CN106243566A - A kind of color inhibition, PVC floor that inking is good and preparation method thereof - Google Patents

A kind of color inhibition, PVC floor that inking is good and preparation method thereof Download PDF

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Publication number
CN106243566A
CN106243566A CN201610697853.4A CN201610697853A CN106243566A CN 106243566 A CN106243566 A CN 106243566A CN 201610697853 A CN201610697853 A CN 201610697853A CN 106243566 A CN106243566 A CN 106243566A
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CN
China
Prior art keywords
parts
pvc floor
inking
good
color inhibition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610697853.4A
Other languages
Chinese (zh)
Inventor
邬国祥
邬富琴
邬甫荣
邬柯力
芦阳
邬柯洁
刘雪华
徐飞
林道成
邬瑞祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangyin Fuhua Packing Material Co Ltd
Original Assignee
Jiangyin Fuhua Packing Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangyin Fuhua Packing Material Co Ltd filed Critical Jiangyin Fuhua Packing Material Co Ltd
Priority to CN201610697853.4A priority Critical patent/CN106243566A/en
Publication of CN106243566A publication Critical patent/CN106243566A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00—Making preforms
    • B29B11/06—Making preforms by moulding the material
    • B29B11/10—Extrusion moulding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/24—Calendering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/02—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B29C2043/5816—Measuring, controlling or regulating temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B29C71/02—Thermal after-treatment
    • B29C2071/027—Tempering, i.e. heating an object to a high temperature and quenching it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/002—Panels; Plates; Sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Abstract

The present invention relates to a kind of color inhibition, PVC floor that inking is good, being included by raw material (mass parts): Corvic 100 parts, plasticizer 08 parts, filler: calcium carbonate 10 15 parts, titanium dioxide 8 15 parts, Pulvis Talci 5 10 parts, heat stabilizer 1.5 3 parts, lubricant 0.5 2 parts, anti-yellowing agent 0.5 2 parts, glucose 0.5 1 parts, triethyl phosphate 0.5 1 parts, hygroscopic agent 0.2 0.8 parts, surface modifier 0.05 1.2 parts.Wherein surface modifier preferred boric acid esters.The present invention is by improving PVC floor proportioning, making the PVC floor prepared not only have the yellowing-resistant ageing properties of excellence, service life is longer, and has preferable inking effect, improve printing-ink and sprawl effect in PVC floor, make acquisition excellent press pattern present the PVC floor of ability.

