CN106317685A - PVC (polyvinyl chloride) floor good in bacteriostatic type inking property and preparation method of PVC floor - Google Patents
PVC (polyvinyl chloride) floor good in bacteriostatic type inking property and preparation method of PVC floor Download PDFInfo
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- CN106317685A CN106317685A CN201610697269.9A CN201610697269A CN106317685A CN 106317685 A CN106317685 A CN 106317685A CN 201610697269 A CN201610697269 A CN 201610697269A CN 106317685 A CN106317685 A CN 106317685A
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- pvc
- floor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a PVC (polyvinyl chloride) floor. The PVC floor is prepared from raw materials including, by weight, 100 parts of vinyl chloride resin, 0-8 parts of plasticizer, 10-15 parts of filler and calcium carbonate, 8-15 parts of titanium dioxide, 5-10 parts of talcum powder, 1.5-3 parts of heat stabilizer, 0.5-1 part of an internal lubricant, 0.3-1 part of an external lubricant; 0.05-0.2 part of nano silver, 0.1-0.3 part of clove oil, 0.5-1 part of glucose, 0.5-1 part of triethyl phosphate, 0.2-0.8 part of a hygroscopic agent and 0.05-1.2 parts of a surface modification agent which is preferably boric acid eaters. Through improvement of formulation of the PVC floor, good bacteriostatic effect of the PVC floor is achieved, the PVC floor is more suitable for home decoration, good inking effect is achieved, spreading effect of printing ink on the PVC floor is improved, and the PVC floor with good presentation capability of printing patterns is realized.
Description
Technical field
The invention belongs to plastic floor technical field, be specifically related to the PVC floor that a kind of antibacterial type inking is good.
Background technology
Plastic floor (PVC floor), is mainly composed of pvc material, and PVC floor can make two kinds, and one is same
The saturating heart of matter, it is simply that the decorative pattern material from the end to face is just as.Also having a kind of is combined type, it is simply that topmost one layer is
Pure PVC transparent layer, below plus printed layer and foaming layer." plastic floor " refers to the ground using pvc material to produce
Plate.PVC floor is enriched due to its pattern, and color is various and is widely used in each side of house and business.
It addition, PVC floor the most not only limits to the field being applied to public opening, PVC floor is because of its laying construction
Convenience, is also increasingly becoming the selection of house fitting-up, improves the antibacterial ability of PVC floor, makes to meet household and uses requirement also
It it is the problem needing to be thought better of.
Constantly promote the coloring texture of PVC floor surface detail, improve the ink coloring effect at PVC floor substrate surface
Those skilled in the art are made to need the problem of thinking.
Summary of the invention
The technical problem to be solved is to provide, for above-mentioned prior art, the PVC that a kind of antibacterial type inking is good
Floor, by improving the composition proportion of PVC floor, makes PVC floor have preferable inking effect and color presents ability, simultaneously
There is bacteriostasis.
The present invention solves the technical scheme that the problems referred to above are used: the PVC floor that a kind of antibacterial type inking is good, by such as
The raw material of lower mass parts is prepared from
Corvic 100 parts,
Plasticizer 0-8 part,
Filler: calcium carbonate 10-15 part, titanium dioxide 8-15 part, Pulvis Talci 5-10 part,
Heat stabilizer 1.5-3 part,
In-lubricant 0.5-1 part,
External lubricant 0.3-1 part,
Nanometer silver 0.05-0.2 part,
Oleum Caryophylli 0.1-0.3 part,
Glucose 0.5-1 part,
Triethyl phosphate 0.5-1 part,
Hygroscopic agent 0.2-0.8 part,
Surface modifier 0.05-1.2 part.
Described hygroscopic agent is triethanolamine, improves the PVC floor adsorptivity to printing-ink.Meanwhile, glucose can change
The water resistant ability of kind PVC floor surface printing ink.
Described surface modifier is borate ester, including castor oil acid triethanolamine borate, ricinoleic acid boric acid
Ester and glycerol triethanolamine borate, two glyceryl borates and triethanolamine borate, first-selected castor oil acid triethanolamine boric acid
Ester, ricinoleic acid borate.Oleum Ricini acids borate has bigger molecular volume, and its molecular surface area is less, has
Help improve PVC floor surface characteristic, make ink preferably sprawl, improve the inking effect on PVC floor surface, and ink printing
The pattern of layer presents ability, makes apparent, texture.
