid/dodecanoic acid and 1,6-are own
26 parts of the polymer of diamidogen, 6 parts of carbon fiber, Graphene 4 parts, modified polyolefin through fiber 4.15 parts, hydroxypropyl cellulose 2.1 parts,
0.66 part of kieselguhr, 2,2' methylene bis (4,6-di-tert-butyl-phenyl) sodium phosphate 2.4 parts, dilauryl thiodipropionate 3
Part, p isopropylbenzoic acid base benzene diphenyl ester 0.8 part, 3-(2-aminoethyl) hydroxypropyl methyl dimethoxysilane 3 parts.
5. according to the production method of the arbitrary described a kind of racket netting twine of claim 1-4, it is characterised in that Jiang Geyuan
Material mixes, melt extrudes, cools down, wire drawing, winding.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610766338.7A CN106317868A (en) | 2016-08-30 | 2016-08-30 | String for badminton racket |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610766338.7A CN106317868A (en) | 2016-08-30 | 2016-08-30 | String for badminton racket |
Publications (1)
Publication Number | Publication Date |
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CN106317868A true CN106317868A (en) | 2017-01-11 |
Family
ID=57789201
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610766338.7A Pending CN106317868A (en) | 2016-08-30 | 2016-08-30 | String for badminton racket |
Country Status (1)
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CN (1) | CN106317868A (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1191148A (en) * | 1996-12-12 | 1998-08-26 | 株式会社高纤 | Filament for racket |
CN1395001A (en) * | 2001-07-11 | 2003-02-05 | 耀亿工业股份有限公司 | Abrasion-proof high-elasticity strings structure and its production method |
CN102383312A (en) * | 2011-10-24 | 2012-03-21 | 富阳市球拍行业技术研究开发中心 | Preparation method of badminton net thread |
CN104918665A (en) * | 2013-04-19 | 2015-09-16 | 株式会社高纤 | Racquet string and method for producing same |
-
2016
- 2016-08-30 CN CN201610766338.7A patent/CN106317868A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1191148A (en) * | 1996-12-12 | 1998-08-26 | 株式会社高纤 | Filament for racket |
CN1395001A (en) * | 2001-07-11 | 2003-02-05 | 耀亿工业股份有限公司 | Abrasion-proof high-elasticity strings structure and its production method |
CN102383312A (en) * | 2011-10-24 | 2012-03-21 | 富阳市球拍行业技术研究开发中心 | Preparation method of badminton net thread |
CN104918665A (en) * | 2013-04-19 | 2015-09-16 | 株式会社高纤 | Racquet string and method for producing same |
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Application publication date: 20170111 |