Description

A kind of color inhibition, PVC floor that inking is good and preparation method thereof
Technical field
The invention belongs to plastic floor technical field, be specifically related to a kind of color inhibition, PVC floor that inking is good.
Background technology
Plastic floor (PVC floor), is mainly composed of pvc material, and PVC floor can make two kinds, and one is same The saturating heart of matter, it is simply that the decorative pattern material from the end to face is just as.Also having a kind of is combined type, it is simply that topmost one layer is Pure PVC transparent layer, below plus printed layer and foaming layer.PVC floor is enriched due to its pattern, and color is various and is widely used in House and each side of business.
Constantly promote the coloring texture of PVC floor surface detail, improve the ink coloring effect at PVC floor substrate surface It it is one of factor strengthening product competitiveness.Additionally, in order to obtain longer service life, the anti-yellowing property to plastic floor There has also been higher requirement.
Summary of the invention
The technical problem to be solved provides a kind of color inhibition, inking good for above-mentioned prior art PVC floor, by improving the composition proportion of PVC floor, makes PVC floor have preferable inking effect, color presents ability, with Time there is longer service life.
The present invention solves the technical scheme that the problems referred to above are used: a kind of color inhibition, the PVC floor that inking is good, by The raw material of following mass parts is prepared from
Corvic 100 parts,
Plasticizer 0-8 part,
Filler: calcium carbonate 10-15 part, titanium dioxide 8-15 part, Pulvis Talci 5-10 part,
Heat stabilizer 1.5-3 part,
Lubricant 0.5-2 part,
Anti-yellowing agent 0.5-2 part,
Glucose 0.5-1 part,
Triethyl phosphate 0.5-1 part,
Hygroscopic agent 0.2-0.8 part,
Surface modifier 0.05-1.2 part.
Described hygroscopic agent is triethanolamine, improves the PVC floor adsorptivity to printing-ink.Meanwhile, glucose can change The water resistant ability of kind PVC floor surface printing ink.
Described surface modifier is borate ester, including castor oil acid triethanolamine borate, ricinoleic acid boric acid Ester and glycerol triethanolamine borate, two glyceryl borates and triethanolamine borate, first-selected castor oil acid triethanolamine boric acid Ester, ricinoleic acid borate.Oleum Ricini acids borate has bigger molecular volume, and its molecular surface area is less, has Help improve PVC floor surface characteristic, make ink preferably sprawl, improve the inking effect on PVC floor surface, and ink printing The pattern of layer presents ability, makes apparent, texture.
Described plasticizer is that dioctyl phthalate, phthalic acid two (2-propyl group heptan) ester, phthalic acid two are different One or more combination in nonyl ester or polyesters plasticizer.
Described heat stabilizer includes that organotin or metal soap complex stabilizer, described metal soap complex stabilizer are hard The combination of two or more metals in fat acid barium, zinc stearate, chromium stearate, calcium stearate, preferably barium+zinc, barium+zinc+cadmium, calcium+ The combination of zinc.
Described organotin is di-n-butyltin dilaurate, dibutyitin maleate, butyl maleate dibutyl tin, sulfur Alcohol methyl stannum.
Described lubricant is stearic acid, paraffin, Tissuemat E, polysiloxanes.
Described anti-yellowing agent is hexamethyl phosphoric triamide, N-(carboethoxyphenyl-N '-methyl-N '-phenyl formamidine) Mixture with antioxidant.
The color inhibition of the present invention, the preparation method of the PVC floor that inking is good be, Corvic is preheated to 70～ 80 DEG C, add plasticizer, stir 60～120s, add filler, stir, add residue dispensing；System is warming up to 100～110 DEG C, speed of agitator is set and continues more than 6min to 1200～1600 turns/min, reaction；Then 45～50 it are cooled to DEG C, discharging；Mixed material is transferred to planet extruding machine, planet Extruder temperature 100～150 DEG C is set, proceeds to mill afterwards Machine is mixing, rolls through calender, and rolling temperature is 170～210 DEG C, is cooled to room temperature sizing, then temper softening, temperature 35～40 DEG C, rolling.
Compared with prior art, it is an advantage of the current invention that:
Adding the anti-yellowing agent of certain deal in PVC raw material, the jaundice extending PVC floor is aging.
By improving the proportioning of PVC floor, make the PVC floor prepared have preferable inking effect, improve printing-ink PVC floor sprawls effect, makes acquisition excellent press pattern present the PVC floor of ability.Sliding by adjusting in filler The content of stone powder, contributes to improving the lubricity of PVC floor to improve inking；Add triethyl phosphate in the feed, make print Brush ink is sprawled more smooth and easy in PVC floor, and then it is uniform to be easy to inking；It addition, the present invention with the addition of boric acid in the feed Esters, as surface modifier, improves the ink spreading ability in PVC surface, eliminates local inking thickness difference, improves inking Effect.