Described plasticizer is that dioctyl phthalate, phthalic acid two (2-propyl group heptan) ester, phthalic acid two are different
One or more combination in nonyl ester or polyesters plasticizer.
Described heat stabilizer includes that organotin or metal soap complex stabilizer, described metal soap complex stabilizer are hard
The combination of two or more metals in fat acid barium, zinc stearate, chromium stearate, calcium stearate, preferably barium+zinc, barium+zinc+cadmium, calcium+
The combination of zinc.
Described organotin is di-n-butyltin dilaurate, dibutyitin maleate, butyl maleate dibutyl tin, sulfur
Alcohol methyl stannum.
Described in-lubricant is high fatty alcohol, fatty acid ester, external lubricant be higher fatty acids, fatty acid amide, paraffin,
Tissuemat E, polysiloxanes.
The preparation method of the PVC floor that the antibacterial type inking of the present invention is good is, Corvic is preheated to 70～
80 DEG C, add plasticizer, stir 60～120s, add filler, stir, add residue dispensing；System is warming up to
100～110 DEG C, speed of agitator is set and continues more than 6min to 1200～1600 turns/min, reaction；Then 45～50 it are cooled to
DEG C, discharging；Mixed material is transferred to planet extruding machine, planet Extruder temperature 100～150 DEG C is set, proceeds to mill afterwards
Machine is mixing, rolls through calender, and rolling temperature is 170～210 DEG C, is cooled to room temperature sizing, then temper softening, temperature
35～40 DEG C, rolling.
Compared with prior art, it is an advantage of the current invention that:
Adding nanometer silver and the Oleum Caryophylli of certain deal in PVC raw material, containing eugenol in Oleum Caryophylli, described eugenol is to often
The putrefaction bacteria seen and the growth of toxic bacteria all have inhibitory action in various degree, make PVC floor finished product have sterilization, antibacterial effect
Really.
By improving the proportioning of PVC floor, make the PVC floor prepared have preferable inking effect, improve printing-ink
PVC floor sprawls effect, makes acquisition excellent press pattern present the PVC floor of ability.Sliding by adjusting in filler
The content of stone powder, contributes to improving the lubricity of PVC floor to improve inking；Add triethyl phosphate in the feed, make print
Brush ink is sprawled more smooth and easy in PVC floor, and then it is uniform to be easy to inking；It addition, the present invention with the addition of boric acid in the feed
Esters, as surface modifier, improves the ink spreading ability in PVC surface, eliminates local inking thickness difference, improves inking
Effect.
Invention additionally provides the preparation method of this PVC floor, simplify preparation flow, improve production effect.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
PVC floor, raw material measures in parts by mass and includes: Corvic 100 parts, plasticizer 5 parts, filler: calcium carbonate
10 parts, titanium dioxide 8 parts, Pulvis Talci 10 parts, heat stabilizer 2 parts, in-lubricant 0.5 part, external lubricant 0.5 part, nanometer silver
0.05 part, Oleum Caryophylli 0.2 part, glucose 0.5 part, triethyl phosphate 0.5 part, triethanolamine 0.2-0.8 part, castor oil acid
Triethanolamine borate 0.2 part.
Above-mentioned plasticizer is that dioctyl phthalate, phthalic acid two (2-propyl group heptan) ester arbitrary proportion and 2 parts are big
The mixture of Oleum Glycines.
Above-mentioned heat stabilizer is that barium stearate, zinc stearate are by the mixture of 1:1 mass ratio.
Above-mentioned in-lubricant is fatty acid ester or high fatty alcohol, and external lubricant is Tissuemat E, liquid paraffin, tristearin
One or more mixture in acid, fatty acid amide.
The preparation method of PVC floor is, Corvic is preheated to 70～80 DEG C, adds plasticizer, stirs 60s,
Add all filleies, after stirring, add residue dispensing；System is warming up to 100～110 DEG C, speed of agitator is set
To 1200 turns/min, reaction continues 10min；Then 45～50 DEG C it are cooled to, discharging；Mixed material is transferred to planet extrusion molding
Machine, arranges planet Extruder temperature 100～150 DEG C, proceeds to mill mixing afterwards, and calender rolls, rolling temperature be 170～
210 DEG C, it is cooled to room temperature sizing, then temper softening, temperature 35～40 DEG C, rolling.
Embodiment 2
The raw material of preparing of PVC floor with the main distinction of embodiment 1, the PVC floor in the present embodiment prepare raw material by matter
Amount part metering includes: Corvic 100 parts, plasticizer 6 parts, filler: calcium carbonate 10 parts, titanium dioxide 10 parts, cunning
Stone powder 5 parts, heat stabilizer 1.5 parts, in-lubricant 0.5 part, external lubricant 0.8 part, nanometer silver 0.1 part, Oleum Caryophylli 0. 3
Part, glucose 0.5 part, triethyl phosphate 0.5 part, triethanolamine 0.4 part, triethanolamine borate 0.05 part.
Above-mentioned plasticizer is CPE.
Above-mentioned heat stabilizer is that barium stearate, zinc stearate, chromium stearate are by the mixture of 1:1:0.5 mass ratio.
Embodiment 3
The raw material of preparing of PVC floor with the main distinction of embodiment 1, the PVC floor in the present embodiment prepare raw material by matter
Amount part metering includes: Corvic 100 parts, plasticizer 6 parts, filler: calcium carbonate 12 parts, titanium dioxide 8 parts, Talcum
8 parts of powder, heat stabilizer 2 parts, in-lubricant 0.8 part, external lubricant 0.8 part, nanometer silver 0.05 part, Oleum Caryophylli 0. 3 parts,
Glucose 0.5 part, triethyl phosphate 0.5 part, triethanolamine 0.4 part, ricinoleic acid borate and glycerol triethanolamine
0.5 part of the mixture of borate.
Above-mentioned heat stabilizer is that calcium stearate, zinc stearate are by the mixture of any mass ratio.
Embodiment 4
The raw material of preparing of PVC floor with the main distinction of embodiment 1, the PVC floor in the present embodiment prepare raw material by matter
Amount part metering includes: Corvic 100 parts, plasticizer 6 parts, filler: calcium carbonate 12 parts, titanium dioxide 8 parts, Talcum
8 parts of powder, heat stabilizer 2 parts, in-lubricant 0.8 part, external lubricant 0.8 part, nanometer silver 0.2 part, Oleum Caryophylli 0.2 part, Portugal
Grape sugar 0.5 part, triethyl phosphate 0.5 part, triethanolamine 0.4 part, ricinoleic acid borate 0.75 part.
Above-mentioned heat stabilizer is organotin, is selected in di-n-butyltin dilaurate, dibutyitin maleate, maleic acid only son
One or two or more kinds in ester dibutyl tin, thiol methyl tin.
PVC floor prepared by the various embodiments described above is white, has bacteriostasis, it is adaptable to house fitting-up.Also simultaneously
Having preferable inking effect, through test, printing-ink preferably can be sprawled in this PVC floor, and color is strong, and coloring is all
Even, significantly improve the ink texture of PVC floor.
In addition to the implementation, present invention additionally comprises other embodiments, all employing equivalents or equivalence to replace
The technical scheme that mode is formed, all should fall within the scope of the hereto appended claims.
Claims (9)
1. the PVC floor that an antibacterial type inking is good, it is characterised in that: it is prepared from by the raw material of following mass parts
Corvic 100 parts,
Plasticizer 0-8 part,
Filler: calcium carbonate 10-15 part, titanium dioxide 8-15 part, Pulvis Talci 5-10 part,
Heat stabilizer 1.5-3 part,
In-lubricant 0.5-1 part,
External lubricant 0.3-1 part,
Nanometer silver 0.05-0.2 part,
Oleum Caryophylli 0.1-0.3 part,
Glucose 0.5-1 part,
Triethyl phosphate 0.5-1 part,
Hygroscopic agent 0.2-0.8 part,
Surface modifier 0.05-1.2 part.
The PVC floor that antibacterial type inking the most according to claim 1 is good, it is characterised in that: described hygroscopic agent is three second
Hydramine.
The PVC floor that antibacterial type inking the most according to claim 1 is good, it is characterised in that: described surface modifier is
Borate ester.
The PVC floor that antibacterial type inking the most according to claim 3 is good, it is characterised in that: described borate ester includes
Castor oil acid triethanolamine borate, ricinoleic acid borate and glycerol triethanolamine borate, two glyceryl borates and
Triethanolamine borate.