Invention additionally provides the preparation method of this PVC floor, simplify preparation flow, improve production effect.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
PVC floor, raw material measures in parts by mass and includes: Corvic 100 parts, plasticizer 5 parts, filler: calcium carbonate 10 parts, titanium dioxide 8 parts, Pulvis Talci 10 parts, heat stabilizer 2 parts, lubricant 1 part, anti-yellowing agent 1.2 parts, glucose 0.5 Part, triethyl phosphate 0.5 part, triethanolamine 0.2-0.8 part, castor oil acid triethanolamine borate 0.2 part.
Above-mentioned plasticizer is that dioctyl phthalate, phthalic acid two (2-propyl group heptan) ester arbitrary proportion and 2 parts are big The mixture of Oleum Glycines.
Above-mentioned heat stabilizer is that barium stearate, zinc stearate are by the mixture of 1:1 mass ratio.
Above-mentioned lubricant is one or more the mixing in Tissuemat E, liquid paraffin, stearic acid, fatty acid amide Thing.
Above-mentioned anti-yellowing agent is hexamethyl phosphoric triamide, N-(carboethoxyphenyl-N '-methyl-N '-phenyl formamidine) With antioxidant according to 10:(6-8): the mixture of (10-15).
The preparation method of PVC floor is, Corvic is preheated to 70～80 DEG C, add plasticizer, stirring 60～ 120s, adds filler, stirs, add residue dispensing；System is warming up to 100～110 DEG C, speed of agitator is set extremely 1200～1600 turns/min, reaction continues more than 6min；Then 45～50 DEG C it are cooled to, discharging；Mixed material is transferred to row Star extruding machine, arranges planet Extruder temperature 100～150 DEG C, proceeds to mill mixing afterwards, rolls through calender, calendering temperature Degree is 170～210 DEG C, is cooled to room temperature sizing, then temper softening, temperature 35～40 DEG C, rolling.
Embodiment 2
The raw material of preparing of PVC floor with the main distinction of embodiment 1, the PVC floor in the present embodiment prepare raw material by matter Amount part metering includes: Corvic 100 parts, plasticizer 6 parts, filler: calcium carbonate 10 parts, titanium dioxide 10 parts, cunning Stone powder 5 parts, heat stabilizer 1.5 parts, lubricant 1.3 parts, anti-yellowing agent 1 part, glucose 0.5 part, triethyl phosphate 0.5 Part, triethanolamine 0.4 part, triethanolamine borate 0.05 part.
Above-mentioned plasticizer is CPE.
Above-mentioned heat stabilizer is that barium stearate, zinc stearate, chromium stearate are by the mixture of 1:1:0.5 mass ratio.
Above-mentioned lubricant is Tissuemat E, the mixture of stearic acid arbitrary proportion.
Embodiment 3
The raw material of preparing of PVC floor with the main distinction of embodiment 1, the PVC floor in the present embodiment prepare raw material by matter Amount part metering includes: Corvic 100 parts, plasticizer 6 parts, filler: calcium carbonate 12 parts, titanium dioxide 8 parts, Talcum 8 parts of powder, heat stabilizer 2 parts, lubricant 1.6 parts, anti-yellowing agent 1.5 parts, glucose 0.5 part, triethyl phosphate 0.5 part, Triethanolamine 0.4 part, 0.5 part of the mixture of ricinoleic acid borate and glycerol triethanolamine borate.
Above-mentioned heat stabilizer is that calcium stearate, zinc stearate are by the mixture of any mass ratio.
Above-mentioned lubricant is liquid paraffin.
Embodiment 4
The raw material of preparing of PVC floor with the main distinction of embodiment 1, the PVC floor in the present embodiment prepare raw material by matter Amount part metering includes: Corvic 100 parts, plasticizer 6 parts, filler: calcium carbonate 12 parts, titanium dioxide 8 parts, Talcum 8 parts of powder, heat stabilizer 2 parts, lubricant 2 parts, anti-yellowing agent 0.8 part, glucose 0.5 part, triethyl phosphate 0.5 part, three Ethanolamine 0.4 part, ricinoleic acid borate 0.75 part.
Above-mentioned heat stabilizer is organotin, is selected in di-n-butyltin dilaurate, dibutyitin maleate, maleic acid only son One or two or more kinds in ester dibutyl tin, thiol methyl tin.
PVC floor prepared by the various embodiments described above is white, and color inhibition is aging, and service life is long, and inking is effective, warp Test, printing-ink preferably can be sprawled in this PVC floor, and color is strong bright-coloured, uniform coloring, significantly improves PVC The ink texture on floor.
In addition to the implementation, present invention additionally comprises other embodiments, all employing equivalents or equivalence to replace The technical scheme that mode is formed, all should fall within the scope of the hereto appended claims.