The PVC floor that antibacterial type inking the most according to claim 1 is good, it is characterised in that: described plasticizer is adjacent benzene
In dioctyl phthalate dioctyl ester, phthalic acid two (2-propyl group heptan) ester, diisononyl phthalate or polyesters plasticizer one
Kind or two or more combinations.
The PVC floor that antibacterial type inking the most according to claim 1 is good, it is characterised in that: described heat stabilizer includes
Organotin or metal soap complex stabilizer, described metal soap complex stabilizer is barium stearate, zinc stearate, stearic acid
The combination of two or more metals in chromium, calcium stearate.
The PVC floor that antibacterial type inking the most according to claim 6 is good, it is characterised in that: described organotin is February
Cinnamic acid di-n-butyl tin, dibutyitin maleate, butyl maleate dibutyl tin, thiol methyl tin.
The PVC floor that antibacterial type inking the most according to claim 1 is good, it is characterised in that: described in-lubricant is high
Level fatty alcohol, fatty acid ester, external lubricant is higher fatty acids, fatty acid amide, paraffin, Tissuemat E, polysiloxanes.
9. according to the preparation method of the good PVC floor of antibacterial type inking described in any claim in claim 1 to 8, its
It is characterised by: Corvic is preheated to 70～80 DEG C, adds plasticizer, stir 60～120s, add filler, stirring
Uniformly, residue dispensing is added；System is warming up to 100～110 DEG C, speed of agitator is set to 1200～1600 turns/min, instead
More than 6min should be continued；Then 45～50 DEG C it are cooled to, discharging；
Mixed material is transferred to planet extruding machine, planet Extruder temperature 100～150 DEG C are set, proceed to mill afterwards and mix
Refining, through calender roll, rolling temperature is 170～210 DEG C, be cooled to room temperature sizing, then temper softening, temperature 35～
40 DEG C, rolling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610697269.9A CN106317685A (en) | 2016-08-22 | 2016-08-22 | PVC (polyvinyl chloride) floor good in bacteriostatic type inking property and preparation method of PVC floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610697269.9A CN106317685A (en) | 2016-08-22 | 2016-08-22 | PVC (polyvinyl chloride) floor good in bacteriostatic type inking property and preparation method of PVC floor |
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| Publication Number | Publication Date |
|---|---|
| CN106317685A true CN106317685A (en) | 2017-01-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610697269.9A Pending CN106317685A (en) | 2016-08-22 | 2016-08-22 | PVC (polyvinyl chloride) floor good in bacteriostatic type inking property and preparation method of PVC floor |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942207A (en) * | 2010-10-28 | 2011-01-12 | 曾广胜 | Wood powder-polyvinyl chloride compound material and preparation method thereof |
| CN103788542A (en) * | 2014-01-20 | 2014-05-14 | 桐城市诚信木塑科技材料有限公司 | Environment-friendly wood plastic floor and manufacturing method thereof |
| CN103934912A (en) * | 2013-08-30 | 2014-07-23 | 安徽美祥实业有限公司 | Preparation method of PVC flooring having fire retardance, low smoke, low-temperature resistance and cigarette burning resistance |
| CN105037992A (en) * | 2015-05-20 | 2015-11-11 | 中十冶集团环保科技有限公司 | Metal tailing sand lignified sheet material and preparation method thereof |
-
2016
- 2016-08-22 CN CN201610697269.9A patent/CN106317685A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942207A (en) * | 2010-10-28 | 2011-01-12 | 曾广胜 | Wood powder-polyvinyl chloride compound material and preparation method thereof |
| CN103934912A (en) * | 2013-08-30 | 2014-07-23 | 安徽美祥实业有限公司 | Preparation method of PVC flooring having fire retardance, low smoke, low-temperature resistance and cigarette burning resistance |
| CN103788542A (en) * | 2014-01-20 | 2014-05-14 | 桐城市诚信木塑科技材料有限公司 | Environment-friendly wood plastic floor and manufacturing method thereof |
| CN105037992A (en) * | 2015-05-20 | 2015-11-11 | 中十冶集团环保科技有限公司 | Metal tailing sand lignified sheet material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张留成等编: "《高分子材料进展》", 30 June 2005, 北京：化学工业出版社 * |
| 王成涛等编著: "《天然食品配料—生产及应用》", 30 June 2010, 北京：化学工业出版社 * |
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Application publication date: 20170111 |
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