Claims (10)

1. a color inhibition, PVC floor that inking is good, it is characterised in that: it is prepared from by the raw material of following mass parts
Corvic 100 parts,
Plasticizer 0-8 part,
Filler: calcium carbonate 10-15 part, titanium dioxide 8-15 part, Pulvis Talci 5-10 part,
Heat stabilizer 1.5-3 part,
Lubricant 0.5-2 part,
Anti-yellowing agent 0.5-2 part,
Glucose 0.5-1 part,
Triethyl phosphate 0.5-1 part,
Hygroscopic agent 0.2-0.8 part,
Surface modifier 0.05-1.2 part.
Color inhibition the most according to claim 1, the PVC floor that inking is good, it is characterised in that: described hygroscopic agent is three second Hydramine.
Color inhibition the most according to claim 1, the PVC floor that inking is good, it is characterised in that: described surface modifier is Borate ester.
Color inhibition the most according to claim 3, the PVC floor that inking is good, it is characterised in that: described borate ester includes Castor oil acid triethanolamine borate, ricinoleic acid borate and glycerol triethanolamine borate, two glyceryl borates and Triethanolamine borate.
Color inhibition the most according to claim 1, the PVC floor that inking is good, it is characterised in that: described plasticizer is adjacent benzene In dioctyl phthalate dioctyl ester, phthalic acid two (2-propyl group heptan) ester, diisononyl phthalate or polyesters plasticizer one Kind or two or more combinations.
Color inhibition the most according to claim 1, the PVC floor that inking is good, it is characterised in that: described heat stabilizer includes Organotin or metal soap complex stabilizer, described metal soap complex stabilizer is barium stearate, zinc stearate, stearic acid The combination of two or more metals in chromium, calcium stearate.
Color inhibition the most according to claim 6, the PVC floor that inking is good, it is characterised in that: described organotin is February Cinnamic acid di-n-butyl tin, dibutyitin maleate, butyl maleate dibutyl tin, thiol methyl tin.
Color inhibition the most according to claim 1, the PVC floor that inking is good, it is characterised in that: described lubricant is stearic Acid, paraffin, Tissuemat E, polysiloxanes.
Color inhibition the most according to claim 1, the PVC floor that inking is good, it is characterised in that: described anti-yellowing agent is six Methyl acid phosphate Disnalon (Ferrer)., N-(carboethoxyphenyl-N '-methyl-N '-phenyl formamidine) and the mixture of antioxidant.
10. according to color inhibition described in any claim in claim 1 to 9, the preparation method of PVC floor that inking is good, It is characterized in that: Corvic is preheated to 70～80 DEG C, add plasticizer, stir 60～120s, add filler, stir Mix uniformly, add residue dispensing；System is warming up to 100～110 DEG C, speed of agitator is set to 1200～1600 turns/min, Reaction continues more than 6min；Then 45～50 DEG C it are cooled to, discharging；
Mixed material is transferred to planet extruding machine, planet Extruder temperature 100～150 DEG C are set, proceed to mill afterwards and mix Refining, through calender roll, rolling temperature is 170～210 DEG C, be cooled to room temperature sizing, then temper softening, temperature 35～ 40 DEG C, rolling.
CN201610697853.4A 2016-08-22 2016-08-22 A kind of color inhibition, PVC floor that inking is good and preparation method thereof Pending CN106243566A (en)

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CN201610697853.4A CN106243566A (en) 2016-08-22 2016-08-22 A kind of color inhibition, PVC floor that inking is good and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610697853.4A CN106243566A (en) 2016-08-22 2016-08-22 A kind of color inhibition, PVC floor that inking is good and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163431A (en) * 2017-05-26 2017-09-15 东台市荣达塑业有限公司 A kind of PVC formulas for strengthening erosion-resisting characteristics
CN109021451A (en) * 2018-07-21 2018-12-18 东营大明新型建材有限责任公司 PVC organic matter stabilizer Profile Formulation and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942207A (en) * 2010-10-28 2011-01-12 曾广胜 Wood powder-polyvinyl chloride compound material and preparation method thereof
CN103788542A (en) * 2014-01-20 2014-05-14 桐城市诚信木塑科技材料有限公司 Environment-friendly wood plastic floor and manufacturing method thereof
CN103934912A (en) * 2013-08-30 2014-07-23 安徽美祥实业有限公司 Preparation method of PVC flooring having fire retardance, low smoke, low-temperature resistance and cigarette burning resistance
CN105037992A (en) * 2015-05-20 2015-11-11 中十冶集团环保科技有限公司 Metal tailing sand lignified sheet material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942207A (en) * 2010-10-28 2011-01-12 曾广胜 Wood powder-polyvinyl chloride compound material and preparation method thereof
CN103934912A (en) * 2013-08-30 2014-07-23 安徽美祥实业有限公司 Preparation method of PVC flooring having fire retardance, low smoke, low-temperature resistance and cigarette burning resistance
CN103788542A (en) * 2014-01-20 2014-05-14 桐城市诚信木塑科技材料有限公司 Environment-friendly wood plastic floor and manufacturing method thereof
CN105037992A (en) * 2015-05-20 2015-11-11 中十冶集团环保科技有限公司 Metal tailing sand lignified sheet material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163431A (en) * 2017-05-26 2017-09-15 东台市荣达塑业有限公司 A kind of PVC formulas for strengthening erosion-resisting characteristics
CN109021451A (en) * 2018-07-21 2018-12-18 东营大明新型建材有限责任公司 PVC organic matter stabilizer Profile Formulation and preparation method thereof

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